GB2424893A - Synthesis of ion imprinted polymer particles - Google Patents

Synthesis of ion imprinted polymer particles

Info

Publication number
GB2424893A
GB2424893A GB0610829A GB0610829A GB2424893A GB 2424893 A GB2424893 A GB 2424893A GB 0610829 A GB0610829 A GB 0610829A GB 0610829 A GB0610829 A GB 0610829A GB 2424893 A GB2424893 A GB 2424893A
Authority
GB
United Kingdom
Prior art keywords
polymer particles
ion
imprinted polymer
erbium
ion imprinted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB0610829A
Other versions
GB0610829D0 (en
GB2424893B (en
Inventor
Kala Ramakrishnan
Mary Gladis Joseph
Talasila Prasada Rao
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Council of Scientific and Industrial Research CSIR
Original Assignee
Council of Scientific and Industrial Research CSIR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Council of Scientific and Industrial Research CSIR filed Critical Council of Scientific and Industrial Research CSIR
Publication of GB0610829D0 publication Critical patent/GB0610829D0/en
Publication of GB2424893A publication Critical patent/GB2424893A/en
Application granted granted Critical
Publication of GB2424893B publication Critical patent/GB2424893B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/268—Polymers created by use of a template, e.g. molecularly imprinted polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/282—Porous sorbents
    • B01J20/285—Porous sorbents based on polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/305—Addition of material, later completely removed, e.g. as result of heat treatment, leaching or washing, e.g. for forming pores
    • B01J20/3057—Use of a templating or imprinting material ; filling pores of a substrate or matrix followed by the removal of the substrate or matrix
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F6/00—Post-polymerisation treatments
    • C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Ion imprinted polymer materials are synthesized containing metal ion recognition sites. These particles are synthesized by copolymerizing with functional and cross linking monomers in presence of at least one imprint metal ion in the form of ternary complex. The polymerization was carried out by q -irradiation (in the absence of initiator) or photochemical and thermal polymerization (in presence of initiator, AIBN). These materials were ground and sieved after drying to obtain erbium ion imprinted polymer particles. The erbium ion was removed from the polymer particles by leaching with mineral acid which leaves cavities/binding sites in the polymer particles. The resultant polymer particles can be used as solid phase extractants for selective enrichment of erbium ions from dilute aqueous solutions.
GB0610829A 2003-12-31 2003-12-31 Synthesis of ion imprinted polymer particles Expired - Fee Related GB2424893B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IN2003/000427 WO2005063382A1 (en) 2003-12-31 2003-12-31 Synthesis of ion imprinted polymer particles

Publications (3)

Publication Number Publication Date
GB0610829D0 GB0610829D0 (en) 2006-07-12
GB2424893A true GB2424893A (en) 2006-10-11
GB2424893B GB2424893B (en) 2007-07-25

Family

ID=34717548

Family Applications (1)

Application Number Title Priority Date Filing Date
GB0610829A Expired - Fee Related GB2424893B (en) 2003-12-31 2003-12-31 Synthesis of ion imprinted polymer particles

Country Status (5)

Country Link
JP (1) JP4414396B2 (en)
CN (1) CN100448526C (en)
AU (1) AU2003296866A1 (en)
GB (1) GB2424893B (en)
WO (1) WO2005063382A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100723919B1 (en) * 2006-02-16 2007-08-10 성균관대학교산학협력단 Selective separation of heavy metal ion using the metal ion imprinted polymer(miip)
KR100861452B1 (en) * 2007-03-05 2008-10-02 성균관대학교산학협력단 Method for preparing surface-imprinted polyacrylate microsphere in the form of core-shell for the selective separation of heavy metal ion
JP2010100708A (en) * 2008-10-22 2010-05-06 Mukogawa Gakuin Molecularly imprinted polymer and method for preparing the same
KR101016231B1 (en) * 2009-02-04 2011-02-25 성균관대학교산학협력단 Method for preparing porous imprinted polymer particles for the selective separation of heavy metal ions
KR101118760B1 (en) 2009-12-29 2012-03-13 재단법인대구경북과학기술원 Molecular imprinted polymers for detecting Pentraxin protein and the methods thereof
US20140186970A1 (en) * 2011-11-02 2014-07-03 Empire Technology Development Llc Imprinted photonic polymers and methods for their preparation and use
GB2516215A (en) * 2013-05-23 2015-01-21 Univ Lincoln Metals recovery method and polymer for use in metals re-covery and process for making such a polymer
CN103285837B (en) * 2013-06-27 2015-04-08 武汉科梦环境工程有限公司 Preparation method of adsorption material with high selectivity on different heavy metal ions
CN106552590A (en) * 2016-11-21 2017-04-05 西北矿冶研究院 Preparation method of heavy metal ion imprinted magnetic chitosan adsorbent
CN106979930B (en) * 2017-05-23 2018-04-24 中国科学院地质与地球物理研究所 A kind of method of free iron content in quantitative analysis Soil/Sediment Samples
CN109364770B (en) * 2018-11-28 2021-02-12 江苏大学 Preparation method and application of gadolinium ion imprinting nano carbon material composite membrane
CN112791712B (en) * 2021-01-05 2022-05-10 南开大学 Adsorbent for removing protein-bound uremic toxin through blood perfusion and preparation method thereof
CN115141305B (en) * 2022-07-06 2023-09-19 中国科学院赣江创新研究院 Functional polymer, preparation method thereof and method for preparing ion imprinting polymer by using functional polymer

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003034043A2 (en) * 2001-10-16 2003-04-24 The Johns Hopkins Universtiy Molecularly imprinted polymer solution anion sensor

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1226311C (en) * 2002-06-26 2005-11-09 天津大学 Magnetic composite microsphere of molecular blot polymer and its suspemsion polymerization process for preparing it

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003034043A2 (en) * 2001-10-16 2003-04-24 The Johns Hopkins Universtiy Molecularly imprinted polymer solution anion sensor

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Analytica Chimica Acta, 2003, Vol. 488, No. 2, Daniel S. et. al., pages 173-182. *
Tetrahedron Letters, 1999, Vol. 39, No. 47, Garcia R. et. al., pages 8651-8654. *

Also Published As

Publication number Publication date
WO2005063382A1 (en) 2005-07-14
GB0610829D0 (en) 2006-07-12
JP2007518545A (en) 2007-07-12
JP4414396B2 (en) 2010-02-10
AU2003296866A1 (en) 2005-07-21
GB2424893B (en) 2007-07-25
CN100448526C (en) 2009-01-07
CN1886189A (en) 2006-12-27

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Legal Events

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PCNP Patent ceased through non-payment of renewal fee

Effective date: 20171231