GB2492808A - High speed composite manufacture - Google Patents

High speed composite manufacture Download PDF

Info

Publication number
GB2492808A
GB2492808A GB1112004.5A GB201112004A GB2492808A GB 2492808 A GB2492808 A GB 2492808A GB 201112004 A GB201112004 A GB 201112004A GB 2492808 A GB2492808 A GB 2492808A
Authority
GB
United Kingdom
Prior art keywords
component
pressure
cure
mould
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB1112004.5A
Other versions
GB201112004D0 (en
GB2492808B (en
Inventor
David Skertchly
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Global Composites Group Ltd
Original Assignee
Global Composites Group Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Global Composites Group Ltd filed Critical Global Composites Group Ltd
Priority to GB1112004.5A priority Critical patent/GB2492808B/en
Publication of GB201112004D0 publication Critical patent/GB201112004D0/en
Publication of GB2492808A publication Critical patent/GB2492808A/en
Application granted granted Critical
Publication of GB2492808B publication Critical patent/GB2492808B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/003Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/04Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/08Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
    • B29K2105/0872Prepregs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2307/00Use of elements other than metals as reinforcement
    • B29K2307/04Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2863/00Use of EP, i.e. epoxy resins or derivatives thereof as mould material

Abstract

A method of fabricating a composite component comprising positioning the uncured composite component between two mould parts, heating the component to a temperature in the range of 150-250°C and applying a pressure in excess of 5MPa to the component; wherein the pressure is increased over a period of 200-450ms. The pressure and temperature may be maintained for about 1minute ±30seconds to wholly cure the component. The high pressure and rapid application of pressure induces a high rate of cure without degrading the material. The method is particularly suitable for the short cycle time required by the automotive industry.

Description

HIGH SPEED COMPOSITE MANUFACTURE
Background
The current invention relates to the manufacture of composite materials and in particular manufacturing processes to improve the speed of manufacture.
Composite materials are formed of a thermosetting matrix material reinforced with fibres. For example, a thermosetting polymer matrix may be reinforced with carbon fibres. Composite materials are utilised extensively for the manufacture of high-performance components, for example in the aircraft industry, due to their strength and weight properties.
Composite components are manufactured by curing the matrix material, typically a thermosetting plastic, comprising the reinforcing fibres at elevated temperatures and pressures. For example, typical temperatures are in the region of 80 to 180°C and pressures are in the region of O.2J6MPa to O.55MPa. The cure time required is typically 15 to 180 minutes.
Manufacture times of 15 to 180 minutes are incompatible with the high production rates of the mass-market automotive industry which requires components to have a manufacture time of the order of 1 minute. This incompatibility has prevented composite materials being widely utilised in automotive manufacture. Increased temperatures may provide a faster cure of the component, but the higher temperature leads to degradation of the matrix material properties. It is common to include a proportion of thermoplastic material in the matrix to act as a toughening agent. A particular problem occurs with such matrices when they are cured using conventional processes but at higher temperatures as phase inversion occurs between the thermosetting and thermoplastic components.
A process to increase the speed of production of composite components, with acceptable degradation of the material, may enable the use of composite materials in the automotive industry.
Summary
Aspects of the invention are set out in the claims.
Description of the drawings
Embodiments of the present invention will now be further described, by way of example, with reference to the drawings, wherein:-Figure 1 shows an apparatus for forming composite components; and Figure 2 shows a flow chart of a process for forming composite components.
Detailed description
The detailed description provided below in connection with the appended drawings is intended as a description of the present examples and is not intended to represent the only forms in which the present example may be constructed or utilized. The description sets forth the functions of the example and the sequence of steps for constructing and operating the example.
However, the same or equivalent functions and sequences may be accomplished by different examples.
Figure 1 shows an apparatus 10 for fabricating composite components. Top and bottom mould tools 11, 12 are provided with mould faces 13, 14 shaped to form a composite material into the required component shape. The mould tools are mounted in a press 15 configured to move the mould tools together and apply pressure to a component formed in the mould. The top and/or bottom mould tools are provided with temperature control systems to maintain an elevated temperature during pressing. For example, a temperature in the range 150°C and 250°C with an accuracy of ±2°C. The curing process may include an exothermic reaction and accordingly the temperature control system may require a cooling system as well as a heating system.
The press is capable of creating a pressure of 5 to 60 MPa in the component being formed. In an embodiment a 58 tonne press may be utilised to create a pressure of 57MPa in the component. The press is configured to increase the pressure rapidly, in contrast to the typical slow increase usually utilised for forming composite components. For example, the pressure may increase to the required level over a period of 200 to 400ms.
The mould tools are formed of a material sufficiently strong to maintain their shape and apply the required loads to the component, while also maintaining the required temperatures. Steel or Aluminium may be appropriate. The mould tool faces are configured to enable the component to release from the mould, for example the mould faces may be polished and coated with a suitable release agent.
The mould tool is optionally configured to constrain the size of the component, but there is only minimal flow of the materials during cure. Stops are not necessary, but may be incorporated to control component thickness providing the tool configuration ensures appHcation of full pressure to the component.
Figure 2 shows a flow-chart of an embodiment of a process for rapid formation of composite components. At block 20 pre-preg fibres are laid up in the required configuration. At block 21 the mould surfaces are pre-heated. At block 22 the component is placed on the lower mould surface and the top mould surface is lowered to bring it close to the component, but not apply pressure, such that the component is heated. At block 23 the press is activated and the applied load is increased rapidly over the defined period to the required level. At block 24 the pressure is maintained and the temperature controlled at the required level. At block 25 the pressure is relieved and the component removed.
In an example a sample component was prepared of 4 layers of twill weave carbon fibre pre-preg weighing 3SOgsm impregnated in a black pigmented, flame retardant, toughened epoxy resin system designated MTM58FRB supplied by Advanced Composites Group. The mould surfaces were pre-heated to 160°C and the sample placed on the lower mould surface. The upper surface was brought into close proximity to the sample and maintained for 40±5 seconds. Full load of 58 tonnes was applied to the sample in 350±10 milliseconds to give a sample pressure of 57MPa. The pressure and temperature were maintained for 1 minute ±30 seconds which was sufficient to wholly cure the component.
The high pressure and rapid application of pressure induces a high rate of cure without degrading the material as occurs with existing techniques when cure rates are accelerated using high temperatures. The apparatus and/or process described herein therefore allows the fabrication of composite components in timescales compatible with the requirements of the automotive industry.
It will be understood that the benefits and advantages described above may relate to one embodiment or may relate to several embodiments. It will further be understood that reference to an' item refers to one or more of those items.
The steps of the methods described herein may be carried out in any suitable order, or simultaneously where appropriate. Additionally, individual blocks may be deleted from any of the methods without departing from the spirit and scope of the subject matter described herein. Aspects of any of the examples described above may be combined with aspects of any of the other examples described to form further examples without losing the effect sought.
It will be understood that the above description of a preferred embodiment is given by way of example only and that various modifications may be made by those skilled in the art. The above specification, examples and data provide a complete description of the structure and use of exemplary embodiments of the invention. Although various embodiments of the invention have been described above with a certain degree of particularity, or with reference to one or more individual embodiments, those skilled in the art could make numerous alterations to the disclosed embodiments without departing from the spirit or scope of this invention.
GB1112004.5A 2011-07-13 2011-07-13 High speed composite manufacture Expired - Fee Related GB2492808B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1112004.5A GB2492808B (en) 2011-07-13 2011-07-13 High speed composite manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1112004.5A GB2492808B (en) 2011-07-13 2011-07-13 High speed composite manufacture

Publications (3)

Publication Number Publication Date
GB201112004D0 GB201112004D0 (en) 2011-08-31
GB2492808A true GB2492808A (en) 2013-01-16
GB2492808B GB2492808B (en) 2013-11-20

Family

ID=44586500

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1112004.5A Expired - Fee Related GB2492808B (en) 2011-07-13 2011-07-13 High speed composite manufacture

Country Status (1)

Country Link
GB (1) GB2492808B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014114955A1 (en) * 2013-01-25 2014-07-31 Penso Holdings Ltd Method and apparatus for production of carbon fibre components
ITFI20130158A1 (en) * 2013-07-03 2015-01-04 Massimiliano Becagli PROCEDURE FOR THE REALIZATION OF RIGID PRODUCTS DERIVED FROM TRADITIONAL FABRICS
US20210016521A1 (en) * 2019-07-19 2021-01-21 The Boeing Company Method of forming a reinforced panel component and a related apparatus

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0237871A1 (en) * 1986-03-19 1987-09-23 The Budd Company Vacuum compression molding method using preheated charge
EP0283108A1 (en) * 1987-03-16 1988-09-21 Gencorp Inc. Method for molding FRPs

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050184421A1 (en) * 2002-01-18 2005-08-25 De Nagybaczon Ernest N. Dynamically forced wetting of materials and products produced therefrom
US20120220179A1 (en) * 2009-11-17 2012-08-30 Kurashiki Boseki Kabushiki Kaisha Spun yarn and intermediate for fiber-reinforced resin, and molded article of fiber-reinforced resin using the same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0237871A1 (en) * 1986-03-19 1987-09-23 The Budd Company Vacuum compression molding method using preheated charge
EP0283108A1 (en) * 1987-03-16 1988-09-21 Gencorp Inc. Method for molding FRPs

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014114955A1 (en) * 2013-01-25 2014-07-31 Penso Holdings Ltd Method and apparatus for production of carbon fibre components
ITFI20130158A1 (en) * 2013-07-03 2015-01-04 Massimiliano Becagli PROCEDURE FOR THE REALIZATION OF RIGID PRODUCTS DERIVED FROM TRADITIONAL FABRICS
US20210016521A1 (en) * 2019-07-19 2021-01-21 The Boeing Company Method of forming a reinforced panel component and a related apparatus

Also Published As

Publication number Publication date
GB201112004D0 (en) 2011-08-31
GB2492808B (en) 2013-11-20

Similar Documents

Publication Publication Date Title
US9981430B2 (en) Press moulding method
KR102231918B1 (en) Coated fiber-reinforced resin molding and process for producing same
GB2492808A (en) High speed composite manufacture
KR20180135203A (en) Carbon riber and mesh structure tight processing carbon fiber prepreg and manufacturing method of the same
CN108215241B (en) Rapid molding method of resin-based composite material
US9987832B2 (en) Honeycomb sandwich panel paint ready surface
CN108215242B (en) Forming method of resin-based composite material
WO2014086406A1 (en) High speed composite manufacture
RU2723856C1 (en) Method of making composite bumper for ground vehicle

Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 20220713