GB2225331A - Curable polysiloxane compositions - Google Patents
Curable polysiloxane compositions Download PDFInfo
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- GB2225331A GB2225331A GB8923168A GB8923168A GB2225331A GB 2225331 A GB2225331 A GB 2225331A GB 8923168 A GB8923168 A GB 8923168A GB 8923168 A GB8923168 A GB 8923168A GB 2225331 A GB2225331 A GB 2225331A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S528/901—Room temperature curable silicon-containing polymer
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Description
1 1 1 CURABLE COMPOSITIONS 2225331 1 2 This invention relates to curable
compositions and particularly to compositions containing a curable silicone.
According to the present invention a composition curable at room temperature comprises a silanol-terminated polyorganosiloxane, a crosshnldng agent which is an organic silane free of isocyanate groups and a metal organic compound containing a Ti-O-P bond.
The compositions of the present invention when cured have a much reduced tendency to be coloured yellow than compositions containing other types of metal organic compounds and also other types of cross-linking agents.
The Ti-O-P group containing metal organic compounds may be used as catalysts, crosslinkers, chain extenders, adhesion promoters or water scavengers. The exact role of the Ti-O-P bond containing metal organic compound will be dependant upon the type of silane, curing agent or crosslinker employed.
The compositions of the present invention are those based on polyorganosiloxanes which are silanol terminated and such siloxanes are those containing a hydroxyl group bonded to a silicon atom and which form a cured product by means of crosslinking.
Siloxanes of a wide range of viscosities and molecular weights can be used in the present invention and the siloxanes can have a wide range of chemical compositions containing various organic groups. Two or more different siloxanes can be mixed and cured simultaneously in a single composition in accordance with the present invention. Alkyl siloxanes or aryl siloxanes can be used as can alkyl-aryl siloxanes and examples of these are di-hydro)cy-di-alkyl polysiloxanes, e.g. dihydroxydimethyl polyk 1 3 siloxane and dihydroxy alkylaryl polysiloxanes, e.g. dihydroxymethylphenyl polysiloxane.
Siianol-terminated polyorganosiloxanes are well known and preferably have a viscosity in the range of from about 100 to about 400,000 centipoise and more preferably from about 1000 to 250,000 centipoise when measured at 250C. These silanol terminated fluids can be made by treating a higher molecular weight organopolysiloxane, such as dimethyl-polysfloxane with water in the presence of a mineral acid, or base catalyst, to tailor the viscosity of the polymer to the desired range. Methods for making such high molecular weight organopolysiloxane utilized in the production of silanol-terminated polydiorganosiloxane are well known. For example hydrolysis of a diorganohalosilane such as dimethyldichlorosilane, diphenyldichlorosilane, methylvinyldichlorosilane, or mixtures thereof, can provide for the production of low molecular weight hydrolysate. Equilibration thereafter can provide for higher molecular weight organopolysiloxane. Equilibration of cyclopolysiloxane such as octamethylcyclotetrasiloxane, octaphenylcyclotetrasiloxane, or mixtures thereof, will also provide for higher molecular weight polymers. Other methods that can be employed to make silanol-terminated polydiorganosiloxanes are more particularly described in U.S. Patent No. 2 607 792 to Warrick and U.K Patent No. 835 790 The compositions of the present invention include as a crosslinking agent an organic silane which is free of isocyanate groups. Examples of classes of silanes which are useful in the compositions of the present invention are those generally known as alkoxy silanes, oxime silanes and allcyl silanes with hydrolysable Si-N groups.
1 4 Alkoxy silanes which can be used are those having the general formula RxSi(OR1)4-x in which R represents a monovalent radical having 1 to 18 carbon atoms and is a hydrocarbon radical, a halohydrocarbon radical or a cyanoalkyl radical, R' is a monovalent radical which is a halogenated aliphatic hydrocarbon radical or an aliphatic hydrocarbon radical both having preferably less than 5 carbon atoms and x is 0 or 1. Examples of R groups are akl groups such as methyl, ethyl, propyl, hexyl or octadecyl, alkenyl radicals such as vinyl, allyl, hexenyl and methallyl radicals, cycloaliphatic hydrocarbon radicals, or alkyl hydrocarbon radicals such as benzyl radicals and aryl radicals. R' can be an alkyl group such as methyl, ethyl, propyl or butyl or a halogenated radical such as betachloroethyl, beta-chlorobutyl and beta-bromopropyl radicals. Specific silanes which are of use in the compositions of the present invention are methyltrimethoxy silane, tetraethoxy silane, ethyltrimethoxy silane, vinyltrimethoxy silane, tetrabutoxy silane, and phenyltrimethoxy silane.
Examples of oxime-silanes are those of the general formula R2 4-n Si(ON = CR32)n where each R2 represents an alkyl group having less than 6 carbon atoms, a vinyl group, an allyl group or a phenyl group and each R3 represents an alkyl group having from 1 to 6 carbon atoms and may be the same or different groups, a phenyl group or a cyclo aliphatic group and n has an average value of from 2.1 to 3. In the general formula for the oxime-silanes R2 may be for example, methg ethyl, propyl, vinyl, allyl or phenyl. Examples of specific oximesfianes are methyltris(methylethyl ketoxime) silane, vinyltris(methylethylketoxime)silane, methyltris (diethyl ketoxime) silane and phenyltris(methylethylketoxime) silane.
The crosslinking agent can also be an alkyl silane with hydrolysable Si-N groups of the general formula RI(CH3)Si(N(R1)R6)2 in which R' represents an alkyl radical, an alkoxy group or cycloalkyl radical with up to 8 carbon atoms, R' represents H, -C(O)R1 or R' in which R' represents an akl, cycloalkyl, aryl or aralkyl radical.
Examples of these silanes which can be employed are dimethyldi-N methyl benzamidosilane, ethoxy methyl-di-N-methyl benzamidosilane, dimethyl-dibutyl aminosilane, dimethylcyclohexylarninosilane, methyl ethyl-di-N-methylbenzarriidosilane, methyl-propyl-di-N-methylbenz amidosilane and dicyclohexylaminosilanes. In the formula each R' group can be the same or can be different.
The metal organic compounds containing a Ti-O-P group useful in the present invention are such as those produced by reacting an organic phosphorus compound containing a P-OH group with a titanium orthoester.
Typical organic phosphorus compounds which can be used are the trivalent and pentavalent acid phosphorus compounds having the general formulae:- 6 OR? OR 11 0 0 1 10 1 R12 11 li I') HO - P -OR HO - P - OH; 0-P - 0 - P OR 11.11 - 1 1 0 0 OH OH (A) (B) (C) 1 R? HO - P - 0 R13 OH 1 1 1 14 1 HO - P - 0; OH; HO - P - OH R - p 11 11 0 0 1 (D) (E) (F) (G) In the above mentioned formulae the R group identified represents substituted or unsubstituted hydrocarbon radicals and may be the same or different within each individual formula. Specific examples of the compounds are di-n-butyl acid phosphate, di(2-ethyl hexyl) acid phosphate, di-hexyl acid phosphate, mono-butyl acid phosphate, monohexyl acid phosphate, mono-2-ethyl hexyl acid phosphate, di-(2-ethyl hexyl) acid pyrophosphate, chloro-methyl phosphohic acid, propyl phosphonic acid, vinyl phosphonic acid, methyl phosphonic acid and ethyl (methyl) phosphinic acid.
Mono-alkyl acid phosphates or di-akl acid phosphates can be used to prepare the Ti-0-P group containing compounds but it is preferred to employ a mixture of the mono- and di-akl acid phosphates.
The alkyl acid phosphate is reacted with a titanium orthoester such as one having the general formula Ti(OR154 in which R16 represents a substituted or unsubstituted hydrocarbon group and in any one compound two or more R16 groups may be- the same or different. Typical orthoesters are those containing alkyl groups with up to 10 If A 1 7 carbon atoms, preferably up to 6 carbon atoms in each alkyl group and such orthoesters, are tetra isopropyl titanate, tetra-n-butyl titanate, tetran-propyl titanate, tetra-iso-butyl titanate, tetra-2-ethyl hexyl titanate, and tetra-diethylene glycol titanate.
The preferred Ti-O-P group containing compounds usually are the reaction products of the titanium orthoester and alkyl acid phosphate in an amount of from 0. 1 mole to 4 moles alkyl acid phosphate per mole of the titanium orthoester. Preferably the Ti:P mole ratio of the Ti-O-P group containing compound is within the range L0.5 to 12.
Usually the Ti-O-P group containing compound is prepared by reacting the titanium orthoester and the alkyl acid phosphate at room temperature and, if desired, removing any alcohol formed during the reaction under reduced pressue. Whilst it is preferred to remove the alcohol it is not necessary to do so.
The compositions of the present invention are prepared by mixing the essential ingredients in the absence of moisture together with any other desired components such as fillers or pigments. The filler can be one which reinforces the cured composition or not and typical fillers are those based on silica e.g. fumed silica, precipitated silica, silica aerogel or others such as calcium carbonate, fine mica or magnesia.
If desired the composition can contain a solvent to produce compositions of chosen viscosity which can be spread or otherwise applied to the surface to be treated.
Compositions containing from 0.1 to 30 parts by weight, preferably from 0. 5 to 25 parts by weight of the crosslinking agent per 100 parts by weight of the polyorganosiloxane are useful. Also the 8 amount of the TPO-P group containing compound is usually in the range 0.1 to 25 parts by weight, preferably 0.5 to 15 parts by weight and more preferably 0.5 to 8 parts by weight per 100 parts of the polyorganosiloxane.
Compositions of the present invention can be used as a coating material, a casting material, a filler or as a sealant. The compositions cure on exposure to the atmosphere producing crosslinked products having a much reduced tendency to be discoloured.
Each of the synthesis examples illustrates a process for synthesizing a Ti-O-P group containing metal organic compound which is useful in the present invention.
Synthesis EMMJ21C 1 To a round bottomed flask equipped with a stirrer, dropping funnel thermometer and distillation apparatus (still-head, condenser and receiver) and containing 1.0 mole (284 gms) of tetraisopropyl titanate there was slowly added from the funnel 1.0 mole (266g) of a commercial mixture of approximately equi-molar proportions of mono-2-ethylhexyl acid phosphate and di-2-ethylhexyl acid phosphate whilst stirring the reaction mixture. On completion of the addition the temperature of the mixture was raised to 90-950C and the isopropyl alcohol released during the reaction was distilled off. 426g of a clear, pale yellow liquid was obtained.
Synthesis Example 2 A Ti-O-P group containing metal organic compound was prepared in a manner similar to that described in Synthesis Example 1 from 1.0 mole (340 gms) of tetra-n-butyl titanate and 1.0 mole (224 gms) of a commercial mixture of approximately equi-molar proportions of 1 a 9 mono-hexyl acid phosphate and di-hexyl acid phosphate. On removal of the n-butanol produced in the reaction, 434g of a clear, almost colourless liquid was obtained.
Synthesis FwMi2le 3 A Ti-O-P group containing metal organic compound was prepared in a manner similar to that described in Synthesis Example 1 from 1.0 mole (284 gms) tetraisopropyl titanate and 4.0 moles (1064 gms) of a commercial mixture of approximately equi-molar proportions of mono-2-ethylhexyl acid phosphate and di-2-ethyl hexyl acid phosphate. On removal of the isopropyl alcohol (240 gms; 4.0 moles) produced in the reaction, 1108g of a clear, yellow viscous liquid was obtained.
Synthesis Examj21e 4 A Ti-O-P group containing metal organic compound was prepared in a manner similar to Synthesis Example 1 from 1.0 mole (284 gms) of tetraisopropyl titanate and 1.0 mole (206 gms) of commercially available methyl acid pyrophosphate. On removal of the isopropanol produced in the reaction, 394g of a solid, white product was obtained.
Synthesis Ejp-Mi2le 5 A Ti-O-P group containing metal organic compound was prepared in a manner similar to Synthesis Example 1 from 1.0 mole (284 gms) of tetraisopropyl titanate and 1.0 mole (224 gms) of a commercial mixture of approximately equi-molar proportions of mono-hexyl acid phosphate and dPhexyl acid phosphate. On removal of the isopropanol produced in the reaction, 399g of a clear, pale yellow liquid was obtained.
&uthesis Example 6 A Ti-O-P group containing metal organic compound was prepared in a manner similar to Synthesis Example 1 from 1.0 mol (340 gms) of tetraisobutyl titanate and 1.0 mole (224 gms) of a commercial mixture of approximately equi-molar proportions of mono-hexyl acid phosphate and di-hexyl acid phosphate. On removal of the isobutanol produced in the reaction, 430g of a clear, pale yellow viscous liquid was obtained.
P:Le22aration Qf- the Silicone Sealant Masterbatches and Evaluation Qf the Ti-0 -P jeroup containing metal o coMpounds.
EXAMPLE 1
700 parts by weight of -dihydroxy-polydimethyl siloxane having a viscosity of 10,000 centipoise at 251C and 140 parts by weight of a methyl terminated polydimethylsiloxane having a viscosity of 300 centistokes at 251C were thoroughly mixed in a planetary mixer under reduced pressure. Once mixed, 100 parts by weight of fumed silica was added and thoroughly incorporated into the mixture again under reduced pressure.
Parts by weight of the resultant silicone masterbatch was placed in a commercially available mixing cartridge fitted with a titanate/silane injector. The cartridge is known as Injection Style Semkit Package Model 654 and supplied by Semco (a division of PRC).
3 parts by weight of methyl trimethoxy silane and 0.005 mole of a Ti-O-P group containing metal organic compound was injected and thoroughly mixed into the silicone masterbatch.
11 The resultant compositions were spread on PTFE plates to a thickness of about 2 mm and allowed to cure in air at room temperature. The Skin-over time Tack-free iime and Cure-through time for the compositions were determined and the colour of the cured sealant noted. Table 1 lists the titanates tested and the results obtained.
1^ TABLE 1
TITANIUM COMPOUND SILANE CURING SKIN OVER TA CK FREE CURE COLOUR OF TESTED AGENTEMPLOYED TIME TIME THROUGH CURED TIME SE,4LANT IEHAP10.5Ti[OCH(CH3)213 CH3Si(OMe)3 10 mins 10-15 mins < 10 hrs COLOURLESS [EHAP]l.oTi[OCH(CH3)212.0 CH3Si(OMe)3 10 mins 10-15 mins < 10 hrs COLOURLESS [EHAP]1.0Ti[O(CH2)3CH3]2.0 CH3Si(OMe)3 10 mins 10-15 mins < 10 hrs COLOURLESS IEHAP]4.OT' CH3Si(OMe)3 15 mins 50-60 mins < 24 hrs COLOURLESS [HAPI,.,Ti[OCH(CH3)212.0 CH3Si(OMe)3 10 mins 20 mins < 10 hrs COLOURLESS 1'W]1.2T'lo(CH2)3CH3]2.0 CH3SK0M03 10 mins 20 mins < 10 hrs COLOURLESS TILCOM KE2 C113Si(OMC)3 10 mins 20 mins < 10 hrs PALE YELLX)W NONE i(OMe)3 8 hrs 24 hrs <48 hrs COLOURLESS NOTE:- (1) Ile Ti-O-P group containing metal-organic compounds shown in Table I were prepared as previously described and derived from tile commercially available equi-molar mixtures of either mono-and di-2- ethylhexyl acid phosphate [EHAPI, or mono- and di hexyl acid phosphate [HAP].
(2) TILCOM KE2, which is diisopropoxy-titanium bis(ethylacetoacetate), is a commercially available product supplied by the Chemicals Division of Tioxide UK Limited and tested for purposes of comparison.
m 13 EXAMPLE2
650 parts by weight of w- 'o -dihydroxy-poly-dimethylsiloxane having a viscosity of 80,000 centipoise at 250C and 250 parts by weight of a methyl terminated polydimethylsiloxane having a viscosity of 1000 centistokes at 251C were thoroughly mixed in a planetary mixer under reduced pressure. 80 parts by weight of fumed silica was added and thoroughly incorporated into the mixture, again under reduced pressure. 100 parts by weight of the resultant silicone masterbatch was placed in a commercially available mixing cartridge fitted with a titanate/silane injector. 3.5 parts by weight of methyl-tri(methyl ethyl ketoximino) silane and 0.005 mole of a Ti-O-P group containing metal organic compound was injected and thoroughly mixed into the silicone masterbatch. Use of the injection style mixing cartridge significantly reduces the possibility of moisture ingress during the incorporation of the titanate and silane into the silicone masterbatch.
The resultant compositions were spread onto a PTFE plate to a thickness of about 2 mm and allowed to cure in air at room temperature. The Skin- over time, Tack-free time and Cure-through time for the compositions were determined and the colour of the cured sealant noted. Table 2 lists the titanates tested and the results obtained.
TABLE 2
TITANIUM COMPOUND SILANE CURING SKIN OVER TACKFREE CURE COLOUR OF TESTED AGENTEMPLOIED TIME TIME THROUGH CURED TIME SEALANT AM CH3-13 NONE MeSi[O-N=C 8 hrs 22 hrs 48 hrs PALE YELLOW TILCOM KE2 09 4 hrs 6 hrs <24 hrs YELLOW/PALE ORANGE [EHAP11.0Ti[OCH(CH3)212.0 to of to to PALEYELLOW [EHM]1.0T'LO(CH2)3CH3]2.0 cc 11 of to 99 [HM],.,Ti[OCH(CH3)212.0 111.2T'lo(CH2)3CH3]2.0 1 ' 1.1 4:!,.
1 1 ' 1 EXAMPLE 3
450 parts by weight Of tl- -dihydroxy-poly-dimethylsiloxane having a viscosity of 50,000 centistokes at 251C and 109 parts by weight of a methyl terminated polydimethylsiloxane were thoroughly mixed in a planetary mixer under reduced pressure. 70 parts by weight of fumed silica and 7 parts by weight of dibutyl tin dilaurate were added and thoroughly incorporated into the mixture, again under reduced pressure.
parts by weight of the resultant silicone masterbatch was placed in a commercially available mixing cartridge fitted with a titanate/silane injector. 5.0 parts by weight of methyl-, ethoxy- bis (Nmethyl benzamido) silane [Vernetzer BA] and 0.012 mole of a Ti-O-P group containing metal organic compound was injected and thoroughly mixed into the silicone masterbatch.
The resultant compositions were spread onto a PTFE plate to a thickness of about 2 mm and allowed to cure in air at room temperature. The Skin- over time, Tack-free time and Cure-through time for the compositions were determined and the colour of the cured sealant noted. Table 3 list the titanates tested and the results obtained.
TABLE 3
TITANIUM COMPOUND SILANE CURING SKINOVER TACKFREE CURE COLOUR OF TESTED AGENTEMPLOYED TIME TIME THROUGH CURED TIME SE,4LANT --Me CH3 -,', 1 NONE. Si[N-C < 10 mins < 10 mins <24 hrs WHITE -CIHS]2 C2H50' b IITANATE'N 00 30 mins 60-70 mins If PALE ORANGE [EHAP11.0Ti[OCH(CH3)212.0 09 10 mins 15 mins of WHITE [EHAP]1.0Ti[O(CH2)3CH3]2.0 20 mins 25 mins [EHAP]1.0T'IOCH2CH(CH3)212.0 30 mins 60-70 mins [EHAP11.0Ti[O(CH2)2CH3]2.0 20 mins 25 mins If NOTE:- 1) 'nTANATE 'M which is di isobutoxy-titanium bis(ethylacetoacetate), was tested or comparative purposes.
4, - (n 17
Claims (21)
1. A composition curable at room temperature which comprises a silanolterminated polyorganosiloxane, a cross-linking agent which is an organic silane free of isocyanate groups and a metal organic compound containing a Ti-O-P bond.
2. A composition according to claim 1 in which the said silanolterminated polyorganosiloxane is selected from the class consisting of alkyl siloxanes, aryl siloxanes and alkyl-aryl siloxanes.
3. A composition according to claim 1 or 2 in which the said silanolterminated polyorganosiloxane has a viscosity at 250C in the range of from about 100 to about 400,000 centipoise.
4. A composition according to claim 3 in which the viscosity at 250C of the said silanol-terminated polyorganosiloxane is in the range of from about 1000 to 250,000 centipoise.
5. A composition according to any one of the preceding claims in which the said cross-linking agent is an alkoxy silane.
6. A composition according to any one of claims 1 to 4 in which the said cross-linking agent is an oxime silane.
7. A composition according to any one of claims 1 to 4 in which the said cross-linking agent is an alkyl silane with hydrolysable Si-N groups.
8. A composition according to any one of preceding claims in which the said metal organic compound is a compound produced by reacting an organic phosphorus compound containing a P-OH group with a titanium orthoester.
18
9. A composition according to claim 8 in which the said phosphorus compound is selected from phosphorus compounds having the following general formulae OR OR 0 0 HO-P-OR HO - P - OH RO -P - 0 -OR 0 OH OH R OH R OH 1 1 1 1 HO- P - R HO- P - R HO-P-OH R - P - R 11 h 0 0 in which R represents a substituted or unsubstituted hydrocarbon radical and within each individual formula each R group is the same or is different.
10. A composition according to claim 8 in which the said organic phosphorus compound is a mixture of mono- and di-alkyl acid phosphates.
11. A composition according to claim 8 in which the said organic phosphorus compound is an alkyl acid phosphate.
12. A composition according to claim 11 in which the said titanium orthoester is a compound of the formula Ti(OR)4 in which R represents an alkyl group containing up to 10 carbon atoms.
13. A composition according to claim 12 in which the said alkyl group contains up to 6 carbon atoms.
v 19
14. A composition according to anyone of claims 1 to 7 in which the said metal organic compound is a compound produced by reacting an alkyl acid phosphate with a titanium orthoester and in which the Ti:P molar ratio is from 10: 1 to 1A.
15. A composition according to claim 14 in which the said Ti:P molar ratio is from 2:1 to 1:2.
16. A composition according to any one of claims 1 to 7 in which the said metal organic compound is a compound produced by reacting an alkyl acid phosphate with a titanium orthoester and removing alcohol formed during the reaction.
17. A composition according to any one of the above claims in which the said cross-linking agent is present in an amount of 0.1 to 30 parts by weight per 100 parts of said polyorganosiloxane.
18. A composition according to claim 17 in which the amount of crosslinking agent is from 0.5 to 25 parts by weight per 100 parts of said polyorganosiloxane.
19. A composition according to any of the preceding claims in which the amount of said metal organic compound is in the range 0.1 to 25 parts by weight per 100 parts of said polyorganosfioxane.
20. A composition according to claim 19 in which the amount of metal organic compound is in the range 0.5 to 15 parts by weight per 100 parts polyorganosiloxane.
21. A composition according to claim 19 or 20 in which the amount of metal organic compound is in the range 0.5 to 8 parts by weight per 100 parts polyorganosiloxane.
1990atThe Patent 0Mce. State Emm,66171 Holborn,UndonWC1R4TP.Purther copies maybe obtainedtrom The patent OfAce.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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GB888825864A GB8825864D0 (en) | 1988-11-04 | 1988-11-04 | Curable compositions |
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GB8923168D0 GB8923168D0 (en) | 1989-11-29 |
GB2225331A true GB2225331A (en) | 1990-05-30 |
GB2225331B GB2225331B (en) | 1992-02-19 |
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GB8923168A Expired - Fee Related GB2225331B (en) | 1988-11-04 | 1989-10-13 | Curable compositions |
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US (1) | US5032660A (en) |
JP (1) | JP2763939B2 (en) |
BE (1) | BE1002268A5 (en) |
CA (1) | CA2000719C (en) |
DE (1) | DE3936107A1 (en) |
FR (1) | FR2638755B1 (en) |
GB (2) | GB8825864D0 (en) |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5302198A (en) * | 1990-09-14 | 1994-04-12 | Ncr Corporation | Coating solution for forming glassy layers |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9014564D0 (en) * | 1990-06-29 | 1990-08-22 | Courtaulds Coatings Holdings | Coating compositions |
JP4600611B2 (en) * | 1999-10-29 | 2010-12-15 | 昭和電工株式会社 | Abrasion-resistant water-repellent paint and articles having an abrasion-resistant water-repellent surface |
GB0112899D0 (en) * | 2001-05-29 | 2001-07-18 | Ici Plc | Coatings |
US8771807B2 (en) * | 2011-05-24 | 2014-07-08 | Air Products And Chemicals, Inc. | Organoaminosilane precursors and methods for making and using same |
EP2753655B1 (en) | 2011-09-07 | 2019-12-04 | Dow Silicones Corporation | Titanium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0076630A2 (en) * | 1981-10-05 | 1983-04-13 | Dow Corning Corporation | Color stable chelated titanate compositions |
GB2123432A (en) * | 1982-06-17 | 1984-02-01 | Matsumoto Seiyaku Kogyo Kk | Room temperature curable silicone compositions |
EP0175635A2 (en) * | 1984-09-11 | 1986-03-26 | Essex Group Inc. | High density moisture resistant mica cylinders |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2607792A (en) * | 1949-04-27 | 1952-08-19 | Dow Corning | Method of preparing dimethylpolysiloxane diols |
GB835790A (en) * | 1957-07-12 | 1960-05-25 | Rhone Poulenc Sa | Improvements in or relating to siloxane elastomers |
US3275668A (en) * | 1961-07-31 | 1966-09-27 | Cities Service Oil Co | Organometallic orthophosphates |
US3422126A (en) * | 1965-03-19 | 1969-01-14 | Du Pont | Preparation of titanium alkylorthophosphates |
GB1350420A (en) * | 1971-01-06 | 1974-04-18 | Gen Electric | Alkanedioxy titanium chelates |
US3856839A (en) * | 1971-01-06 | 1974-12-24 | Gen Electric | Alkanedioxy titanium chelates |
CA1103266A (en) * | 1975-05-15 | 1981-06-16 | Salvatore J. Monte | Alkoxy titanate salts useful as coupling agents |
US4094853A (en) * | 1975-05-15 | 1978-06-13 | Kenrich Petrochemicals, Inc. | Alkoxy titanate salts useful as coupling agents |
US4087402A (en) * | 1975-09-30 | 1978-05-02 | Kenrich Petrochemicals, Inc. | Organo-titanate chelates and their uses |
US4069192A (en) * | 1976-01-30 | 1978-01-17 | Kenrich Petrochemicals, Inc. | Liquid thermosetting resins containing titanate salts |
US4192792A (en) * | 1978-07-20 | 1980-03-11 | Kenrich Petrochemicals, Inc. | Atactic polypropylene |
JPS5917138B2 (en) * | 1980-06-30 | 1984-04-19 | 松本製薬工業株式会社 | Crosslinking method |
JPS57168946A (en) * | 1981-02-18 | 1982-10-18 | Matsumoto Seiyaku Kogyo Kk | Room temperature curing silicone composition |
JPS58162660A (en) * | 1982-03-19 | 1983-09-27 | Toray Silicone Co Ltd | Primer composition |
JPS58222149A (en) * | 1982-06-18 | 1983-12-23 | Matsumoto Seiyaku Kogyo Kk | Curable silicone composition |
JPS59170173A (en) * | 1983-03-18 | 1984-09-26 | Toagosei Chem Ind Co Ltd | Sealing agent |
GB8418517D0 (en) * | 1984-07-20 | 1984-08-22 | Tioxide Group Plc | Titanium compositions |
JPS6241263A (en) * | 1985-08-16 | 1987-02-23 | Shin Etsu Chem Co Ltd | Dynamic fatigue-resistant silicone rubber composition |
-
1988
- 1988-11-04 GB GB888825864A patent/GB8825864D0/en active Pending
-
1989
- 1989-10-13 GB GB8923168A patent/GB2225331B/en not_active Expired - Fee Related
- 1989-10-16 CA CA002000719A patent/CA2000719C/en not_active Expired - Fee Related
- 1989-10-17 US US07/422,459 patent/US5032660A/en not_active Expired - Lifetime
- 1989-10-25 NL NL8902643A patent/NL8902643A/en active Search and Examination
- 1989-10-30 DE DE3936107A patent/DE3936107A1/en not_active Withdrawn
- 1989-10-31 BE BE8901160A patent/BE1002268A5/en not_active IP Right Cessation
- 1989-11-02 JP JP1287313A patent/JP2763939B2/en not_active Expired - Fee Related
- 1989-11-03 FR FR8914462A patent/FR2638755B1/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0076630A2 (en) * | 1981-10-05 | 1983-04-13 | Dow Corning Corporation | Color stable chelated titanate compositions |
GB2123432A (en) * | 1982-06-17 | 1984-02-01 | Matsumoto Seiyaku Kogyo Kk | Room temperature curable silicone compositions |
EP0175635A2 (en) * | 1984-09-11 | 1986-03-26 | Essex Group Inc. | High density moisture resistant mica cylinders |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5302198A (en) * | 1990-09-14 | 1994-04-12 | Ncr Corporation | Coating solution for forming glassy layers |
Also Published As
Publication number | Publication date |
---|---|
CA2000719A1 (en) | 1990-05-04 |
JP2763939B2 (en) | 1998-06-11 |
BE1002268A5 (en) | 1990-11-13 |
JPH02182761A (en) | 1990-07-17 |
CA2000719C (en) | 2000-01-04 |
DE3936107A1 (en) | 1990-05-10 |
GB8825864D0 (en) | 1988-12-07 |
GB2225331B (en) | 1992-02-19 |
FR2638755B1 (en) | 1993-10-08 |
US5032660A (en) | 1991-07-16 |
FR2638755A1 (en) | 1990-05-11 |
NL8902643A (en) | 1990-06-01 |
GB8923168D0 (en) | 1989-11-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
732E | Amendments to the register in respect of changes of name or changes affecting rights (sect. 32/1977) | ||
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20031013 |