GB2277736A - Sprayable mortars - Google Patents

Sprayable mortars Download PDF

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Publication number
GB2277736A
GB2277736A GB9408568A GB9408568A GB2277736A GB 2277736 A GB2277736 A GB 2277736A GB 9408568 A GB9408568 A GB 9408568A GB 9408568 A GB9408568 A GB 9408568A GB 2277736 A GB2277736 A GB 2277736A
Authority
GB
United Kingdom
Prior art keywords
aggregate
mortar composition
modulus
mortar
elasticity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB9408568A
Other versions
GB2277736B (en
GB9408568D0 (en
Inventor
Wainer Mori
Josef Scherer
Roland Wolfseher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandoz AG
Original Assignee
Sandoz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandoz AG filed Critical Sandoz AG
Publication of GB9408568D0 publication Critical patent/GB9408568D0/en
Publication of GB2277736A publication Critical patent/GB2277736A/en
Application granted granted Critical
Publication of GB2277736B publication Critical patent/GB2277736B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00146Sprayable or pumpable mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00663Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/50Flexible or elastic materials

Abstract

A sprayable mortar for repairing reinforced concrete comprises cement and an aggregate with an average static modulus of elasticity of 15,000 to 40,000 N/mm<2>. Especially good results are obtained when the aggregate comprises sand and small proportions of limestone dust, micro rock dust or micro rock dust fibres. The protective layers obtained are notable for their good flexibility.

Description

SPRAY MORTAR The invention relates to a sprayable repair mortar composition and more particularly to such a composition for use on reinforced concrete.
When reinforced concrete is to be repaired, a layer of repair mortar, typically 30-35mm thick, is applied thereto, generally by spraying. The repair mortar should be able to withstand dimensional changes in the substrate without suffering damage for a reasonable period of time. A measure of this ability is provided by the characteristic crack length.- of the mortar.
When a prism of the mortar composition is subjected to a deflection test using a centre point loading apparatus, the prism deflects with increasing load and on the reverse face of the prism from the loaded face there is formed a region of microcracks which region is characteristic of the particular composition under test. Eventually these cracks will join to form a major crack and the prism will fail. The characteristic crack length may be calculated from a knowledge of the fracture energy of the composition (the area under the characteristic bellshaped curve of stress against deflection obtained from the abovementioned deflection test), the elasticity modulus (E-modulus) of the composition, and the ultimate centric tensile strength of the composition. The greater the characteristic crack length, the better performing the material.The best materials have high fracture energy as well as long characteristic crack length.
It has now been found that it is possible to prepare a repair mortar composition with outstanding properties as evidenced by a long characteristic crack length. The invention therefore provides a mortar composition for the repair of concrete surfaces, which comprises cement and aggregate, the aggregate having an overall average static modulus of elasticity of from 15,000-40,000 N/mm2 The static elasticity modulus (usually known as the "E-modulus") of the aggregate to be used in the compositions of this invention is unusually "soft", the figure for the aggregate in a conventional spray mortar being of the order of 25,000 to over 60,000 N/mm2. The E modulus is commonly measured by means of an ultrasonic testing apparatus; a typical example of such an apparatus is the Steinkamp Type BP 5 ultrasonic tester (ex Dr.-Ing. G.
Steinkamp, Bremen Germany). The E-modulus is the average E-modulus of the aggregate; it is permissible to have an aggregate component with an E-modulus in excess of the upper limit of 40,000 N/mm2, provided that the aggregate comprises sufficient aggregate of a lower E-modulus to bring the average within the range mentioned hereinabove.
Depending on the field of application, all known types of cement may be used in the usual quantities, Portland cement being preferred.
The "soft" E-modulus range of the aggregate may be attained by the choice of aggregate employed and by its use in conjunction with natural mineral materials having a fibrous structure. The aggregate used is preferably sand in which the proportion of sand having a high E-modulus is small. In practice, sand types having a grain size of 4 mm maximum are selected. The sand mixture employed should preferably have an average modulus of elasticity of 20,000-30,000 N/mm2 and in particular should be below 25,000 N/mm2. Typically suitable natural fibrous mineral materials are limestone dust (which may be coarse-grained), micro rock dust, micro rock dust fibres or similar fibrous materials.Such materials are preferably present in the compositions of the invention in amounts of 0.5 to 2.5% by weight of the total weight of the dry mortar composition.
The mortar composition of this invention is preferably applied to a substrate by spraying, preferably by the dry spraying process.
When sprayed as a repair mortar on to a substrate, the mortar composition according to the invention hardens to give a layer with a high fracture energy and long characteristic crack length, and this manifests itself in high flexibility, high frost resistance and a low modulus of elasticity. In contrast to conventional products which produce hardened protective layers with a modulus of elasticity of over 30,000 N/mm2, the compositions according to the invention may be used to obtain protective layers with a modulus of elasticity of below 25,000 N/mm2. Thus, the compositions according to the invention may be employed whenever it is desired to produce a malleable top layer which is insensitive towards cracks. The improved ductility and the low modulus of elasticity of the mortar compositions allows the reduction and even complete elimination of shrinkage reinforcement.Thus, layers need not be so thick and single-layer application may often be employed.
It has been found that the combination of the fibrous materials limestone dust and micro rock dust fibres with sand as hereinabove described and cement gives particularly good results, outstanding in the case of the crack test hereinabove described. Especially good combinations are those in which the weight percentages of limestone dust and micro rock dust fibres are 1.5 and 0.8-1.5 respectively. If no other components are present, the sand comprises from 7778% and cement comprises the remainder. If other components are desired, some adjustments to the sand and cement quantities are necessary, but such are well within the skill of the art.
Other components suitable for use in sprayable mortar compositions according to the invention are well known to the art. These constituents may be added in the usual proportions, depending on the field of use. For example, it is possible to add silica fume or fly ash as a filler, or known fibre reinforcement. All constituents are mixed in the dry state by known processes, and fed pneumatically to the spray nozzle of any dry spraying machine (e.g. MEYCO Piccola, MEYCO Unica ex Meynadier AG., Winterthur, Switzerland), where they are mixed with water and sprayed. The quantity of water may vary depending on conditions, but may readily be determined in any situation by the skilled worker.Typical water/binder weight ratios (where binder naturally includes such materials as silica fume or fly ash, where these are present) for a dry spraying operation are from 0.3-0.6, preferably from 0.4-0.5. An accelerator is normally not used. The application depth may vary from 12 to 100 mm.
The invention is further described with reference to the following non-limiting examples in which all parts are by weight.
Example 1 Constituents modulus of density proportions elasticity N/mm2 kg/m3 % by weight cement 18,000 (17,000-21,000) 2000-2150 20.0 sands 24,000 (23,000-83,000) 2670-3050 77.7 limestone dust 24,000 2500 1.5 micro rock dust 17,000 (crosswise) 2500 0.8 fibres 170,000 (lengthwise) sprayable mortar 22,137 2131 100 The various constituents are mixed in the dry state and water is added at the spray nozzle in such a rate as to give a ratio of water/binding agent of 0.4. This ratio is used in the subsequent examples.
Examples 2 to 12 Further examples of appropriate sprayable mortar mixes are given in the table, where the proportions of the various constituents are given in percentages by weight. In the table, "MSM" is micro rock dust, "MSM PF" is micro rock dust fibres and "KTSM" is limestone dust . The limestone dust is coarse grain (4 mm) material.
Table
Example cement sands KSTM MSM MSM PF 2 20 77.7 1.5 0.8 3 20 75.5 3 1.5 4 20 72 5 3 5 15 74.5 10 0.5 6 15 75 10 7 20 77.7 1.5 0.8 8 20 77 2.5 0.5 9 20 69.2 10 0.8 10 20 77 1.5 1.5 11 20 77 3 12 20 77 3 Example 13 The compositions of Examples 1 and 10 are subjected to testing according to the test method RILEM 50-FMC draft recommendation. A commercially-available repair mortar comprising by weight 42% cement, 33% sand (0.15-1.20mm), 17% sand (1.20-2.38mm), 3.4% silica fume, 3.3% calcium oxide, and the remainder miscellaneous minor quantities of admixtures is subjected to the same testing procedure. From the testing, the characteristic crack lengths are determined. The results are as follows: Example 1 435mm Example 10 382mm Commercial composition 262mm The crack performances of the compositions according to the invention are considerably superior to that of the commercially-available composition.
The compositions are sprayed on to a concrete substrate. In subsequent flexibility testing, the compositions according to the invention prove to be superior to the commercial composition in terms of flexibility and durability.

Claims (7)

Patent Claims
1. A mortar composition for the repair of concrete surfaces, which comprises cement and aggregate, the aggregate having an overall average static modulus of elasticity of from 15,000-40,000 N/mm2
2. A mortar composition according to claim 1, wherein the aggregate is a combination of sand and natural mineral material having a fibrous structure.
3. A mortar composition according to claim 1 or claim 2, wherein the natural mineral material is selected from at least one of limestone dust, micro rock dust and micro rock dust fibres.
4. A mortar composition according to claim 3, wherein the natural mineral material comprises from 0.5 to 2.5% by weight of the total weight of the dry mortar composition.
5. A mortar composition according to claim 2, wherein the sand has an average modulus of elasticity of 20,000-30,000 N/mm2 and a maximum particle size of 4mm.
6. A process of repairing a concrete surface, comprising the spraying thereon of a mortar composition according to claim 1.
7. A process according to claim 6, wherein the spraying is carried out by the dry spraying process.
GB9408568A 1993-05-04 1994-04-29 Spray mortar Expired - Fee Related GB2277736B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4314612 1993-05-04

Publications (3)

Publication Number Publication Date
GB9408568D0 GB9408568D0 (en) 1994-06-22
GB2277736A true GB2277736A (en) 1994-11-09
GB2277736B GB2277736B (en) 1996-09-25

Family

ID=6487073

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9408568A Expired - Fee Related GB2277736B (en) 1993-05-04 1994-04-29 Spray mortar

Country Status (7)

Country Link
JP (1) JPH06345509A (en)
CA (1) CA2122647A1 (en)
CH (1) CH688411A5 (en)
DE (1) DE4415558A1 (en)
FR (1) FR2704854B1 (en)
GB (1) GB2277736B (en)
IT (1) IT1272236B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2192464A1 (en) * 2001-11-16 2003-10-01 Los Santos Parejo Diego De Mortar based on cement and sand comprises mix including calcarenite and medium and coarse sands
ES2211319A1 (en) * 2002-05-23 2004-07-01 Eduardo Ramirez de Arellano Concentrated one-coat mortar, method for making the same, and method for applying the same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE29613699U1 (en) * 1996-04-18 1996-10-31 Kschiwan Joerg Wall coating

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1144024A (en) * 1965-03-25 1969-03-05 Gullhoegens Bruk Ab Binding agent for plaster and/or mortar, and mortar mixtures produced therefrom
GB1325518A (en) * 1971-01-20 1973-08-01 Ardex Chemie Gmbh Mortar mix for the production of composition floors or floor surfaces

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0517196A (en) * 1991-07-11 1993-01-26 Nippon Cement Co Ltd Grouting material for repairing concrete structure
JP3002759B2 (en) * 1991-09-06 2000-01-24 住友大阪セメント株式会社 Repair cement-based injection material composition
ZW19392A1 (en) * 1991-12-20 1993-04-14 Csir Pumpable grout

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1144024A (en) * 1965-03-25 1969-03-05 Gullhoegens Bruk Ab Binding agent for plaster and/or mortar, and mortar mixtures produced therefrom
GB1145239A (en) * 1965-03-25 1969-03-12 Gullhoegens Bruk Ab Binding agent for plaster and/or mortar, and mortar mixtures produced therefrom
GB1325518A (en) * 1971-01-20 1973-08-01 Ardex Chemie Gmbh Mortar mix for the production of composition floors or floor surfaces

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2192464A1 (en) * 2001-11-16 2003-10-01 Los Santos Parejo Diego De Mortar based on cement and sand comprises mix including calcarenite and medium and coarse sands
ES2211319A1 (en) * 2002-05-23 2004-07-01 Eduardo Ramirez de Arellano Concentrated one-coat mortar, method for making the same, and method for applying the same

Also Published As

Publication number Publication date
ITRM940273A1 (en) 1995-11-03
GB2277736B (en) 1996-09-25
CA2122647A1 (en) 1994-11-05
GB9408568D0 (en) 1994-06-22
JPH06345509A (en) 1994-12-20
DE4415558A1 (en) 1994-11-10
ITRM940273A0 (en) 1994-05-03
IT1272236B (en) 1997-06-16
FR2704854A1 (en) 1994-11-10
CH688411A5 (en) 1997-09-15
FR2704854B1 (en) 1998-12-18

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PCNP Patent ceased through non-payment of renewal fee

Effective date: 19990429