GB2259711A - Rolling bearing lubricant - Google Patents

Rolling bearing lubricant Download PDF

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Publication number
GB2259711A
GB2259711A GB9210979A GB9210979A GB2259711A GB 2259711 A GB2259711 A GB 2259711A GB 9210979 A GB9210979 A GB 9210979A GB 9210979 A GB9210979 A GB 9210979A GB 2259711 A GB2259711 A GB 2259711A
Authority
GB
United Kingdom
Prior art keywords
lubricant
bearing
rolling bearing
steel
outer race
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB9210979A
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GB9210979D0 (en
GB2259711B (en
Inventor
Yoichi Imamura
Fusasuke Goto
Norihiro Aoki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NSK Ltd
Original Assignee
NSK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NSK Ltd filed Critical NSK Ltd
Publication of GB9210979D0 publication Critical patent/GB9210979D0/en
Publication of GB2259711A publication Critical patent/GB2259711A/en
Application granted granted Critical
Publication of GB2259711B publication Critical patent/GB2259711B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/66Special parts or details in view of lubrication
    • F16C33/6603Special parts or details in view of lubrication with grease as lubricant
    • F16C33/6633Grease properties or compositions, e.g. rheological properties
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/02Specified values of viscosity or viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/082Inorganic acids or salts thereof containing nitrogen
    • C10M2201/083Inorganic acids or salts thereof containing nitrogen nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/02Bearings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30Parts of ball or roller bearings
    • F16C33/58Raceways; Race rings
    • F16C33/62Selection of substances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Rolling Contact Bearings (AREA)

Abstract

A lubricant composition (G), comprising a polyether as a base oil, is filled in a bearing composed of an outer race (1), an inner race (2) and rolling elements (3). The polyether lubricant has a kinematic viscosity of 90-160 cSt at 40 DEG C. The outer race (1) and/or inner race (2) of the bearing can be made of steel having an oxygen content not higher than 6 ppm with a hardened raceway surface. <IMAGE>

Description

7 - c c - 4 1 "ROLLING BEARING"
This invention relates to a rolling bearing, and especially to a rolling bearing effectively usable under such usage conditions that a housing with the rolling bearing held thereon is elastically deformed by external force and off-load is applied to the bearing due to the resulting deformation or in such a field that the bearing is used at high temperature and high speed and under heavy load.
In the case of a rolling bearing employed, for example, in an alternator of an automobile, its outer race is prone to damage, primarily flaking and the like because its aluminum-made housing undergoes elastic deformation due to external force and off-load is hence applied. In the case of a rolling bearing employed in an electromagnetic clutch, on the other-hand, a shaft is made of aluminum so that its inner race to which off-load is exerted due to elastic deformation of the shaft is more susceptible to damage.
Employed as such conventional rolling bearings for automobiles are ball bearings each of which uses, for both outer and inner races, a bearing steel such as high-carbon chromium bearing steel having an oxygen content of 9 ppm or so. Standard heat treatment (socalled "whole quench hardening") has been applied to the race more susceptible to damage (i.e., the outer race in the case of an alternator or the inner race in the case of an electromagnetic clutch) to impart rolling contact fatigue strength thereto, and a grease comprising as a base oil a synthetic polyester lubricant or poly-a-olefin lubricant having a kinematic viscosity of 30-50 cSt at 400C is filled as a lubricant.
Reflecting the technological developments in recent years, bearings to be employed in electrical components of automobiles such as alternators and electromagnetic clutches are required to meet increasingly stringent usage conditions. In particular, usage conditions for bearings to be used in alternators are becoming far more stringent, including higher temperature and speed because of higher engine performance and heavier load due to an increased belt tension. Bearings of the conventional specification, however, cannot cope with such changes in usage conditions, leading to frequent occurrence of the problem that their life is shortened due to premature flaking of the raceway sur- faces of their outer races. There is accordingly an outstanding demand for the effective solution of the problem.
With the above-described problem of the prior art in view, the present invention has as an object the provision of a rolling bearing which does not develop premature flaking even at high temperature and speed and under heavy load.
The present inventors have proceeded with an extensive investigation on the premature flaking phenomenon of bearings in electrical components for vehicles, especially in alternators, the usage conditions of which bearings are becoming more stringent, as described above, resulting in the finding of some causes for the premature flaking phenomenon. This finding has led to the completion of the present invention.
The present invention therefore provides a rolling bearing composed of an outer race, an inner race and rolling elements interposed between the outer race and the inner race. The rolling bearing is filled with lubricant composition which comprises, as a base oil, polyether lubricant having a kinematic viscosity of is 90-160 cSt at 400C.
Preferably, the outer race and/or inner race of the rolling bearing is made of steel having an oxygen content not higher than 6 ppm and a raceway surface thereof has been hardened to a necessary hardness by heat treatment. The polyether lubricant can preferably be a polyphenyl ether lubricant, for example, a polyalkyldiphenyl ether lubricant.
The rolling bearing according to the present invention has brought about numerous advantages. In particular, use of a polyether lubricant having a kinematic viscosity of 90-160 cSt at 400C as a base oil makes it possible to bring about the advantage that, even under severe conditions of high temperature, high speed and heavy load, an oil film of an appropriate thickness can be retained between rolling elements and races so the premature flaking phenomenon of bearings can be effectively prevented. This advantage can be enhanced where the races of the rolling bearing are made of steel having an oxygen content not higher than 6 ppm and the raceway surfaces thereof.are hardened to a necessary hardness by heat treatment.
is The present invention will now be explained by way of example in the following description and the appended claims, taken in conjunction with the accompanying drawings in which:
FIG. 1 is a vertical cross-section of a sealed radial ball bearing to be described subsequently in Example 1; FIG. 2 is a cross-section of the bearing of FIG. 1, taken along line II- II of FIG. 1.
FIG. 3 is a graph showing differences in bearing life due to differences in the lubricant composition filled in each bearing; FIG. 4 is a graph illustrating effects for the prolongation of bearing life by the carburization of the races of a bearing; and FIG. 5 is a graph depicting effects on bearing life by reduction in the oxygen content of bearing steel.
Among the causes for the premature flaking phenomenon of bearings, there are particularly strong correlations between the kind and viscosity of a base oil for a grease used as a lubricant and the premature flaking phenomenon. Marked flaking is observed with greases whose base oils have a kinematic viscosity lower than 90 eSt at 40C, because such greases -presumably fail to ensure the formation of an oil film of a thickness required under such high temperature and speed and heavy load conditions as described above and hence to provide appropriate damper effects. In contrast, the use of a polyether lubricant having a kinematic viscosity of at least 90 cSt but not higher than 160 cSt at 4TC as a base oil has been found to retain an oil film of a thickness efficient even at high temperature and high speed and further to have a pressure viscosity index effective for heavy load, thereby making it possible to extremely effectively inhibit the premature flaking phenomenon of bearings. Incidentally, kinematic viscosities higher than 160 cSt at 400C tend to result in excessive agitation resistance by the filled greases upon operation of bearings so that phenomena such as a torque increase and heat generation would become more conspicuous. Such high kinematic viscosities are therefore not preferred.
As another cause, influence by impurities in steel employed as a bearing material is observed. It has also been found that use of a high-purity material with the total content of such impurities reduced to an oxygen content not higher than 6 ppm is effective for the prevention of the premature flaking phenomenon.
Further, application of heat treatment such as carburization, carbonitridation or induction hardening to the raceway surface of an outer race, to which raceway surface off-load is exerted, has been found to permit diffusion of carbon atoms in a top layer of the raceway surface to result in reinforcement by solid solution, an increase in the content of residual austenite and the development of residual compressive strain, effectively contributing to the prevention of the premature flaking phenomenon.
Based on these findings, the present inventors have completed the present invention as mentioned above. The present invention will hereinafter be described in more detail on the basis of the following examples. It should however be borne in mind that the present invention is not limited to or by the following examples. Example 1 FIG. 1 is a vertical cross-section of a sealed radial ball bearing (JIS bearing No. 6303) according to first embodiment of this invention, whereas FIG. 2 is cross-section taken along line II-II of FIG. 1. In- terposed between an outer race 1 and an inner race 2 are rolling elements 3. The rolling elements 3 are rotatably held by corrugated retainers 5 integrated together by connecting rivets 4. A lubricant grease G is filled between the inner race 2 and the outer race 1 and is sealed by seal members 6.
Using that bearing as a test sample, differences in anti-flaking life depending primarily on differences in the lubricant composition filled in the bearing were substantiated.
A test was conducted as an actual machine test in which the test sample was mounted on the side of a pulley of an alternator and the presence or absence of flaking on each raceway surface was observed after being operated for a predetermined time. The revolution speed was changed over between 9,000 rpm and 18,000 rpm at every loth second, so that a rapid acceleration-deceleration endurance test was conducted.
A bearing according to the present invention was filled with a grease as a lubricant composition, which grease contained as a base oil a polyalkyldiphenyl ether lubricant having a kinematic viscosity in the range of from 90 cSt to 160 cSt at 400C. As a steel, a steel having an oxygen content of 6 ppm, namely, a socalled high-purity carburized steel, was used. The t raceway surface of an outer race had been subjected to carburization.
A bearing of Comparative Example 1 was filled with a grease as a lubricant composition, which grease contained as a base oil a polyester lubricant having a kinematic viscosity in a range of 30-50 cSt at 400C. As a steel, a high-carbon chromium bearing steel having an oxygen content of 9 ppm was used. The raceway surface of an outer race had been subjected to standard heat treatment (whole quench hardening).
A bearing of Comparative Example 2 was filled with a grease as a lubricant composition, which grease contained as a base oil a poly-a- olefin lubricant having a kinematic viscosity in a range of 30-50 cSt at 400C. As a steel, a steel having an oxygen content of 6 ppm, namely, a so- called high-purity carburized steel was used. The raceway surface of an outer race had been subjected to carburization.
The test was conducted on 5 pieces of each of the above test samples. Using as a basis the time in which development of flaking was observed first among the sample pieces of Comparative Example 1, the presence or absence of developed flaking in an operation time 5 times as long as the former time was observed. Th e results are shown in FIG. 3.
According to the results of the severe alternator actual machine test, development of flaking was observed at an early stage on all the sample pieces of -Comparative Example 1 directed to the conventional product. In Comparative Example 2 in which the conventional grease was filled as a lubricant composition, two out of the five sample pieces developed flaking at an early stage although they were the same in steel and heat treatment as the sample pieces of the present invention.
In contrast, the sample pieces of the invention sample were all free from flaking, thereby clearly demonstrating the marked effects for the prolongation of the bearing life by the use of the lubricant according to the present invention. Example 2 Effects for the prolongation of bearing life by the carburization of bearing races were substantiated.
Thrust ball bearings were used as test samples. A life comparison test was conducted on those equipped with races made of conventional high capbon chromium bearing steel (SUJ2) and subjected to whole quench hardening and also on those equipped with races made of chromium steel (SCr420) and subjected to carburization. The results of the life comparison test are shown in a a Weibull chart of FIG. 4.
The test samples were mounted on a thrust-type life testing machine and tested under the following conditions.
Maximum Hertzian stress (Pmax): 560 kgf/mm2 Revolution speed (N): 3,000 rpm Lubricant: #150 turbine oil Temperature: 125-1300C From FIG. 4, effects for the prolongation of bearing life by carburization are clear. Example 3 Differences in effects for bearing life by differences in the content of oxygen in steels employed for bearings (namely, the levels of impurities in the steels, in other words, the degrees of purity of the steels) were substantiated.
As test samples, thrust ball bearings were used as in Example 2. Using a thrust-type life testing machine, a test was conducted under the following conditions on test samples made of conventional steel whose oxygen content was 9 ppm and also on test samples made of high-purity steel whose oxygen content was 6 ppm.
Maximum Hertzian stress (Pmax): 500 kgf/mm2 Revolution speed (N): 1,000 rpm Lubricant: #68 turbine oil The results are shown in a Weibull chart of FIG.
5.
From the figure, the life-prolonging effects of high-purity steel whose oxygen content is 6 ppm are evident.
In the above embodiments, carburization was applied as heat treatment. As well, carbonitridation, induction heating, standard heat treatment and the like can also be used effectively.
It is to be noted that the rolling bearing acCording to the present invention is not limited to the ball bearings in the above examples but include ball bearings of other types and roller bearings.
Further, the present invention can be equally applied to rolling bearings of the type where no seal members are directly provided on the bearings.
In the rolling bearing according to the present invention, the lubricant composition can be added with known additives as needed. These known additives include thickeners, oxidation inhibitors, rust preventives, extreme pressure additives, o-iiiness agents, corrosion inhibitors, solid lubricants, etc. For example, sodium nitrite can be added as a rust preventive.
i 1 2 3 4 5 6 1 2 3 4 3 1 2 3 1 2 3

Claims (5)

CLAIMS:
1. A rolling bearing composed of an outer race, an inner race and rolling elements interposed between the outer race and the inner race, wherein the bearing is filled with a lubricant composition comprising, as a base oil, a polyether lubricant whose kinematic viscosity is 90-160 cSt at 4CC.
2. The rolling bearing of claim 1, wherein the outer race and/or inner race of the rolling bearing is made of steel having an oxygen content not higher than 6 ppm and a raceway surface thereof has been hardened to a predetermined hardness by heat treatment.
1
3. The rolling bearing of claim 1 or 2, wherein 2 the polyether lubricant is a polyphenyl ether lubricant.
4. The rolling bearing of claim 3, wherein the polyphenyl ether lubricant is a polyalkyldiphenyl ether lubricant.
5. A rolling bearing substantially as hereinbefore described with reference to, and as shown in, the accompanying drawings.
GB9210979A 1991-09-20 1992-05-22 Rolling bearing Expired - Fee Related GB2259711B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24117991 1991-09-20

Publications (3)

Publication Number Publication Date
GB9210979D0 GB9210979D0 (en) 1992-07-08
GB2259711A true GB2259711A (en) 1993-03-24
GB2259711B GB2259711B (en) 1995-07-05

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GB9210979A Expired - Fee Related GB2259711B (en) 1991-09-20 1992-05-22 Rolling bearing

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DE (1) DE4217566C2 (en)
FR (1) FR2681655B1 (en)
GB (1) GB2259711B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2269598A (en) * 1992-08-06 1994-02-16 Nsk Ltd Rolling bearing
US5385412A (en) * 1991-09-20 1995-01-31 Nsk Ltd. Rolling bearing
US6165289A (en) * 1996-02-08 2000-12-26 Nsk Ltd. Water-resistant long-life rolling bearing

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3646467B2 (en) * 1996-07-31 2005-05-11 日本精工株式会社 Rolling bearing
US6267511B1 (en) 1998-03-05 2001-07-31 Nsk Ltd. Rolling bearing

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB601604A (en) * 1944-05-30 1948-05-10 Carbide & Carbon Chem Corp Improvements in production of polyoxypropylene compounds
GB615188A (en) * 1945-08-22 1949-01-03 Carbide & Carbon Chem Corp Lubricating grease compositions
GB642255A (en) * 1946-09-30 1950-08-30 Bataafsche Petroleum Lubricating compositions
EP0064236A1 (en) * 1981-05-06 1982-11-10 Bayer Ag Polyethers, their preparation and their use as lubricants

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62132031A (en) * 1985-12-03 1987-06-15 Ntn Toyo Bearing Co Ltd Rolling bearing
JPH0788851B2 (en) * 1987-08-25 1995-09-27 日本精工株式会社 Rolling bearing
US4992111A (en) * 1988-08-15 1991-02-12 N.T.N. Corporation Bearing race member and method of fabrication
GB2235212B (en) * 1989-07-25 1993-08-11 Nippon Seiko Kk Rolling bearing
DE3926577A1 (en) * 1989-08-11 1991-02-14 Leybold Ag VACUUM PUMP WITH A ROTOR AND ROTOR BEARINGS OPERATED WITH VACUUM
US5298323A (en) * 1989-10-11 1994-03-29 Nippon Seiko Kabushiki Kaisha Bearing steel and rolling bearing made thereof
DE9102855U1 (en) * 1991-03-09 1991-06-20 Leybold Ag, 6450 Hanau, De

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB601604A (en) * 1944-05-30 1948-05-10 Carbide & Carbon Chem Corp Improvements in production of polyoxypropylene compounds
GB615188A (en) * 1945-08-22 1949-01-03 Carbide & Carbon Chem Corp Lubricating grease compositions
GB642255A (en) * 1946-09-30 1950-08-30 Bataafsche Petroleum Lubricating compositions
EP0064236A1 (en) * 1981-05-06 1982-11-10 Bayer Ag Polyethers, their preparation and their use as lubricants

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5385412A (en) * 1991-09-20 1995-01-31 Nsk Ltd. Rolling bearing
GB2269598A (en) * 1992-08-06 1994-02-16 Nsk Ltd Rolling bearing
GB2269598B (en) * 1992-08-06 1995-12-06 Nsk Ltd Rolling bearing
US6165289A (en) * 1996-02-08 2000-12-26 Nsk Ltd. Water-resistant long-life rolling bearing

Also Published As

Publication number Publication date
GB9210979D0 (en) 1992-07-08
GB2259711B (en) 1995-07-05
DE4217566A1 (en) 1993-03-25
DE4217566C2 (en) 1998-09-17
FR2681655B1 (en) 1994-09-23
FR2681655A1 (en) 1993-03-26

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746 Register noted 'licences of right' (sect. 46/1977)

Effective date: 20010426

PCNP Patent ceased through non-payment of renewal fee

Effective date: 20060522