GB2367783A - Moulding a door skin using a press - Google Patents

Abstract

A method of manufacturing a door skin includes the steps of providing a wood composite flat blank 10. The blank 10 is placed between the platens 46,48 of a heated press 44, the platens 46,48 being heated to a temperature sufficient to soften the resins in the blank 10 and to thereby soften the blank 10. Sufficient pressure is applied to close the platens 46,48 and thereafter the pressure is applied to increased pressure levels for thereby causing the blank to be deformed into a molded shape determined by the configuration of the platens 46,48. The press 44 is degassed and the molded blank is then removed from between the platens 46,48.

Description

METHOD OF MANUFACTURING A MOLDED DOOR SKIN FROM A WOOD COMPOSITE The disclosed invention is to a method for manufacturing a molded door skin from a wood composite material. More particularly, the disclosed invention is to a method for manufacturing a molded door skin in which a solid blank sheet of wood composite material is heated in a press to a temperature sufficient to soften the blank, after which the press platens are pressure actuated to close and the pressure thereafter cyclically increased to thereby deform the blank into a molded configuration suitable for a door skin and ultimately for being assembled into a door.

Hollow core doors are used in both interior and exterior applications. A hollow core door may be a flush door, that is one flat or planar on both major surfaces.

Alternatively, the hollow core door may be a"molded" door, that is one having a series of three dimensional panels formed into the skins as they are being manufactured. Molded door skins are relatively expensive, because the capital cost is quite high due to the need for dies, presses, and the like. The skins used for flush doors, on the other hand, are relatively inexpensive, but they do not provide the aesthetic features sometimes required by consumers.

Many hollow core doors are made from door skins formed from wood composite materials. These wood composite materials may include particle board, flake board, hard board and medium density fiber board ("MDF").

The wood composites utilize a resin binder, which frequently is a thermal setting resin, in order to maintain the wood fibers forming the composite in solid form. The wood composites are not moisture impervious, so doors utilizing such skins may not be suitable for exterior applications. Should the composite material absorb moisture, whether in liquid or gas form, then the door components may swell and the door distort.

Fiberglass and steel doors do not have the same moisture absorbing tendency, and hence are more frequently used for exterior applications.

Because of the cost differential between a wood composite flush skin and a wood composite molded skin, attempts have been made to transform flush skins into molded skins. Those prior efforts have not resulted in a commercially acceptable door skin, principally because the appearance of the surface is not satisfactory. Prior efforts to transform a flush skin into a molded skin have generally resulted in a skin having a cracked, marred, or otherwise aesthetically unpleasing configuration and appearance.

Standard molded door skins are formed from a relatively thick mat or bat of material, which is thereafter compressed in a press to a relatively thin thickness. The mat is dry in the case of MDF or has a very high water content in the case of hard board, with the result for the latter that the water is squeezed out during the pressing operation. Because the mat is in a very flexible state during the pressing operation, then the resulting skin has sharply defined features acceptable to consumers because the wood fibers can flow in order to conform to the mold. Due in part to the high capital costs involved to create molded skins, the manufacturer frequently requires that an individual order be for a large number of skins in order to permit maximum operating efficiencies. Smaller orders become cost prohibitive.

Those skilled in the art will recognize that there is a need for a method of manufacturing a molded door skin from a wood composite which permits a standard flush skin blank to be used as the base material, and which results in a molded door skin having the features and surface characteristics acceptable to consumers.

A method of manufacturing a door skin, according to the invention, comprises the steps of: a) providing a wood composite flat blank; b) placing the blank between the platens of a heated press, the platens being heated to a temperature sufficient to soften a resin in the blank and to thereby soften the blank; c) closing the platens; d) applying the pressure to the platens, thereby causing the blank to be deformed into a molded shape determined by a configuration of the platens ; e) degassing the press; and f) removing the molded blank from between the platens.

The above and other objects and advantages and novel features of the present invention will become apparent in view of the following detailed description of the preferred embodiment of the invention, illustrated in the accompanying drawings, wherein: Fig. 1 is a schematic flow chart of a manufacturing process of the invention ; Fig. 2 is a fragmentary cross sectional view of the flat blank used with the invention; Fig. 3 is a fragmentary cross sectional view of a molded skin; Fig. 4 is a fragmentary cross sectional view of the blank of Fig. 2 between the platens of the press used with the invention ; Fig. 5 is a graph illustrating pressure versus time in a first cycle according to one embodiment of the invention; Fig. 6 is a graph illustrating pressure versus time for a second cycle according to the invention; Fig. 7 is an elevational view of a molded door; and Fig. 8 is a fragmentary cross sectional view taken along the line 8-8 of Fig. 7.

Flush flat wood composite blank 10, as best shown in Fig. 2, has oppositely disposed parallel, planar surfaces 12 and 14. The blank 10 is a wood composite, preferably one bound together with thermal setting resins, such as medium density fiber board or hard board. MDF frequently uses urea formaldeyde resin as the binder, which material softens or melts at temperatures of between 320 F. to about 425 F. MDF blanks are available in various thicknesses and weights, ranging from 3 millimeters to 7 millimeters. I prefer that the blank 10 be relatively thick, in order to make available wood fiber material which may stretch during the pressing operation in order to provide sharp, well defined features. Flat blank 10 is transformed into a molded skin 16, as best shown in Fig. 3, through the process illustrated in Fig. 1. Fig. 3 illustrates the design element 18 which is formed in the skin, in order to provide the aesthetic appearance of, for example, the skin used with the door 20 of Fig.

7. The skin 16 of Fig. 3 has opposed surfaces 22 and 24, formed from the surfaces 12 and 14 of the blank 10. The skin 16 has parallel first portion 26 and second portion 28. The second portion 28 is integral with planar first portion 26 through offset portions 30 and 32. The offset portions 30 and 32 preferably have a configuration facilitating removal of the skin 16 from the platens of the press upon conclusion of the forming process. The portions 26,28, 30 and 32 have different thicknesses due to the stretching process forming skin 16. For example, with a blank 10 having a thickness of 4 mm, then the first portion 26, forming part of the skin major surface, and the second portion 28 may have a thickness of slightly less than 4 mm, and the offset portions 30,32 a thickness of about 3 mm due to the compression resulting from the stretching performed upon the blank 10 in order to create the design element 18. The amount of compression achieved however is directly proportional to the initial density, for example with a material having a density of 600 kg/m3 the amount of compression could be as high as 25% but with a higher density material, say 800 kg/m3, the amount could be as low as 5 to 10%.

Flush blank 10 is received at loading station 32 of Fig. 1. The blank 10 has a density of about 750 to about 800 Kg/m3, and a thickness of from about 3 mm to about 7 mm. The blank 10 has an initial moisture content of about 8% by weight.

Blank 10 is then forwarded to a sealing station 36, where a liquid or foam sealant is applied by roll coating, spraying, or curtain coating. The sealant is applied in solution with a solid to fluid ratio of 2/3: 1 and at a dry weight of about 2 to about 3 gm/ft2. The sealant is applied only to what is to be the exterior surface of the skin 16 resulting from the blank 10, so that the wood fiber of opposite surface 22 is available to accept the polyvinyl acetate (PVA) used for adhesively securing the skin 16 to the door frame. The sealer may be dried at 38, such as with an infrared lamp. The sealant applied to the surface 14 may contain a colorant, such as when the door 20 is suitable for staining.

Numerous sealers are known in the art. Preferably the sealer is an impress sealer, such as available from Akzo Noble. The sealer helps to clean the mold, aids in elasticity of the wood fiber, and improves the definition of the surface features.

From drier 38, the blank 10 is then preferably and optionally transferred to steam vessel 40. The blank 10 is exposed to a low pressure saturated steam within vessel 40. While in the vessel 40, the temperature of the blank 10 increases, and the blank 10 also absorbs moisture so that it exits the vessel 40 with a moisture content of about 15 to about 20% by weight. As noted previously, the resins binding the wood composite and wood fibers of the blank 10 are thermal setting resins, and the temperature increase in the vessel 10 begins the process of remelting the resin and thereby causing the blank 10 to become relatively soft.

I have also found that increasing the moisture content in the vessel 40 may be facilitated by sanding the blank 10 on both surfaces before starting the process. Sanding the surfaces appears to remove the resin located at the surface, so that moisture absorption is increased. Those skilled in the art recognize that wood fibers swell as moisture is absorbed, so the steam applied in vessel 40 serves the purpose of expanding the wood fibers, so that same may thereafter be stretched during the forming process, and also melting the resin in order to soften the blank 10.

I have found that low pressure steam should be used in the vessel 40. Moreover, care must be taken in how long the blank 10 is exposed to the steam. Should the blank be exposed to the steam for less than 30 seconds, then there may not be sufficient moisture absorption for wood fiber swelling, nor sufficient heat for resin softening. Should the blank 10 be exposed to the steam for too long, such as for more than one minute, then I have found that the surfaces 12 and 14 of the blank 10 tend to become blistered and discolored. Should the surface be blistered or discolored, then the resulting skin may not be suitable for a commercially acceptable door skin, or may require further processing.

Although I prefer that the blank 10 be exposed to moisture in the form of steam, those skilled in the art will recognize that other processes may be utilized. For example, mists of water may be sprayed onto the surfaces of the blank 10, followed by microwave or infrared heating. Regardless of how applied, moisture absorption is desirable in order to facilitate wood fiber swelling.

As elsewhere explained, moisture absorption may not be necessary in certain instances, where longer press times are available. With steam vessel 40 and a 4 mm thick blank 10 of MDF, the cycle time may be so quick as 40 seconds.

From steam vessel 40, the blank 10 may be transported to barrier station 42, at which a moisture impervious barrier is applied to exterior surface 14 over the sealer. The moisture impervious barrier need only be applied for those skins intended for exterior applications. Its use gives an improved finish and it can therefore be employed to advantage for internal applications where superior appearance is desired. I prefer that the moisture impervious barrier be either a melamine impregnated crepe paper or a phenolic resin crepe paper applied over the sealer. A suitable paper may be purchased from Akzo Nobel under their name SWEDOTECO flexible primer films TGPN and TXP. I prefer the use of a crepe paper substrate for applying the resin, because crepe paper has an expansion factor sufficient to accommodate the expansion which occurs when the design element 18 is formed. The crepe paper therefore will not rip, tear, or otherwise provide an interrupted surface through which moisture could migrate.

Those skilled in the art will recognize that the cross linking polymeric resin system forming the moisture barrier may alternatively be applied as a two component liquid, sprayed or otherwise applied to the surface 14.

Other sorts of moisture barriers are also useful.

A further advantage of the crepe paper barrier is that same may be colored, such as to permit a wood grain or other pattern or ornamentation to be applied to the resulting surface 24. The moisture impervious barrier also adds hardness to the skin, and provides abrasion resistance. Improved abrasion resistance is helpful during shipping, where the skins and doors may become scratched or otherwise marred. The resin takes about 40 seconds to cure, and seals the face of the skin. The stretched portion of the blank 10 forming the design element 18 is susceptible to swelling, so the moisture barrier reduces that possibility.

The blank 10 then is transferred to press 44, in which the configuration of Fig. 3 is impressed. I prefer that the press be a high pressure press of about 2,500 tons, in order to apply as much as 1. 2 tons per square inch pressure to the blank 10 during the pressing operation. The press 44 has platens 46 and 48, as best shown in Fig. 4. The platens 46 and 48 are each preferably a chrome plated steel die, preferably a hard chrome plating having a 70 Rockwell hardness. I prefer that the surfaces 50 and 52 of the platens 46 and 48 have the hard chrome plating, in order to resist accumulation of wood sugars which otherwise might occur.

Each of the platens 46 and 48 preferably has a thickness of about 4 inches, and each of the platens 46 and 48 is heated. I prefer that the platens 46 and 48 be electrically heated, such as by a Kalrod, although oil circulation or steam circulation may be acceptable heat media. However heated, I prefer that the platens be maintained at a relatively high temperature of between about 3200F. and 425 , and more preferably between 370 F. and 380 F. The high temperature should be maintained throughout the pressing operation, which takes about 60 seconds with preconditioning and about 4 minutes without, in order to assure that the binding resin in the blank 10 remelts and remains flowable during the pressing operation.

The platen 46 has a male die element 54, with the platen 48 having a female die element 56. Preferably the die elements 54 and 56 are mirror images, in order to prevent the formation of thickness variations in the resulting skin. The press 44 causes that portion of the blank 10 forming the design element 18 to be expanded or stretched, so thickness variations, as could arise if the die elements 54 and 56 were not mirror images, could result in non-uniform flowing of the softened wood composite material. While Fig. 4 discloses only simple die elements 54 and 56, those skilled in the art will recognize that the molded door of Fig. 7 will require die elements with multiple apertures, the exact number and shape being dependent upon the configuration, size, and appearance of the door. The process through use of different die elements is suitable for manufacture of all currently known door designs.

I have found that the blank 10 may be transformed into a commercially acceptable molded skin 16 through softening the blank 10 initially in the steam vessel 40, and thereafter pressing the blank 10 between the platens 46 and 48 in response to a cyclic increasing pressure regimen. Moreover, I have found that an acceptable molded skin 16 may be formed when the press 40 has means permitting degassing of the blank 10 in order to remove air, steam, vapor, and other volatiles, which otherwise could blister the surfaces of the skin. Degassing may be achieved by releasing the pressure, as is shown in the Fig. 5 graph, or by providing vents in the platens, as is shown in the Fig. 6 graph. Regardless of how the degassing is accomplished, I have found that an acceptable molded skin 16 may be formed where the pressure is cyclically applied at ever increasing levels, in order to cause the wood fiber and resin to flow until the desired configuration is achieved while also providing a means to remove gases.

Fig. 5 discloses pressure versus time for a press 40 in which pressure in the platens 46 and 48 is cyclically released in order to degas the blank 10. As best shown in Fig. 5, the blank 10 is placed between the platens 46 and 48, such as shown in Fig. 4, in the region 58. The pressure is then relatively slowly increased at 60 to a first predetermined pressure. Once the first predetermined pressure is achieved, then it is maintained at 62 for a period of time sufficient to further heat the resin and to cause the wood fibers and resin to begin to flow. The pressure within platens 46 and 48 is then released at 64, and the blank 10 degassed from there through 66. The pressure is then increased at 68, and maintained at 70. The pressure maintained at 70 is higher than the pressure maintained at 62. The rate of increase of the pressure at 68 is much quicker than the relatively slow increase at 60, because I have found that an initial relatively low rate of pressure increase causes less stress to be applied to the wood fibers and the resin. They move more slowly, in view of their relatively hard and expanded condition. Once the initial configuration of the skin 16 is achieved through pressure application at 62, then the subsequent cycles serve the purpose of sharpening the definition of the design element 18 while also smoothing the surface 24 by allowing resin to accumulate at the surface.

After the pressure has been maintained at 70, then the pressure is again released at 72, in order to permit degassing to occur to 74. The pressure is increased at 76, maintained at 72 at a level higher than at 70, and then relieved at 80 in order to permit degassing at 82.

The pressure is then rapidly applied at 84, maintained at 86, and then relieved at 88. Degassing occurs at 90, followed by pressure application at 92, pressure maintenance at 94, and pressure release at 96. The skin 16 may then be removed from the mold at 98.

I have found that the pressures 70,78, 86, and 94 should each be higher than the peak pressure achieved in the immediately precedent cycle. Peak pressure at 94 may be 1.2 tons per square inch, which is a relatively high pressure. I have also found that the end maintenance periods 86 and 94 should be longer than the previous cycles 62,70, and 78, in order to provide better definition to the design element 18. I prefer that there be between 3 and 6 pressure cycles, of ever increasing peak pressure. The ever increasing peak pressures, in combination with maintaining platens 46 and 48 at the elevated temperatures, cause the wood fibers to change their state to form the contour of design element 18, cause the blank 10 to remain relatively soft, and improve the surface finish of the surface 24, so that same is commercially acceptable and suitable for painting, staining, or other ornamentation.

I have found that the number of pressure cycles and the degree to which the platens 46 and 48 close will vary, depending upon the thickness of the blank 10 and the material from which it is made. The pressure may be controlled by either regulating the spacing between the platens 46 and 48, or by regulating the pressure applied to the platens for closing them. Typically, only one of the platens 46 and 48 will be moveable relative to the other, so control over the hydraulic pressure, applied to the movable platen is effective for controlling the pressure cycle.

As noted earlier, although I prefer that the blank 10 be moistened in steam vessel 40 in order to soften the resin and swell the wood fibers, same is not necessary if the press cycle is sufficiently long. In that event, the blank 10 will be dry when placed into the press 44, with a moisture content of about 8%. Because the platens 46 and 48 are heated, then they provide sufficient heat through radiation to soften the resin and thereby the blank 10. Although the wood fibers in the blank 10 will not swell and thereby have additional enhanced flowability, a relatively long press cycle will minimize impacts in that regard.

Fig. 6 discloses a pressure versus time cycle where the platens 46 and 48 have vents therethrough for permitting degassing to occur. Thus there is no need to release the pressure, but I have found that there continues to be a need for ever increasing peak pressure and a need to maintain those peak pressures.

The blank 10 is placed into the mold at 100, and the pressure slowly increased at 102. The pressure is maintained at 104, and then increased at 106. It should be recognized that with vented platens 46 and 48, degassing occurs substantially continuously throughout the pressing cycle. The pressure is maintained at 108 and then increased at 110. The pressure is then increased at 114, and maintained at 116. The pressure is increased at 118, and maintained at 120. The pressure is increased at 122, maintained at 124, and then reduced at 126 in order to permit the blank 16 to be removed at 128.

I have found that completion of the pressing cycles of Figs. 5 and 6 causes the skin 16 to have an as-removed moisture content of about 3% to about 4% by weight. Thus, because of the heat applied by the platens 46 and 48, the moisture content of the blank 10 is substantially reduced during the formation process. It could be lowered even further by increasing the press time.

Additionally, the resultant finished skin 16 has a density of about 800 to about 1,000 Kg/m3, higher than the density of blank 10. The increased density makes the skin 16 harder, thus improving the strength of the resulting door. Additionally, the increased density provides a better surface for painting. This increased density is attributable to the pressing applied to the blank 10 by the platens 46 and 48.

Formation of the design element 18 causes that portion of the blank 10 forming the design element 18 to be expanded or stretched by about 15% to about 25% by length, as shown in Figure 3 by the arrows A-A.

Moreover, the portion 28 of design element 18 has a reduced thickness on the order of about 25%, due to the need to provide wood fiber for the increased length.

Once the skin 16 has been removed from the press at 98 or 128, then it is forwarded to the reconditioning station 130 at which the skin 16 is remoistened to a moisture content of about 8%. Trimming and primming may be performed after remoisturising. Priming is not necessary if the crepe paper barrier is used. The remoistening may be achieved by water mists or the like or passing the skin across a water bath. A wetting agent may be added to the water to improve the rate of absorption. Once reconditioned, then the skin is transferred to door forming station 132, at which each skin is adhesively secured to a door frame, preferably a wooden frame, in order to form a door. Fig. 7 discloses an exemplary door. Should the door 20 of Fig. 7 be an exterior door, then a further moisture impervious barrier may be applied to the exposed edges of the frame at 134 by edge banding or painting.

Fig. 8 discloses a fragmentary cross sectional view of an exterior door pursuant to the invention, having molded door skins 16 adhesively secured to frame 136, such as with PVA. Those skilled in the art will recognize that the frame 136 extends about the periphery of the rectangular skins 16, and typically will comprise two wooden stiles extending along the longitudinal edges and two wooden rails extending horizontally and vertically. Additionally, while I disclose that the skins 16 are spaced apart, they may have a core, such as provided by foam disposed between them.

Melamine impregnated crepe paper or phenolic resin crepe paper 138 is disposed wholly about the exterior surface 24 of the outer most skin 16. As noted previously, the melamine impregnated or phenolic resin crepe paper 138 provides a moisture impervious barrier minimizing water absorption by the door 20. Other cross linkable moisture barriers may of course be used with the invention. In order to further increase the moisture resistance of the door 20 of Fig. 7, then an additional moisture impervious barrier 140 may be applied to the exposed edges 142 of the frame 136 and the edges 144 of the skins 16. This further barrier 140 may also be a melamine impregnated or phenolic resin crepe paper. I have found that the crepe paper is so thin, that same may overlap the layers 138 without imparting an undesirable appearance to the surface. The barrier 140 must also be cross linked, and this may occur by infrared heating or the like. The barriers 138 and 140, and the surface 24 having no barrier, are suitable for painting, staining, or other ornamentation.

Claims (13)

1. A method of manufacturing a door skin, comprising the steps of: a) providing a wood composite flat blank ; b) placing the blank between the platens of a heated press, the platens being heated to a temperature sufficient to soften a resin in the blank and to thereby soften the blank; c) closing the platens; d) applying the pressure to the platens, thereby causing the blank to be deformed into a molded shape determined by a configuration of the platens; e) degassing the press; and f) removing the molded blank from between the platens.

2. The method of claim 1, wherein: a) the blank contains volatile components other than moisture that are degassed out of the press during said application of pressure to the platens.

3. The method of either claim 1 or Claim 2, wherein: a) said degassing is performed during said application of pressure to the platens.

4. The method of claim 3, wherein: a) each of the platens has at least one vent through which said degassing occurs.

5. The method of any preceding claim, wherein: a) each of the platens includes at least one aperture for determining the molded shape of the blank being deformed.

6. The method of any preceding claim, wherein: a) at least one portion of a first major surface of the molded blank is non-planar.

7. The method of any preceding claim, including the step of: a) reducing a thickness of at least one portion of the blank by at least about 5%.

8. The method of claim 7, wherein: a) the at least one portion of the blank is reduced in thickness by no greater than about 25%.

9. The method of claim 8, including the step of: a) maintaining application of pressure to the platens at a level of up to about 1.2 tons per square inch.

10. The method of any preceding claim, including the step of: a) selecting as the blank a wood composite flat blank having a density before placement of the blank between the platens of less than about 800 kg/m'.

11. The method of any preceding claim, including the step of: a) selecting as the blank a wood composite flat blank having a density before placement of the blank between the platens of greater than about 600 kg/m3.

12. The method of either claim 10 or claim 11, wherein: a) the blank has a density after removal of the blank from between the platens of no greater than 1,000

kg/m\

13. The method of either claim 10 or claim 11, wherein: a) the blank has a density after removal of the blank from between the platens of between 800 and 1,000 kg 1m3.

13. The method of either claim 10 or claim 1, wherein: a) the blank has a density after removal of the blank from the platens of greater than 800 kg/m3.

14. The method of any preceding claim, including the step of: a) stretching a first portion of the blank by at least about 15% by length, as measured along a first major surface of the blank.

15. The method of claim 14, wherein: a) the first portion is stretched by no more than about 25% by length, as measured along the first major surface.

16. The method of any preceding claim, including the step of: a) increasing the moisture content of the flat blank to a preselected content prior to placing the blank between the platens.

17. The method of claim 16, including the step of: a) exposing the blank to low pressure steam in order to increase the moisture content.

18. The method of claim 16, including the step of: a) exposing the flat blank to saturated steam for a period sufficient to increase the moisture content to about 15% to about 20% per weight.

19. The method of claim 16, including the step of: a) exposing the flat blank to saturated steam for a period sufficient to increase the moisture content to at least about 15% by weight.

20. The method of claim 19, including the step of: a) decreasing the moisture content of the flat blank after placing the blank between the platens to a level of no more than about 4% by weight.

21. The method of any one of claims 16 to 18, including the step of: a) applying a sealer to a first major surface of the flat blank prior to increasing the moisture content.

22. The method of claim 21, including the step of: a) applying a sealer which is colored.

23. The method of either claim 21 or claim 22, including the step of: a) drying the sealer prior to increasing the moisture content.

24. The method of any preceding claim, including the step of: a) applying a moisture barrier to a major surface of the flat blank prior to placing the blank between the platens.

25. The method of claim 24, wherein the moisture barrier is cross linkable.

26. The method of claim 25, wherein the moisture barrier is impregnated with a melamine or phenolic resin.

27. The method of claim 24, including the step of: a) providing as the moisture barrier, a melamine or phenolic resin system.

28. The method of any preceding claim, including the step of: a) maintaining the platens at a temperature of from about 320ouf. to about 425 F.

29. The method of claim 28, including the step of: a) maintaining the platens at a temperature of from about 370 F. to about 380ouf.

30. The method of any preceding claim, wherein: a) the flat blank is self-supporting.

31. A door skin produced by the method of any preceding claim.

Amendments to the claims have been filed as follows

a) maintaining application of pressure to the

platens at a level of up to about 1. 2 tons per square inch.

10. The method of any preceding claim, including the step of: a) selecting as the blank a wood composite flat blank having a density before placement of the blank between the platens of less than about 800 kg/m3.

11. The method of any preceding claim, including the step of: a) selecting as the blank a wood composite flat blank having a density before placement of the blank between the platens of greater than about 600 kg/m3.

12. The method of either claim 10 or claim 11, wherein: a) the blank has a density after removal of the blank from the platens of greater than 800 kg/mn.