GB2388815A

GB2388815A - Improvements in and relating to liquid impermeable and liquid vapour/gas permeable fabrics

Info

Publication number: GB2388815A
Application number: GB0314282A
Authority: GB
Inventors: David Avril; George Simpson; Kelly Filmer
Original assignee: Don and Low Ltd
Current assignee: Don and Low Ltd
Priority date: 2002-09-21
Filing date: 2003-06-19
Publication date: 2003-11-26
Anticipated expiration: 2023-06-19
Also published as: GB0314282D0; GB0222005D0; GB2388815B

Abstract

A vapour permeable fabric comprises a first reflective layer laminated to a second filamentous layer for example by calendering. The first reflective layer may comprise a single metallic or reflective foil, a polymeric foil with metallic (eg. aluminium or an alloy thereof) or reflective material applied thereto, or a laminate of multiple reflective foils interspersed with non reflective foils. The reflective layer may be microporous or micro perforated. The filamentous layer may comprise a non woven (eg spun-bonded) or a woven polymeric fabric. Suitable polymers for either layer include polypropylene, polyamides or polyesters. In an alternative embodiment the reflective layer comprises a filamentous layer wherein the filaments are spun from a blend comprising a polymeric material and a reflective material. Said reflective material may be supplied as a masterbatch and may comprise finely ground aluminium (or an alloy thereof) particles in a polymer matrix. The invented fabrics may be used in the construction industry for example as housewrap, as roofing or flooring underlay or in cavity wall insulation.

Description

1 2388815

IMPROVZ:NT8 IN AND RELATING TO LIQUID IELE

LIQUID VOUR/GAS PEALE F - RICS

5 FIELD OF INVENTION

The present invention relates generally to permeable fabrics such as liquid impermeable and liquid vapour/gas permeable fabrics. The invention more particularly, though not exclusively, relates to air and/or water 10 vapour permeable fabrics. Such fabrics or materials may find particularly beneficial application as construction fabrics, such as in the building industry, e.g. as house-

wrap or as roofing underlay or in flooring.

15 BACKGROUND TO INVENTION

Liquid impermeable and liquid vapour permeable materials, including laminates, are known.

Various films or membranes of coextruded or monolayer construction are available which, by virtue of 20 a plurality of micropores or by molecular diffusion mechanisms, have the characteristics of providing a barrier to, for example, aqueous liquids, while at the same time allowing the passage of moisture vapour. A microporous membrane having such properties was 25 previously made by Exxon Corporation under the trade name "EXXAIRE", a polyolefinic membrane with excellent vapour transport characteristics. Such is now available from their successor, Tredegar Film Products (formerly Exxon Films) as BF-116W. However, such membranes typically 30 possess inadequate tensile strength properties and low resistance to tear for unsupported use, and in many applications require to be combined with other materials to improve these properties.

[', 7.'32 1tiB

EP 0 570 215 A, by the present Applicant, discloses use of a laminate as a roofing underlay material wherein said laminate comprises: a liquid impermeable and liquid vapour permeable microporous membrane; and a substrate, 5 the membrane and substrate being intermittently bonded to preserve the liquid vapour transmission properties of the membrane. The laminate is provided with a supporting substrate on both sides of the membrane, the membrane and the substrates being intermittently bonded to preserve 10 the liquid vapour transmission properties of the membrane. In one form one or both of the substrates of said laminate is a spunbonded polymeric non-woven material. The spunbonded non-woven substrate of said laminate is formed as a web to be subsequently calender 15 bonded simultaneously with thermal lamination to the membrane. EP 0 570 215 A discloses that the spunbonded polymeric non-woven material may be ultraviolet ( W) stabilized. Further, the previously available "EXXAIRE" 20 membrane was temperature stabilized. Thus EP 0 571 215 A discloses a breathable building membrane including an under layer formed of a microporous polymeric film and a top layer formed of a filamentous polymeric fabric which is bonded to the under layer, said under and top layers 25 being disposed in overlying relationship and being stabilized respectively against heat degradation and ultraviolet light degradation.

The content of EP 0 570 215 A is incorporated herein by reference.

Pl?92'GH

EP 0 742 305 A, also by the present Applicant, discloses use as a building material (and particularly as a roofing underlay) of a laminated fabric comprising at least two layers of non-woven sheet material, said fabric 5 comprising: (1) a first layer of compressed melt-blown material having an average pore size diameter in the range from 1 Am to about 8 m; and (2) a second layer of a material having an open 10 porous structure, and wherein the second layer of material is of a spun bonded structure.

The layers comprising the fabric are bonded by a point-bonding technique, such as a calendering 15 treatment.

The total area of said points is between 7% and 40% of the fabric area, and the compressed melt-blown material may be rendered into a compressed condition during lamination of the layers.

20 The content of EP 0 742 305 A is incorporated herein by reference.

GB 2 355 430 A by Hunt Technology Limited, discloses a breathable building membrane including an under layer formed of a microporous polymeric film and a top layer 25 formed of a filamentous polymeric fabric (spunbond) which is bonded to the under layer, said under and top layers being disposed in overlying relationship and being stabilised respectively against heat degradation and ultraviolet light degradation, and said top layer having 30 a top surface bearing a moisture vapour permeable P1 2921GB

reflective coating. It is suggested that the reflective coating comprises a thin metallic layer, such as aluminium, the thin metallic layer belug applied by plasma deposition onto the top surface of the top fabric 5 layer to a thickness of about 40 nm. It is reported that wherein the fabric of the top layer is made from spunbonded filaments and wherein the deposited metallic coating coats the surfaces of the individual filaments which collectively form the top surface layers of the 10 spunbonded fabric top layer, such that the deposited metallic coating does not form a discrete layer on the top surface of the top layer.

The content of GB 2 355 430 A is incorporated herein by reference.

15 GB 2 355 430 A notes a number of problems in the art, e.g. condensation within a roof or cavity wall space and infra-red (JR) loading on building membranes which may lead to material degradation. Go 2 355 430 A seeks to address such problems, but in a way which gives rise 20 to other problems, including cost and complexity of material manufacture as well as material robustness.

It is an object of at least one embodiment of at least one aspect of the present invention to obviate or at least mitigate one or more of the aforementioned 25 problems.

It is a further object of at least one embodiment of at least one aspect of the present invention to provide an improved building material such as a synthetic breathable building membrane suitable for use as a wall P12921GB

breather membrane or housewrap, and also most preferably, for use as a roofing underlay.

It is noted by the present Applicant that roofing underlayment fabrics can rise up beneath roof tiles, 5 causing rooftile lift in certain wind conditions. This phenomenon is measurable and is termed "wind lift".

Stiff fabrics tend to address this problem by being less susceptible to lift by the wind. Stiff fabrics, however, may produce unwanted noise caused by flexing in windy 10 conditions. A balance between fabric stiffness and noise levels is sought for building fabrics.

It is a further object of at least one embodiment of at least one aspect of the present invention to provide an improved building material which obviates or at least 15 mitigates the abovementioned problems.

It is a yet further object of at least one embodiment of at least one aspect of the present invention to provide a building material having in combination a metallised gas permeable infra-red 20 reflective means, ultraviolet light stabilization means, and heat stabilization means, which is moisture impermeable and gas and/or moisture vapour permeable to assist in guarding against roof space or cavity wall condensation, and which increases resistance of the 25 building material to degradation, thereby increasing the life and durability of such material.

The inventors of the present invention have identified a need for an improved construction fabric, which has the following properties: P: 2 921GB

(i) the ability to resist the ingress of wind driven rain and snow; (ii) good moisture vapour transmission properties; and 5 (iii) a surface or means capable of reflecting infra-red radiation/heat.

Fabrics meeting the requirements of (i) and (ii) are taught by EP 0 570 215 A and by EP 0 742 305 A. The present invention enhances the teaching of these 10 disclosures by providing an infra-red reflecting surface

to the products described in each of these documents. A method of achieving a reflecting surface by plasma coating of aluminium is described in GB 2 355 430 A. However, a disadvantage quoted in that disclosure is that

15 some of the aluminium coating may rub off on the calender bowl during lamination, with a subsequent loss in reflectance. It is the present inventor's belief that in one or more embodiments of one or more aspects of the present invention disclosed herein, this problem will be 20 addressed by complete encapsulation of the metallic component. There is also an additional advantage in that the metallic component will not flake off in handling during use, e.g. the construction process or transportation. 25 It is a still further object of one or more embodiments of one or more aspects of the present invention to provide a breathable building fabric having means for providing ultraviolet and heat stabilization and moisture vapour permeable reflective means which acts 30 to reduce the infra-red loading of the entire building P1 2921(;B

fabric, in use, thereby further increasing the resistance of the building membrane to degradation. Moreover, when the building fabric serves as a roofing underlay, during the construction or repair of a roof when the underlay S can be totally exposed for periods, e.g. of three months or more, and affords the only protection to the building, the moisture vapour permeable reflective means enhances this protection.

10 SUMMARY OF INVENTION

- According to a first aspect of the present invention there is provided a filamentous polymeric fabric, filaments of which comprise a polymeric material and a reflective material.

15 The filamentous polymeric material may be formed from a 'tspunbond" process, and may therefore be termed a spunbond fabric.

Preferably the filamentous polymeric fabric is breathable, that is to say moisture vapour permeable and 20 preferably air/gas permeable.

Preferably the reflective material is capable of reflecting at least infra-red (JR) radiation and/or heat.

Infra-red radiation is normally taken to be in the wavelength region 0.75 Am to 1,000 'm, and most 25 particularly herein 5 Am to 50 m.

The filamentous polymeric fabric preferably has an emissivity of about 0. 1 to about 0.6, and preferably about 0.1 to 0.3.

Emissivity is a measure of reflectance, with a 30 totally absorbing surface having an emissivity of 1 P12921GH

( 8 (one), and a totally reflecting surface having an emissivity of O (zero).

The reflective material may substantially comprise a metal or metallic based material, e.g. aluminium or an 5 alloy thereof.

The polymeric material may comprise additives such as ultra-violet (UV) stabilizers, hydrophobic additives, flame retardants, pigments (e.g. colour pigments), and/or plasticizers. 10 The polymeric material may be a thermoplastic polymer, e.g. selected from polypropylene, polyamide or polyester. According to a second aspect of the present invention there is provided a filamentous polymeric 15 fabric filaments of which comprise a polymeric material having a metallic material added thereto.

According to a third aspect of the present invention there is provided a breathable fabric comprising a filamentous polymeric fabric according to the first or 20 second aspects.

Preferably the breathable fabric comprises a laminate material including a first layer comprising the filamentous polymeric fabric and a second layer comprising a breathable polymeric membrane, e.g. a 25 microporous or microperforated polymeric membrane. The microporous or microperforated polymeric membrane may be vapour permeable and liquid impermeable.

Preferably the first and second layers are intermittently bonded together. The first layer may Pl2921;B

:/ 9 comprise a top (outer) layer, and the second layer may comprise an under (inner) layer.

The first and second layers may be stabilised respectively against ultraviolet light degradation and 5 heat degradation.

The breathable polymeric membrane may comprise an ultra-violet (W) stabilised breathable membrane which may or may not have a hydrophobic treatment applied via the melt or topically.

10 The breathable polymeric membrane may comprise a melt-blown film or a microporous or microperforated film.

Such may provide good water hold-out properties combined with good moisture vapour transmission properties.

The membrane may be made from a thermoplastic 15 polymer selected from: polypropylene, polyolefins, polyesters or polyamides.

The filamentous polymeric fabric may be made from a thermoplastic polymer selected from: polypropylene, polyolefins, polyesters or polyamides.

20 Preferably the breathable polymeric membrane comprises: a liquid impermeable and liquid vapour permeable membrane; and the filamentous polymeric fabric comprises a substrate, the membrane and substrate being intermittently bonded to preserve the liquid vapour 25 transmission properties thereof.

The laminate may be provided with a supporting substrate on both sides of the membrane, the membrane and the substrates being intermittently bonded to preserve the liquid vapour transmission properties thereof.

30 The laminate may include a woven fabric layer.

P12921GB

The woven fabric of said laminate may be in the form of a scrim intermittently bonded to one of the other laminate components.

The woven fabric of said laminate may be bonded to 5 the membrane.

In one form, one or both of the substrates of said laminate is a spunbonded polymeric non-woven material.

The spunbonded non-woven substrate of said laminate may be formed as a web to be calender bonded either 10 simultaneously (ON-LINE) or subsequently (OFF-LINE) with thermal lamination to the membrane. The web of said laminate may be of a weight of between 10 g/m2 and 200 g/m2. The web of said laminate may be of a weight of between 30 g/m2 and 90 g/m2.

15 The membrane of said laminate may be of monolayer or multilayer construction.

The layers of the laminate may be thermally bonded.

The bonded area of said laminate may form between 5% and 50% of the surface area of the laminated layers, e.g. 20 around 71/%. The bonded area of said laminate may form between 14% and 20% of the surface area of the laminated layers, and preferably around 19%.

The filamentous polymeric fabric may comprise a first spunbond fabric, and the breathable fabric may 25 comprise the first spunbond fabric, the breathable polymeric membrane and a second spunbond fabric.

The first spunbond fabric and breathable polymeric membrane may be intermittently bonded by a first bonding pattern, and the breathable polymeric membrane and the 30 second spunbond fabric may be intermittently bonded by a P1292IGB

second bonding pattern. The first bonding pattern and the second bonding pattern may be similar or may be dissimilar. According to a fourth aspect of the present 5 invention there is provided a breathable building or construction material comprising a filamentous polymeric fabric according to the first or second aspects, or a breathable fabric according to the third aspect.

The breathable building material may be adapted for 10 use as a roofing underlay. However, the breathable building material may be advantageously adapted for use as a housewrap, e.g. in timber frame constructions, or as a wall breather membrane, or in other construction uses such as a temporary cover, e.g. a building cover or 15 scaffolding cover, tent, tarpaulin or the like. The breathable building material may also find use as a flooring material.

According to a fifth aspect of the present invention there is provided use as a building or construction 20 material of a filamentous polymeric fabric according to the first or second aspects or a breathable fabric according to the third aspect.

According to a sixth aspect of the present invention there is provided a method of manufacturing a filamentous 25 polymeric fabric comprising the steps of: providing a polymeric material and a reflective material; and forming the polymeric material and the reflective material into a filamentous polymeric fabric.

Pl292iC;B

Preferably the step of forming is carried out using a spunbond process.

Preferably the reflective material is a metallic material or a metal, and the polymeric material and 5 reflective material are provided as a metallised polymer masterbatch, e.g. in pelletised form.

Advantageously the metal, e.g. aluminium, is finely ground and added to a polymeric melt used to produce the spunbond material.

10 The reflective component may be an aluminiumised/aluminised masterbatch.

Preferably the step of forming includes the further step of: calendering the filamentous polymeric fabric, e.g. 15 with a first point embossing pattern.

According to a seventh aspect of the present invention there is provided a method of manufacturing a filamentous polymeric fabric comprising the steps of: providing a polymeric material having a metallic 20 material added thereto; and forming the polymeric material and the metallic material into a filamentous polymeric fabric.

According to an eighth aspect of the present invention there is provided a method of manufacturing a 25 breathable fabric comprising the steps of: forming a filamentous polymeric fabric according to the method of the sixth or seventh aspects; providing a breathable polymeric membrane; and laminating the filamentous polymeric fabric and the 30 breathable polymeric membrane one to the other.

Pl292LGB

In one implementation (so-called "OFF-LINE") the filamentous polymeric fabric is formed and rolled prior to lamination.

In such method, the step of forming includes the 5 steps of: laying down filaments so as to form the filamentous polymeric fabric; and calendering the filamentous polymeric fabric, e.g. with a first point embossing pattern.

10 Calendering is a thermal bonding technique involving the application of a combination of heat and pressure.

Further, in such method the steps of laminating includes the step of: calendering the filamentous polymeric fabric and 15 membrane together, e. g. with a second point emboss pattern. The first and second point emboss patterns may be selected to be substantially the same or different.

In a second implementation (so-called ''ON-LIME") the 20 membrane is laid down on the (loose), i.e. unembossed or unbended, filamentous polymeric fabric or vice versa.

In such method the step of laminating includes the step of: calendering the filamentous polymeric fabric and 25 membrane together, e.g. with a first point emboss pattern. According to a ninth aspect of the present invention there is provided a building construction including a filamentous polymeric fabric according to the first or Pl2921GB

( 14 second aspects, or a breathable fabric according to the third aspect.

The building construction comprises a roof such as a tiled roof structure. Alternatively, the building 5 construction may comprise a timber frame or a cavity wall. Alternatively the building construction comprises a floor. According to a tenth aspect of the present invention there is provided a building including a building 10 construction according to the ninth aspect.

According to an eleventh aspect of the present 15 invention there is provided a laminated breathable fabric having as a layer thereof a reflective film or membrane.

Preferably, the reflective film may comprise a breathable (moisture vapour permeable and optionally air/gas permeable) film, e.g. a microperforated or 20 microporous metallised film Microperforated film is believed by the Applicant to be advantageous to microporous film as microperforated films typically have a greater reflectance and, therefore, better infra-red (JR) performance.

25 The microperforated metallised film may comprise microperforations of 0.1 mm to 15 mm in diameter.

The microperforations or micropores may advantageously have a size of, e. g. around 0.1 mm to 1.0 mm, and preferably around 0.6 mm, and preferably also a 30 surface coverage of around 2% to 10%.

['1292'.;B

Typically, there may be provided around 30 microperforated holes/inch.

The membrane may comprise a polymeric material and a reflective material.

5 Preferably the reflective material is capable of reflecting at least infra-red radiation and/or heat.

Preferably the reflective film or membrane has an emissivity of about 0.1 to about 0.6, and preferably about 0.1 to about 0.3.

10 The reflective material may substantially comprise a metal or metallic based material, e.g. aluminium or an alloy thereof.

The reflective membrane may comprise a single layer membrane. 15 Alternatively the reflective membrane may comprise a multiple layer membrane, e.g. a three layer membrane wherein a middle layer includes the reflective material.

The membrane in such cases may be of an "AB" or "ABA" type, wherein 'tA" is a first polymeric material 20 advantageously including a W stabilizer, and "B" is a second polymeric material including the reflective material. The reflective material may be provided as an additive to a polymeric material melt used to produce the 25 membrane, e.g. as a finely ground metal, or metallic based material, e.. aluminium or a material including aluminium. In a multiple layer membrane, the melt additive may be used to provide a layer "B" of second polymer material P12921GB

including the reflective material of an,'AB" or "ABA" type membrane.

As another alternative, the reflective membrane may comprise a multiple layer membrane, e.g. a three layer 5 membrane wherein a middle layer comprises the reflective material deposited onto one of the layers. For example, the membrane may be of an "AC" or "ACA" type in which ''A" is a first polymeric material, advantageously including a W stabilizer, and "C" is a reflective material deposited 10 onto one of the first polymer material layers "A".

The first polymeric layer "A" may be around 10 Em to 30 Em in thickness, and preferably around 15 Em thick.

The reflective material "C" may be around 10 nm to 100 nm thick, and preferably around 40 nm thick.

15 The reflective material may be deposited by a deposition process, e.g. vacuum vapour deposition or plasma deposition.

The polymeric material(s) may comprise one or more additives such as ultra-violet (W) stabilizers, 20 hydrophobic additives, flame retardants, pigments (e.g. colour pigments), and/or plasticizers.

The polymeric material(s) may be a thermoplastic polymer(s), e.g. selected from polypropylene, polyamide or polyester.

25 The fabric may also comprise at least one breathable polymeric film or membrane layer, and/or at least one filamentous polymeric fabric layer.

Advantageously, in one embodiment the reflective film may be laminated to the at least one breathable 30 polymeric membrane. In another embodiment the reflective P12921GB

( 17 film may be laminated to the at least one filamentous polymeric fabric layer.

In one advantageous implementation, the laminated breathable fabric may comprise the reflective film, a 5 breathable polymeric membrane and a filamentous polymeric fabric layer comprising a spunbond layer.

Preferably the film, membrane and spunbond layers are intermittently bonded to preserve the moisture vapour transmission properties thereof.

10 In a modification, a further spunbond layer is provided between the film and membrane. The further spunbond layer may provide additional strength.

Preferably the further spunbond layer contains an ultra-violet stabiliser and/or a hydrophobic additive.

15 Preferably the film, further spunbond layer membrane and spunbond layer are intermittently bonded to preserve the moisture vapour transmission properties thereof.

The laminated breathable fabric may include a woven fabric layer.

20 The woven fabric of said laminated breathable fabric may be in the form of a scrim intermittently bonded to one of the other laminate components.

The woven fabric of said laminated breathable fabric may be bonded to the at least one breathable polymeric 25 film or membrane layer, or to the at least one filamentous polymeric fabric layer, or to the reflective membrane. According to a twelfth aspect of the present invention there is provided a laminated breathable fabric P12921GB

having as a layer thereof a metal or metallised film or membrane. According to a thirteenth aspect of the present invention there is provided a breathable building or 5 construction material comprising a laminated breathable fabric according to the eleventh or twelfth aspects.

The breathable building material may be adapted for use as a roofing underlay. Alternatively the breathable building material may be advantageously adapted for use 10 as a housewrap e.g. for use in timber frame constructions, or as a wall breather membrane, or in other construction uses such as a temporary cover, e.g. a building cover or scaffolding cover, tent, tarpaulin or the like. The breathable building material may also find 15 use as a flooring material.

According to a fourteenth aspect of the present invention there is provided use as a building or construction material of a laminated breathable fabric according to the eleventh or twelfth aspects.

20 According to a fifteenth aspect of the present invention there is provided a method of manufacturing a laminated breathable fabric comprising the steps of: providing a reflective film; providing a filamentous polymeric fabric; and 25 forming the reflective film and filamentous polymeric fabric into a laminated breathable fabric.

Preferably the step of forming is carried out by calendering. Preferably, the reflective film is a microperforated 30 film, e.g. of an "AB", "ABA", "AC" or "ACA" construction, P12921(,}3

and the step of providing the film comprises the steps of forming the film and then microperforating the film.

According to a sixteenth aspect of the present invention there is provided a method of manufacturing a 5 laminated breathable fabric comprising the steps of: providing a metal or metallised film; providing a filamentous polymeric fabric layer; and forming the metal or metallised film and filamentous polymeric fabric into a laminated breathable fabric.

10 Preferably the step of forming is carried out by calendering. According to a seventeenth aspect of the present invention there is provided a building construction including a laminated breathable fabric according to the 15 eleventh or twelfth aspects.

The building construction comprises a roof such as a tiled roof structure. Alternatively, the building construction may comprise a timber frame or a cavity wall. Alternatively the building construction comprises a 20 floor.

According to an eighteenth aspect of the present invention there is provided a building, including a building construction according to the seventeenth aspect. 25 According to a nineteenth aspect of the present invention there is provided a laminated breathable fabric comprising at least one breathable polymeric film or membrane layer, laminated to at least one filamentous polymeric fabric layer, wherein a reflective material is Pi 2 92.G

provided on the breathable polymeric film or membrane layer. The reflective material may comprise a layer of reflective material, and may be provided by a deposition 5 process, e.g. vacuum vapour deposition or plasma deposition. The reflective material may substantially comprise a metal or metallic based material, e.g. aluminium or an alloy thereof.

10 The filamentous polymeric fabric layer may substantially comprise a spunbond layer.

The breathable polymeric film may be provided between the reflective material and the at least one filamentous polymeric fabric layer.

15 Alternatively and advantageously the reflective material may be provided between the breathable polymeric film and the at least one filamentous polymeric fabric layer. According to a twentieth aspect of the present 20 invention there is provided a laminated breathable fabric comprising at least one breathable polymeric film or membrane layer,laminated to at least one filamentous polymeric fabric layer, wherein a metallic material is provided on the breathable polymeric film or membrane 25 layer.

According to a twenty first aspect of the present invention there is provided a woven polymeric fabric, '292iGS

! 21 strands of which comprise a polymeric material and a reflective material.

Preferably the strands are in the form of tapes.

Preferably the reflective material is preferably 5 capable of reflecting at least infra-red (JR) radiation and/or heat.

Preferably the woven polymeric fabric has an emissivity of about 0.1 to about 0.6, and preferably about 0.1 to about 0.3.

The polymeric material may comprise additives such as ultra-violet (W) stabilizers, hydrophobic additives, IS flame retardants, pigments (e.g. colour pigments) and/or plasticizers. The tapes may be of a mono-layer construction.

Alternatively, the tapes may be of a multi-layer construction. In a multilayer construction the 20 reflective material may be added to an inner layer of a co-extruded tape.

In one embodiment the multi-layered tape may be a three layer construction wherein a centre layer contains the reflective material and the outer layers contain a UV 25 stabilizer.

According to a twenty second aspect of the present invention there is provided a woven polymeric fabric strands of which comprise a polymeric material and a metallic material added thereto.

Pl2921GB

According to a twenty third aspect of the present invention there is provided a breathable fabric comprising a woven polymeric fabric according to the twenty first or twenty second aspects.

5 Advantageously the construction of the woven fabric is selected so as not to impair moisture vapour transmission properties of the fabric.

Preferably the breathable fabric comprises a laminate material including a first layer comprising the 10 woven polymeric fabric and a second layer comprising a breathable polymeric membrane.

Preferably the first and second layers are intermittently bonded together, preferably to preserve the moisture vapour transmission properties thereof.

15 Preferably the breathable fabric further comprises a third layer of filamentous polymeric material, the first, second and third layers being intermittently bonded together preferably to preserve the moisture vapour transmission properties thereof.

20 Preferably the breathable fabric comprises a laminate material including a first layer comprising the woven polymeric fabric, and a second layer comprising a breathable polymeric membrane.

Preferably the first and second layers are bonded 25 together. The first layer may comprise a top (outer) layer and the second layer may comprise an under (inner) layer. The first and second layers may be stabilised respectively against ultra-violet light degradation, and 30 heat degradation.

PI 2 921G5

( 23 The breathable polymeric membrane may comprise an ultra-violet stabilized breathable membrane which may or may not have a hydrophobic treatment applied via the melt or topically.

5 According to a twenty fourth aspect of the present invention there is provided a breathable building or construction material comprising a woven polymeric fabric according to the seventeenth or eighteenth aspects, or a breathable fabric according to the twenty second aspect.

10 The breathable building material may be adapted for use as a roofing underlay. Alternatively the breathable building material may be advantageously adapted for use as a housewrap, e.g. in timber frame constructions, or as a wall breather membrane, or in other construction uses 15 such as a temporary cover, e.g. a building cover or scaffolding cover, tent, tarpaulin or the like. The breathable building material may also find use as a flooring material.

According to a twenty fifth aspect of the present 20 invention there is provided use as a building or construction material of a woven polymeric fabric according to the twenty first or twenty second aspects, or a breathable fabric according to the twenty third aspect. 25 According to a twenty sixth aspect of the present invention there is provided a method of manufacturing a woven polymeric fabric comprising the steps of: providing a polymeric material and a reflective material; P'292lGB

forming the polymeric material and the reflective material into strands, e.g. tapes or threads; weaving the strands together.

Preferably the reflective material is a metallic 5 material or a metal, and the polymeric material and reflective material are provided as a metallised polymer masterbatch. Advantageously the metal, e.g. aluminium, is finely ground and added to a polymeric melt used to produce the 10 strands.

The reflective component may be an aluminiumised/aluminised masterbatch.

According to a twenty seventh aspect of the present invention there is provided a method of manufacturing a 15 woven polymeric fabric comprising the steps of: providing a polymeric material and a metallic material; forming the polymeric material and the metallic material into strands; and 20 weaving the strands together.

According to a twenty eighth aspect of the present invention there is provided a method of manufacturing a breathable fabric comprising the steps of: forming a woven polymeric fabric according to the 25 method of the twenty fifth or twenty sixth aspects; providing a breathable polymeric membrane; and laminating the woven polymeric fabric and the breathable polymeric membrane one to the other.

According to the twenty ninth aspect of the present 30 invention there is provided a building construction P1292IGB

( 25 including a woven polymeric fabric according to the seventeenth or eighteenth aspects, or a breathable fabric according to the twenty first aspect.

The building construction comprises a roof such as a 5 tiled roof structure. Alternatively, the building construction may comprise a timber frame or a cavity wall. Alternatively the building construction comprises a floor. According to a thirtieth aspect of the present 10 invention there is provided a building including a building construction according to the twenty sixth aspect. In a modification the breathable fabric further comprises a fourth layer of filamentous polymeric 15 material between the woven polymeric fabric and the membrane. Preferably the first layer, fourth layer, second layer and third layer are intermittently bonded, preferably to preserve the moisture vapour transmission 20 properties thereof.

According to a thirty first aspect of the present invention there is provided strands, threads or tapes adapted for use in manufacture of the woven polymeric fabric of the twenty first or twenty second aspects or 25 the breathable fabric of the twenty third aspect.

According to a thirty second aspect of the present 30 invention there is provided a fabric comprising: P;2 92 1;B

( a polymeric fabric comprising a polymeric material and a reflective material, or a polymeric material layer having formed thereon a continuous breathable layer comprising or including a 5 reflective material.

The polymeric fabric or the polymeric material layer may advantageously be a filamentous polymeric fabric, or alternatively a breathable polymeric film or a woven polymeric fabric.

10 Preferably the polymeric fabric is made from a masterbatch comprising a polymeric material and a reflective material.

According to a thirty third aspect of the present invention there is provided a fabric comprising: 15 a polymeric fabric comprising a polymeric material and a metallic material, or a polymeric material layer having formed thereon a continuous breathable layer comprising or including a metallic material.

20 According to a thirty fourth aspect of the present invention there is provided a breathable fabric comprising a fabric according to the thirty second or thirty third aspects.

According to a thirty fifth aspect of the present 25 invention there is provided a breathable building or construction material comprising a fabric according to the thirty second or thirty third aspects.

According to a thirty sixth aspect of the present invention there is provided use as a building or P12321CB

construction material of a fabric according to the thirty second or thirty third aspects.

According to a thirty seventh aspect of the present invention there is provided a method of manufacturing a 5 polymeric fabric comprising the steps of: providing a polymeric material and a reflective material; forming the polymeric material and reflective material into a polymeric fabric.

10 Preferably the reflective material is added to the polymeric material as a melt additive.

According to a thirty eighth aspect of the present invention there is provided a method of manufacturing a polymeric fabric comprising the steps of: 15 providing a polymeric material and a metallic material; forming the polymeric material and metallic material into a polymeric fabric.

According to a thirty ninth aspect of the present 20 invention there is provided a method of manufacturing a breathable fabric comprising the steps of: forming a polymeric fabric according to the method of the thirty seventh or thirty eighth aspects; providing at least one breathable layer; 25 laminating the polymeric fabric and breathable layer one to the other.

P1292IGB

BRIEF DESCRIPTION OF DRAWINGS

Embodiments of the present invention will now be described by way of example only, and with reference to 5 the accompanying drawings, which are: Figures l(a), (a), (c) schematic sectional side views of first, second and third embodiments of breathable 10 fabrics according to the present invention; Figure 2 a schematic diagram of an apparatus for manufacture of 15 filamentous polymeric fabrics according to the present invention; Figure 3 a schematic diagram of a 20 lamination apparatus for manufacture of breathable fabrics according to the present invention; 25 Figure 4 a schematic diagram of an apparatus for manufacture of filamentous polymeric fabrics and lamination thereof to manufacture breathable fabrics P12921GB

according to the present invention; Figure 5 a schematic diagram of an 5 apparatus for manufacture of a polymeric membrane in the form of a microperforated film for use in the breathable fabrics of Figures l(a), (b) or (c); Figures 6ta), (a) schematic diagrams of a production apparatus and a microperforation apparatus, respectively, for manufacture 15 of a polymeric membrane in the form of a melt-blown film for use in the breathable fabrics of Figures l(a), (b) or (c).

20 Figures 7(a), (b), (c) schematic sectional side views of fourth, fifth and sixth embodiments of breathable fabrics according to the present invention; Figure 7(d) a schematic representation of a pattern of microperforations in a fabric according to the present invention.

P1292iGB

30 l Figures 8(a), (b) schematic sectional side views of seventh and eighth embodiments of breathable fabrics according to the 5 present invention; Figure 9 a schematic diagram of an apparatus for manufacture of strands (tapes) for manufacture 10 of the breathable fabrics of Figures 8 (a) or (b); Figure 10 a schematic diagram of an alternative apparatus for manufacture of strands (tapes) for manufacture of the breathable fabrics of Figures 8(a) or (b); 20 Figure '1 a cross-sectional side view of a part of a roof including the fabric of Figures l(a), (b) or (c), Figures 7(a), (b), (c) or Figures lO(a) or (b); and Figure 12 a cut-away perspective view of a wall including the fabric of Figures l(a), (b) or (c), Figures 7(a), (b), (c) or 30 Figures lO(a) or (b).

P12922GB

DETAILED DESCRIPTION OF DRAWINGS

FIRST EXAMPLE

5 Referring to Figure l(a), there is illustrated a filamentous polymeric fabric 5a according to a first embodiment of the present invention. Filaments of the filamentous polymeric fabric 5a comprise a polymeric material and a reflective metallic material.

10 The filamentous polymeric material 5a is formed from a "spunbond'' process as will hereinafter be described in greater detail, and is therefore termed a "spunbond" fabric. The filamentous polymeric fabric 5a is breathable, 15 that is to say moisture vapour permeable and air permeable, and the reflective material is capable of reflecting at least infra-red (JR) radiation and/or heat.

The reflective material typically substantially comprises a metal or metallic based material, and in this 20 embodiment comprises aluminium or an alloy thereof.

The polymeric material can comprise additives such as an ultra-violet (UV) stabiliser, hydrophobic additives, flame retardants, pigments (e.g. colour pigments), and/or plasticizers. The polymeric material 25 is a thermoplastic polymer, e.g. selected from polypropylene, polyamide or polyester, and in this embodiment is polypropylene.

A breathable fabric lOa comprises in part filamentous polymeric fabric 5a. The breathable fabric 30 lOa comprises the filamentous polymeric fabric 5a and a Pl292IGB

( second layer comprising a breathable, e.g. microperforated or microporous polymeric membrane 15a.

The breathable polymeric membrane 15a is vapour permeable and liquid impermeable.

5 The first and second layers 5a, 15a are intermittently bonded together, the first layer 5a comprising a top (outer) layer, and the second layer 15a comprising an under (inner) layer. The first and second layers 5a, 15a are advantageously stabilized respectively 10 against W light degradation and heat degradation. In this example the breathable polymeric membrane 15a comprises a W stabilised breathable membrane, which may or may not have a hydrophobic treatment applied via the melt or topically. The breathable polymeric membrane 15a 15 is selected from one of a melt-blown film or a microporous or microperforated film. Further, the membrane 15a is made from a thermoplastic polymer selected from: polypropylene, polyolefins, polyesters or polyamides, and in this embodiment polypropylene.

20 A melt blown fabric comprises a mass of micro filaments, typically 1 Em to 5 Em diameter. This mass of filaments may or may not be calendered, i.e. the mass may be subjected to pressure with or without the application of heat. The calender rollers may be smooth, or a 25 combination of smooth and embossed. The degree of calendering applied will depend on the required balance of properties of water hold out versus moisture vapour transmission. A microporous film is prepared from a polyolefin/filler mix. The filler may be Calcium P12921GB

f Carbonate, Titanium Dioxide or similar. The film is stretched either mono-axi;.ly or bi-axially in such a way that micropores of approximately 0.2 Am are formed through the film. Such a process is described in the EP 5 0 309 073 A to Exxon.

The Applicant considers the addition of a W stabiliser to prevent ultraviolet degradation on exposure to light to be beneficial. In addition, the properties of the membrane 15a may be enhanced by a hydrophobic 10 agent which may be added to the melt or applied topically. The Applicant considers the use of a hydrophobic agent to be particularly beneficial in the i case of a melt blown fabric, where it will improve the water holdout properties of the final product. In 15 addition, contact with house timbers, which have been treated with water based timber treatments can have an adverse effect on the water hold out properties. This can be minimised by the application of a suitable hydrophobic treatment.

20 Thus the breathable polymeric membrane 15a comprises: a liquid impermeable and liquid vapour permeable membrane; and the filamentous polymeric fabric 5a comprises a substrate, the membrane and substrate j being intermittently bonded to preserve the liquid vapour 25 transmission properties thereof.

In a modification the breathable fabric 5a comprises only the filamentous polymeric fabric. Such may be sufficient for some less demanding applications, e.g. housewrap. P12921GB

In a second embodiment shown in Figure l(b), the laminate lOb is provided with a supporting substrate 5b, 20b on both sides of the membrane 15b, the membrane 15b and the substrates 5b, 20b being intermittently bonded to 5 preserve the liquid vapour transmission properties thereof. The further supporting substrate 2Ob is also a filamentous polymeric fabric, the same or similar to the substrate 5b.

The laminate lea, lOb optionally includes a woven 10 fabric layer (not shown). The woven fabric of said laminate can be in the form of a scrim intermittently bonded to one of the other laminate components. The woven fabric of said laminate lOa;lOb can be bonded to the membrane 15a;15b. In one form, one or both of the 15 substrates 5a; 5b, 20b of said laminate lOa;lOb is a spunbonded polymeric non-woven material. The spunbonded nonwoven substrate 5a; 5b, 20b of said laminate lOa; lOb is/are formed as a web(s) to be subsequently calender bonded simultaneously with thermal lamination to the 20 membrane 15a;15b. The web(s) of said laminate lOa; lOb are typically of a weight of between 10 g/m2 and 200 g/m2, and particularly between 30 g/m2 and 90 g/m2. The membrane 15a;15b of said laminate lOa;lOb can be of monolayer or multilayer construction.

25 The layers of the laminate lOa; lOb are in this embodiment thermally calender bonded. The bonded area of said laminate lOa;lOb forms between 5% and 50% of the surface area of the laminated layers, particularly between 14% and 20%, and advantageously around 191.

Pl2921GB

( 35 In the second embodiment the filamentous polymeric fabric 5b comprises a first spunbond fabric, and the breathable fabric lob comprises the first spunbond fabric 5b, the breathable polymeric membrane 15b and a second 5 spunbond fabric 20b. The first spunbond fabric 5b and breathable polymeric membrane 15b are intermittently bonded together by a first bonding pattern, and the breathable polymeric membrane 15b and the second spunbond fabric 20b are intermittently bonded by a further bonding 10 pattern. The bonding pattern and the further bonding pattern may be similar or may be dissimilar.

In a third embodiment shown in Figure l(c) the laminate lOc is further provided with a third spunbond fabric 21c between the first spunbond fabric 5c and the 15 membrane 15c.

The filamentous polymeric fabric 5a;5b;5c/ breathable fabric lOailOb;lOc find use as a breathable building or construction material 25a;256;25c. The breathable building material 25a;25b;25c can be adapted 20 for use as a roofing underlay. However, the breathable building material 25a;25b;25c can also advantageously be adapted for use as a housewrap, or alternatively wall breather membrane, or alternatively as a temporary cover, e.g. a building cover or scaffolding cover, or tent, 25 tarpaulin or the like. The breathable building material 25a, 25b, 25c can also find use as a flooring material.

The filamentous polymeric fabric 5a;5b;5c is manufactured by a method comprising the steps of: providing a polymeric material and a reflective material; 30 and forming the polymeric material and the reflective Pl2921GB

( material into the filamentous polymeric fabric 5a;5b;5c.

The step of forming is carried out using a spunbond process. The reflective material is a metallic material or a metal, and the polymeric material and reflective 5 material are provided as a metallised polymer masterbatch. Advantageously the metal (in this embodiment aluminium) is finely ground and added to a polymeric melt used to produce the spunbond material.

The reflective component can be an 10 aluminiumised/aluminised masterbatch such as SILVER 210-

30-E1 or ARX V 01/015 IR.

SILVER 210-30-E1 available from Silberline Plastics Limited is an aluminized polymer masterbatch offering: very fine particle size aluminium flake pigment; low 15 dusting, dry granular delivery form; compatibility with a wide range of thermoplastics. SILVET 210-30-E1 provides a very fine particle size aluminium flake pigment in a free flowing, non-dusting, meterable, granular form. It provides direct pigmentation of extruded articles and 20 colouration of masterbatch and compound, where its high metal content offers considerable formulating flexibility. This grade is compatible with a wide range of thermoplastics, including styrenics, polyoleflns, polyamides, polycarbonates, polyesters and acetals.

25 Due to its fine particle size, SIGNETS 210-30-E1 has very high opacity. Loadings of 0.3% to 1.2% in the final pigmented article are typical. It is normally sufficient to tumble blend the granules with polymers and any other colorants and additives before processing. As with all 30 aluminium flake pigments, the use of high shear forces P12921GB

! should be minimised as they cause loss of brightness and metallic effect.

Properties of SILVER 210-30-E1 are: Aluminium pigment content = 69.0% minimum by weight 5 Carrier content = 29.0% minimum by weight Nonvolatile content = 98.5% minimum at 100-C Median flake diameter = approximately 8 m.

ARX V 01/015 IR available from ARGUS Additive Plastics GmbH is an Infrared-reflector-Masterbatch 10 having an absorption region within the IR range.

The step of forming normally includes the further step of: calendering the filamentous polymeric fabric, e.g. with a point emboss pattern.

The breathable fabric 10a;10b;10c is manufactured by 15 a method comprising the steps of: forming the filamentous polymeric fabric 5a;5b; 5c; providing the breathable polymeric membrane 15a;15;15c; and laminating the filamentous polymeric fabric 5a;5b;5c and the breathable polymeric membrane 15a;15b;15c one to the other.

20 Referring to Figures 2 and 3, in one implementation (so-called OFFLINE") the filamentous polymeric fabric 5a;5b;5c is formed and rolled prior to lamination. The filamentous polymeric fabric 5a;5b;5c is formed by spunbond apparatus 100, and laminated by laminator 150, 25 as will hereinafter be described.

In such method, the step of forming includes the steps of: laying down filaments so as to form the filamentous polymeric fabric 5a;5b;5c and calendering the filamentous polymeric fabric 5a;5b;5c, e.g. with a first 30 point emboss pattern. Calendering is a thermal bonding Pl2921GB

technique involving the application of a combination of heat and pressure.

Further, in such method the steps of laminating includes the step of calendering the filamentous 5 polymeric fabric 5a;5b;5c and membrane 15a; 15b;15c together, e.g. with a second point emboss pattern.

The first and second point emboss patterns can be selected to be substantially the same or different.

The spunbond apparatus 100 comprises a polymer feed 10 for forming filaments and a plurality of filament spinners 103. Additives such as the reflective material can be introduced in the polymer feed prior to melting and subsequent mixing in an extruder. Filaments are cooled by cooling means 104 and loose laid as a web 106 15 on a spinbelt 105. A conveyor 107 conveys the web 106 to a point bonding calender 108. The calender 108 has three embossing bowls, a first embossing bowl 10Sa with a 19% embossing area (so-called STANDARD BOND) and a diamond embossing pattern, a second bowl 108b which is 20 smooth, and a third bowl 108c with a 72% embossing area (so-called LO-BOND) with a round embossing pattern. The web 106 is selected to be passed between the first and second bowls 108a, 103b or the second and third bowls 108b, 108c dependent upon the embossing pattern to be 25 selected. After calendering the web 106 forms a spun fabric 109, i.e., the filamentous polymer fabric 5a, 5b, 20b; 5c, 20c, 21c. The spunbond fabric 109 is then rolled on wind- up roller 110.

The spunbonding processing thus involves passing a 30 polymer melt through a die with a plurality of holes, to Pl2921GH

form a mass of filaments. The filaments are stretched, cooled, and formed into a loose web on a conveyor belt, and then passed through a calender. The calender comprises a smooth roller and an embossed roller, the 5 embossing pattern of which may typically cover from 72% to 35% of the surface area, and which may be a diamond, round or other shape. The smooth bowl of the calender should be of the swim roll type, i.e. is capable of being bent' to accommodate variations in thickness of the web.

10 Both bowls of the calender should be heated, the temperature selected being dependent on the type of polymer being processed, and on the balance of properties required in the end product.

The laminator 150 comprises unwind stands 151a,151b 15 from which a reel of spunbond fabric 109 and membrane 15a;15b;15c, respectively are unrolled and passed through a laminating calender 152. The calender 152 has two embossing bowls, a first embossing bowl 152a with an embossed pattern and a second bowl 152b which is smooth.

20 The embossed pattern may be the same as that of one of the embossed bowls 108a, 10Sc of the spunbond apparatus 100 or may be different. The laminator 150 also comprises an accumulator 153 and a winder 154.

Referring to Figure 4, in a second implementation 25 (so-called ''ONLINE") the filamentous polymeric fabric 5a;5b;5c is laid down (loose) on the membrane. The filamentous polymeric fabric 5a;5b;5c is formed and laminated by spunbond/laminator apparatus 200.

In such method the step of laminating includes the 30 step of calendering the filamentous polymeric fabric PlZ921GB

5a;5b;5c and membrane 15a;15b;15c, e.g. with a point emboss pattern. -

The spunbond/laminator apparatus 200 is similar to the spunbond apparatus 100 of Figure 2. However, in the 5 apparatus 200 there is provided a film unwind stand from which a roll of membrane 15a;15b;15c is unwound and laminated to unbended web 206.

In the case where the membrane 15a;15b;15c is a microperforated film, the membrane 15a;15b;15c can be 10 manufactured by cast film apparatus 300 shown in Figure 5. The cast film apparatus 300 comprises a polymer feed 301, an extruder 302 including a film extrusion means 303 for forming a film 304 (membrane 15a;15b;15c), a chill roll 305, a film orientation means 306 (mono or bi-axial) 15 and a film winder 307.

Alternatively in the case where the membrane 15a;15b;15c is a microperforated film the membrane 15a;15b;15c can be manufactured by blown film apparatus 400 and microperforation apparatus 450 shown in Figures 20 6(a) and (b) respectively. Blown film apparatus 400 comprises a polymer feed 401, extruder 402 including film extruded means 403 for forming a blown film bubble 404 to provide film 407 (membrane 15a:15b:15c) , a film orientation means 405 (mono- or bi-axial) and a film 25 winder 406.

Microperforation apparatus 450 comprises an unwind stand 451, microperforation means 452 and wind up stand 453. It will be appreciated that the filamentous 30 polymeric fabrics 5a;5b;5c forming part of a laminate of P12921GP

an embodiment of the present invention may be used as a single layer product. In such case the filamentous polymeric fabric may have a weight of around 100 g/m2 to 150 g/m2. In other cases, e.g. the two-layer fabric 5a, 5 the filamentous polymeric fabric may have a weight of around 60 g/m2 to 100 g/m2 and the membrane 15a may have a weight of around 30 g/m2 (and typically a thickness of around 30 microns).

10 SECOND EXAMPLE

Referring to Figure 7(a) there is illustrated a laminated breathable fabric lOd according to a fourth embodiment of the present invention having as a layer thereof a reflective film or membrane 30d.

15 The reflective film 30d comprises a breathable (moisture vapour permeable and optionally air permeable) film, and in this embodiment a microperforated metallised film. The reflective film 30d advantageously contains a TV stabilizer. In this embodiment, the reflective film 20 30d comprises a gas barrier polypropylene film having a metal (e.g. aluminium) foil laminated thereto. The reflective film 30d typically has a thickness of 25 Am to 30 m, and is

manufactured by a cast or blown method. The reflective film 30d is microperforated so as 25 to be gas permeable and then laminated to the at least one breathable polymeric membrane 15d. The microperforations are typically of the order of 0.1 mm to 1.0 mm in diameter.

I" 2921GH

* The fabric lOd comprises the at least one breathable polymeric membrane layer 15d, and also at least one filamentous polymeric fabric layer 5d.

As illustrated in Figure 7(a) the reflective film 5 3Od is laminated to the at least one breathable polymeric membrane 15d. In a modification, however, the reflective film 30d is laminated to the at least one filamentous polymeric fabric layer 5d.

As shown in Figure 7(a) the laminated breathable 10 fabric led comprises the reflective film 30d, the breathable polymeric membrane 15d and the spunbond filamentous polymeric fabric layer 5d. The film Bed, membrane 15d and spunbond 5d are intermittently bonded to preserve the moisture vapour transmission properties 15 thereof.

In a fifth embodiment shown in Figure 7(b) a further spunbond layer 20e is provided between the film 30e and membrane 15e. The further spunbond layer 20e provides additional strength.

20 A sixth embodiment is shown in Figure 7(c) which illustrates a laminated breathable fabric lOh having as a layer thereof a reflective film 30h. The reflective film 30h comprises a three layer structure comprising a first polyolefin polymer layer 35h formed, e.g. of 25 polypropylene or a copolymer of polyethylene and polypropylene, upon which is deposited a second layer 40h of metal, such as aluminium, e.g. by vacuum vapour or plasma deposition. Third layer 45h comprises a polymer layer also formed of polypropylene or a copolymer of 30 polyethylene and polypropylene.

Pl292iG5

The reflective film 30h typically has a thickness of 25 Em to 30 m, and is typically manufactured by a cast or blown method employing the apparatus of Figures 5 or 6(a). 5 The reflective film 30h is made by, for example, forming a first polymer layer 35h, followed by vacuum vapour or plasma deposition of a layer 40h of aluminium metal upon the polymer layer 35h. The polymer layer 35h with the metal deposit layer 40h formed thereon is then 10 laminated to a second polymer layer 45h using a calender with, for example, heated smooth rolls. The polymer layers 35h and 45h typically have a thickness of approximately 15 m. The metal layer 40h typically has a thickness of the order of 40 nm.

15 The fabric lOh also comprises at least one spunbond filamentous polymer fabric layer 5h.

The three layer reflective film 30h is formed and microperforated, e.g. employing the apparatus of Figure 6(b), prior to lamination to the at least one spunbond 20 filamentous polymer fabric layer 5h. The microperforations are typically of the order of 0.1 mm to 1.0 mm in diameter.

Typically the reflective film 30h has an optical density of 2 to 2.5, as measured by a Tobias 25 Densitometer.

The emissivity of the microperforated reflective film 30h was measured according to ASTM C 1371-98, giving a value of typically 0.23 to 0.28, and in one case 0.14.

Figure 7(d) shows a typical pattern of 30 microperforations in the reflective film 30h which are P1292 IGB

! spaced apart, typically at around 4.5 mm and 5 mm, in an offset pattern as shown by arrows 60 and 65 respectively.

The microperforated offset pattern assists in maintaining the strength of the reflective film 30h.

5 As shown in Figure 7(c) the laminated breathable fabric lob comprises the reflective film 30h and the spunbond filamentous polymeric fabric layer 5h. The film 30h and spunbond 5h are intermittently bonded to preserve the moisture vapour transmission properties thereof in a 10 similar manner to the first and second embodiments. Such bonding may be performed using an embossed calender.

During lamination of the reflective film 30h to the spunbond layer 5h, the polymer layer 45h of the reflective film 30h is optionally caused to melt and 15 thereby adhere to the spunbond layer 5h. In this way, polymer layer 45h can be considered to be a so-called hot melt adhesive.

Like layers of the fabrics lOd;lOe;lOh comprise the same material as those of the fabrics 5a;5b of the first 20 and second embodiments. Particularly the spunbond layers 5d;5e;15e;5h can contain a W stabiliser and/or a hydrophobic additive.

Also the film 30d;30e, further spunbond 20d, membrane 15d;15e, and spunbond 5d;5e are intermittently 25 bonded to preserve the moisture vapour transmission properties thereof, in a similar manner to the first and second embodiments.

The laminated breathable fabric lOd;lOerlOh finds use as a breathable building or construction material 30 25d;25e;25h. The breathable building material P1 2421GB

25d;25e;25h can be adapted for use as a roofing underlay.

However, alternatively the breathable building material 25d;25e;25h can advantageously be adapted for use as a housewrap or wall breather membrane, or alternatively as 5 a temporary cover, e.g. a building cover or scaffolding cover, or tent, tarpaulin or the like. The breathable building material 25d, 25e, 25h may also find use as a flooring material.

The laminated breathable fabric lOd;lOe;lOh is 10 manufactured by a method comprising the steps of: providing the reflective film 30d;30e;30h forming a filamentous polymeric fabric 5d;5e;5h and forming the reflective film 30d;30e;30h and filamentous polymeric fabric 5d;5e;5h into the laminated breathable fabric 15 lOc;lOd;lOh. The step of providing the reflective film 30d;30e;30h may be carried out using the apparatus of Figure 5 or Figures 6(a) and (b).

In respect of reflective film 30d;30e, the reflective material is a metallic material or a metal, 20 and the polymeric material and reflective material are provided as a metallised polymer master-batch. The metal, e.g. aluminium, is finely ground and added to a polymeric melt used to produce the reflective membrane.

The manufacture of such a membrane comprising a 25 microporous polypropylene film is described in EP 0283 200 A by Exxon. The aluminized masterbatch is a concentrate of finely ground aluminium particles in a suitable carrier to give good dispersion throughout the melt. P] 292 IGB

The step of forming is carried out by calendering.

Such method may be carried out "OFF-LINE': using the apparatus of Figures 2 and 3 or "ON-LINE'' using the apparatus of Figure 4.

5 The fabric 10d may comprise a reflective film 30d having a weight of around 30 g/m2, a membrane 15d having a weight of around 25 gtm2 to 35 g/m2 and a filamentous polymeric fabric layer 5d having a weight of around 60 g/m2 to 100 g/m2.

10 The fabric 10h may comprise a reflective film 30h having a weight of around 30 g/m2 and a filamentous polymeric fabric layer 5h having a weight of around 60 g/m2 to 100 g/m2.

It will be understood that breathable membranes are 15 typically inherently weak, and in order to achieve the high tensile and nail tear properties required by the construction industry, the membrane can be reinforced by combining it with a reinforcing layer or layers. The preferred reinforcing layer(s) as disclosed is a nonwoven 20 fabric produced by a spunbonding process referred to herein as a spunbond', but other types of reinforcing, such as a carded nonwoven fabric or a woven fabric or scrim, may be provided, either in place of the spunbond or in addition to the spunbond.

THIRD EXAMPLE

Referring to Figure 8(a) there is illustrated a woven polymeric fabric 5f according to a seventh embodiment of the present invention, strands of which Y12921GY

comprise a polymeric material and a reflective material.

The strands are in the form of tapes 35f.

The reflective material is capable of reflecting at least infra-red (JR) radiation/heat. The reflective 5 material typically substantially comprises a metal or metallic based material, and in this embodiment comprises aluminium or an alloy thereof.

The polymeric material can comprise additives such as ultra-violet (W) stabiliser, hydrophobic additives, 10 flame retardants, pigments (e.g. colour pigments) and/or plasticisers. The tapes 35f can be of a monolayer construction.

Alternatively, the tapes 35f can be of a multi-layer construction. In a multi-layer construction the 15 reflective material can be added to an inner layer of a co-extruded tape 35f. In one embodiment the multi layered tape 35f is a three layer construction, wherein a centre layer contains the reflective material and the outer layers contain a W stabilizer.

20 A breathable fabric lOf comprises in part woven polymeric fabric 5f. The construction of the woven fabric 5f is selected so as not to impair moisture vapour transmission properties of the fabric lOf.

The breathable fabric lOf comprises a laminate 25 material including a first layer comprising the woven polymeric fabric 5f and a second layer comprising a breathable polymeric membrane 15f. The first and second layers 5f,15f are intermittently bonded together preferably to preserve the moisture vapour transmission 30 properties thereof.

P) 2923GB

! The breathable fabric lOf comprises a third layer of filamentous polymeric material 20f, the first, second and third layers Sf,15f,20f being intermittently bonded together to preserve the moisture vapour transmission 5 properties thereof.

The breathable fabric lOf thus comprises a laminate material including a first layer comprising the woven polymeric fabric 5f, and a second layer comprising a breathable polymeric membrane 15f. The first layer 5f 10 comprises a top layer and the second layer 15f comprises an under layer. The first and second layers 5f,15f are stabilized respectively against ultra-violet light degradation and heat degradation. The breathable polymeric membrane 15f comprises a W stabilized 15 breathable membrane, which may or may not have a hydrophobic treatment applied via the melt or topically.

In an eighth embodiment as shown in Figure 8(b) the laminate lOg is further provided with a further spunbond fabric 2lg between the woven fabric 5g and the membrane 20 15g. Thus in the seventh embodiment the breathable fabric lOg further comprises a fourth layer of filamentous polymeric material 21g between the woven polymeric fabric 5g and the membrane 15g.

The first layer 5g, fourth layer 21g, second layer 25 15g and third layer 20g are advantageously intermittently bonded preferably to preserve the moisture vapour transmission properties thereof.

The woven polymeric fabric 5f;5g/breathable fabric lOf;lOg find use as a breathable building material 30 25f;25g. The breathable building material 25f;25g can be Pl2921GB

adapted for use as a roofing underlay. However, the breathable building material 25f;25g can advantageously he adapted for use as a housewrap or wall breather membrane, or alternatively as a temporary cover, e.g. a S building cover or scaffolding cover, tent, tarpaulin or the like. The breathable building material may also find use as a flooring material.

The woven polymeric fabric 5f;5g is manufactured by a method comprising the steps of: providing a polymeric 10 material and a reflective material; forming the polymeric material and the reflective material into strands, e.g. tapes or threads; and weaving the strands together. The reflective material is a metallic material or a metal, and the polymeric material and reflective material are 15 provided as a metallised polymer masterbatch as is the first example.

The breathable fabric lOf;lOg is manufactured by a method comprising the steps of: forming the woven polymeric fabric 5f;5g; providing a breathable polymeric 20 membrane 15f;15g; and laminating the woven polymeric fabric 5f;5g and the breathable polymeric membrane 15f;15g one to the other.

Such method can be carried out using either of the tape forming apparatus 500, 600 of Figures 9 or 10, a 25 weaving loom (not shown), either of the membrane forming apparatus 300; 400, 450 of Figure 5 or Figures 6(a) and (b), respectively, and the lamination apparatus 150 of Figure 3.

The tape forming apparatus 500 of Figure 9 comprises 30 a spinneret apparatus having a polymer feed 501, an Pl29?:GB

extruded 502 including a tape extrusion means 503 for forming spun tapes 504, a quencher 505, an accumulator 506, an orientation/annealing means 507 and wind up spools 508.

5 The tape forming apparatus 600 of Figure 10 comprises a slit film apparatus having a polymer feed 601, an extruder 602 including a tape extrusion means 603 for forming a cast film 604, a chill roll 605, a film slitting means 606, an orientation/annealing means 607 10 and wind up spools 609 for tapes 610.

The fabric lOf,lOg may comprise a woven fabric 25f,25g, having a weight of around 50 g/m2, a membrane 15f,15g having a weight of around 30 g/m2, and a filamentous polymeric fabric 20f,20g having a weight of 15 around 30 g/m2 to 100 g/m2.

Referring now to Figure 11, there is shown a cross sectional side view of part of a building construction comprising a roof 700, e.g. a tiled roof, including a filamentous polymeric fabric 5a-5g/ breathable fabric 20 lOalOg as a roofing underlay and a plurality of tiles 701. As can be seen, the roof 700 may include a plurality of overlapping lengths of fabric 5a5g, lOa lOg. Referring finally to Figure 12, there is shown a 25 crosssectional side view of part of a building construction comprising a cavity wall 800 of a timber frame 801, including a filamentous polymeric material 5a-

5g/breathable fabric lOa-lOg as a ''housewrap", (i.e. an outermost skin 802 of a timber frame 801), the 30 construction being finished by external skin 803 P1292IGB

comprising bricks or the like. The building is typically constructed by erecting the timber frame 801 with outermost skin 802 and thereafter finished with the external skin 803.

5 It will be appreciated that the embodiments of the present invention hereinbefore described are given by way of example only, and are not meant to limit the scope of the invention in any way.

It will be understood that although the fabrics of 10 the present invention find particularly advantageous use in the building and/or construction industry, the fabrics of the invention may also find use in other sectors.

Normally in such use, including roofing and housewrap, the reflecting layer can be disposed so as to be outer 15 facing, e.g. to keep heat in and/or out. However, it will be appreciated that a reflective side of the breathable fabrics according to the present invention may be disposed outermost or innermost, e.g. in construction or building applications.

20 Also, a non-reflective/non-metallic side of a laminated fabric of the present invention may be non pigmented or pigmented. For example, the colour white is preferred to augment the non-IR absorptive aspect of the fabric. Alternatively, the non-reflective/non-metallic 25 side may be coloured, e.g. green.

Further, although the disclosed examples suggest calendering as the preferred lamination technique, other techniques may be suitable, e.g. ultrasonic spot welding or adhesive bonding.

P12921GB

l The preferred disclosed lamination process is a thermal bond technique; hence one should select polymers for the membrane and reinforcing fabric(s), which are thermally compatible. The lamination process may be 5 carried out in line, i.e. during the spunbond manufacturing process, when the membrane is fed on to the web on unbended fibres prior to calendering. The mass is then passed through the calender where the fibres are bonded to each other and to the membrane simultaneously.

10 Alternatively and beneficially the lamination may be carried out of line, i.e. as a totally independent process, where each component is already partly or wholly bonded, or is a microporous film. Components are passed simultaneously through a free standing calender with a 15 smooth and embossed roller. In either case, the embossed roller should have an embossing area of 72% to 35% of the surface area, and should have a diamond, round or other shape. The smooth roll should be of the swim roll type.

Other lamination methods, such as ultrasonic or 20 adhesive may be used, but it is desired that, whatever method is selected, bonding is carried out at discrete points only, so as not to impair the Moisture Vapour Transmission properties of the end product.

P12921GP

Claims

53.','.;

.......CLME:

. CLAIMS..CLME: 1. A laminated breathable fabric having as a layer thereof a reflective film or membrane.

2. A laminated breathable fabric as claimed in claim 1, wherein the reflective film or membrane comprises a moisture vapour permeable and air/gas permeable film.

10 3. A laminated breathable fabric as claimed in either of claims 1 or 2, wherein the reflective film or membrane comprises a microperforated or microporous metallised film.

4. A laminated breathable fabric as claimed in claim 3, wherein the microperforated or microporous metallised film comprises microperforations or micropores of around 0.1 mm to 15 mm in diameter.

20 5. A laminated breathable fabric as claimed in either of claims 3 or 4, wherein the microperforations or micropores have a size of around 0.1 mm to 1.0 mm.

6. A laminated breathable fabric as claimed in any of 25 claims 3 to 5, wherein the miroperforations or micropores are around 0.6 mm in diameter.

P12 'lGB

54 '.: ' '.

( 7. A laminated breathable fabric as claimed in any of claims 3 to 6, wherein the microperforations or micropores have a surface coverage of around 2% to 10%.

5 8. A laminated breathable fabric as claimed in any of claims 3 to 7, wherein there are provided around 30 microperforated holes/inch.

9. A laminated breathable fabric as claimed in any 10 preceding claim, wherein the reflective film or membrane comprises a polymeric material and a reflective material.

10. A laminated breathable fabric as claimed in claim 9, wherein the reflective material is capable of reflecting at 15 least infra-red radiation and/or heat.

11. A laminated breathable fabric as claimed in any preceding claim, wherein the reflective film or membrane has an emissivity of about 0.1 to about 0.6.

12. A laminated breathable fabric as claimed in claim ll, wherein the reflective film or membrane has an emissivity of about 0.1 to about 0.3.

25 13. A laminated breathable fabric as claimed in any claim 9, wherein the reflective material substantially comprises a metal or metallic based material.

P12921GB

c J 14. A laminated breathable fabric as claimed in claim 13, wherein the metal or metallic based material comprises aluminium or an alloy thereof.

5 15. A laminated breathable fabric as claimed in any preceding claim, wherein the reflective film or membrane comprises a single layer film or membrane or a multiple layer film or membrane.

10 16. A laminated breathable fabric as claimed in any preceding claim when dependent upon claim 9, wherein the reflective film or membrane comprises a three layer film or membrane, wherein a middle layer includes the reflective material. 17. A laminated breathable fabric as claimed in either of claims 15 or 16, wherein the reflective film or membrane is of an "AB" or "ABA" type, wherein "A" is a first polymeric material optionally including a W stabilizer, and "B" IS a 20 second polymeric material including the reflective material. lS. A laminated breathable fabric as claimed in claim 9, or any of claims 1G to 17 when dependent upon claim 9, 25 wherein the reflective material is provided as an additive to a polymeric material melt used to produce the reflective film or membrane.

P12921Gh

56:.. ' ' '.

( 19. A laminated breathable fabric as claimed in either of claims 15 or 16 when dependent upon claim 9, wherein the reflective film or membrane comprises a multiple layer film or membrane, wherein a middle layer comprises the 5 reflective material deposited onto one of the layers.

20. A laminated breathable fabric as claimed in either of claims 15 or 16 when dependent upon claim 9, or claim 19, wherein the reflective film or membrane is of an "AC" or 10 "ACA'' type in which "A" is a first polymeric material, optionally including a W stabilizer, and "C" is a reflective material deposited onto one of the first polymer material layers "A".

15 21. A laminated breathable fabric as claimed in claim 20, wherein the first polymeric layer "A" is around 10 Em to 30 Em in thickness.

22. A laminated breathable fabric as claimed in either of 20 claims 20 or 21, wherein the reflective material layer "C" is around lo nm to 100 no thick.

23. A laminated breathable fabric as claimed in any of claims 19 to 22, wherein the reflective material layer is 25 deposited by a deposition process such as vacuum vapour deposition or plasma deposition.

24. A laminated breathable fabric as claimed in claim 9, wherein the polymeric material(s) comprises one or more P12 92 1GB

57.. f additives selected from ultra-violet (UV) stabilizers, hydrophobic additives, flame retardants, pigments, colour pigments, and/or plasticisers.

5 25. A laminated breathable fabric as claimed in either of claims 9 or 24, wherein the polymeric material(s) is a thermoplastic polymer(s) selected from polypropylene, polyamide or polyester.

10 26. A laminated breathable fabric as claimed in any preceding claim, wherein the fabric comprises at least one breathable polymeric film or membrane layer and/or at least one filamentous polymeric fabric layer.

15 27. A laminated breathable fabric as claimed in claim 26, wherein the reflective film or membrane is laminated to the at least one breathable polymeric membrane or the reflective film or membrane is laminated to the at least one filamentous polymeric fabric layer.

28. A laminated breathable fabric as claimed in either of claims 26 to 28, wherein the laminated breathable fabric comprises the reflective film, a breathable polymeric membrane and a filamentous polymeric fabric layer 25 comprising a spunbond layer, the film, membrane and spunbond layer being intermittently bonded to preserve the moisture vapour transmission properties thereof.

Pl 921CB

d: 58:' ' ' ' '

( 29. A laminated breathable fabric as claimed in claim 28, wherein a further spunbond layer is provided between the film and membrane, the further spunbond layer providing additional strength, the further spunbond layer containing 5 an ultra-violet stabiliser and/or a hydrophobic additive, and the film, further spunbond layer, membrane and spunbond layer being intermittently bonded to preserve the moisture vapour transmission properties thereof.

10 30. A laminated breathable fabric as claimed in any preceding claim, wherein the laminated breathable fabric includes a woven fabric layer.

31. A laminated breathable fabric having as a layer 15 thereof a metal or metallised film or membrane.

32. A breathable building or construction material comprising a laminated breathable fabric as claimed in any of claims 1 to 30 or claim 31.

33. A breathable building material as claimed in claim 32, wherein the breathable building material is adapted for use as a roofing underlay, a housewrap, a wall breather membrane, or for other construction uses such as a 25 temporary cover or as a flooring material.

34. Use as a building or construction material of a laminated breathable fabric as claimed in any of claims 1 to 30 or claim 31.

Pl292 IGS

59: 35. A method of manufacturing a laminated breathable fabric comprising the steps of: providing a reflective film; providing a filamentous polymeric fabric; and 5 forming the reflective film and filamentous polymeric fabric into a laminated breathable fabric.

36. A method of manufacturing a laminated breathable fabric as claimed in claim 35, wherein the step of forming 10 is carried out by calendering.

37. A method of manufacturing a laminated breathable fabric as claimed in claim 36, wherein the reflective film is a microperforated film such as an "AB", "ABA", "AC" or 15 "ACA" construction, and the step of providing the film comprises the steps of forming the film and then microperforating the film.

38. A method of manufacturing a laminated breathable 20 fabric comprising the steps of: providing a metal or metallised film; providing a filamentous polymeric fabric layer; and forming the metal or metallised film and filamentous polymeric fabric into a laminated breathable fabric.

39. A building construction including a laminated breathable fabric as claimed in any of claims l to 30 or claim 31.

P12'321GB

an. . v À ... ! 40. A building construction including a laminated breathable fabric as claimed in claim 39, wherein the building construction comprises: a roof, a tiled roof, a pitched roof, a timber frame, a cavity wall or a floor.

41. A building including a building construction as claimed in either of claims 39 or 40.

42. A laminated breathable fabric comprising at least one 10 breathable polymeric film or membrane layer laminated to at least one filamentous polymeric fabric layer, wherein a reflective material is provided on the breathable polymeric film or membrane layer.

15 43. A laminated breathable fabric comprising at least one breathable polymeric film or membrane layer, laminated to at least one filamentous polymeric fabric layer, wherein a metallic material is provided on the breathable polymeric film or membrane layer.

44. A filamentous polymeric fabric, filaments of which comprise a polymeric material and a reflective material.

45. A filamentous polymeric fabric filaments of which 25 comprise a polymeric material and a metallic material.

46. A woven polymeric fabric strands of which comprises a polymeric material and a reflective material.

P12921GP

47. A woven polymeric fabric strands of which comprise a polymeric material and a metallic material.

5 48. A fabric comprising: a polymeric fabric comprising a polymeric material and a reflective material, or a polymeric material layer having formed thereon a continuous breathable layer comprising or including a 10 reflective material.

49. A fabric comprising: a polymeric fabric comprising a polymeric material and a metallic material, or 15 a polymeric material layer having formed thereon a continuous breathable layer comprising or including a metallic material.

50. A laminated breathable fabric as hereinbefore 20 described with reference to the accompanying drawings.

51. A breathable building or construction material as hereinbefore described with reference to the accompanying drawings. 52. Use as a building or construction material of a laminated breathable fabric as hereinbefore described with reference to the accompanying drawings.

P' 2 9 2 1 C3

- 62:,;,,:,

/ 53. A method of manufacturing a laminated breathable fabric as hereinbefore described with reference to the accompanying drawings.

5 54. A building construction including a laminated breathable fabric as hereinbefore described with reference to the accompanying drawings.

55. A building including a laminated breathable fabric as 10 hereinbefore described with reference to the accompanying drawings. P] 2921GB