GB2202527A - Hydraulic setting compositions - Google Patents
Hydraulic setting compositions Download PDFInfo
- Publication number
- GB2202527A GB2202527A GB08806914A GB8806914A GB2202527A GB 2202527 A GB2202527 A GB 2202527A GB 08806914 A GB08806914 A GB 08806914A GB 8806914 A GB8806914 A GB 8806914A GB 2202527 A GB2202527 A GB 2202527A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- cement
- hydraulic
- calcium carbonate
- glass fibres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 53
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000011398 Portland cement Substances 0.000 claims abstract description 14
- 239000003365 glass fiber Substances 0.000 claims abstract description 14
- 239000011396 hydraulic cement Substances 0.000 claims abstract description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 11
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 11
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 11
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920001577 copolymer Polymers 0.000 claims abstract description 9
- 239000003513 alkali Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 239000012779 reinforcing material Substances 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 239000011435 rock Substances 0.000 claims abstract description 6
- 238000009423 ventilation Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000000839 emulsion Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 239000000945 filler Substances 0.000 claims description 7
- 239000004568 cement Substances 0.000 claims description 6
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 239000000565 sealant Substances 0.000 claims description 3
- 235000019738 Limestone Nutrition 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- 239000010881 fly ash Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000006028 limestone Substances 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 239000011268 mixed slurry Substances 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000013065 commercial product Substances 0.000 claims 2
- 239000008199 coating composition Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 239000002657 fibrous material Substances 0.000 description 2
- 239000011527 polyurethane coating Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D11/00—Lining tunnels, galleries or other underground cavities, e.g. large underground chambers; Linings therefor; Making such linings in situ, e.g. by assembling
- E21D11/38—Waterproofing; Heat insulating; Soundproofing; Electric insulating
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00146—Sprayable or pumpable mixtures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00724—Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/70—Grouts, e.g. injection mixtures for cables for prestressed concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/802—White cement
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Structural Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mining & Mineral Resources (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
A setting composition suitable for use in rock strata control as a coating or grouting composition or as a covering for underground ventilation walls, curtains, timber and rubble comprises in combination a hydraulic cement such as white portland cement, an aggregate filter material such as calcium carbonate, a water borne copolymer of polyvinylacetate and polyvinylalcohol and a fibrous reinforcing material such as alkali resistant glass fibres. A two pack composition for on site mixing is also disclosed.
Description
Hydraulic Setting Compositions
THIS invention relates to hydraulic setting compositions.
In one application of the present invention there is provided a hydraulic setting composition suitable for underground use, for example, for covering tunnel walls for strata control, covering ventilation walls and curtains, as a fire or ventilation sealant for the coating of timber, and as an anti-friction coating of rock and rubble.
The composition according to the invention may also be used in ground and rock stabilisation and consolidation. The composition of the present invention has the advantage of being capable of being applied over polyurethane coatings already present in the mine and may also be used for thermal protection for deep underground application.
The composition on setting has the further advantages of having a low flammability, high flexibility and low toxicology.
It will be understood, however, that the composition is not limited to underground use as it may also be used in other applications.
According to the invention a hydraulic setting composition comprises a hydraulic cement, a suitable aggregate filler material, a polymeric material comprising a water borne copolymer of polyvinylacetate and polyvinylalcohol and a fibrous reinforcing material.
The hydraulic cement may be any suitable cement such- as rapid hardening Portland cement, ordinary
Portland cement or White Portland cement.
Preferably, however, the hydraulic cement comprises white Portland cement. The hydraulic cement may include fly ash as a diluent.
The aggregate may be of a particle size ranging from 15 microns to 3 mm diameter. The aggregate may comprise limestone and/or quartz. Preferably, however, the aggregate comprises calcium carbonate or silica particles or a combination thereof.
The fibrous reinforcing material may comprise mineral or ceramic fibres or the like but preferably comprises glass fibres. In the preferred form of the invention the fibrous material comprises alkali resistant glass fibre of between 6 and 15 mm in length.
Further according to the invention a method of forming a hydraulic setting composition as set out above comprises the steps of [a] forming a dry mix containing a hydraulic
cement, an aggregate filler material and a
fibrous material; [b] adding a water based emulsion containing a
copolymer of polyvinylacetate and polyvinyl
alcohol to the dry mix or vice versa; and [c] intimately mixing the dry mix with the
emulsion to obtain an intimately mixed slurry.
In the method according to this aspect of the invention the emulsion is preferably an emulsion of a copolymer of polyvinylacetate and polyvinylalcohol. The emulsion preferably contains between 30 and 80 solids and preferably has an elasticity on drying of between 80% and 100%. The thermal qualities of the emulsified material are preferably such that degradation only sets in at a temperature in excess of 350"C.
The dry mix preferably comprises white Portland cement, calcium carbonate particles of between 15 microns and 15 mm in size and alkali resistant glass fibres of about 6 to 15 mm in length.
According to a further aspect of the present invention there is provided a method of coating a surface comprising the steps of applying a hydraulic setting material as described above to the surface and allowing it to set. Thus, the coating method may be for the purposes of underground strata control inside mine tunnels or the like whether on existing polyurethane coatings or on virgin rock, for covering ventilation walls or curtains, for thermal protection in deep underground application, for covering timber as a fire sealant, or for covering rock or rubble to prevent friction or any related application. The setting composition may also be used as a grouting material.
An example of the present invention will now be described without thereby limiting the scope of the invention to the embodiment of the example.
EXAMPLE
A two pack pre-mix of a setting composition according to the invention was made up by [a] mixing, by weight, 44 parts white Portland
cement, 56 parts of a calcium carbonate
aggregate of particle size of about 75 micron anff 1 part of an alkali resistant glass fibre
of about 8 mm in length
and [b] diluting 16 litres of a commercially available
adhesive based on polyvinylacetate/polyvinyl
alcohol and sold under the trade name "TAC 615' with 24 litres of water. ["TAC 615" is a
trade description of a commercially available
copolymer . of polyvinylacetate and
polyvinylalcohol marketed in South Africa by
TAC National (Pty.) Limited.]
The two pack pre-mix is mixed on site in the weight ratio of 25:8 dry mix::emlusion and applied to the surface to be treated by means of a suitable nozzled spray gun using compressed air as a carrier medium. Alternatively the composition may be applied by hand such as by brushing, roller coating, or trowelling the composition to the surface to be coated.
Tests done with the above composition confirmed good adherence thereof to various underground surfaces and low flammability and toxiology as well as a high flexibility of the cured composition in use.
Various modifications of the invention may be devised without departing from the spirit of the invention.
Thus the setting rate of the composition may be increased by including a high alumina cement in the hydraulic cement component of the composition.
Furthermore, superplasticisers such as sulfonated melamines [i.e. "Melment F10" as sold by Hoechst AG.i may be incorporated into the composition to reduce water demand and hence to reduce viscosity of the mix and thereby to promote the rate of strength build-up during setting of the composition.
Claims (23)
1. A hydraulic setting composition comprising a
hydraulic cement, aggregate filler material, a
polymeric material comprising a water borne
copolymer of polyvinylacetate and polyvinyl
alcohol and a fibrous reinforcing material.
2. The hydraulic setting composition of claim 1
wherein the hydraulic, cement is selected from
the group comprising rapid hardening Portland
cement, Ordinary Portland cement and White
Portland cement.
3. The hydraulic setting composition of claim 2
wherein the hydraulic cement includes fly ash
as a diluent.
4. The composition of claim 2 wherein the
hydraulic cement is white Portland cement.
5. The composition of claim 1 wherein the
aggregate is of a particle size ranging from
about 15 microns to about 3mm diameter.
6. The composition of claim 1 wherein the
aggregate filler material is selected from the
group comprising particles of limestone,
quartz and a combination thereof.
7. The composition of claim 1 wherein the
aggregate filler material is selected from the
group comprising particles of calcium
carbonate, silica particles and a combination
thereof.
8. The composition of claim 1 wherein the fibrous
reinforcing material is selected from the
group comprising mineral fibres, ceramic
fibres and glass fibres.
9. The composition of claim 8 wherein the fibrous
reinforcing material comprises alkali
resistant glass fibres.
10. The composition of claim 9 wherein the glass
fibres are of a length between 6 and 15mm.
11. The composition according to claim 1
comprising a mixture of white Portland cement,
calcium carbonate particles of particle size
of about 75 micron and alkali-resistant glass
fibres of about 8mm in length in a mass ratio
cement : calcium carbonate : glass fibres of
about 44 : 56 : 1 in combination with a
polymeric material comprising a copolymer of
polyvinylacetate and polyvinylalcohol which is
stable at temperatures of below 350"C and
which has an elasticity on drying of between
80 and 100%.
12. A composition substantially as herein
described with reference to the accompanying
example.
13. A method of forming a hydraulic setting
composition comprising the steps of
[a] forming a dry mix containing a hydraulic
cement, an aggregate filler material and
a fibrous reinforcing material;
[b] adding a water based emulsion containing
a copolymer of polyvinylacetate and
polyvinylalcohol to the drymix or vice
versa; and
[c] intimately mixing the dry mix with the
emulsion to obtain an intimately mixed
slurry.
14. The method of claim 12 wherein the emulsion
contains between 30 and 80% solids in the form
of a copolymer of polyvinylacetate and
polyvinylalcohol having an elasticity on
drying of between 80 and 100%.
15. The method of claim 13 wherein the emulsified
polymeric material is of a type which is
thermally stable at temperatures of below 350cm.
16. The method of claim 12 wherein the dry mix
comprises a mixture of white Portland cement,
calcium carbonate particles of particle size
between 15 microns and 15mm and alkali
resistant glass fibres of about 6 to 15mm in
length.
17. The method of claim 15 wherein the components
are present in the dry mix in a ratio of
cement : calcium carbonate : glass fibres of
44 : 56 : 1 parts per mass.
18. A method of coating a surface for the purpose
of rock strata control or to provide thermal
protection or a fire or ventilation sealant or
a friction-reducing coating to the surface in
question, comprising the steps of applying a
composition as claimed in any one of claims 1
to 11 to the surface and allowing it to set.
19. The method of claim 17 wherein the coating
composition is applied to the surface by
spraying.
20. A two-pack pre-mix suitable for use in
producing a composition as claimed in claim 1
wherein the first pack includes a mixture of
a hydraulic cement, aggregate filler material
and fibrous reinforcing material and the
second pack comprises the polymeric material
in a water based emulsion form.
21. The two-pack pre-mix of claim 19 wherein the
first pack comprises a mixture of white
Portland cement, calcium carbonate and alkali-resistant glass fibre in a mass ratio
cement : calcium carbonate : glass fibres of
about 44 : 56 : 1 and the polymeric emulsion
of the second pack comprises a water based
polyvinylacetate/polyvinylalcohol copolymer
emulsion which is commerically sold under the
trade name "TAC 615", the commercial product
being diluted by the addition of about 150%
water by volume to the commercial product and
the two packs containing the dry and wet
components in a mass ratio of about 25 : 8.
22. A method of coating an underground surface
substantially as herein described particularly
with reference to the accompanying example.
23. A hydraulic setting composition substantially as herein described with reference to the accompanying example.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ZA872193 | 1987-03-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
GB8806914D0 GB8806914D0 (en) | 1988-04-27 |
GB2202527A true GB2202527A (en) | 1988-09-28 |
Family
ID=25578804
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08806914A Withdrawn GB2202527A (en) | 1987-03-25 | 1988-03-23 | Hydraulic setting compositions |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB2202527A (en) |
ZW (1) | ZW2488A1 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0352585A2 (en) * | 1988-07-23 | 1990-01-31 | Henkel Kommanditgesellschaft auf Aktien | Dust suppressant for the concrete spraying process |
EP0841468A1 (en) * | 1996-11-06 | 1998-05-13 | Hochtief Aktiengesellschaft Vorm. Gebr. Helfmann | Fire protection system in a reinforced concrete tubings linned tunnel |
AT414009B (en) * | 2002-04-17 | 2006-08-15 | Kubek Erhard Dipl Ing | CONCRETE CONSTRUCTION |
WO2007054545A2 (en) * | 2005-11-09 | 2007-05-18 | Deutsches Wollforschungsinstitut An Der Rwth Aachen E.V. | Composite materials containing hydraulic binders |
WO2009019471A1 (en) * | 2007-08-08 | 2009-02-12 | Halliburton Energy Services, Inc. | Sealant compositions and methods of use |
US8276666B2 (en) | 2007-08-08 | 2012-10-02 | Halliburton Energy Services Inc. | Sealant compositions and methods of use |
AU2013204279B2 (en) * | 2007-08-08 | 2014-11-13 | Halliburton Energy Services, Inc. | Sealant compositions and methods of use |
RU2807641C1 (en) * | 2023-02-16 | 2023-11-20 | Общество с ограниченной ответственностью "Пром Т" | Composition for seamless rigid waterproofing |
-
1988
- 1988-03-21 ZW ZW24/88A patent/ZW2488A1/en unknown
- 1988-03-23 GB GB08806914A patent/GB2202527A/en not_active Withdrawn
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0352585A2 (en) * | 1988-07-23 | 1990-01-31 | Henkel Kommanditgesellschaft auf Aktien | Dust suppressant for the concrete spraying process |
EP0352585A3 (en) * | 1988-07-23 | 1990-12-19 | Henkel Kommanditgesellschaft Auf Aktien | Dust suppressant for the concrete spraying process |
EP0841468A1 (en) * | 1996-11-06 | 1998-05-13 | Hochtief Aktiengesellschaft Vorm. Gebr. Helfmann | Fire protection system in a reinforced concrete tubings linned tunnel |
AT414009B (en) * | 2002-04-17 | 2006-08-15 | Kubek Erhard Dipl Ing | CONCRETE CONSTRUCTION |
WO2007054545A2 (en) * | 2005-11-09 | 2007-05-18 | Deutsches Wollforschungsinstitut An Der Rwth Aachen E.V. | Composite materials containing hydraulic binders |
WO2007054545A3 (en) * | 2005-11-09 | 2008-09-04 | Deutsches Wollforschinst | Composite materials containing hydraulic binders |
WO2009019471A1 (en) * | 2007-08-08 | 2009-02-12 | Halliburton Energy Services, Inc. | Sealant compositions and methods of use |
US8276666B2 (en) | 2007-08-08 | 2012-10-02 | Halliburton Energy Services Inc. | Sealant compositions and methods of use |
AU2008285481B2 (en) * | 2007-08-08 | 2013-06-20 | Halliburton Energy Services, Inc. | Sealant compositions and methods of use |
AU2013204279B2 (en) * | 2007-08-08 | 2014-11-13 | Halliburton Energy Services, Inc. | Sealant compositions and methods of use |
RU2807641C1 (en) * | 2023-02-16 | 2023-11-20 | Общество с ограниченной ответственностью "Пром Т" | Composition for seamless rigid waterproofing |
Also Published As
Publication number | Publication date |
---|---|
GB8806914D0 (en) | 1988-04-27 |
ZW2488A1 (en) | 1988-07-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |