GB2430484A - Furnace gas cooler and cleaner utilising movable heat resistant bodies - Google Patents

Furnace gas cooler and cleaner utilising movable heat resistant bodies Download PDF

Info

Publication number
GB2430484A
GB2430484A GB0600019A GB0600019A GB2430484A GB 2430484 A GB2430484 A GB 2430484A GB 0600019 A GB0600019 A GB 0600019A GB 0600019 A GB0600019 A GB 0600019A GB 2430484 A GB2430484 A GB 2430484A
Authority
GB
United Kingdom
Prior art keywords
bodies
chamber
gas
cooling
cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB0600019A
Other versions
GB0600019D0 (en
Inventor
Michael Harris
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
M G H RECYCLING Ltd
Original Assignee
M G H RECYCLING Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by M G H RECYCLING Ltd filed Critical M G H RECYCLING Ltd
Publication of GB0600019D0 publication Critical patent/GB0600019D0/en
Publication of GB2430484A publication Critical patent/GB2430484A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/008Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28CHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
    • F28C3/00Other direct-contact heat-exchange apparatus
    • F28C3/10Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material
    • F28C3/12Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material the heat-exchange medium being a particulate material and a gas, vapour, or liquid
    • F28C3/14Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material the heat-exchange medium being a particulate material and a gas, vapour, or liquid the particulate material moving by gravity, e.g. down a tube
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D19/00Regenerative heat-exchange apparatus in which the intermediate heat-transfer medium or body is moved successively into contact with each heat-exchange medium
    • F28D19/02Regenerative heat-exchange apparatus in which the intermediate heat-transfer medium or body is moved successively into contact with each heat-exchange medium using granular particles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28GCLEANING OF INTERNAL OR EXTERNAL SURFACES OF HEAT-EXCHANGE OR HEAT-TRANSFER CONDUITS, e.g. WATER TUBES OR BOILERS
    • F28G13/00Appliances or processes not covered by groups F28G1/00 - F28G11/00; Combinations of appliances or processes covered by groups F28G1/00 - F28G11/00
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

A furnace gas cooling and cleaning apparatus, comprising a chamber 1 having a gas in let 2 at a lower part thereof and a gas outlet 3 at an upper pan thereof, the chamber containing a plurality of relatively movable heat resistant bodies (e.g. refractory spheres) and having an outlet at the lowermost pan of the chamber provided with a movable shutter 8 by which the bodies can leave the chamber, means for conveying the bodies from the chamber along a mesh tray 9 and for contacting the bodies with cooling and cleaning water provided by sprays 16, a lifting bucket conveyor 17 to lift the cooled wet bodies to the top of the chamber, and valve means in the form of a rotating vane feeder 19 at the top of the chamber for admitting the cooled wet bodies into the chamber whilst preventing the escape of gases from the chamber. Preferably, the exhaust gases pass upwardly through a body of spheres in the chamber while the spheres are circulated through the chamber. The apparatus is designed particularly for cooling and cleaning furnace exhaust gases prior to filtration of particulates, for example, in a bag filter.

Description

FURNACE GAS COOLER AND CLEANER
Field of the Invention
This invention relates to a cooler and cleaner for furnace gases, for example from an incinerator furnace.
Background to the Invention
Furnaces are used for a wide variety of purposes, some of which, for example the incineration of animal carcasses, produce particulate pollutants. To meet environmental laws, these need to be filtered from the exhaust gas stream before it is discharged to the atmosphere. A convenient and economical type of gas filter is the bag filter, which uses a porous bag of a woven or non-woven textile material. While the fibres used to form the material may be heat-resistant to some extent, bag filters cannot be operated at the high temperatures at which combustion gases leave the furnace - typically in excess of 1000 C. It is there- fore necessary to cool the gases first.
Conventional gas coolers comprise a water-cooled heat exchanger in which the gases are passed through tubes surrounded by a body of cooling water. While this can give effective cooling, there is a tendency for the tubes to be gradually blocked by the gas-borne particulates deposited inside them. This requires the furnace to be shut down periodically to permit cleaning of the heat exchanger, a costly process in itself, quite apart from the cost of shutting down the furnace.
It is therefore desirable to find some other way of cooling the gases.
Summary of the Invention
The invention provides a furnace gas cooling apparatus as defined in Claim 1.
The means for cooling the bodies may comprise a cooling tray where contact with the ambient air removes heat from the bodies, or it may comprise means for contacting the bodies with cleaning and cooling water, for example a water spray.
The bodies are solid objects of any shape permitting the objects to move relative to each other so as to pass downward through the chamber without jamming together. Conveniently, the bodies will be at least approximately spherical. Preferably, the bodies are at least of a size which will pass through a mesh no smaller than 10mm, and more preferably no smaller than 20mm. BaIls from 25 to 50mm diameter have been found to be especially effective, being sufficiently large to ensure a reasonable gas flow rate therethrough while pre- senting a large enough surface area for heat transfer and for the capture of par- ticulate impurities on the surface thereof.
The bodies may be of ceramic material or of metal, for example stainless steel.
The bodies are preferably conveyed from the lower end of the chamber by a vibrating mesh screen, passing beneath water spray heads serving to cool the bodies and wash off any particulates and other contaminants captured by the bodies during their passage through the chamber.
The screen suitably delivers the bodies into a water-filled sump, from where they are conveyed back up to the top of the tower. The temperature of the gases emerging from the chamber may be monitored and controlled by in- creasing or decreasing the speed at which the bodies are conveyed back to the top of the chamber, for example by a bucket conveyor, and increasing or de- creasing the opening of a throat at the base of the chamber controlling the egress of the bodies from the chamber.
It has been found that furnace gases at approximately 1000 C entering the apparatus can be cooled to substantially ambient temperature by passage through a chamber containing approximately 1 metre depth of 25mm ceramic balls. It has also been found that very little dust remains in the gases dis- charged from the apparatus, such that the life of the bag filters is substantially increased, or the final filter may even be unnecessary. The particulates are re- moved from the water in a settlement tank or lagoon, permitting the water to be reused, and the solids disposed of.
A fan may be used to draw the gases through the apparatus.
As an alternative to the final bag filter on the outlet of the apparatus, a second, similar apparatus may be connected to the outlet. The second appara- tus may include in the chamber a water spray or water sprays to ensure that the recirculating bodies are kept wet so as to entrain and remove any residual par- ticulates in the cooled gas flow from the first apparatus. This second apparatus could also be used independently as a gas cleaner.
Brief Description of the Drawing
In the drawings, which illustrates diagrammatically exemplary embodimerits of the invention: Figure 1 shows an apparatus according to one embodiment; and Figure 2 illustrates a control system applicable to the apparatus shown in Figure 1.
Detailed Description of the Illustrated Embodiment
Referring first to Figure 1, the apparatus comprises a chamber I in the form of a vertical cylinder having an exhaust gas inlet 2 in the side thereof adja- cent to the lower end of the chamber. The chamber I is suitably formed of steel lined with a refractory liner. In use, the gas inlet 2 will be connected to the gas outlet of a furnace. The gas inlet 2 will have a mesh across it to prevent the egress of the solid contents of the chamber 1, while allowing the passage of the exhaust gases. The mesh may be formed, for example, of intersecting steel rods or bars. The upper part of the chamber I has a gas outlet 3 to which is connected a conduit 4 leading to a centrifugal fan 5 driven by an electric motor 6 and serving to draw the gases through the chamber. The outlet 7 of the fan 5 may be coupled to a bag filter of conventional form (not shown) to remove any residual suspended solid particles from the gas flow before it is discharged to the atmosphere.
The chamber I contains a large number of ceramic spheres, for example of 25 to 50mm diameter, and has at the lowermost part thereof an outlet for the spheres provided with a movable shutter 8 to control the height of the opening, thereby controlling the rate at which the spheres leave the chamber. The spheres are discharged from the chamber I on to a mesh tray 9 mounted above a channel member 10 mounted on rubber blocks 11 carried by supports 12. An electric motor 13 mounted beneath the channel rotates an eccentric weight 14 to vibrate the channel member and mesh tray, thereby causing the spheres to flow along the tray and to drop from the end of the tray into a sump 15. Water sprays 16 mounted above the tray 9 spray water on to the spheres on the tray, cooling them and washing off any pollutants adhering to the spheres. The wa- ter collects in the channel 10 and is discharged into the sump 15. Run- off from the sump carrying suspended dust and like pollutants is directed to a settlement tank or lagoon (not shown), where the solids settle out for disposal. The water can then be recycled, after treatment if necessary to remove soluble pollutants.
A bucket conveyor 17 extends into the sump 15 to lift the wet spheres therefrom and carry them to the upper end of the chamber, where they are dis- charged into a chute 18 through an opening in the front face thereof. The chute 18 is provided with a rotating vane feeder 19 at the lower end thereof, permitting controlled flow of the spheres back into the chamber, while preventing escape of the gases flowing through it. The vane feeder 19 is driven by an electric mo- tor 20 (Figure 2).
Referring now to Figure 2, the apparatus may be controlled, according to one embodiment of the invention, by means of a controller 21, which monitors the gas outlet temperature by means of a sensor 22 in the gas stream, for ex- ample a thermocouple, and then increases or decreases the flow rate of the spheres through the chamber. This can be achieved by increasing or decreas- ing the height of the opening in the lower part of the chamber by raising or low- ering the shutter 8. This may be effected by a motor 23 operating a rack and pinion drive on the shutter. At the same time, the rate at which the spheres are transported to the top of the chamber may be increased or decreased by in- creasing or decreasing the speed of the motor 24 driving the bucket conveyor 17, and the rate of admission of the spheres may be increased or decreased by changing the speed of rotation of the vane feeder 19 by controlling the speed of the motor 20. The controller 21 may be a simple programmable process controller; such devices are well-known. If necessary, the rate of feed of the spheres along the mesh tray 11 may be influenced by controlling the speed of the vibration motor 13.
While the illustrated embodiment includes water cooling and washing of the spheres, it will be appreciated that the invention is not limited to the use of water, and includes the use of air cooling of the spheres, for example by simple heat transfer to the ambient air, or by the use of a forced flow of cooling air us- ing a fan. The spheres may, in such circumstances, be provided with a rough- ened surface to facilitate temporary adhesion of particulate matter, thereby pro- viding a cleaning function for the gas stream as well as cooling.

Claims (23)

1. A furnace gas cooling apparatus, comprising a cooling chamber having an exhaust gas inlet at a lower part thereof and a gas outlet at an upper part thereof, the chamber containing a plurality of relatively movable heat- resistant bodies and having an outlet at the lowermost part of the chamber by which the bodies can leave the chamber, means for conveying the bodies from the chamber and for cooling the bodies, a lifting conveyor to lift the cooled bod- ies to the top of the chamber, and valve means at the top of the chamber for admitting the cooled bodies into the chamber while preventing escape of ex- haust gases therefrom.
2. Apparatus according to Claim 1, wherein the means for cooling the bodies comprises means for contacting the bodies with cleaning and cooling water.
3. Apparatus according to Claim 2, wherein the means for contacting the bodies with water comprises a water spray.
4. Apparatus according to Claim 2 or 3, wherein the means for con- tacting the bodies with water comprises a sump into which the bodies fall and through which water flows.
5. Apparatus according to any preceding claim, wherein the bodies are spherical.
6. Apparatus according to any preceding claim, wherein the bodies are sized so as to pass through a mesh no smaller than 10mm.
7. Apparatus according to Claim 6, wherein the bodies are sized so as to pass through a mesh no smaller than 20mm.
8. Apparatus according to Claim 7, wherein the bodies have a di- ameter of 25 to 50mm.
9. Apparatus according to any preceding claim, wherein the bodies are formed of a ceramic material.
10. Apparatus according to any of Claims I to 8, wherein the bodies are formed of metal.
II. Apparatus according to Claim 10, wherein the bodies are formed of stainless steel.
12. Apparatus according to any preceding claim, wherein the means for conveying the bodies from the chamber comprises a vibrating mesh surface.
13. Apparatus according to any preceding claim, wherein the lifting conveyor is a bucket conveyor.
14. Apparatus according to any of Claims 1 to 12, wherein the lifting conveyor comprises an auger.
15. Apparatus according to any preceding claim, wherein the valve means comprises a rotary vane feeder.
16. Apparatus according to any preceding claim, wherein the gas out- let is connected to a bag filter.
17. Apparatus according to any of Claims 1 to 15, wherein the gas outlet is connected to a gas cleaning apparatus, comprising a cleaning chamber having a gas inlet at a lower part thereof and a gas outlet at an upper part thereof, the chamber containing a plurality of relatively movable bodies and hay- ing an outlet at the lowermost part of the chamber by which the bodies can leave the chamber, means for conveying the bodies from the chamber and for contacting the bodies with cleaning water, a lifting conveyor to lift the wet bodies to the top of the chamber, and valve means at the top of the chamber for admit- ting the wet bodies into the chamber while preventing escape of gases there- from.
18. Apparatus according to any preceding claim, wherein the gas out- let is connected to an extractor fan.
19. A furnace gas cooling apparatus, substantially as described with reference to, and/or as shown in, the drawings.
20. A furnace having an exhaust gas outlet coupled to the exhaust gas inlet of an apparatus according to any preceding claim.
21. Gas cleaning apparatus, comprising a cleaning chamber having a gas inlet at a lower part thereof and a gas outlet at an upper part thereof, the chamber containing a plurality of relatively movable bodies and having an outlet at the lowermost part of the chamber by which the bodies can leave the cham- ber, means for conveying the bodies from the chamber and for contacting the bodies with cleaning water, a lifting conveyor to lift the wet bodies to the top of the chamber, and valve means at the top of the chamber for admitting the wet bodies into the chamber while preventing escape of gases therefrom.
22. Apparatus according to Claim 21, wherein the bodies are spheri- cal.
23. Apparatus according to Claim 21 or 22, wherein the chamber in- cludes at least one water spray for spraying water on to the bodies therein.
GB0600019A 2005-09-27 2006-01-03 Furnace gas cooler and cleaner utilising movable heat resistant bodies Withdrawn GB2430484A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB0519619.1A GB0519619D0 (en) 2005-09-27 2005-09-27 Furnace gas cooler and cleaner

Publications (2)

Publication Number Publication Date
GB0600019D0 GB0600019D0 (en) 2006-02-08
GB2430484A true GB2430484A (en) 2007-03-28

Family

ID=35335485

Family Applications (2)

Application Number Title Priority Date Filing Date
GBGB0519619.1A Ceased GB0519619D0 (en) 2005-09-27 2005-09-27 Furnace gas cooler and cleaner
GB0600019A Withdrawn GB2430484A (en) 2005-09-27 2006-01-03 Furnace gas cooler and cleaner utilising movable heat resistant bodies

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GBGB0519619.1A Ceased GB0519619D0 (en) 2005-09-27 2005-09-27 Furnace gas cooler and cleaner

Country Status (1)

Country Link
GB (2) GB0519619D0 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108151048A (en) * 2017-12-26 2018-06-12 徐州安诚矿山设备有限公司 A kind of household burns coal furnace
CN110901020A (en) * 2019-11-27 2020-03-24 天长市诚信塑业有限公司 Cooling device is used in plastic material production and processing

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446388A (en) * 1943-10-20 1948-08-03 Brassert & Co Preheating furnace blast
GB848683A (en) * 1956-01-23 1960-09-21 North Western Gas Board Improvements in gas purifying apparatus
SU1012000A1 (en) * 1981-04-06 1983-04-15 Государственный Научно-Исследовательский Энергетический Институт Им.Г.М.Кржижановского Regenerative heat exchanger
DE3407341A1 (en) * 1984-02-29 1985-08-29 Peter 4630 Bochum Kähmann Heat exchanger

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2446388A (en) * 1943-10-20 1948-08-03 Brassert & Co Preheating furnace blast
GB848683A (en) * 1956-01-23 1960-09-21 North Western Gas Board Improvements in gas purifying apparatus
SU1012000A1 (en) * 1981-04-06 1983-04-15 Государственный Научно-Исследовательский Энергетический Институт Им.Г.М.Кржижановского Regenerative heat exchanger
DE3407341A1 (en) * 1984-02-29 1985-08-29 Peter 4630 Bochum Kähmann Heat exchanger

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108151048A (en) * 2017-12-26 2018-06-12 徐州安诚矿山设备有限公司 A kind of household burns coal furnace
CN110901020A (en) * 2019-11-27 2020-03-24 天长市诚信塑业有限公司 Cooling device is used in plastic material production and processing
CN110901020B (en) * 2019-11-27 2021-08-03 天长市诚信塑业有限公司 Cooling device is used in plastic material production and processing

Also Published As

Publication number Publication date
GB0519619D0 (en) 2005-11-02
GB0600019D0 (en) 2006-02-08

Similar Documents

Publication Publication Date Title
CN108431532B (en) Method and apparatus for controlled transport of workpieces through a fluidized bed dryer
JP2620027B2 (en) Method and apparatus for heat treating metal castings
JPH11508026A (en) Conveyor and cooling device for bulk material
EP2099548B1 (en) Method and apparatus for filtering process gas
CN101184968A (en) Apparatus and method for thermally removing coatings and/or impurities
CN106625263A (en) Aluminum and magnesium polishing dust wet-method efficient process and clean operation integration system device
CN107019974B (en) Filter medium deashing device and hot gas filtration system
US4508277A (en) Apparatus for reclaiming foundry sand
GB2430484A (en) Furnace gas cooler and cleaner utilising movable heat resistant bodies
CN107019978A (en) Moving granular bed filter, hot gas filtration system and method
US4549698A (en) Method of reclaiming foundry sand
KR102379790B1 (en) Salt Roasting Device
JPH08243331A (en) Flue gas and/or oil mist treatment and device therefor and waste water treatment and device therefor
CN115522018B (en) Cleaning device for bearing ring and control method thereof
US3731910A (en) Cupola structure
CN110170234A (en) It is a kind of for build detection gas blow-off system
JPH08224424A (en) Dust collector
US6299695B1 (en) Method and apparatus for processing ceramic components
KR101862147B1 (en) Dust collecting equipment
US4256045A (en) Apparatus and method for treating a gas with a liquid
CN205323434U (en) Filtering medium heating device
JP6376689B2 (en) Heat treatment apparatus and treatment method for powder
RU2309255C1 (en) Dust removing apparatus for retractable conveyor
US3985510A (en) Flash reactor unit
JP6452144B2 (en) Powder processing equipment

Legal Events

Date Code Title Description
WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)