GB2217324A - 3,5-Dichloro-4-(hexafluoropropyloxy)phenylisocyanate - Google Patents

3,5-Dichloro-4-(hexafluoropropyloxy)phenylisocyanate Download PDF

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Publication number
GB2217324A
GB2217324A GB8910036A GB8910036A GB2217324A GB 2217324 A GB2217324 A GB 2217324A GB 8910036 A GB8910036 A GB 8910036A GB 8910036 A GB8910036 A GB 8910036A GB 2217324 A GB2217324 A GB 2217324A
Authority
GB
United Kingdom
Prior art keywords
dichloro
hexafluoropropyloxy
phenylisocyanate
formula
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB8910036A
Other versions
GB8910036D0 (en
GB2217324B (en
Inventor
Josef Drabek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB8910036D0 publication Critical patent/GB8910036D0/en
Publication of GB2217324A publication Critical patent/GB2217324A/en
Application granted granted Critical
Publication of GB2217324B publication Critical patent/GB2217324B/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/78—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C07C217/82—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
    • C07C217/84—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to an acyclic carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C265/00—Derivatives of isocyanic acid
    • C07C265/12—Derivatives of isocyanic acid having isocyanate groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C275/30—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by halogen atoms, or by nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/46—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylureas
    • C07C275/48—Y being a hydrogen or a carbon atom
    • C07C275/54—Y being a carbon atom of a six-membered aromatic ring, e.g. benzoylureas

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Breeding Of Plants And Reproduction By Means Of Culturing (AREA)
  • Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Saccharide Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

The invention relates to 3, 5-dichloro-4-(hexafluoropropyloxy)phenylisocyanate, useful as an intermediate for substituted N-benzoyl-N'-3, 5-dichloro-4-hexafluoropropyloxyphenylureas, pest control agents.

Description

4-(Hexafluoropropyloxy)phenylisocyanate The present invention relates to 4-hexafluoropropyloxy)phenylisocyanate useful as an intermediate for substituted N-benzoy-N'-3, 5-dichloro-4-bexafluoropropyloxyphenylureas which are useful in pest control.
The invention relates to the compound of formula I
The compound of formula I is useful as an intermediate for substituted N-benzoyl-N'-3,5-dichloro-4-hexafluoropropyloxy- phenylureas which are described and claimed in copending British Patent Application No. 8624335.
The N-benzOyl-N'-3,5-dichloro-4-hexafluoropropyloxyphenylureas of GB Application No. 8624335 may be produced e.g. by reacting the compound of formula I
with a compound of formula II
wherein R1 is hydrogen or fluorine and R2 is fluorine or chlorine.
The 4-(hexafluoropropyloxy)phenylisocyanate of formula I (b.p.
950C/O.Ol torr) can be prepared e.g. by phosgenating the aniline of formula III
by methods which are commonly employed in the art.

Claims (2)

What is claimed is:
1. The compound of formula I
2. A process for the production of a compound of formula I comprising phosgenating a compound having the formula III
GB8910036A 1985-10-14 1989-05-02 3,5-dichloro-4-(hexafluoropropyloxy)phenylisocyanate Expired - Lifetime GB2217324B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH442085 1985-10-14

Publications (3)

Publication Number Publication Date
GB8910036D0 GB8910036D0 (en) 1989-06-21
GB2217324A true GB2217324A (en) 1989-10-25
GB2217324B GB2217324B (en) 1990-03-28

Family

ID=4275804

Family Applications (3)

Application Number Title Priority Date Filing Date
GB8624335A Expired - Lifetime GB2182329B (en) 1985-10-14 1986-10-10 Benzoylphenylureas
GB8910035A Expired - Lifetime GB2217323B (en) 1985-10-14 1989-05-02 3,5-dichloro-4-(1,1,2,3,3,3-hexafluoropropyloxy)aniline
GB8910036A Expired - Lifetime GB2217324B (en) 1985-10-14 1989-05-02 3,5-dichloro-4-(hexafluoropropyloxy)phenylisocyanate

Family Applications Before (2)

Application Number Title Priority Date Filing Date
GB8624335A Expired - Lifetime GB2182329B (en) 1985-10-14 1986-10-10 Benzoylphenylureas
GB8910035A Expired - Lifetime GB2217323B (en) 1985-10-14 1989-05-02 3,5-dichloro-4-(1,1,2,3,3,3-hexafluoropropyloxy)aniline

Country Status (22)

Country Link
EP (1) EP0219460B1 (en)
JP (1) JPS6293268A (en)
KR (1) KR900008136B1 (en)
CN (1) CN1014110B (en)
AT (1) ATE63112T1 (en)
AU (1) AU597278B2 (en)
BR (1) BR8604995A (en)
CA (1) CA1291151C (en)
CY (1) CY1683A (en)
DE (1) DE3679024D1 (en)
DK (2) DK488186A (en)
EG (1) EG17946A (en)
ES (1) ES2038125T3 (en)
GB (3) GB2182329B (en)
HK (1) HK33893A (en)
IL (1) IL80271A (en)
MX (1) MX173307B (en)
SG (1) SG117592G (en)
SU (1) SU1588277A3 (en)
TR (1) TR23026A (en)
ZA (1) ZA867736B (en)
ZW (1) ZW20486A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0221847A3 (en) * 1985-10-29 1988-03-23 Ciba-Geigy Ag Benzoyl urea salts
DE3613062A1 (en) * 1986-04-18 1987-10-29 Hoechst Ag N-BENZOYL-N'-PHENYL (THIO) UREAS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS A PEST CONTROL
IT1213420B (en) * 1986-12-19 1989-12-20 Donegani Guido Ist "N (-2,6-DIFLUOROBENZOIL) -N'-3-CHLORINE -41,1,2-TRIFLUORO-2- (TRIFLUOROMETOSSI) ETHOXYOUS PHENYL UREA WITH INSECTICIDE ACTIVITY.
IT1230675B (en) * 1987-09-04 1991-10-29 Donegani Guido Ist N- (ALOBENZOIL) -N'-2-ALO-4 (1,1,2-TRIFLUORO-2- (TRIFLUOROMETOSSI) ETHOXY) PHENYL UREE INSECTICIDE ACTIVITY
DE3740633A1 (en) * 1987-12-01 1989-06-15 Bayer Ag SUBSTITUTED BENZOYL (THIO) UREA
GB8905741D0 (en) * 1989-03-13 1989-04-26 Shell Int Research Process for preparing carbamates,and intermediates therin
WO2000062617A1 (en) * 1999-04-15 2000-10-26 Consejo Superior De Investigaciones Cientificas Method for controlling a mediterranean fruit fly pest
US6681886B2 (en) * 2001-12-11 2004-01-27 Visteon Global Technologies, Inc Flexibly coupled electric power assist steering system

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2726684A1 (en) * 1977-06-14 1979-01-04 Hoechst Ag Insecticidal di:halo-benzoyl-phenylurea derivs. - useful for plant protection or textile preservation
DE2801316A1 (en) * 1978-01-13 1979-07-19 Bayer Ag SUBSTITUTED N-PHENYL-N '- (2-CHLORINE-6-FLUORO-BENZOYL) UREAS, METHOD FOR THEIR PRODUCTION AND THEIR USE AS INSECTICIDES
US4418991A (en) * 1979-09-24 1983-12-06 Breger Joseph L Presbyopic contact lens
AR242020A1 (en) * 1981-07-30 1993-02-26 Dow Chemical Co Substituted n-aroyl n'-phenyl urea compounds
DE3217620A1 (en) * 1982-05-11 1983-11-17 Bayer Ag, 5090 Leverkusen 2,5-DIHALOGENBENZOYL (THIO) UREA, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS A PEST CONTROL
IL76708A (en) * 1984-10-18 1990-01-18 Ciba Geigy Ag Substituted n-benzoyl-n'-(2,5-dichloro-4(1,1,2,3,3,3-hexafluoropropyloxy)-phenyl)ureas,their preparation and pesticidal compositions containing them

Also Published As

Publication number Publication date
AU6383386A (en) 1987-04-16
AU597278B2 (en) 1990-05-31
GB2217323B (en) 1990-03-28
DK111692D0 (en) 1992-09-10
JPS6293268A (en) 1987-04-28
ES2038125T3 (en) 1993-07-16
MX173307B (en) 1994-02-15
GB8910035D0 (en) 1989-06-21
GB8910036D0 (en) 1989-06-21
CN86106647A (en) 1987-07-01
CN1014110B (en) 1991-10-02
IL80271A0 (en) 1987-01-30
GB2182329A (en) 1987-05-13
JPH034543B2 (en) 1991-01-23
CA1291151C (en) 1991-10-22
IL80271A (en) 1991-12-15
EP0219460A2 (en) 1987-04-22
CY1683A (en) 1993-10-10
EG17946A (en) 1992-06-30
GB2217324B (en) 1990-03-28
EP0219460A3 (en) 1988-04-20
GB8624335D0 (en) 1986-11-12
BR8604995A (en) 1987-07-14
DE3679024D1 (en) 1991-06-06
GB2182329B (en) 1990-02-14
SU1588277A3 (en) 1990-08-23
ATE63112T1 (en) 1991-05-15
ZW20486A1 (en) 1987-06-17
TR23026A (en) 1989-02-10
SG117592G (en) 1993-01-29
KR870003975A (en) 1987-05-06
ZA867736B (en) 1987-06-24
DK488186A (en) 1987-04-15
EP0219460B1 (en) 1991-05-02
MX4015A (en) 1993-09-01
KR900008136B1 (en) 1990-10-31
DK488186D0 (en) 1986-10-13
GB2217323A (en) 1989-10-25
HK33893A (en) 1993-04-16
DK111692A (en) 1992-09-10

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19941010