GB2249213A - A battery - Google Patents

A battery Download PDF

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Publication number
GB2249213A
GB2249213A GB9004958A GB9004958A GB2249213A GB 2249213 A GB2249213 A GB 2249213A GB 9004958 A GB9004958 A GB 9004958A GB 9004958 A GB9004958 A GB 9004958A GB 2249213 A GB2249213 A GB 2249213A
Authority
GB
United Kingdom
Prior art keywords
battery
layer
electrode
multilayer composite
electrically
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB9004958A
Other versions
GB9004958D0 (en
Inventor
Alexander Gilmour
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dowty Electronic Components Ltd
Original Assignee
Dowty Electronic Components Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dowty Electronic Components Ltd filed Critical Dowty Electronic Components Ltd
Priority to GB9004958A priority Critical patent/GB2249213A/en
Publication of GB9004958D0 publication Critical patent/GB9004958D0/en
Publication of GB2249213A publication Critical patent/GB2249213A/en
Withdrawn legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/661Metal or alloys, e.g. alloy coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/16Cells with non-aqueous electrolyte with organic electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Primary Cells (AREA)

Abstract

A battery comprising at least one electrochemical cell in which the, or each of the, electrochemical cells includes a bipolar multilayer composite electrode member (5), which member has a layered structure comprising: - a positive electrode material (6) deposited on an electrically @ conducting foil member (7); - an electrically insulating layer (8); - an electrically conducting layer (9); and - a negative electrode (10); wherein the bipolar multilayer electrode member is formed as a single unit (5). <IMAGE>

Description

A BATTERY This invention relates to a battery having at least one electrochemical cell and, in particular, a battery having at least one electrochemical cell which includes a multilayer bipolar composite electrode.
In accordance with the present invention, a battery comprises at least one electrochemical cell in which the, or each of the, electrochemical cells includes a bipolar multilayer composite electrode member, which member has a layered structure comprising: - a positive electrode material deposited on an electrically conducting foil member; - an electrically insulating layer; - an electrically conducting layer; and - a negative electrode; wherein the bipolar multilayer electrode member is formed as a single unit.
In one form of battery made in accordance with the present invention the, or each, electrochemical cell also includes a liquid electrolyte material.
In a particular form of the present invention including liquid electrolyte material, the bipolar multilayer electrode member is wound together with a separate sheet of separator material to form a core member which is at least partially immersed in the liquid electrolyte material.
Alternatively, in a battery including liquid electrolyte material the bipolar multilayer electrode member is folded to form a core member which is at least partially immersed in the liquid electrolyte material.
In a second form of battery made in accordance with the present invention, the or each electrochemical cell includes solid electrode material which is disposed so that in the formed battery the solid electrolyte material is disposed between the positive and negative electrode.
In one particular arrangement of this form of battery the solid electrolyte material and the bipolar multilayer composite electrode member are wound together to form the core member.
Preferably, the negative electrode is formed from lithium metal or a lithium alloy.
Preferably, the electrically conducting layer is a vapour deposited layer of metal, for example vapour deposited copper or nickel. Alternatively a simple foil, for example copper or nickel, member may be used.
The electrically insulating layer may be formed from any suitable material for example, Aluminium Oxide, Polyester material, Polypropylene, Polyethylene or a fluoro-polymer (e.g. 'Tefzel').
Preferably, the electrically conducting foil member onto which the positive electrode material is deposited is Aluminium foil.
A battery made in accordance with the present invention may be a primary or secondary battery.
In a specific example of the present invention, the bipolar multilayer composite electrode member has a layered structure as follows: - a Manganese Dioxide positive electrode which is deposited on an electrically conducting aluminium foil member; - an electrically insulating layer; - a copper or nickel foil member; and - a lithium metal or lithium alloy negative; wherein the layers are formed as a unitary member.
The invention will now be illustrated by way of description of an example with reference to the accompanying drawings, in which: Figure 1 shows a schematic representation of a battery made in accordance with the present invention; and Figure 2 shows a schematic representation of bipolar multilayer composite electrode member incorporated in a battery as shown in Figure 1.
Now referring to the drawings, a battery made in accordance with the present invention comprises: - a casing 1 which forms the negative terminal of the battery; - a cap member 2 which forms the positive terminal of the battery; - a sealing member 3 which in addition to sealing the internal atmosphere of the battery from the external atmosphere, is positioned to electrically insulate the negative terminal from the positive terminal and vice-versa; - liquid electrolyte material 4 sealed within the casing 1; and - a wound core member 5 positioned and sealed within the casing 1.
The wound core member 5 comprises a multilayer composite electrode which is wound together with a thin sheet of separator material.
The multilayer composite electrode comprises a five layered structure, in which the layers are made up as follows: - a first layer 6 which comprises the positive electrode; - a second layer 7 onto which the first layer 6 is deposited and which comprises a foil member; - a third layer 8 which comprises an electrically insulating layer; - a fourth layer 9 which comprises an electrically conducting layer; and - a fifth layer 10 which comprises the negative electrode.
In one particular example the multilayer composite electrode comprises: - a first layer 6 cf Manganese Dioxide (MnO2) with Carbo- Black binder of between 100 and 20 microns thickness; - a second layer 7 of aluminium foil of between 9 and 18 macrons thickness; - a third layer 8 o- aluminium oxide of between 5 and 10 microns thickness; - a fourth layer 9 of vapour deposited metal for example, copper or nickel of approximately 1 micron thickness; and - a fifth layer 10 of lithium metal or lithium alloy of between 30 and 60 microns thickness.
This multilayer composite electrode is bipolar in nature, and has a total thickness of between 100 and 300 microns.
For assembly into the battery the multilayer composite electrode is wound with the negative electrode 10 facing inwardly with a sheet of separator material in order to form the core of the battery. The multilayer composite electrode is wound in this configuration because the lithium metal or lithium alloy forming the layer 10 is more likely to deform than the Manganese Dioxide (MnO2) layer 6, which would crumble, under the forces induced by winding.
In an alternative configuration the multilayer composite electrode may be folded, and then placed in the electrolyte material.

Claims (1)

1. A battery comprising at least one electrochemical cell in which the, or each of the, electrochemical cells includes a bipolar multilayer composite electrode member, which member has a layered structure comprising: - a positive electrode material deposited on an electrically conducting foil member; - an electrically insulating layer; - an electrically conducting layer; and - a negative electrode; .-.Awherein the bipolar multilayer electrode member is formed as a single unit.
GB9004958A 1990-03-06 1990-03-06 A battery Withdrawn GB2249213A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB9004958A GB2249213A (en) 1990-03-06 1990-03-06 A battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9004958A GB2249213A (en) 1990-03-06 1990-03-06 A battery

Publications (2)

Publication Number Publication Date
GB9004958D0 GB9004958D0 (en) 1990-05-02
GB2249213A true GB2249213A (en) 1992-04-29

Family

ID=10672061

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9004958A Withdrawn GB2249213A (en) 1990-03-06 1990-03-06 A battery

Country Status (1)

Country Link
GB (1) GB2249213A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4091184A (en) * 1977-08-19 1978-05-23 The United States Of America As Represented By The Secretary Of The Air Force High power, rechargeable, pile type silver zinc battery
EP0239343A2 (en) * 1986-03-24 1987-09-30 Ensci, Inc. Battery element and battery incorporating doped tin oxide coated substrate

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4091184A (en) * 1977-08-19 1978-05-23 The United States Of America As Represented By The Secretary Of The Air Force High power, rechargeable, pile type silver zinc battery
EP0239343A2 (en) * 1986-03-24 1987-09-30 Ensci, Inc. Battery element and battery incorporating doped tin oxide coated substrate

Also Published As

Publication number Publication date
GB9004958D0 (en) 1990-05-02

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Legal Events

Date Code Title Description
WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)