GB2429456A - Method for stabilization of ethoxyquin, and aqeuous C1-C3 carboxylic acid containing solutions comprising ethoxyquin as antioxidant - Google Patents
Method for stabilization of ethoxyquin, and aqeuous C1-C3 carboxylic acid containing solutions comprising ethoxyquin as antioxidantInfo
- Publication number
- GB2429456A GB2429456A GB0624070A GB0624070A GB2429456A GB 2429456 A GB2429456 A GB 2429456A GB 0624070 A GB0624070 A GB 0624070A GB 0624070 A GB0624070 A GB 0624070A GB 2429456 A GB2429456 A GB 2429456A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethoxyquin
- carboxylic acid
- stabilization
- weight
- containing solutions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004258 Ethoxyquin Substances 0.000 title abstract 5
- 235000019285 ethoxyquin Nutrition 0.000 title abstract 5
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 title abstract 5
- 229940093500 ethoxyquin Drugs 0.000 title abstract 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title abstract 4
- 230000006641 stabilisation Effects 0.000 title abstract 3
- 238000011105 stabilization Methods 0.000 title abstract 3
- 239000003963 antioxidant agent Substances 0.000 title abstract 2
- 230000003078 antioxidant effect Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 abstract 6
- 235000010323 ascorbic acid Nutrition 0.000 abstract 3
- 229960005070 ascorbic acid Drugs 0.000 abstract 3
- 239000011668 ascorbic acid Substances 0.000 abstract 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 3
- 235000006708 antioxidants Nutrition 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/725—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of liquids or solids
- A23B2/729—Organic compounds; Microorganisms; Enzymes
- A23B2/742—Organic compounds containing oxygen
- A23B2/754—Organic compounds containing oxygen containing carboxyl groups
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/725—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of liquids or solids
- A23B2/729—Organic compounds; Microorganisms; Enzymes
- A23B2/771—Organic compounds containing hetero rings
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/70—Preservation of foods or foodstuffs, in general by treatment with chemicals
- A23B2/725—Preservation of foods or foodstuffs, in general by treatment with chemicals in the form of liquids or solids
- A23B2/788—Inorganic compounds
-
- A23L3/3508—
-
- A23L3/3544—
-
- A23L3/358—
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
- C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
- C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D215/20—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/62—Three oxygen atoms, e.g. ascorbic acid
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Food Science & Technology (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicinal Preparation (AREA)
Abstract
The present invention relates to a method for stabilization of ethoxyquin in aqueous C1-C3 carboxylic acid - containing solutions, where 0.1 - 0.5 weight % ascorbic acid, preferably 0.3 - 0.4 weight % and/or 0.1 - 1 weight % sulphite, preferably 0.4 - 0.7 weight % is added to said solution. The invention also relates to aqueous C1-C3 carboxylic acid - containing solutions comprising ethoxyquin as antioxidant, where said solution comprises 0.1 - 0.5 weight % ascorbic acid, preferably 0.3 - 0.4 weight %, and/or 0.1 - 1 weight % sulphite, preferably 0.4 - .07 weight %. The invention also relates to the use of ascorbic acid sulphite for stabilization of ethoxyquin in aqueous C1-C3 carboxylic acid - containing solutions.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO20041959A NO321226B1 (en) | 2004-05-12 | 2004-05-12 | Process for Stabilizing Ethoxyquin in Aqueous Formic Acid Solution, Aqueous Formic Acid Solution comprising Ethoxyquin as Antioxidant, and Use for Stabilizing Ethoxyquin |
PCT/NO2005/000160 WO2005108371A1 (en) | 2004-05-12 | 2005-05-12 | Method for stabilization of ethoxyquin, and aqueous c1-c3 carboxylic acid - containing solutions comprising ethoxyquin as antioxidant |
Publications (3)
Publication Number | Publication Date |
---|---|
GB0624070D0 GB0624070D0 (en) | 2007-01-10 |
GB2429456A true GB2429456A (en) | 2007-02-28 |
GB2429456B GB2429456B (en) | 2009-02-18 |
Family
ID=34880517
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB0624070A Expired - Fee Related GB2429456B (en) | 2004-05-12 | 2005-05-12 | Method for stabilization of ethoxyquin in aqueous C1-C3 carboxylic acid containing solutions by adding ascorbic acid and sulphite |
Country Status (3)
Country | Link |
---|---|
GB (1) | GB2429456B (en) |
NO (1) | NO321226B1 (en) |
WO (1) | WO2005108371A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1859681A1 (en) * | 2006-05-24 | 2007-11-28 | Addcon Agrar GmbH | Method for preserving animal tissue by use of a chemical composition |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4772710A (en) * | 1983-07-15 | 1988-09-20 | Von Magius Niels W | Ethoxyquin salts of alkanoic acids |
EP0666300A2 (en) * | 1994-02-07 | 1995-08-09 | Nof Corporation | Method for inhibiting oxiation of oils and fats or fatty acids |
WO2004045317A1 (en) * | 2002-11-15 | 2004-06-03 | Yara International Asa | Preservative agent |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5167835A (en) * | 1991-11-06 | 1992-12-01 | Nalco Chemical Company | Method of scavenging oxygen from boiler waters with substituted quinolines |
-
2004
- 2004-05-12 NO NO20041959A patent/NO321226B1/en not_active IP Right Cessation
-
2005
- 2005-05-12 WO PCT/NO2005/000160 patent/WO2005108371A1/en active Application Filing
- 2005-05-12 GB GB0624070A patent/GB2429456B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4772710A (en) * | 1983-07-15 | 1988-09-20 | Von Magius Niels W | Ethoxyquin salts of alkanoic acids |
EP0666300A2 (en) * | 1994-02-07 | 1995-08-09 | Nof Corporation | Method for inhibiting oxiation of oils and fats or fatty acids |
WO2004045317A1 (en) * | 2002-11-15 | 2004-06-03 | Yara International Asa | Preservative agent |
Also Published As
Publication number | Publication date |
---|---|
NO20041959D0 (en) | 2004-05-12 |
NO20041959L (en) | 2005-11-14 |
GB2429456B (en) | 2009-02-18 |
NO321226B1 (en) | 2006-04-10 |
WO2005108371A1 (en) | 2005-11-17 |
GB0624070D0 (en) | 2007-01-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20170512 |