GB2354587A - Detecting abnormal temperature rise in cells of a battery - Google Patents

Detecting abnormal temperature rise in cells of a battery Download PDF

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Publication number
GB2354587A
GB2354587A GB0018024A GB0018024A GB2354587A GB 2354587 A GB2354587 A GB 2354587A GB 0018024 A GB0018024 A GB 0018024A GB 0018024 A GB0018024 A GB 0018024A GB 2354587 A GB2354587 A GB 2354587A
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United Kingdom
Prior art keywords
cells
temperature
battery unit
temperature sensor
sensors
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Granted
Application number
GB0018024A
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GB2354587B (en
GB0018024D0 (en
Inventor
Shoichi Toya
Hideki Okajima
Takashi Oda
Tadashi Furukawa
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Sanyo Electric Co Ltd
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Sanyo Electric Co Ltd
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Priority claimed from JP22328199A external-priority patent/JP3913411B2/en
Priority claimed from JP29604199A external-priority patent/JP3670907B2/en
Application filed by Sanyo Electric Co Ltd filed Critical Sanyo Electric Co Ltd
Publication of GB0018024D0 publication Critical patent/GB0018024D0/en
Publication of GB2354587A publication Critical patent/GB2354587A/en
Application granted granted Critical
Publication of GB2354587B publication Critical patent/GB2354587B/en
Anticipated expiration legal-status Critical
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/482Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for several batteries or cells simultaneously or sequentially
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/63Control systems
    • H01M10/637Control systems characterised by the use of reversible temperature-sensitive devices, e.g. NTC, PTC or bimetal devices; characterised by control of the internal current flowing through the cells, e.g. by switching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/64Heating or cooling; Temperature control characterised by the shape of the cells
    • H01M10/643Cylindrical cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/64Heating or cooling; Temperature control characterised by the shape of the cells
    • H01M10/647Prismatic or flat cells, e.g. pouch cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/651Means for temperature control structurally associated with the cells characterised by parameters specified by a numeric value or mathematical formula, e.g. ratios, sizes or concentrations
    • H01M10/652Means for temperature control structurally associated with the cells characterised by parameters specified by a numeric value or mathematical formula, e.g. ratios, sizes or concentrations characterised by gradients
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6551Surfaces specially adapted for heat dissipation or radiation, e.g. fins or coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6554Rods or plates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2200/00Safety devices for primary or secondary batteries
    • H01M2200/10Temperature sensitive devices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2200/00Safety devices for primary or secondary batteries
    • H01M2200/10Temperature sensitive devices
    • H01M2200/106PTC
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/204Racks, modules or packs for multiple batteries or multiple cells
    • H01M50/207Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
    • H01M50/213Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for cells having curved cross-section, e.g. round or elliptic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/249Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders specially adapted for aircraft or vehicles, e.g. cars or trains
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/42Grouping of primary cells into batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Automation & Control Theory (AREA)
  • Secondary Cells (AREA)

Abstract

A battery unit comprises a plurality of cells (1) and a smaller number of temperature sensors (5) adjacent thereto. Cells (1) without adjacent temperature sensors are connected to those with sensors to produce a mixed assembly. Heat collecting members (6) may be attached to the cells that do not have an adjacent sensor (5). The sensors may be PCT elements or thermistors. In another arrangement (figure 9) where all the cells have adjacent temperature sensors of the type which change in resistance with temperature, the sensors are divided into a plurality of blocks and in each block the sensors are connected in series. A temperature rise detecting circuit measures the resistance of each block and detects any abnormal temperature rise by comparing the resistance of the blocks of sensors with each other.

Description

2354587
Title of the Invention Battery Unit
This applications is based on applications No. 11-223281 filed in Japan on Aug.
6,1999, and No. 11-296041 filed in Japan on Oct. 19,1999, the contents of which incorporated hereinto by references.
Background of the invention
The present invention relates to a battery unit in which a plural number of cells are connected in series or in parallel, and especially to a battery unit which can detect abnormal temperature rise of at least one of a large number of cells constituting a battery unit for use in an electric car.
Battery units are widely known which are provided with temperature sensors such as PTC elements for detecting abnormal temperature rise of a cell so as to prevent deterioration, heating trouble and the like of the cell from occurring.
Further, electric power device devices for driving an electric car motor have been proposed, each of which contains a large number of cells electrically connected in series and can provide high voltage and high current. And electric power devices for use in electric cars are known each of which is provided with temperature sensors. Such an electric power device has been disclosed, for example, in Japanese Non-examined Patent Publication No.270094/1998.
In the electric power device disclosed in the Publication, a temperature sensor is adhered to each of the cells constituting a battery unit, and abnormal temperature rise is detected by measuring total electric resistance of the temperature sensors.
However, the electric power device disclosed in this Publication requires the same number of temperature sensors with that of the cells constituting the I device, since a temperature sensor is adhered to each of the cells. An electric power device for use in an electric car demanding high output and high voltage contains an extremely large number of cells, and therefore, it requires an extremely large number of temperature sensors.
As a result, such a device has a disadvantage that since its parts and assembling processes such as connecting processes of the temperature sensors increase in number, its manufacturing cost becomes high.
Therefore, a first object of the present invention is to provide a battery unit which comprises a large number of connected cells and can detect abnormal temperature rise of a cell with a reduced number of temperature sensors adhered to the cells.
As shown in Fig. 1, the abnormal temperature rise detecting device disclosed in the Publication No. 270094/1998, a PTC sensor 10 is adhered from outside to each of the cells constituting a battery unit, and all of the adhered PTC sensors 10 are connected in series to a resistance measuring device to measure total resistance of the PTC sensors. When at least one of the cells to which PTC sensors are adhered respectively receives abnormal temperature rise, resistance of a PTC sensor 10 adhered to the cell increases extremely, and the resistance measuring device detects the abnormality.
However, in the abnormal temperature rise detecting device disclosed in this Publication, all of the PTC sensors 10 adhered respectively to the cells are connected in series and total resistance of theconnected PTCsensorslOis measured to detect abnormal temperature rise. Here, each PTC sensor 10 has its inherent difference i.e. dispersion of temperature characteristic. Therefore, as the number of the connected PTC sensors increases, such dispersions of the PTC sensors 10 are summed up, and all of the dispersions of the PTC sensors are added to the measured value of total resistance. Especially, as described in the Publication No, 270094/1998, when a temperature sensor is adhered to each of 126 or 252 cells constituting a battery source device for use in an electric car and total resistance of the temperature sensors is measured, the 2 measured value contains a extremely large total of dispersions.
Consequently, if a cell receives abnormal temperature rise and resistance value of a PTC sensor adhered to the cell extremely increases, sometimes the increased resistance value cannot be detected since each PTC sensor has dispersion as abovementioned. In addition, w hen these dispersions are taken into account and a threshold value for detecting increase of resistance value is set as a high value including dispersion value, abnormal temperature rise cannot be detected till the resistance value becomes above the threshold value, and there is a problem that detection of abnormal temperature rise takes much time.
Further, in an abnormal temperature rise detecting device disclosed in the Publication, since all of PTC sensors adhered respectively to 126 cells are connected in series, it is impossible to detect which one of the 126 cells receives abnormal temperature rise. Therefore, treatments such as mending and exchange of the cells and the device must be carried out in a wide range. Thus, this device has a disadvantage that maintenance, inspection and the like thereof cannot be rapidly achieved.
Therefore, a second object of the present invention is to provide a battery unit having an abnormal temperature rise detecting device which can precisely detect abnormal temperature rise of a cell without being influenced by dispersion of temperature characteristic of each temperature sensor, can rapidity detect resistance value increase caused by abnormal temperature rise to reduce detecting time and can detect abnormal temperature rise of a cell in rather small range ever if the device is used in an electric power device comprising a plural number of cells so that treatment for the abnormality maintenance and inspection of the device and the like can be rapidly carried out.
The above and further objects and features of the present invention will more fully be apparent from the following detailed description with accompanying drawings.
3 Summary of the Invention
A battery unit according to the present invention comprises a large number of cells connected in series or in parallel. Temperature sensors for detecting cell temperature are respectively adhered to cells constituting the battery unit. One temperature sensor is adhered to one cell, but temperature sensors are not adhered to all of the cells. In a battery unit having this structure, a less number of temperature sensors than that of the connected cells are provided, and cells adjacently provided with temperature sensors respectively and cells not provided with temperature sensors are mixedly connected.
The temperature sensor is a PTC sensor or a thermistor.
Each of the cell not provided with any temperature sensor may be provided with a heat collecting member for collecting temperature of a cell and transferring temperature data of the cell to a temperature sensor.
In this battery unit, a cell provided with a temperature sensor and a cell provided with a heat collecting member are connected adjacent to each other.
A temperature sensor is preferably disposed at a position on the surface of a cell near the adjacent cell provided with a heat collecting member.
Main material of the heat collecting member is one selected from the group consisting of iron, nickel, copper, aluminum and an alloy containing one of these metals.
Further, the battery unit comprises a plural number of cells each provided with a temperature sensor and calls each provided with a heat collecting member, and the temperature sensors adhered to the cells can be electrically connected in series to one another through the heat collecting members.
In the battery unit mentioned above. each cell provided with a heat collecting member is preferably disposed between the cells each provided with a temperature sensor.
Further, in the battery unit mentioned above, a temperature sensor may 4 be disposed between adjacent two cells and heat collecting members may be respectively provided on the cells on both sides of the temperature sensor.
In such a battery unit, since a heat collecting member is provided on the surface of a cell and connected to a temperature sensor, cell temperature is collected by the temperature sensor and transferred to the temperature sensor.
Thereby the heat collecting member can detect abnormal temperature rise of a cell. As a result, by connecting less number, not the same number, of temperature sensors than that of the cells constituting the battery unit, abnormal temperature rise of all of the cells can be detected.
Consequently, the battery unit can reduce temperature sensors in number and thereby assembling processes and parts of the battery unit can be reduced in number, so that manufacturing cost thereof can be lowered.
Further, according to the present invention, since temperature sensors are divided into small blocks and a control unit detects abnormality of each small block, abnormality can be detected in a rather small range of the small block with less number of temperature sensors than that of the cells connected in the battery unit.
Further, a battery unit according to the present invention is provided with a plural number of cells and an abnormal temperature rise detecting device comprising temperature sensors adhered respectively to the cells, resistance of each temperature sensor changing during a temperature rise, and an abnormal temperature rise detecting circuit for measuring resistance value of the temperature sensors and detecting abnormal temperature rise of a cell. The temperature sensors are divided into a plural number of temperature sensor blocks. In each sensor block, the same number of temperature sensors are connected in series. On the other hand, the abnormal temperature rise detecting circuit detects abnormal temperature rise by comparing resistance values of the temperature sensor blocks with each other.
In a battery unit having this structure, a plural number of temperature sensors are divided into temperature sensor blocks, and resistance values of the temperature sensors are respectively measured. And when difference between the resistance values becomes above a predetermined value, abnormality of a cell is detected.
According to the present invention, since resistance values of the temperature sensor blocks are compared with one another, differences i.e. dispersions of temperature characteristic of the temperature sensors can be set off. Therefore, when any one of the cells receives abnormal temperature rise and resistance value of a PTC sensor adhered to the cell extremely increases, only the increased value can be precisely detected.
As a result, abnormality can be detected precisely and without errors, free from influence of dispersions of temperature sensors such as PTC sensors.
In addition, since dispersions of temperature sensors are set off, it is not necessary to set unnecessarily large a set value of difference between resistance values of temperature sensors for detecting abnormal cell temperature. Thereby the abnormal temperature rise detecting device can sensitively react to increase of resistance value, and the detecting time ran be shortened.
In addition, since the temperature sensors such as PTC sensors are divided into temperature sensor blocks, if abnormal temperature rise is caused in any one of a large number of cells, the detection can be carried out in every temperature sensor block and thereby treatment such as mending or exchange can be achieved in a rather narrow range to speed up the maintenance inspection and the like.
As a result a battery unit having this structure can precisely and rapidly detect abnormal temperature rise of a cell when it is used as a battery source, which comprises an extremely large number of connected cells, for an electric car and a hybrid type car. And the battery unit is safe and easily is maintained and inspected, so that it can be easily treated as a battery source for an electric car and the like.
6 Brief Description of the Drawings
Fig. 1 is a connecting circuit diagram of a conventional abnormal temperature rise detecting device.
Fig. 2 is a perspective view of an embodiment of a battery unit according to the present invention.
Fig. 3 is a connecting circuit diagram of a temperature sensor.
Fig. 4 is a perspective view of another embodiment of a battery unit according to the present invention.
Fig. 5 is a perspective view of another embodiment of a battery unit according to the present invention.
Fig. 6 is a perspective view of another embodiment of a battery unit according to the present invention.
Fig. 7 is a perspective view of another embodiment of a battery unit according to the present invention.
Fig. 8 is a perspective view of another embodiment of a battery unit according to the present invention.
Fig. 9 is a temperature detecting circuit diagram of the battery unit of Fig.8.
Fig. 10 is an exploded perspective view of another embodiment of a battery unit according to the present invention.
Fig. 11 is a plan view of a battery module of the battery unit of Fig. 10.
Fig. 12 is a circuit diagram of an abnormal temperature rise detecting device.
Detailed Description of the Invention
Embodiments of the present invention will be described in the following 30 with reference to the appended drawings. A battery unit shown in Fig. 2 7 comprises six cylindrical cells 1 which are all longitudinally connected in series to form a cylindrical shape. Each cell 1 comprises a nickel hydrogen cell, but may comprises nickel-cadmium cell or a lithium ion cell.
In the battery unit, a dished connecting member 2 is spot-welded between each two cells 1. The connecting member 2 electrically connects adjacent two cells 1 in series and at the same time mechanically connects them.
And the battery unit comprising connected six cells 1 is provided with a positive and a negative electrode terminals at both ends thereof respectively. The positive electrode terminal 3 has a projection 3A at the center thereof, while the negative electrode terminal 4 has a hole 4A at the center thereof.
By inserting a projection 3A of a positive electrode terminal 3 of a battery unit into a hole 4A of a negative electrode terminal 4 of another battery unit, they can be connected. Therefore, more, for example, two or three battery units each having such structure can be longitudinally connected with each other into a longer cylindrical shape containing 12 or 18 cells. Further, since the positive electrode terminal 3 and the negative electrode terminal 4 have such different shapes from each other, battery units can be prevented from being put in erroneous directions when they are arranged laterally in parallel.
A plural number of battery units according to the present invention each comprising six cells can be arranged and contained in a case or the like so as to function as an electric power device. Cells connected in the electric power device can be increased in number by connecting an increased number of battery units, and such an electric power device can be used as an electric power device for an electric car which requires high power and high voltage.
In the battery unit shown in Fig. 2, a temperature sensor 5 and a heat collecting member 6 are provided on the surface of each cell. The temperature sensor 5 comprises an element such as a PTC element whose resistance changes as temperature changes. The temperature sensor 5 is so designed that the higher temperature becomes, the more largely resistance changes, and that resistance largely changes in an atmosphere of 600C to 1209C. On the other 8 hand, the main material of the heat collecting member 6 is one selected from the group consisting of iron, nickel, copper, aluminum and an alloy containing either of these metals.
The heat collecting member 6 ran collect heat of the cell 1 to which the heat collecting member 6 is adhered and maintain the temperature of the heat.
And the heat maintained by the heat collecting member 6 is transferred from the heat collecting member 6 to the temperature sensor 5. Thereby the temperature sensor 5 can detect the heat of the cell to which the heat collecting member 6 is adhered. Consequently, the temperature sensor 5 is preferably disposed adjacent to the heat collecting member 6.
In the battery unit shown in Fig. 2, the six cells 1 are provided with four temperature sensors 5 and two heat collecting members 6. The four temperature sensors 5 are adhered to the surfaces of two opposite end cells 1 and two middle cells 1 of the six cells 1. And the two heat collecting members 6 are adhered to the surfaces of the remaining two cells 1. Therefore, the heat collecting member 6 is disposed between two temperature sensors 5. The heat collecting members 6 together with the temperature sensors 5 are formed into a long and narrow strip. The strip comprising the heat collecting members 6 and the temperature sensors 5 is wholly laminated with a resin or the like and thereby insulated from the outer cases of the cells 1. And the temperature sensors 5 and the heat collecting members 6 formed into a strip and laminated, together with the battery unit comprising six cells 1, are covered with a heatshrinkable tube (not shown), to be in close adhesion to the cells 1. The heat collecting members 6 which are in close adhesion to the cells 1 can collect heat of the cells 1. The size of each heat collecting member 6 is in the range of 3 % to 60 % of the surface area of the cell 1. By making the heat- collecting member 6 large in size, heat of the cell 1 can be more effectively collected, but sometimes radiating effect of the cell 1 is reduced. Therefore, optimum size of the heatcollecting member 6 is selected with taking into account the radiating effect of the cell 1. In addition, the heat collecting member 6 comprises a heat collecting 9 section 6A for collecting heat of the cell 1 and two connecting leg sections 6B for connection with the temperature sensor 5, the connecting leg sections 6B protruding from the opposite ends of the heat collecting section 6B respectively. Each connecting leg section 6B is adhered onto the temperature sensor 5.
Further. layer in the heat collecting member 6 has, for example, twolayer structure. In this case, the heat collecting member 6 comprises an inner contact with the cell 1 and an outer layer not in contact with the cell 1. And the outer layer is made of a material having heat conductivity lower than that of the inner layer, so that heat collected by the heat collecting member 6 can be maintained.
In this battery unit, the temperature sensors 5 are electrically connected in series with each other in a route different from that of the cells connected in series. Fig. 3 is an example of a circuit diagram connecting in series all the temperature sensors 5 adhered to all the battery units in an electric power device comprising a plural number of battery units. However, instead of connecting all the temperature sensors 5 in series, temperature sensors 5 contained in each battery unit, every two or every three battery units can be connected in series, and then whole of them can be connected in parallel.
Resistance of the temperature sensors 5 connected in series changes by abnormal temperature rise of a cell to which the temperature sensor is adhered. Therefore, if abnormal temperature rise of only one cell occurs, the temperature sensors 5 connected in series car detect it and can detect electric power device trouble. Since the heat collecting members 6 comprise metal or like heat conductive member. they can also serve as lead plates for connecting the temperature sensors with one another.
Fig. 4 shows another embodiment of the present invention, in which the connecting leg section 46B for connecting the heat collecting member 46 to the temperature sensor 45 is formed large in size to cover the whole temperature sensor 45. The heat collecting member 46 having such structure can more precisely transfer collected temperature data to the temperature sensor 45. In this Figure, numeral 41 indicates a cell, numeral 42 indicating the dished connecting member while numeral 46A indicating the heat collecting section.
Fig. 5 and 6 show other different embodiments of the present invention, in which three temperature sensors 55, 65 and three heat collecting members 56, 66 are adhered to the connected six cells 51, 61. In these embodiments, the heat collecting member 56, 66 is provided adjacent to the temperature sensor 55, 65 so that the temperature sensors 56, 65 are disposed alternately with the heat collecting members 56, 66. By changing and controlling the number of the temperature sensors and the heat collecting members with respect to the number of the cells in such a manner, the number of the temperature sensors can be reduced. Thus, the heat collecting members and temperature sensors are titled into the battery unit with connecting the heat collecting members to the temperature sensors. And by providing one temperature sensor for every two cells, two cells can be monitored by one temperature sensor. By providing two temperature sensors for every three cells, three cells can be monitored by two temperature sensors. Further, by providing one temperature sensor for every three cells, three cells can be monitored by one temperature sensor. In these Figures, numerals 51, 61 indicate the cells. numerals 52, 62 indicating the dished connecting members, numerals 56A, 66A indicating the heat collecting sections and numerals 56B, 66B indicating the connecting leg sections.
Fig.7 shows a further different embodiment of the present invention, in which three temperature sensors 75 and six heat collecting members are provided for the six cells. In the battery unit shown in Fig. 7, the temperature sensor 75 is disposed between two cells 71 and in a position opposed to the dished connecting member 72. Each heat collecting member 76 is adhered to each of the six cells, and the connecting leg sections 76B of the adjacent two heat collecting members 76 are connected to the outer surface and the inner surface of the temperature sensor 75 respectively. Further, on every two cells 71 of the middle four cells except two opposite end ones of the six cells7l, the heat collecting member 76 comprising integrated two heat collecting sections 76A is disposed. By using this heat collecting member 76, two heat collecting sections 76A of only one heat collecting member 76 can be adhered to the surfaces of the two cells respectively. As a result, necessary heat collecting members can be reduced in number, and thereby parts and assembling processes can be also reduced in manufacturing battery units.
As mentioned above, in the battery unit shown in Fig. 7, since the heat collecting members 76 are disposed on all of the cells 71 and the heat collecting members are connected to the temperature sensors 75, abnormal temperature rise of all of the six cells 71 can be detected by three temperature sensors 75.
The number of the temperature sensors 75 disposed between the cells can be appropriately changed.
Now, another embodiment of the present invention shown in Figs. 8 and 9 will be described. Unlike the abovementioned embodiments shown in Figs. 2 to 7, the battery unit shown in Figs. 8 and 9 is not provided with any heat collecting member. In the battery unit shown Fig. 8, six cells 81 constitute a battery module 87. And a plural number of battery modules connected in series constitute a battery unit.
The number of battery modules 87 connected in a battery unit can be optionally selected. By connecting, for example, 32 battery modules, a battery unit comprising 192 cells connected to each other can be obtained. And more battery modules can be connected. Further, the number of cells constituting a battery module can be also optionally selected, and more than six or less than six cells can constitute a baftery module.
In the battery unit shown in Fig. 8. a battery module 87 is constituted of six cells 81 which are connected in series to form a cylindrical shape. Two of the six cells 81 of the battery module 87 are each provided with a temperature sensor 85, and the remaining four cells 81 are not provided with any temperature sensor. In each of remaining battery modules 87, similarly, two of the six cells 81 are each provided with a temperature sensor 85. Therefore, with this structure, the number of temperature sensors 85 can be reduced in comparison with a case in which each cell 81 is provided with a temperature 12 sensor 85, However, the number of temperature sensors 85 and space size between the temperature sensors 85 in a battery module are not limited by the abovementioned description, but may be optionally determined.
Further, in the battery unit shown in Fig. 8, a total of four temperature sensors 85 are connected to one another in series so that two battery modules 87 constitute a small block. Four temperature sensors 85 constitute a small block. The battery unit is divided into a plural number of small blocks. And at every small block, temperature of the temperature sensor 85 is detected. The temperature sensor 85 may comprise a PTC element or a thermistor. A PTC element has a characteristic that resistance thereof rapidly changes when it reaches the working temperature. If the working temperature is, for example, 930C, the temperature sensor 85 comprising a PCT element sometimes cannot detect abnormal temperature rise till temperature of the cell reaches near 100'C. Therefore, sometimes it takes much time for the temperature sensor 85 to detect abnormal temperature rise.
On the other hand, a thermistor has a characteristic that resistance thereof gradually changes while temperature changes from low (-200C) to high (1 59C). And the temperature sensor 85 comprising a thermistor can rapidly detect abnormal temperature rise by comparing temperature with a regulation value and controlling selection of the regulation value. Further, a unit price of a thermistor is low in comparison with that of a PTC element, and production cost of a temperature sensor 85 can be reduced.
Fig. 9 is a diagram of a temperature detecting circuit in which control unit ECU and a display 8 are connected to the battery unit shown in Fig. 8.
Temperature data of the temperature sensors 85 divided to form a small block is inputted in the control unit ECU.
Absolute temperature of each small block is detected and compared with a predetermined regulation value and thereby abnormal temperature rise can be detected. The regulation value is set, for example, at 609C. When abnormal temperature rise is detected at every small block, the display 8 13 indicates which small block is in abnormal state. As a result, even in a battery unit in which a large number of cells are connected, abnormal points can be easily detected.
Further, since the range of the abnormal portion can be detected at every small block, maintenance such as exchange and repairing can be easily carried out.
The control unit ECU can compare inputted temperature signal of each small block with the regulation value at every small block. By this, temperature difference between the small blocks, that is temperature dispersion can be detected. For example, if detected temperature of a small block is 800C. and detected temperatures of the other small blocks are normal temperatures of 450C to 50"C., the temperature difference between them is detected. And when the temperature difference is above a regulation value, it is judged and detected that the battery unit is in abnormal state. i.e. that abnormal cell or cells are included in the battery unit. In this case, the display 8 can indicate which small block is in the abnormal state.
In the embodiment shown in Figs. 8 and 9, since the temperature sensors 85 are divided into small blocks and abnormal temperature detection of each small block is carried out as abovementioned, detection of abnormal state in small range of the small block can be achieved with less number of temperature sensors than that of the cells connected in the battery unit. Further, since the control unit ECU uses the inputted temperature data ofthe small blocks as parameters of self-discharging and charging efficiency and controls battery conditions such as remaining capacity, detailed calculations of battery conditions can be achieved with inputted temperature data of each small block.
Further, a battery unit according to the present invention in which a plural number of temperature sensors are divided into temperature sensor blocks is used as battery sources of electric cars and hybrid-type cars in which driving source comprises combination of a internal combustion engine and a battery-driven motor. Fig. 10 is an exploded perspective view of appearance of a 14 battery unit according to the present invention for use as a battery source. This battery source 11 has a rectangular parallelepiped shape enclosed with an upper and a lower holder cases 12, an intermediate case 13 and end plates 14 on both sides.
As shown in Fig. 11, the battery source 11 contains therein battery modules 97 in each of which six cylindrical cells are longitudinally connected to form a cylindrical shape and all of the six cells are electrically connected in series. Eight battery modules 97 having such structure are laterally arranged, and above this arrangement of eight battery modules 97, similar arrangement of eight battery modules 97 is layered by means of the intermediate case13. As a result, a total of 96 cells 91 are contained in the battery source 11, and all of these 96 cells are connected in series by lead plates provide on the end plates 14. Further, by connecting a plural number of such battery sources each containing 96 cells, the number of the connected cells can be increased to an integral multiple of 96. Therefore, the battery source 11 can provide necessary electric source voltage, output current and the like in accordance with size and output of an electric car.
In the battery module 97 comprising six cells 91 longitudinally connected to form a cylindrical shape, PTC sensors are used as the temperature sensors.
In the following embodiment, PTC sensors 15 are used as the temperature sensors. Therefore, the temperature sensor blocks are used as the PTC sensor blocks. The PTC sensors 15 are fixed to the outside of the battery module 97. In the battery module 97 shown in this Figure, one PTC sensor 15 is adhered to each of the cells. Therefore, the temperature sensor blocks are the PTC sensor blocks of the cells 91. Six PTC sensors 15 are connected longitudinally in a line by lead plates so as to correspond to the connected six cells 91. And the lead plates extended from the opposite ends of the connected six PTC sensors are electrically connected through the end plates 14 to the lead plates of the connected six PTC sensors 15 adhered the adjacent battery module.
Thereby all of the PTC sensors 15 adhered to all of the 96 cells contained in the battery source 91 respectively can be electrically connected. Though all of the PTC sensors can be connected in series as abovementioned, PTC sensors adhered to e.g. every two battery modules, that is, adhered to every 12 cells may be connected in series. The PTC sensors are connected in series in blocks of a battery module in such a manner, and electric signals can be taken out from the PTC sensors by extending each lead plate. Further, it is not necessary to adhere PTC sensors to all of the cells respectively, but PTC sensors may be adhered to each other cell so that three PTC sensors are adhered in a battery module.
The PTC sensors 15 adhered as abovementioned can constitute a circuit of only the PTC sensors 15 in a different route from that of the series circuit of the cells 91 through which large current flows. Therefore, since the circuit of the PTC sensors can be a small current circuit, heat generation can be prevented even if a large number of PTC sensors 15 are connected, and at the same time, reduction of the battery power output by the voltage reduction caused by the PTC sensors can be prevented.
In this embodiment, as shown in Fig. 12. every 12 PTC sensors 15 adhered to the 12 cells respectively are connected in series to constitute a PTC sensor block 18. Therefore, the PTC sensors 15 adhered to the 96 cells 91 of the battery source 11 respectively are divided into eight PTC sensor blocks 18, and the PTC sensors 15 of each PTC sensor block are connected in series.
And each of these PTC sensor blocks 18 is connected to an abnormal temperature rise detecting circuit 19. Now, operation of the abnormal temperature rise detecting circuit 19 will be described in the following.
(1) The abnormal temperature rise detecting circuit 19 measures resistance values of all of the PTC sensor blocks 18 connected thereto.
(2) The measured resistance values of the PTC sensor blocks 18 are compared with one another, and difference between the measured values of two PTC sensor blocks 18 is calculated.
(3)The difference is compared with a predetermined value preliminarily 16 inputted in the abnormal temperature rise detecting circuit 19, and when the difference is above the predetermined value, abnormal temperature rise is detected.
(4) When abnormal temperature rise is detected, an abnormality signal is outputted to the control unit ECU of the battery source 11, and the ECU informs that the cell(s) are in abnormal state.
In this manner, the abnormal temperature rise detecting circuit 19 connects in series the PCT sensors of each PTC sensor block, measures resistance of each PTC sensor block, and detects abnormal temperature rise when difference between the resistance of two PTC sensors is above a predetermined value.
Therefore, since difference between resistance of PTC sensor blocks is calculated, differences i.e. dispersions of temperature characteristic of PTC sensors are set off. Consequently, when abnormal temperature rise of any cell is caused and the resistance value of the PTC sensor 15 to which the cell is adhered extremely increases, only the increased value can be precisely detected, since the dispersions of the PTC sensors are set off.
As a result, the detection can be achieved not erroneously but precisely without influence of dispersion of the PTC sensors respectively. And at the same time, the abnormal temperature rise detecting circuit can sensitively correspond resistance increase without necessity of setting the predetermined value as an undesirably large value because dispersion of the PCT sensors is set off, and thereby the detecting time can be shortened.
Further, since the PTC sensors 15 are divided into the PCT sensor blocks 78, if abnormal temperature is caused in any one of 96 cells 91 the detection can be carried out in every PTC sensor block and thereby treatment such as mending or exchange can be achieved in a rather narrow range to speed up the maintenance inspection and the like.
The abnormal temperature rise detecting circuit 19 measures resistance value of each PTC sensor block 18 and calculates difference between the 17 resistance values, as abovementioned. However, the present invention is not limited to this, but abnormal temperature rise may be detected by calculating ratios or multiplication factors of the measured values of the PTC sensor blocks and comparing them with each other.
As the present invention may be embodied in several forms without departing from the spirit of essential characteristics thereof, the present embodiment is therefore illustrative and not restrictive, since the scope of the present invention is defined by the appended claims rather than by the description preceding them, and all changes that fall within meets and bounds of the claims, or equivalence of such meets and bounds thereof are therefore intended to be embraced by the claims.
18

Claims (14)

1. A battery unit comprising a large number of cells connected in series or in parallel, which further comprises a plural number of temperature sensors for detecting cell temperature, each temperature sensor being disposed adjacent to a cell, and the total number of the temperature sensors being less than that of the cells since all of the cells are not provided with temperature sensors respectively.
2. A battery unit as claimed in claim 1, in which the temperature sensor is a PTC element or a thermistor.
3. A battery unit as claimed in claim 1, in which the battery unit is divided into a plural number of small blocks, each small block being constituted by connecting plural number of cells, and the battery unit is further comprises a control unit for receiving outputs of the temperature sensors disposed adjacent to the cells, the control unit calculating the outputs of the temperature sensors of each small block.
4. A battery unit as claimed in claim 1, in which each of the cells not provided with any temperature sensor adjacent thereto is provided with a heat collecting member for collecting heat of the cell and transferring temperature data of the cell to a temperature sensor.
5. A battery unit as claimed in claim 4, in which a cell provided with a temperature sensor and a cell provided with a heat collecting member are disposed adjacent to each other and connected to each other.
6. A battery unit as claimed in claim 4, in which a temperature sensor is disposed at a position on the surface of a cell near the adjacent cell provided 19 with a heat collecting member.
7. A battery unit as claimed in claim 4 in which main material of the heat collecting member is one selected from the group consisting of iron, nickel, copper, aluminum and an alloy containing one of these metals.
8. A battery unit as claimed in claim 4, in which the cells constituting the battery unit consist of a plural number of cells each provided with a temperature sensor and cells each provided with a heat collecting member, and the temperature sensors adhered to the cells are electrically connected in series to one another through the heat collecting members.
9.A battery unit as claimed in claim 4, in which the cells constituting the battery unit consist of a plural number of cells each provided with a temperature sensor and cells each provided with a heat collecting member, and each cell provided with a heat collecting member is disposed between a plural number of cells each provided with a temperature sensor.
10. A battery unit as claimed in claim 4, in which a temperature sensor is disposed between adjacent two cells, and each of the adjacent two cells on both sides of the temperature sensor is provided with a heat collecting member.
11. A battery unit provided with an abnormal temperature rise detecting device comprising (1) a plural number of cells (2) temperature sensors adhered to cells, resistance of each temperature sensor changing during temperature rise, and (3) an abnormal temperature rise detecting circuit for measuring resistance of the temperature sensors and detecting abnormal temperature rise of a cell, (4) the temperature sensors being divided into a plural number of temperature sensor blocks and each temperature censor block connecting the same number of temperature sensors in series, and (5) the abnormal temperature rise detecting circuit detects abnormal temperature rise by comparing resistance values of the temperature sensor blocks with one another.
12. A battery unit as claimed in claim 11, in which the temperature sensor is a PTC element.
13. A battery unit as claimed in claim 11, in which the abnormal temperature rise detecting circuit compares resistance values of the temperature sensor blocks with one another and detects abnormal temperature rise when the difference of the resistance is above a predetermined value.
14. A battery unit substantially as hereinbefore described with reference to Figures 2 to 12 of the accompanying drawings.
21
GB0018024A 1999-08-06 2000-07-21 Battery unit Expired - Fee Related GB2354587B (en)

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JP22328199A JP3913411B2 (en) 1999-08-06 1999-08-06 Battery pack with abnormal temperature rise detection device
JP29604199A JP3670907B2 (en) 1999-03-12 1999-10-19 Assembled battery

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GB2354587A true GB2354587A (en) 2001-03-28
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SE524272C2 (en) 2004-07-20
KR100472818B1 (en) 2005-03-07
GB2354587B (en) 2003-10-22
GB0018024D0 (en) 2000-09-13
SE0002769D0 (en) 2000-07-26
KR20010071112A (en) 2001-07-28

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