GB2214835A - Method and apparatus for desalination - Google Patents

Method and apparatus for desalination Download PDF

Info

Publication number
GB2214835A
GB2214835A GB8802735A GB8802735A GB2214835A GB 2214835 A GB2214835 A GB 2214835A GB 8802735 A GB8802735 A GB 8802735A GB 8802735 A GB8802735 A GB 8802735A GB 2214835 A GB2214835 A GB 2214835A
Authority
GB
United Kingdom
Prior art keywords
condensing
zone
humidifying
feed water
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB8802735A
Other versions
GB8802735D0 (en
Inventor
R Salah Gahin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAHIN DR SALAH
Original Assignee
GAHIN DR SALAH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GAHIN DR SALAH filed Critical GAHIN DR SALAH
Priority to GB8802735A priority Critical patent/GB2214835A/en
Publication of GB8802735D0 publication Critical patent/GB8802735D0/en
Publication of GB2214835A publication Critical patent/GB2214835A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/34Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
    • B01D3/343Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances the substance being a gas
    • B01D3/346Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances the substance being a gas the gas being used for removing vapours, e.g. transport gas
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/10Treatment of water, waste water, or sewage by heating by distillation or evaporation by direct contact with a particulate solid or with a fluid, as a heat transfer medium
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/14Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/16Treatment of water, waste water, or sewage by heating by distillation or evaporation using waste heat from other processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/138Water desalination using renewable energy
    • Y02A20/142Solar thermal; Photovoltaics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

There is provided a method of desalination comprising passing a flow of gaseous medium through a humidifying zone and then through a condensing (or dehumidifying) zone in succession. Heated saline feed water is supplied to the humidifying zone and this is picked up by the flowing gaseous medium, whence it is transported to the condensing section, distillate being formed on the condensing section and collected. It is a feature of the arrangement that the gaseous medium comprises wholly or substantially an inert gas such as nitrogen, carbon dioxide or helium. Further appropriate apparatus is provided for carrying out the method. <IMAGE>

Description

METHOD AND APPARATUS FOR DESALINATION" Description The present invention relates to a method and apparatus for desalination.
It is the principal object of the present invention to provide an improved method of desalination enabling the use of desalination apparatus of a compact form which nevertheless has satisfactory performance efficiency.
According to one aspect of the present invention there is provided a method of desalination comprising creating a flow of gaseous medium comprising substantially an inert gas which passes through a humidifying zone and then passes to a condensing or de-humidifying zone whence the gas passes through said condensing zone; supplying heated saline feed water to the humidifying zone so that the feed water humidifies the gas passing in said humidifying zone whereby humidified gas passes to the condensing zone; and collecting distillate formed by condensing of the humidified gas in said condensing zone.
Preferably the inert gas comprises nitrogen, carbon dioxide or helium.
Preferably the gas is recycled from the condensing zone to the humidifying zone, and the gas flow is preferably created by a fan.
Preferably the feed water supplied to the humidifying zone has a temperature of at least 80 C. In a preferred embodiment the feed water is heated by means of solar energy or by hot water gases from an engine or plant, eg. the exhaust gas of an internal combustion engine, and preferably further the feed water, prior to supply to the humidifying zone, serves as cooling medium in the condensing zone.
Preferably the ratio of the feed water supply rate to the rate of gas flow through the humidifying zone is in the range up to 300 by mass.
According to another aspect of the present invention desalination apparatus comprises a casing structure defining base receiver means, a head part, and column means extending between said base receiver means and the head part; said column means including a humidifying section and a separate condensing or dehumidifying section; ducting in the head part for fluid communication between the humidifying and condensing sections; a feed water distributor in the upper end of the humidifying section for the provision of a downward spray of feed water in the humidifying section; a feed inlet to said distributor; a gas inlet at the lower end of the humidifying section; and cooling means in said condensing or dehumidifying section; said base receiver means including a recepticle for distillate discharged from said condensing or dehumidifying section.
Preferably a recirculation duct is provided for recirculation of gas from the condensing section to the humidifying section. Said condensing or dehumidifying section preferably comprising a direct or indirect type tube or spray device or combination thereof.
Preferably the apparatus includes heating means for the feed water, and preferably said heating means is connected to the cooler of the condensing section whereby feed water is heated in the cooler prior to delivery to said heating means.
The heating means may comprise a solar energy heater or alternatively may comprise a heat exchanger receiving heating medium from a hot waste - gas source.
In a preferred embodiment, means are provided for creating sub-atmospheric pressure conditions in at least one of the humidifying and condensing sections. A fan is preferably provided for gas flow in the apparatus.
Embodiments of the present invention will now be described by way of example with reference to the accompanying drawings wherein : Fig. 1 shows schematically desalination apparatus for carrying out the method of the present invention; Fig. 2 is an elevation of a commercial form of desalination apparatus in accordance with the present invention; Fig. 3 shows schematically a further embodiment of desalination apparatus of the present invention; Fig. 4 shows the graph of maximun humidifier temperature against Total Volume of moist-air in connection with desalination apparatus operating at or around atmospheric pressure; Fig. 5 shows schematically a further embodiment of the invention; and Fig. 6 shows schematically yet a further embodiment of the present invention.
Referring to Fig. 1, a method of desalination is carried out in desalination apparatus 1. The apparatus 1 includes a humidifier zone 2, a condensing or dehumidifying zone 3 and an upper duct 4 fluidly connecting the zones 2, 3. The humidifier zone 2 is of cooling tower form and includes a water distributor 5 at the upper end and a gas inlet 6 at the lower end. A recirculation duct 7 connects the condenser zone 3 to the gas inlet 6, and a fan8 is intercalated in the duct 7 and operates to create a flow of gas through the humidifier zone 2, through the upper duct 4 and whence through the condenser zone 3 (as shown by the arrows).A cooler (not shown) is provided in the condenser zone 3 and saline feed water and/or fresh water and/or distillate water is used for the cooling medium therein, the feed water discharged from the cooler passing to a heat exchanger 9 wherein the feed water is further heated, for example by heating medium flowing in conduit 9A, whence the heated feed water flows to the distributor 5. For reasons that will be explained later, an inert gas is chosen as the recirclating gas, the inert gas comprising for example nitrogen, carbon dioxide or helium.
In operation, upwardly flowing inert gas in the humidifier zone 2 meets a downward spray of heated feedwater from the distributor 5 so that the gas is humidified by the water spray, and the humidified gas flows to the condensing zone 3 via the duct 4. The humidified gas is cooled in the condenser zone 3 resulting in distillate being precipitated from the gas, and this distillate is collected in receiver 10. The cooled gas is recirculated to the humidifier zone 2 via the recirculation duct 7, while concentrated brine precipitated in the humidifier zone 2 is collected in receiver 11. The humidifying and condensing zones 2 can be at any suitable pressure.
In the case where air is used in the apparatus of Fig. 1 rather than inert gas, figure 4 shows the relationship of maximum temperature in the humidifier zone 2 (TH)OC against total volume of moist air at atmospheric pressure (per one Kg dry air) in M3(VM) for a process operating around atmospheric pressure. Similar curves can be developed for processes operating at average pressures which are different (i.e. higher or lower than atmospheric pressure). In particular the curve AB represents the ideal profile for a partial pressure dehumidifier (or condenser) or partial pressure humidifier. It will be noted that the curve AB flattens as the curve approaches the TH = 1000C value, and in fact the closer the temperature TH is to 1000C the lesser the amount of air to be circulated so that the air becomes a mere circulating agent and possibly also a heat transfer augmenting agent. It is preferred therefore that the feed water is heated to a temperature of at least 800C to encourage this characteristic. However with the utilisation of a high temperature as above and with oxygen (of the air) circulating in the recirculation loop there arises the definite risk of corrosion or erosion in the apparatus. Therefore in the present desalination method an inert gas is used instead of air, for the circulating gas, the inert gas comprising for example nitrogen, carbon dioxide or helium.
With regard to optimum performance ratio, it is preferred that the ratio of the feed water rate to the rate of circulating gas flowing into the humidifier zone lies in the range up to 300 by mass.
Fig. 2 shows a suitable commercial apparatus 15 for carrying out the inventive desalination method. Parts equivalent to parts in the schematic figure 1 carry like reference numerals. Thus the apparatus 15 comprises a casing structure 16 including a liquid-receiving base part 17 and a head part 18, the parts 17 and 18 being joined by a necked formation 19 defining a column means.
An upright partition wall 20 extends through the column means 19 to separate the humidifier section 2 from the condensing or dehumidifying section 3.
The humidifier section 2 houses infringment plates 21 or fill plates to encourage the humidifying action, while a suitable cooler 22 is present in the condensing section 3. A demister filter 23 can be located in the duct 4 in the path of the humidified gas flowing to the condensing section 3. The cooler 22 includes a bottom inlet 22A for cooling medium and a top cooling medium outlet 22B, and as explained above it is preferred that the cooling medium is constituted by the saline feed water to enable preheating of the feed water. Alternatively fresh water or distillate water could be used, or indeed a combination of any of the three could be utilised.A port 24 is provided at the bottom of the condensing section 3 for discharge of the circulating gas, and for the closed loop this port 24 is connected to the gas inlet port 6 in the section 2 in the manner of Fig. 1 viz by duct 7: and again a circulating fan can be provided in the recirculation duct. For increased performance efficiency, a high level of thermal insulation will be applied to the casing structure 16.
To heat the pre-heated feed water to a satisfactory entry temperature the feed water is fed from the cooler 22 to a suitable heat exchanger apparatus (per the heat exchanger 9 of Fig. 1). It is particularly preferred that solar energy be used in the further heating up of the feed water, and suitable heating apparatus 25 utilising solar energy is shown in Fig. 3. In the apparatus 25, the feed water is heated indirectly by means of a secondary heating fluid. Thus the apparatus 25 includes a heat exchanger 9 in the form of a solar boiler to the heat withdrawal side 9A of which the feed water is fed, the heat input side 9B of the heat exchanger receiving heating medium neated by solar energy in a heating circuit 26.
By this arrangement, a fluid more compatable with solar energy collection such as "black" liquid (ie liquid with high carbon content) can be used as the secondary heating medium in the circuit 26. The apparatus 25 includes solar collectors 27 and a thermal storage vessel 28.
The collectors 27 may be of the evacuated tube type but it is particularly preferred that parabolic trough type collectors are used since these are believed to give more satisfactory performance for the relatively high input temperatures envisaged by the present invention.
Fig. 5 shows a further embodiment of the desalination apparatus. In this case an integrated solar collector arrangement 29 is used in place of the apparatus 25 of Fig. 3. As can be seen the collector 29 is mounted directly on the casing structure 16 and this will have the advantage of reducing pipeline heat loss.
In Fig. 6 heating of the preheated feed water is achieved by utilising hot waste gases from a plant, specifically the exhaust gases of an internal combustion engine. Thus in this embodiment the heat exchanger 9 is in the form of an exhaust boiler and the heat input side 9B utilises exhaust gases from an I.C. engine 30 (eg. a diesel engine) as the heating medium.
Of course a combination of solar heating and any or many of waste heat supplies for heating the feed water can be embodied for the operation of the desalinator according to the present invention.
Considering the apparatus 15 of Fig. 2, it will be clear that the present invention enables the provision of a desalinator of a very compact dimension, and with realistic heat transfer and evaporation conditions, performance ratios between 8 to 18 can be achieved - which is comparable with the performance ratios of multi-stage flash desalinators.
Closed loop gas flow has been shown, but open-loop flow can be easily obtained simply by removing the ducting between ports 6 and 24 (Fig. 2): the fan (8) will be repositioned eg. at entry to port 6, or exit to port 7.
Of course, instead of having a recirculating gaseous medium comprising wholly an inert gas a gaseous mixture may be used wherein an inert gas predominates.

Claims (18)

Claims
1. A method of desalination comprising creating a flow of gaseous medium comprising substantially an inert gas which passes through a humidifying zone and then passes to a condensing or dehumidifying zone whence the gas passes through said condensing zone; supplying heated saline feed water to the humidifying zone so that the feed water humidifies the gas passing in said humidifying zone whereby humidified gas passes to the condensing zone; and collecting distillate formed by condensing of the humidified gas in said condensing zone.
2. A method as claimed in claim 1, wherein the inert gas comprises nitrogen, carbon dioxide or helium.
3. A method as claimed in claim 1 or claim 2, wherein the gas is recycled from the condensing zone to the humidifying zone.
4. A method as claimed in any one of claims 1 to 3, wherein the gas flow is created by a fan.
5. A method as claimed in any one of the preceding claims, wherein the feed water supplied to the humidifying zone has a temperature of at leat 800C.
6. A method as claimed in any one of the preceding claims, wherein the feed water is heated by means of solar energy or by hot water gases from an engine or plant.
7. A method as claimed in any one of the preceding claims, wherein the feed water, prior to supply to the humidifying zone, serves as cooling medium in the condensing zone.
8. A method as claimed in any one of the preceding claims, wherein the ratio of the feed water supply rate to the rate of gas flow through the humidifying zone is in the range up to 300 by mass.
9. Desalination apparatus comprising a casing structure defining base receiver means, a head part, and column means extending between said base receiver means and the head part; said column means including a humidifying section and a separate condensing or dehumidifying section; ducting in the head part for fluid communication between the humidifying and condensing sections; a feed water distributor in the upper end of the humidifying section for the provision of a downward spray of feed water in the humidifying section; a feed inlet to said distributor; a gas inlet at the lower end of the humidifying section; and cooling means in said condensing or dehumidifying section; said base receiver means including a recepticle for distillate discharged from said condensing or dehumidifying section.
10. Desalination apparatus as claimed in claim 9, wherein a recirculation duct is provided for recirculation of gas from the condensing section to the humidifying section.
11. Desalination apparatus as claimed in claim 9 or 10, wherein said condensing or dehumidifying section comprises a direct or indirect type tube or spray device or combination thereof.
12. Desalination apparatus as claimed in any one of claims 9 to 11, wherein the apparatus includes heating means for the feed water.
13. Desalination apparatus as claimed in claim 12, wherein said heating means is connected to the cooler of the condensing section whereby feed water is heated in the cooler prior to delivery to said heating means.
14. Desalination apparatus as claimed in claim 12 or 13, wherein said heating means comprises a solar energy heater or a heat exchanger receiving heating medium from a hot waste-gas source.
15. Desalination apparatus as claimed in any one of claims 9 to 14, wherein means are provided for creating sub-atmospheric pressure conditions in at least one of the humidifying and condensing sections.
16. Desalination apparatus as claimed in any one of the preceding claims, wherein a fan is provided for gas flow in the apparatus.
17. A method of desalination as claimed in claim 1 and substantially as hereinbefore described.
18. Distillation apparatus substantially as hereinbefore described with reference to and as illustrated in the accompanying drawings.
GB8802735A 1988-02-06 1988-02-06 Method and apparatus for desalination Withdrawn GB2214835A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB8802735A GB2214835A (en) 1988-02-06 1988-02-06 Method and apparatus for desalination

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8802735A GB2214835A (en) 1988-02-06 1988-02-06 Method and apparatus for desalination

Publications (2)

Publication Number Publication Date
GB8802735D0 GB8802735D0 (en) 1988-03-09
GB2214835A true GB2214835A (en) 1989-09-13

Family

ID=10631234

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8802735A Withdrawn GB2214835A (en) 1988-02-06 1988-02-06 Method and apparatus for desalination

Country Status (1)

Country Link
GB (1) GB2214835A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1992019542A1 (en) * 1991-04-26 1992-11-12 Manuel Lumbreras Y Gimenez Method and apparatus for seawater potabilization
US5290403A (en) * 1987-03-17 1994-03-01 Saeaesk Aapo Liquid evaporating apparatus
ES2323340A1 (en) * 2006-08-23 2009-07-13 Jacinto Manuel Portillo Cueva System of desalation of water by solar energy (Machine-translation by Google Translate, not legally binding)
US20130233697A1 (en) * 2012-03-09 2013-09-12 Halliburton Energy Services, Inc. Process for Water Treatment and Generation

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1981003655A1 (en) * 1980-06-11 1981-12-24 Mitsubishi Electric Corp Apparatus for desalinizing brine

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1981003655A1 (en) * 1980-06-11 1981-12-24 Mitsubishi Electric Corp Apparatus for desalinizing brine

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290403A (en) * 1987-03-17 1994-03-01 Saeaesk Aapo Liquid evaporating apparatus
WO1992019542A1 (en) * 1991-04-26 1992-11-12 Manuel Lumbreras Y Gimenez Method and apparatus for seawater potabilization
ES2323340A1 (en) * 2006-08-23 2009-07-13 Jacinto Manuel Portillo Cueva System of desalation of water by solar energy (Machine-translation by Google Translate, not legally binding)
US20130233697A1 (en) * 2012-03-09 2013-09-12 Halliburton Energy Services, Inc. Process for Water Treatment and Generation

Also Published As

Publication number Publication date
GB8802735D0 (en) 1988-03-09

Similar Documents

Publication Publication Date Title
US4120787A (en) Fuel cell water conditioning process and system and deaerator for use therein
US7531030B2 (en) Natural gas dehydrator and system
US4939906A (en) Multi-stage boiler/regenerator for liquid desiccant dehumidifiers
US7066396B2 (en) Method and apparatus for enhanced heat recovery from steam generators and water heaters
US5233843A (en) Atmospheric moisture collection device
US3214351A (en) Falling film convective distillation unit with direct contact condensation
US6981651B2 (en) Heating system
EP3633272B1 (en) Method for recovering heat from flue gas of boiler, and arrangement
CN106839494A (en) Heat pump double caloic coupling humidification dehumidification vapo(u)rization system and methods
US4685617A (en) Method of and apparatus for conditioning air in enclosures
CN108980881A (en) A kind of smoke processing system and method
JPH10306925A (en) High efficiency direct contact high temperature hot water heater
CN102410549A (en) Composite phase change heat exchange system for flue gas heat recovery of boiler
CN205774224U (en) A kind of NMP in working procedure of coating lithium ion cell reclaims essence and steams purifying plant
EP0042605A1 (en) Method of operating a vapour-heated process system
GB2214835A (en) Method and apparatus for desalination
US5769067A (en) Air heater and humidifier using direct contact heating principles and method of operation
CN202511307U (en) Compound phase change heat exchange system for recycling boiler flue gas waste heat
FI72799B (en) SAETT ATT AOSTADKOMMA LAERMEAOTERVINNING UR FUKTIG GAS GENOM VATTENAONGABSORPTION OCH ANLAEGGNING FOER SAETTETS UTFOERANDE.
CA2155935A1 (en) Combustion apparatus
CN206540166U (en) It is a kind of to prevent the residual neat recovering system of dewpoint corrosion
SU1502038A1 (en) Plant for concentrating phosphoric acid
CN1204754A (en) High efficiency direct-contact high temperature water heater
CN109987662A (en) A kind of humidification that solar energy is coupled with LNG removes wet process sea water desalination process
SU1733838A1 (en) Boiler

Legal Events

Date Code Title Description
WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)