GB2527731A - Glazing spacer bar - Google Patents

Glazing spacer bar Download PDF

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Publication number
GB2527731A
GB2527731A GB1406512.2A GB201406512A GB2527731A GB 2527731 A GB2527731 A GB 2527731A GB 201406512 A GB201406512 A GB 201406512A GB 2527731 A GB2527731 A GB 2527731A
Authority
GB
United Kingdom
Prior art keywords
spacer bar
desiccant
range
spacer
bar body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB1406512.2A
Other versions
GB201406512D0 (en
Inventor
Gwain Paterson
Rohit Kale
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
THERMOSEAL GROUP Ltd
Original Assignee
THERMOSEAL GROUP Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by THERMOSEAL GROUP Ltd filed Critical THERMOSEAL GROUP Ltd
Priority to GB1406512.2A priority Critical patent/GB2527731A/en
Publication of GB201406512D0 publication Critical patent/GB201406512D0/en
Priority to EP15163073.8A priority patent/EP2930296A1/en
Publication of GB2527731A publication Critical patent/GB2527731A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663Elements for spacing panes
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663Elements for spacing panes
    • E06B3/66309Section members positioned at the edges of the glazing unit
    • E06B3/66314Section members positioned at the edges of the glazing unit of tubular shape
    • E06B3/66319Section members positioned at the edges of the glazing unit of tubular shape of rubber, plastics or similar materials
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663Elements for spacing panes
    • E06B3/66309Section members positioned at the edges of the glazing unit
    • E06B3/66361Section members positioned at the edges of the glazing unit with special structural provisions for holding drying agents, e.g. packed in special containers

Landscapes

  • Engineering & Computer Science (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Architecture (AREA)
  • Securing Of Glass Panes Or The Like (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

A glazing spacer bar 1 for separating glazing panes 8a, 8b in multiple glazed window units. The spacer bar is formed from a thermoplastic polymer and a blowing/foaming agent and has one or more cavities 2. The spacer bar may be hollow or porous and comprises a desiccant 12 in the form of a powder such as silica gel or desiccant beads. The spacer bar may comprise reinforcing material (5 figure 4) such as glass fibres, glass beads, glass bubbles, polymer fibres, ceramic fibres and or natural fibres. The spacer bar may comprise a UV stabilizer and be backed by a moisture vapour and or gas barrier such as metalized polymeric, polyester, multilayered polyethylene or a metalized polyester film/tape. The spacer bar body cross section may be continuous or have apertures 3 around its perimeter to allow the desiccant to absorb moisture inside the glazing unit. A later embodiment also relates to a method of manufacturing the spacer bar and its use in multiple pane glazing units.

Description

GLAZING SPACER BAR
This invention relates to a novel spacer for use in a sealed multiple glazed unit, particularly a doubk glazed unit.
Although the invention will be described in terms of a double glazed unit, it could also be used for multiple glazed ILnits e.g. triple glazed ILnits.
Known double glazed units typically consist of two glazing panes. usually of glass, which are sealed to and separated by a self-supporting spacer, usually of bar of metal or a plastics extrusion, around the outer edges of the glazing panes. The spacer bar may be hollow and may be formed into any shape by bending and/or by joining (e.g. using corner keys) as is well known in the industry. The spacer bar is sandwiched and sealed between the two glazing panes to form a unit, defining a cavity (interspace) between the glazing panes. The sealing against the glazing panes may be by way of a sealant and/or adhesive e.g. butyl rubber, pohzsuphide or poyuretliane. again as is known in the industry. In order to improve the heat insulation performance of the glazed unit, it is desirable although not essential to introduce an inert gas such as argon and/or xenon or similar gas into the cavity, in which case if the spacer bar is not constructed of 100% metal it is usual to have a composite hollow spacer bar with a gas barrier of metal tape (e.g. of steel or aluminium) around its outer edge i.e. facing away from the cavity (interspace). However the prcscnt invention provides for grcatcr heat insulation still. In addition, a thermoplastic spacer bar eliminates the problem of static electricity build-tip. This probkm is weH known in the industry. When a conventional metal spacer bar is substituted for an energy efficient polymer spacer bar, there is static electricity build-up because of the non-metallic spacer bar material. The static build-up may reduce moisture absorption capacity of the scaled unit, the said spacer system provides solution to this problem.
The present invention rdates to a spacer bar for a multiple glazed unit in which the spacer bar has a body having one or more cavities, wherein the body comprises a thermoplastic polymer and a blowing/foaming agent.
In one embodiment, the spacer bar body is hollow.
Presence of a foamed structure in the spacer bar body reduces the thermal conductivity of the spacer bar, The reduction in therma' conductivity can be significant, for example up to 40% when compared with a non-foamed spacer bar, S The spacer bar body may be porous.
The spacer bar body may be formed of a thermoplastic polymer comprising polypropylene (PP), polyethylene (PB). polycarbonate (PC). polvamidc (PA) commonly known as Nylon, polyvinyl chloride (PVC). p&ystyrene (PS) and or styrenic polymers and co-polymers, or any combination thereof In one embodiment thc thermoplastic polymer comprises or is polypropylene (PP).
The Mowing/foaming agent may be endothermic or exothermic, Thc blowing/foaming agent may comprise 4. 4'-Oxybis-bcnzencsulfonylhydrazidc (OBSH), azodicarbonaniide (ADA). bicarbonates or biurets.
In one embodiment, the spacer bar body may comprise a desiccant, The desiccant may be in the form of a powder. The desiccant may comprise an aluminosilicate, silica geL calcium su'phate, a montmoriflonite clay, calcium chloride, molecular sieve dcsiccants. activated charcoal or combinations thereof The desiccant may be a or 4A desiccant, Presence of a desiccant in the spacer bar body aids in absorbing moisture inside a glazing unit when the spacer bar is in usc in a glazing unit and increases the lifetime of the product. The presence of desiccant in the spacer bar body may also save time and energy of a sealed unit manufacturer by reducing the amount of desiccant which may need to be inserted into any cavity within the spacer bar.
One or more of the cavities of the spacer bar body may contain desiccant. The desiccant may be 3A or 4A desiccant beads.
In one embodiment, the spacer bar body further comprises a reinforcing material. The reinforcing material may be ally suitable material, for example chopped g'ass fibres, milled glass fibres, glass beads, glass bubbles, polymer fibres, ceramic fibres and natural fibres or any combination thereof, The proportion of reinforcing material S within the spacer bar body may be in a range from S to 50% by weight or more preferably from 25 to 50% by weight. Reinforcing material is addcd to improve the mechanical strength/stiffness, dimensional stability and thermal resistance.
In one embodiment, the spacer bar body may further comprise a coupling agent in combination with the reinforcing material. The coupling agent may be polypropylene functionalised with maleic anhydride or SCONA TPPP 9112, The spacer bar body may further comprise one or more pigment masterbatches. Each pigment masterbatch may comprise polypropylene (PP), polyethylene (PE), polyamide (PA), ethylene vinyl acetate, ethylene copolymers or other polymer and or copolymers.
The ability to include a pigment masterbatch allows sealed unit manufacturers to match the colour of the spacer bar to the glazing system.
The spacer bar body may comprise a UV stabibser, The UV stabfliser may be Tinuvin 213. Presence of UV stabiliser eliminates the problem of Li V/thermal degradation and or cracking as well as colour change during the work life.
The spacer bar body may comprise a thermoplastic polymer content in range of 10 to 80%, a reinforcing filler content in range of S to 60%, a moisture absorbing desiccant powder in range of 10 to 70%, a foaming agent in range of 0.1 to 7%. a UV stabiliser in range of 0.1 to 5%, an anti-static agent/additive in range of 0.1 to 5%, a coupling agent in range of 0,1 to 3% and a pigment masterbatch in range of 0.1 to 10%.
The spacer bar body of the present invention may be backed or coated with a moisture, moisture vapour and/or gas barrier. The moisture, moisture vapour and/or gas barrier may be metalized polymeric, poh'ester, muftdayered polyethvene or a nietalhsed polyester film/tape. The barrier may be a fUm/tape with a thickness that is in the range of ito 1000 microns.
The spacer bar may be vacuum sealed in a suitable metahzed polymeric packaging and boxed for storage.
S The spacer bar body may be elongate. The spacer bar body may be self-supporting.
The spacer bar body may have a thermal conductivity iii the range of 0.11 to 0.18, preferably in a range of 0.12 to 0.16 W/(m.K).
The spacer bar body may have a continuous cross section. The cross section of the spacer bar body may alternatively be provided with apertures and/or breaks around or in its perimeter, which may extend along all or part of its length.
The spacer bar body may comprise any of the following three compositions: Example composition I: 1. Polypropylene -39.5 % 2. Glass fibres -20% 3. 3A desiccant powder -30% 4, Blowing agent -0.5 % S. UV stabiliser -1.5 % 6. Anti-static agent -1.7 % 7. Coupling agent -0.8 % 8. Pigment masterbatch -6 % Example composition 2: 1, Polypropylene -46 % 2, Mifled glass fibres -12% 3, Hollow g'ass bubbles -12% 4, 3A desiccant powder -20% 5. Blowing agent -4 % 6, UV stabiliser -I 7, Anti-static agent -0.6% 8, Coupling agent -1,4 % 9. Pigment mnasterbatch -3 % Example composition 3: 1. Polypropylene -39.3 % 2, Mifled glass fibres -18 % 3. Solid glass beads -8 % 4, 3A desiccant powder -26% 5, Blowing agent -2.7 % 6. UV stabiliser -0.5 % 7, Anti-static agent -0,7% 8, Coupling agent -0,8 % 9, Pigment masterbatch -4 % Another aspect of the present invention relates to a method of manufacture of a spacer bar of the present invention. wherein thermoplastic polymer is foamed and extruded to IS form a spacer bar body. This method may comprise compounding/blending the thermoplastic polymer, and extruding the thermoplastic polymer, wherein, a foaming/blowing agent is introduced to the thermoplastic polymer during the polymer compounding/blending process or during a profilc extrusion process.
Another aspect of the present invention rdates to a method of assembling a spacer bar of the present invention into a pre-determined shape for making a sealed unit, for example a rectangular, square or other shape, wherein the method comprises heat welding, blending and/or by using corner keys.
An additional aspect of the present invention relates to a method of manufacturing a multiple glazed unit from a spacer bar of the present invention, wherein the spacer bar is fitted between two glazing panes spaced apart to form a cavity.
Another aspect of the present invention relates to the use of the spacer bar of the present invention in the construction of an insu'ating g'ass unit consisting of two or more parallel sheets/panes of glass or polymer.
Embodiments of the invention will now be described by way of example only and with reference to the figures in which like parts are referred to by use of the same reference number and in which: Figure I shows a cross section through a spacer bar of a first embodiment of the present invention; S Figure 2 shows a cross section through a spacer bar of a second embodiment of the present invention; Figure 3 shows a cross section through a spacer bar of a third embodiment of the present invention; Figure 4 shows a cross section through a spacer bar of a fourth embodiment of the present invention; and Figure 5 shows a cross section through a spacer bar of an embodiment of the present invention in position in a multiple glazed unit.
Figure 1 shows a cross section through a spacer bar of a first embodiment of the present invention. In this embodiment the spacer bar body 1 has been formed from polypropylene, a thermoplastic polymer, which has been foamed during manufacture of the spacer bar body 1 using, azodicarbonamidc. a foaming/blowing agent, though other foaming/blowing agents may be used, Presence of a foamed structure in spacer bar body 1 may reduce the thermal conductivity up to 40% when compared with a non-foamed spacer bar body. The spacer bar includes a cavity 2 formed within the body I which can be filled with a desiccant, The spacer bar body I has perforations or a series of apertures 3 to allow desiccant within the cavity 2 to absorb moisture inside a glazing unit when the spacer bar is in use in a glazing unit, Figure 2 shows a cross section through a spacer bar of a second embodiment of the present invention, In this embodiment the spacer bar body I possesses all of the properties of the spacer bar body I of figure I, Also in this spacer bar body I is a desiccant 4, in this instance calcium sulphate though other desiccants may be used, which aids in absorbing moisture inside a glazing unit when the spacer bar is in usc in a glazing unit and increases the lifetime of the product. Desiccant 4 in the spacer bar body I may also save time and energy of a sealed unit manufacturer by reducing the amount of desiccant which may need to be inserted into the cavity 2, The manufacturer may not be required to fill the spacer bar cavity 2 with desiccant as the spacer bar body I of present invention can absorb the moisture inside a glazing unit when the spacer bar is in use in a glazing unit, due to presence of desiccant 4 within the spacer bar body I. Figure 3 shows a cross scction through a spacer bar of a third embodiment of the present invention. In this embodiment the spacer bar body 1 possesses all of the properties of the spacer bar body 1 of figlLre 1. Also in this spacer bar body 1 is a reinforcing material 5. In this instance the reinforcing material is chopped glass fibres, though other reinforcing materials may be used. Reinforcing material 5 is added to improve the mechanical strength/stiffness, dimensional stability and thermal resistance.
Figure 4 shows a cross section through a spacer bar of a fourth embodiment of the present invention. In this embodiment the spacer bar body 1 is as described in figure 2 and in addition contains a reinforcing material S. In this instance the reinforcing materi& is chopped glass fibres, though other reinforcing materials may be used.
Reinforcing material 5 is added to improve the mechanical strength/stiffness, dimensional stability and thermal resistance.
Figure 5 shows a cross section through a length of spacer bar in accordance the second embodiment of the present invention in position in a multiple glazed unit. The spacer bar comprises a cavity 2 formed within the body 1. The spacer bar body 1 is elongate and of a generafly "if' cross section and has first and second long side waDs I Ia. Jib and first and second short side walls 7a, 7b giving risc to the width and depth of the spacer bar 1 respectively.
The spacer bar contains desiccant 12 within the cavity 2. The spacer bar is in use in a standard double glazed or mu'tiple glazed unit as shown in Figure 9 wherein the glazing panes 8a, 8b are made of glass or polymeric material and/or any other transparent, translucent or opaque material, the cavity 6 between the glazing unit is scaled by using hot melt or warm melt scalants 10. A primary sealant such as layer/bead of polyisobutylene also can be applied on the sides 7a. 7b of the spacer bar I adjacent to glazing panes Sa, b, In order to improve the thermal insulation performance of glazing unit an inert gas such as argon/krypton/xenon may be introduced into the cavity 6 between the panes Sa, Sb.
The cavity 2 within the spacer bar body I contains Grace Davidson Sylosiv K 360 moisture adsorbing ik desiccant beads/granules 12, inserted in a conventional manner. The spacer bar 1 has perforations or series of apertures 3 extending through to the cavity 2 and positioned on long side 1 la to allow desiccant 12 to adsorb moisture inside a glazing unit. The long side 1 la bearing the apertures 3, is positioned to face into the cavity 6 between the g'azing panes 8a, Sb while in use, In this embodiment, the desiccant 12 fills the entire cavity 2 though it may fill only a portion of the cavity in other embodiments.
Whilst the embodiment of figure 2 is shown, any of the embodiments described could be used in the unit of Figure 5.

Claims (4)

  1. Claims 1. A spacer bar for a multiple glazed unit in which the spacer bar has a body having one or more cavities, wherein the body comprises a thermoplastic S polymer and a b'owing/foaming agent.
  2. 2. The spacer bar of claim 1. wherein the bar body is hollow.
  3. 3. The spacer bar of daims I or 2, wherein the spacer bar body is porous.
  4. 4. Thc spaccr bar of any preceding claim, wherein the thermoplastic polymer comprises polypropylene (PP). polyethylene (PE), polycarbonate (PC), polvamide (PA) commonly known as Nylon, polyvinyl ch'oride (PVC) polystyrene (PS) and/or styrenic polymers and co-polymers, or any combination thcrcof.S. The spacer bar of any preceding claim, wherein the b'owing/foaming agent is endothermic or exothermic, 6. Thc spacer bar of any preceding claim, wherein the blowing/foaming agent comprises 4, 4'-Oxybis-benzenesuffonylliydrazide (OBSH), azodicarbonamide (ADA), bicarbonates or biurets.7. The spacer bar of any preceding claim, wherein the spacer bar body comprises a desiccant.8. The spacer bar of claim 7, wherein the desiccant is in the form of a powder.9. The spacer bar of any of claim 7 or 8, wherein the desiccant comprises an duminosihcate, silica gel, calcium sulphate, a montmorillonite day, cakium chloride, molecular sieve desiccants, activated charcoal or a combination thereof.10. The spacer bar of any of claims 7 to 9, wherein the desiccant is a 3A or 4A desiccant.I. The spacer bar of any preceding claim, wherein one or more of the cavities contain desiccant.12. The spacer bar of any of claim I I, wherein the desiccant is 3A or 4A desiccant beads.13. The spacer bar of any preceding claim, wherein the spacer bar body further comprises a reinforcing material.14. The spacer bar of claim 13, wherein the reinforcing material is chopped glass fibres, milled glass fibres, glass beads, glass bubbles, polymer fibres, ceramic fibres and natura' fibres or any combination thereof.15. The spacer bar of claims 13 or 14, wherein the proportion of reinforcing material within the spacer bar body is in the range from S to 50% by weight.16. The spacer bar of any of claims 13 to 15. wherein the proportion of reinforcing material within the spacer bar body is in thc range from 25 to 50% by weight.17. The spacer bar of any of claims 13 to 16. wherein the spacer bar body further comprises a coupling agent in combination with the reinforcing material.18. The spacer bar of claim 17, wherein the coupling agent is (i) polypropylene functionalised with maleic anhydride or (ii) SCONA TPPP 9112.19. The spacer bar of any preceding claim, wherein the spacer bar body further comprises one or more pigment masterbatches.20. The spacer bar of claim 19, wherein the pigment masterbatches comprise polypropylene (PP), polyethykne (PE). polyamide (PA), ethylene vinyl acetate, ethylene copolymers or other polymer and or copolymers, 2!. The spacer bar of ally preceding claim, wherein tile spacer bar body comprises a UV stabiliser, 22. The spacer bar of c'aim 21, wherein the UV stabiiiser is Tinuvin 213.23. The spacer bar of claim 1, wherein the spacer bar body comprises a thermoplastic polymer content in range of 10 to 80%. a reinforcing filler content in range of 5 to 60%, a moisture absorbing desiccant powder in range of 10 to 70%. a foaming agent in range of 0.1 to 7%. a IJV stabiliser in range of 0,1 to 5%. an anti-static agent/additive in range of 0.1 to 5%. a coupling agent in range of 0.1 to 3% and. a pigment masterbatch in range of 0.1 to 10%.24. The spacer bar of any preceding claim. whercin the spacer bar body is backed with a moisture, moisture vapour and/or gas barrier.25. The spacer bar of claim 24, wherein the moisture, moisture vapour and gas barrier is metalized polymeric, polyester, multilayered polyethylene or a metallised polyester film/tape.26. The spacer bar of claim 24 or 25. wherein the barrier is a tape with a thickness that is in the range of 1 to 1000 microns.27. The spacer bar of any preceding claim, wherein the spacer bar is vacuum sealed in a suitable metalized polymeric packaging and boxed for storage, 28. The spacer bar of any preceding claim, wherein the spacer bar body is dongate.29. The spacer bar of any preceding claim, wherein the spacer bar body is self-supporting.30. The spacer bar of any preceding c'aim, wherein the spacer bar body has a thermal conductivity in the range of 0.11 to 0,18 W/(m,K), 3!. The spacer bar of any preceding dairn, wherein the spacer bar body has a thermal conductivity in the range of 0.12 to 0.16 W/(m,K), 32. The spacer bar of any preceding c!aim, wherein the cross section of the spacer bar body is continuous.33. The spacer bar of any of claims 1 to 31, wherein the cross section of the spacer bar body is provided with apertures and/or breaks around or in its perimeter, which may extend along all or part of its length.34. A method of manufacture of a spacer bar of any preceding claim, wherein thermop'astic p&ymer is foamed and extruded to form a spacer bar body.35. The method of claim 34, wherein the manufacturing of the spacer bar comprises compounding/blending the thermop'astic po!vmer, and extruding the thermoplastic po!ymer, wherein, a foaming/b'owing agent is introduced to the thermoplastic polymer during the polymer compounding/blending process or during a profile extrusion process.36. A method of assembhng a spacer bar of any of c!ainis! to 33 into a pre-determined shape for making a sealed unit, for example a rectangular, square or other shape, wherein the method comprises heat welding, blending and/or by using corner keys.37. A method of manufacturing a multiple pane glazing unit from a spacer bar of any of claims 1 to 33, wherein the spacer bar is fitted between two glazing panes spaced apart to form a cavity.38. Use of the spacer bar of any of c!aims I to 33 in the construction of an insulating glass unit consisting of two or more parallel sheets/panes of glass or polymer.39. A spacer bar for use in sealed mu!tip!e g'azed units as described herein or with reference to the drawings and examples.
GB1406512.2A 2014-04-10 2014-04-10 Glazing spacer bar Withdrawn GB2527731A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB1406512.2A GB2527731A (en) 2014-04-10 2014-04-10 Glazing spacer bar
EP15163073.8A EP2930296A1 (en) 2014-04-10 2015-04-09 Glazing spacer bar

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1406512.2A GB2527731A (en) 2014-04-10 2014-04-10 Glazing spacer bar

Publications (2)

Publication Number Publication Date
GB201406512D0 GB201406512D0 (en) 2014-05-28
GB2527731A true GB2527731A (en) 2016-01-06

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Family Applications (1)

Application Number Title Priority Date Filing Date
GB1406512.2A Withdrawn GB2527731A (en) 2014-04-10 2014-04-10 Glazing spacer bar

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GB (1) GB2527731A (en)

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DE3312205A1 (en) 1982-04-03 1983-10-20 Sumitomo Electric Industries, Ltd., Osaka BORED STEEL AND METHOD FOR THE PRODUCTION THEREOF
CN107286365A (en) * 2017-06-06 2017-10-24 滁州市宏源喷涂有限公司 A kind of preparation method of intercalation modifying organo montmorillonite composite foamable agent for polyvinyl chloride
US20190257139A1 (en) * 2016-10-18 2019-08-22 P.E.T. Polymer Extrusion Technology, Inc. Method and system for manufacturing a spacer for translucent panels

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KR102195198B1 (en) * 2015-03-02 2020-12-28 쌩-고벵 글래스 프랑스 Glass fiber-reinforced spacer for insulating glazing
CN108366681A (en) 2015-12-21 2018-08-03 法国圣戈班玻璃厂 Isolation glass element for refrigerator tool
DE102015122714A1 (en) 2015-12-23 2017-07-27 Ensinger Gmbh Spacers for insulating glass panes
DE102016115023A1 (en) 2015-12-23 2017-06-29 Ensinger Gmbh Spacers for insulating glass panes
PT3440299T (en) * 2016-04-05 2021-06-16 Saint Gobain Insulating glass unit for a refrigeration unit
WO2018068899A1 (en) 2016-10-11 2018-04-19 Saint-Gobain Glass France Spacer for insulating glazing units
CN106832685A (en) * 2017-03-21 2017-06-13 南京南油节能科技有限公司 For the profiled spacer for preparing the polychloroethylene composition of profiled spacer and its obtain
CN108410165B (en) * 2018-02-12 2021-01-26 广东新会美达锦纶股份有限公司 Preparation method of color master batch for high-color-fastness low-melting-point polyamide
CN108384225B (en) * 2018-02-12 2021-01-26 广东新会美达锦纶股份有限公司 Color master batch for high-color-fastness low-melting-point polyamide
CN109971074B (en) * 2019-04-17 2022-03-25 余姚中国塑料城塑料研究院 Multilayer co-extrusion composite hollow glass warm edge spacing bar and preparation method thereof
US20230184029A1 (en) * 2020-05-06 2023-06-15 Saint-Gobain Glass France Spacer for insulated glazing
WO2022179965A1 (en) 2021-02-25 2022-09-01 Saint-Gobain Glass France Cold-bendable spacer having improved stiffness
CN113003952A (en) * 2021-03-18 2021-06-22 温州前瞻玻璃科技有限公司 Hollow glass and manufacturing method thereof
WO2023030813A1 (en) 2021-08-31 2023-03-09 Saint-Gobain Glass France Cold-bendable spacer having improved rigidity
CA3240032A1 (en) 2022-04-14 2023-10-19 Nikolai BORCHMANN Spacer with improved mechanical stiffness

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DE19807454A1 (en) * 1998-02-21 1999-08-26 Ensinger Plastics spacer for insulating glass panels
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WO2013117933A2 (en) * 2012-02-09 2013-08-15 Thermoseal Group Limited Spacer for use in a sealed multiple glazed unit
CN103867077A (en) * 2014-03-25 2014-06-18 大连工业大学 Warm edge spacer bar based on ethylene-EVA and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3312205A1 (en) 1982-04-03 1983-10-20 Sumitomo Electric Industries, Ltd., Osaka BORED STEEL AND METHOD FOR THE PRODUCTION THEREOF
US20190257139A1 (en) * 2016-10-18 2019-08-22 P.E.T. Polymer Extrusion Technology, Inc. Method and system for manufacturing a spacer for translucent panels
CN107286365A (en) * 2017-06-06 2017-10-24 滁州市宏源喷涂有限公司 A kind of preparation method of intercalation modifying organo montmorillonite composite foamable agent for polyvinyl chloride

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