GB2422840A - Methods for inhibiting hydrate blockage in oil and gas pipelines using simple quaternary ammonium and phosphonium compounds - Google Patents
Methods for inhibiting hydrate blockage in oil and gas pipelines using simple quaternary ammonium and phosphonium compounds Download PDFInfo
- Publication number
- GB2422840A GB2422840A GB0609874A GB0609874A GB2422840A GB 2422840 A GB2422840 A GB 2422840A GB 0609874 A GB0609874 A GB 0609874A GB 0609874 A GB0609874 A GB 0609874A GB 2422840 A GB2422840 A GB 2422840A
- Authority
- GB
- United Kingdom
- Prior art keywords
- quaternary ammonium
- phosphonium
- oil
- methods
- gas pipelines
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title abstract 4
- 125000001453 quaternary ammonium group Chemical group 0.000 title abstract 4
- 230000002401 inhibitory effect Effects 0.000 title abstract 2
- 150000004714 phosphonium salts Chemical class 0.000 title 1
- -1 hydrocarbon hydrates Chemical class 0.000 abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 abstract 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000001414 amino alcohols Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 230000001276 controlling effect Effects 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 150000004677 hydrates Chemical class 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 230000000116 mitigating effect Effects 0.000 abstract 1
- 230000001603 reducing effect Effects 0.000 abstract 1
- 230000000979 retarding effect Effects 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/003—Additives for gaseous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B37/00—Methods or apparatus for cleaning boreholes or wells
- E21B37/06—Methods or apparatus for cleaning boreholes or wells using chemical means for preventing or limiting, e.g. eliminating, the deposition of paraffins or like substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/22—Hydrates inhibition by using well treatment fluids containing inhibitors of hydrate formers
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
A method and a quaternary ammonium or phosphonium composition used therein for inhibiting, retarding, mitigating, reducing, controlling and/or delaying formation of hydrocarbon hydrates or agglomerates of hydrates. The method may be applied to prevent or reduce or mitigate plugging of conduits, pipes, transfer lines, valves, and other places or equipment where hydrocarbon hydrate solids may form under the conditions. At least one quaternary ammonium or phosphonium compound is added into the process stream, where the compound may be mixed with another compound selected from other amino alcohols, esters, quaternary ammonium, phosphonium or sulphonium salts, betaines, amine oxides, amides, simple amine salts, and combinations thereof.
Description
GB 2422840 A continuation (72) Inventor(s): Vaithlingam Panchalingam
Michael Gregory Rudel Scot Harris Bodnar (74) Agent and/or Address for Service: Forrester Ketley & Co Chamberlain House, Paradise Place, BIRMINGHAM, B3 3HP, United Kingdom
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US51331103P | 2003-10-21 | 2003-10-21 | |
US10/918,192 US20050085675A1 (en) | 2003-10-21 | 2004-08-13 | Methods for inhibiting hydrate blockage in oil and gas pipelines using ester compounds |
US10/918,213 US20050085396A1 (en) | 2003-10-21 | 2004-08-13 | Methods for inhibiting hydrate blockage in oil and gas pipelines using amino alcohols and ester compounds |
US10/918,210 US20050085676A1 (en) | 2003-10-21 | 2004-08-13 | Methods for inhibiting hydrate blockage in oil and gas pipelines using betaines and amine oxides |
US10/918,191 US7264653B2 (en) | 2003-10-21 | 2004-08-13 | Methods for inhibiting hydrate blockage in oil and gas pipelines using simple quaternary ammonium and phosphonium compounds |
US10/918,214 US7381689B2 (en) | 2003-10-21 | 2004-08-13 | Methods for inhibiting hydrate blockage in oil and gas pipelines using amide compounds |
PCT/US2004/033995 WO2005042675A2 (en) | 2003-10-21 | 2004-10-14 | Methods for inhibiting hydrate blockage in oil and gas pipelines using simple quaternary ammonium and phosphonium compounds |
Publications (3)
Publication Number | Publication Date |
---|---|
GB0609874D0 GB0609874D0 (en) | 2006-06-28 |
GB2422840A true GB2422840A (en) | 2006-08-09 |
GB2422840B GB2422840B (en) | 2008-08-27 |
Family
ID=34557884
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB0609874A Expired - Fee Related GB2422840B (en) | 2003-10-21 | 2004-10-14 | Methods for inhibiting hydrate blockage in oil and gas pipelines using simple quaternary ammonium and phosphonium compounds |
Country Status (5)
Country | Link |
---|---|
AU (1) | AU2004285117B2 (en) |
CA (1) | CA2543426C (en) |
GB (1) | GB2422840B (en) |
NO (1) | NO344577B1 (en) |
WO (1) | WO2005042675A2 (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0420061D0 (en) | 2004-09-09 | 2004-10-13 | Statoil Asa | Method |
GB2436575A (en) * | 2006-03-16 | 2007-10-03 | Statoil Asa | Method for protecting hydrocarbon conduits |
WO2008089262A1 (en) * | 2007-01-21 | 2008-07-24 | M-I Llc | Method and pill for remediating hydrate condensate blockage in pipelines |
US9193671B2 (en) | 2010-09-21 | 2015-11-24 | Multi-Chem Group, Llc | Anti-agglomerate gas hydrate inhibitors for use in petroleum and natural gas systems |
WO2012040329A1 (en) * | 2010-09-21 | 2012-03-29 | Multi-Chem Group, Llc | Water removal from anti-agglomerate ldhis |
US9505707B2 (en) * | 2010-12-22 | 2016-11-29 | Nalco Company | Composition and method for reducing hydrate agglomeration |
CN102181275B (en) * | 2011-02-15 | 2013-04-24 | 中国海洋石油总公司 | Composite hydrate inhibitor and application thereof |
GB201117477D0 (en) | 2011-10-11 | 2011-11-23 | Uni I Stavanger | Method |
BR112014015045B1 (en) * | 2011-12-20 | 2020-12-01 | Shell Internationale Research Maatschappij B.V | method to inhibit duct clogging |
EP3420055A4 (en) * | 2016-02-26 | 2020-01-22 | Ecolab USA Inc. | Kinetic hydrate inhibitors for controlling gas hydrate formation in wet gas systems |
IT201600130556A1 (en) | 2016-12-23 | 2018-06-23 | Lamberti Spa | INHIBITORS OF GAS HYDRATES |
IT201600130571A1 (en) * | 2016-12-23 | 2018-06-23 | Lamberti Spa | INHIBITORS OF GAS HYDRATES |
CA3106294A1 (en) | 2018-10-09 | 2020-04-16 | Clariant International Ltd | Unsymmetrically substituted dicarboxylic acid diamido ammonium salts and their use for gas hydrate anti-agglomeration |
US11161804B2 (en) | 2018-10-09 | 2021-11-02 | Clariant International Ltd. | Unsymmetrically substituted dicarboxylic acid diamido ammonium salts and their use for gas hydrate anti-agglomeration |
US11753577B2 (en) | 2019-05-28 | 2023-09-12 | Clariant International Ltd. | Method for inhibiting gas hydrate blockage in oil and gas pipelines |
US11753576B2 (en) | 2019-05-28 | 2023-09-12 | Clariant International Ltd. | Method for inhibiting gas hydrate blockage in oil and gas pipelines |
US20210179917A1 (en) | 2019-12-11 | 2021-06-17 | Clariant International, Ltd. | Method Of And A Composition For Controlling Gas Hydrate Blockage Through The Addition Of A Synergistically Acting Blend With A Quaternary Alkyl Ammonium Compound |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0446616A1 (en) * | 1990-02-09 | 1991-09-18 | Scandinavian Oilfield Chemicals As | Process for inhibiting corrosion in oil production fluids |
WO1995017579A1 (en) * | 1993-12-21 | 1995-06-29 | Shell Internationale Research Maatschappij B.V. | A method for inhibiting the plugging of conduits by gas hydrates |
EP0914407A1 (en) * | 1996-07-23 | 1999-05-12 | Clariant GmbH | Method of inhibiting gas hydrate formation |
WO2001009082A1 (en) * | 1999-07-29 | 2001-02-08 | Akzo Nobel N.V. | Process for preparing esterquats |
WO2002066785A1 (en) * | 2001-02-20 | 2002-08-29 | Baker Hughes Incorporated | Composition and method for inhibition of formation of gas hydrates |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6444852B1 (en) * | 1999-06-24 | 2002-09-03 | Goldschmidt Chemical Corporation | Amines useful in inhibiting gas hydrate formation |
CH696188A5 (en) * | 2002-07-29 | 2007-02-15 | Brooks Pri Automation Switzerl | Detection and cleaning device in a handling apparatus for photomasks. |
-
2004
- 2004-10-14 GB GB0609874A patent/GB2422840B/en not_active Expired - Fee Related
- 2004-10-14 AU AU2004285117A patent/AU2004285117B2/en not_active Ceased
- 2004-10-14 CA CA2543426A patent/CA2543426C/en not_active Expired - Fee Related
- 2004-10-14 WO PCT/US2004/033995 patent/WO2005042675A2/en active Application Filing
-
2006
- 2006-05-18 NO NO20062235A patent/NO344577B1/en not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0446616A1 (en) * | 1990-02-09 | 1991-09-18 | Scandinavian Oilfield Chemicals As | Process for inhibiting corrosion in oil production fluids |
WO1995017579A1 (en) * | 1993-12-21 | 1995-06-29 | Shell Internationale Research Maatschappij B.V. | A method for inhibiting the plugging of conduits by gas hydrates |
EP0914407A1 (en) * | 1996-07-23 | 1999-05-12 | Clariant GmbH | Method of inhibiting gas hydrate formation |
WO2001009082A1 (en) * | 1999-07-29 | 2001-02-08 | Akzo Nobel N.V. | Process for preparing esterquats |
WO2002066785A1 (en) * | 2001-02-20 | 2002-08-29 | Baker Hughes Incorporated | Composition and method for inhibition of formation of gas hydrates |
Also Published As
Publication number | Publication date |
---|---|
CA2543426C (en) | 2010-12-07 |
CA2543426A1 (en) | 2005-05-12 |
AU2004285117B2 (en) | 2009-11-26 |
WO2005042675A3 (en) | 2005-09-22 |
AU2004285117A1 (en) | 2005-05-12 |
GB0609874D0 (en) | 2006-06-28 |
GB2422840B (en) | 2008-08-27 |
NO344577B1 (en) | 2020-02-03 |
NO20062235L (en) | 2006-06-09 |
WO2005042675A2 (en) | 2005-05-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20201014 |