GB2221685A - Moulding compositions - Google Patents
Moulding compositions Download PDFInfo
- Publication number
- GB2221685A GB2221685A GB8918378A GB8918378A GB2221685A GB 2221685 A GB2221685 A GB 2221685A GB 8918378 A GB8918378 A GB 8918378A GB 8918378 A GB8918378 A GB 8918378A GB 2221685 A GB2221685 A GB 2221685A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mechanical elements
- movable mechanical
- composition
- resin
- polyacetal resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B33/00—Constructional parts, details or accessories not provided for in the other groups of this subclass
- G11B33/02—Cabinets; Cases; Stands; Disposition of apparatus therein or thereon
- G11B33/08—Insulation or absorption of undesired vibrations or sounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Abstract
A material for use in the manufacture of movable mechanical elements comprises 20% and 80% by weight of polyacetal resin with the remaining weight percent being polyamide alloy resin or polyether polyamide block copolymers.
Description
MATERIAL FOR USE IN MANUFACTURING
MOVABLE MECHANICAL ELEMENTS
The present invention relates to material for use in the manufacture of movable mechanical elements, and more particularly, to material for use in the manufacture of movable mechanical elements of audio and/or video components.
Audio and/or video apparatus, such as an audio tape recorder and a video tape recorder, include many movable mechanical elements. For example, the movable mechanical elements are used as gears, pulleys, levers, etc. for driving audio and/or video tapes. Recently, such movable mechanical elements are required to be less noisy. That is, each of two movable mechanical elements which mesh or contact with each other are made of material with higher noise depression characteristics.
On the other hand, the movable mechanical elements are increasingly reduced in size and weight. For reducing the size and weight the movable mechanical elements are made smaller and thinner. Therefore, material for manufacturing the movable mechanical elements must have both a better sound depressing ability and a strong rigidity.
Conventionally, one of the movable mechanical elements which mesh or contact with another is made of polyacetal resin and the other is made of polyamide resin. In other words, two movable mechanical elements which mesh or contact with each other are made of different materials.
However, polyacetal resin is a solid material. Thus, there is a limited possibility for reducing noise.
The characteristics (e.g. hardness/softness) of polyamide resins can be altered by alloying the resin to another polymeric component, for instance a polyether. However, the component to which the polyamide is alloyed evaporates as time passes so that the movable mechanical element made of the polyamide alloy resin becomes thin. Thus, after a time two movable mechanical elements made of the polyamide alloy resin which mesh or contact with each other do not mesh well or the clearance between them becomes large and a chattering occurs between them. These drawbacks worsen the operating reliability of the movable mechanical elements.
As described above, conventional materials for use in the manufacture of movable mechanical elements are insufficient for both depressing internal noise and maintaining operating reliability.
The present invention seeks to provide a material for use in the manufacture of movable mechanical elements which has both a better sound depressing ability and a higher operation reliability.
A composition for use in the manufacture of movable mechanical elements according to one aspect of the present invention is comprised of polyacetal resin combined with a polyamide alloy resin. A composition for use in the manufacture of movable mechanical elements according to a second aspect of the present invention is comprised of a polyacetal resin in combination with a polyether block amide resin.
Polyether block amides may be represented by the formula:
in which PA represents the polyamide segment and PE the polyether segment. Such copolymers are marketed under the Trade Mark PEBAX by Atochem Inc.. The copolymers may be obtained by polycondensation of a polyether diol, such as PEG (polyethylene glycol) PPG (polypropylene glycol), PTMG (polytetra-methylene glycol), and a di-carboxyl polyamide, e.g. 6PA, 6-6 PA, 11 PA, 12 PA, 4-6 PA, 6-11 PA, 6-12 PA.
For a better understanding of the present invention and the many attendant advantages thereof reference will be now made by way of example to the accompanying drawing, wherein:
Figure 1 is a plan showing a mechanism of a cassette tape recorder which includes some movable mechanical elements made of the material according to the present invention.
The present invention will be described in detail below referring to the attached drawing.
According to a first embodiment, polyacetal resin and polyether-ester copolymer which is polyamide alloy resin were mixed with each other at several rates as shown in the following table. Then the materials, i.e., the mixtures of the resins were molded into gears such as idler gear 15, reel driving gears 16 and 17, etc. The gears 15, 16 and 17 were mounted in a mechanism of a cassette tape recorder, as shown in FIGURE 1. Then operating noises of the cassette tape recorder were measured for the several samples of mixing rates.
Mixing Rate Polyacetal Polyetherester- Noise Resin amide copolymer Level (db) Sample 1 80 wt% 20 wt% 38 Sample 2 60 wt% 40 wt% 37 Sample 3 40 wt% 60 wt% 35 Sample 4 20 wt% 80 wt% 34 As shown in the table, noise levels of the samples 1 to 4 were depressed and when found to be in a range of 38 - 34 db. The noise levels are depressed as much as by 5 - 6 db when compared with a gear made of conventional material such as polyacetal resin only.
The measurement of the noise levels was performed in a dead room with a background noise of 27 db. The operating noise of the tape recorder was picked up by a microphone at a distance of 10 cm from a section around the gears 15, 16 and 17 (see FIGURE 1). Then the noise levels were read from a sound level meter coupled to the microphone.
If the ratio of the polyetheresteramide copolymer is less than 20 wt%, the rigid polyacetal resin becomes predominant in the material. In this case, the gears made of such a material become insufficient for depressing the operating noise. Further, if the polyetheresteramide copolymer exceeds 80 wt%, although the operating noise can be sufficiently depressed, the mechanical strength of the gears will be worsened. Therefore, the material becomes optimum when it is made of polyacetal resin of between 20 % and 80 % by weight and the remaining weight percent being the polyamide alloy resin.
The polyacetal resin and the polyamide alloy resin are mixed by a conventional double-shaft extruding machine.
Then, the mixture is kneaded and pelletized. The doubleshaft extruding machine can make the composition of the material uniform. In addition, it is also possible to directly mold the material to the gears etc. by mixing pellets with a conventional tumbling machine.
FIGURE 1 shows the mechanism of the cassette tape recorder which includes some movable mechanical elements made of the material according to the present invention, as described above. In FIGURE 1, a pair of reel spindles 12 and 13 are rotatably mounted on a main chassis 11. A motor 14 is fixed between the reel spindles 12 and 13. The turning force of the motor 14 is selectively transmitted to driving the gears 16 and 17 which are provided coaxially with the reel spindles 12 and 13 through a transmission gear 15. Thus, the reel spindles 12 and 13 are selectively rotated.
Further, a head chassis 18 is movably mounted on the main chassis 11. The head chassis 18 holds a recording and playback head 19 and an erasing head 20. The head chassis 18 moves the recording and playback head 19 and the erasing head 20 to an operating position where the recording and playback head 19 and the erasing head 20 contact with a cassette tape (not shown).
During operation, by interlocking with the movement of the head chassis 18, a pinch lever 21 is rotated around a shaft 22 clockwise in the drawing and a pinch roller 23 is brought in contact with a capstan 24 for pressing the cassette tape to the capstan 24.
Further, an ejection lever 25 is moved upward in the drawing by operation of an ejection key to disconnect the tape cassette from the heads 19 and/or 20.
Here, the material for use in the manufacture of movable mechanical elements according to the present invention is adapted for use in the transmission gear 15, the driving gears 16 and 17, guiding parts of the head chassis 18, the ejection lever 25 and its guiding parts, etc.
As described above, the present invention can provide an extremely preferable material for use in the manufacture of movable mechanical elements.
The foregoing description and the drawings are regarded by the applicant as including a variety of individually inventive concepts, some of which may lie partially or wholly outside the scope of some or all of the following claims. The fact that the applicant has chosen at the time of filing of the present application to restrict the claimed scope of protection in accordance with the following claims is not to be taken as a disclaimer or alternative inventive concepts that are included in the contents of the application and could be defined by claims differing in scope from the following claims, which different claims may be adopted subsequently during prosecution, for example for the purposes of a divisional application.
Claims (6)
1. A composition for use in the manufacture of movable mechanical elements wherein the composition comprises a polyacetal resin combined with a polyamide alloy resin.
2. A composition according to claim 1, wherein the polyacetal resin is present in an amount of between 20% and 80% by weight in the composition with the remaining weight percent substantially consisting of polyamide alloy resin.
3. A composition for use in the manufacture of movable mechanical elements wherein the composition comprises a polyacetal resin in combination with a polyether block amide resin.
4. A composition according to claim 3, wherein the polyacetal resin is present in an amount of between 20% and 80% by weight in the composition with the remaining weight percent substantially consisting of the polyether block amide resin.
5. A mechanical element formed from a composition as claimed in any one of the preceding claims.
6. A method for reducing the internal noise caused by movable mechanical elements characterized by manufacturing these movable mechanical elements from a composition as claimed in any one of claims 1 to 4.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10660488 | 1988-08-12 |
Publications (3)
Publication Number | Publication Date |
---|---|
GB8918378D0 GB8918378D0 (en) | 1989-09-20 |
GB2221685A true GB2221685A (en) | 1990-02-14 |
GB2221685B GB2221685B (en) | 1992-07-01 |
Family
ID=14437730
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8918378A Expired - Lifetime GB2221685B (en) | 1988-08-12 | 1989-08-11 | Material for use in manufacturing movable mechanical elements |
Country Status (3)
Country | Link |
---|---|
KR (1) | KR920005338B1 (en) |
GB (1) | GB2221685B (en) |
MY (1) | MY104161A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2665904A1 (en) * | 1990-08-20 | 1992-02-21 | Asahi Chemical Ind | COMPOSITION OF LARGE RIGIDITY BASED ON POLYACETAL RESIN. |
WO2005065943A1 (en) * | 2003-12-24 | 2005-07-21 | Ticona Gmbh | Composite bodies, method for the production thereof and use thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4098843A (en) * | 1976-12-20 | 1978-07-04 | E. I. Du Pont De Nemours And Company | Stabilized polyoxymethylene molding compositions |
EP0047529A2 (en) * | 1980-09-09 | 1982-03-17 | E.I. Du Pont De Nemours And Company | Polyoxymethylene molding blends |
EP0179668A2 (en) * | 1984-10-25 | 1986-04-30 | Celanese Corporation | Process for preparing oxymethylene polymer molding compositions having enhanced resistance to speck formation |
US4640949A (en) * | 1985-05-21 | 1987-02-03 | E. I. Du Pont De Nemours And Company | Stabilized polyoxymethylene compositions |
EP0290761A2 (en) * | 1987-04-29 | 1988-11-17 | Degussa Aktiengesellschaft | Impact resistent polyoxymethylene moulding masses |
GB2210048A (en) * | 1987-09-22 | 1989-06-01 | Asahi Chemical Ind | Polyacetal composition |
-
1989
- 1989-08-11 MY MYPI89001098A patent/MY104161A/en unknown
- 1989-08-11 KR KR1019890011460A patent/KR920005338B1/en not_active IP Right Cessation
- 1989-08-11 GB GB8918378A patent/GB2221685B/en not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4098843A (en) * | 1976-12-20 | 1978-07-04 | E. I. Du Pont De Nemours And Company | Stabilized polyoxymethylene molding compositions |
EP0047529A2 (en) * | 1980-09-09 | 1982-03-17 | E.I. Du Pont De Nemours And Company | Polyoxymethylene molding blends |
EP0179668A2 (en) * | 1984-10-25 | 1986-04-30 | Celanese Corporation | Process for preparing oxymethylene polymer molding compositions having enhanced resistance to speck formation |
US4640949A (en) * | 1985-05-21 | 1987-02-03 | E. I. Du Pont De Nemours And Company | Stabilized polyoxymethylene compositions |
EP0290761A2 (en) * | 1987-04-29 | 1988-11-17 | Degussa Aktiengesellschaft | Impact resistent polyoxymethylene moulding masses |
GB2210048A (en) * | 1987-09-22 | 1989-06-01 | Asahi Chemical Ind | Polyacetal composition |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2665904A1 (en) * | 1990-08-20 | 1992-02-21 | Asahi Chemical Ind | COMPOSITION OF LARGE RIGIDITY BASED ON POLYACETAL RESIN. |
GB2247684A (en) * | 1990-08-20 | 1992-03-11 | Asahi Chemical Ind | Polyacetal resin composition having high-temperature stiffness |
EP0475127A1 (en) * | 1990-08-20 | 1992-03-18 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyacetal resin composition having high-temperature stiffness |
BE1004773A0 (en) * | 1990-08-20 | 1993-01-26 | Asahi Chemical Ind | Composition of a great rigidity a polyacetal resin base. |
GB2247684B (en) * | 1990-08-20 | 1993-10-06 | Asahi Chemical Ind | Polyacetal resin composition having high-temperature stiffness |
US5354798A (en) * | 1990-08-20 | 1994-10-11 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyacetal resin composition having high-temperature stiffness |
WO2005065943A1 (en) * | 2003-12-24 | 2005-07-21 | Ticona Gmbh | Composite bodies, method for the production thereof and use thereof |
US8236430B2 (en) | 2003-12-24 | 2012-08-07 | Ticona Gmbh | Composite bodies, method for the production thereof and use thereof |
Also Published As
Publication number | Publication date |
---|---|
MY104161A (en) | 1994-02-28 |
GB8918378D0 (en) | 1989-09-20 |
KR920005338B1 (en) | 1992-07-02 |
KR900003881A (en) | 1990-03-27 |
GB2221685B (en) | 1992-07-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
746 | Register noted 'licences of right' (sect. 46/1977) |
Effective date: 19981026 |