GB2202180A - The manufacture of lightweight extruded structural profile - Google Patents
The manufacture of lightweight extruded structural profile Download PDFInfo
- Publication number
- GB2202180A GB2202180A GB08808463A GB8808463A GB2202180A GB 2202180 A GB2202180 A GB 2202180A GB 08808463 A GB08808463 A GB 08808463A GB 8808463 A GB8808463 A GB 8808463A GB 2202180 A GB2202180 A GB 2202180A
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- GB
- United Kingdom
- Prior art keywords
- filler
- die
- packed
- resin
- additional
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/18—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of organic plastics with or without reinforcements or filling materials or with an outer layer of organic plastics with or without reinforcements or filling materials; plastic tiles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/12—Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
- B29C67/242—Moulding mineral aggregates bonded with resin, e.g. resin concrete
- B29C67/245—Moulding mineral aggregates bonded with resin, e.g. resin concrete for making articles of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/02—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers
- B29C70/021—Combinations of fibrous reinforcement and non-fibrous material
- B29C70/025—Combinations of fibrous reinforcement and non-fibrous material with particular filler
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
- B29C70/52—Pultrusion, i.e. forming and compressing by continuously pulling through a die
- B29C70/525—Component parts, details or accessories; Auxiliary operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/58—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
- B29C70/66—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres the filler comprising hollow constituents, e.g. syntactic foam
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C3/00—Structural elongated elements designed for load-supporting
- E04C3/02—Joists; Girders, trusses, or trusslike structures, e.g. prefabricated; Lintels; Transoms; Braces
- E04C3/29—Joists; Girders, trusses, or trusslike structures, e.g. prefabricated; Lintels; Transoms; Braces built-up from parts of different material, i.e. composite structures
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/04—Wing frames not characterised by the manner of movement
- E06B3/06—Single frames
- E06B3/08—Constructions depending on the use of specified materials
- E06B3/20—Constructions depending on the use of specified materials of plastics
- E06B3/205—Constructions depending on the use of specified materials of plastics moulded or extruded around a core
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/08—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
- B29K2105/10—Cords, strands or rovings, e.g. oriented cords, strands or rovings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/16—Fillers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/16—Fillers
- B29K2105/165—Hollow fillers, e.g. microballoons or expanded particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2503/00—Use of resin-bonded materials as filler
- B29K2503/04—Inorganic materials
Abstract
In the manufacture of the profile comprising a resin-bonded core of closely compacted particulate filler, the loose filler is packed from a feed tube (14) into an extrusion (or pultrusion) die (10) by means of applied vacuum (27), within a sheath of glass rovings (12) which is used to draw the packed filler through the die. A liquid bonding resin is introduced either via a tube (30, Fig. 1) extending through the feed tube, or via the die (44, 31, 33) to permeate and bond together the packed filler and the sheath. The filler comprises coarser layer mineral foam particles and an additional free-flowing relatively finer material e.g. hollow silicate microspheres, quantities of the coarse and fine fillers being successively introduced into the die by the vacuum, so that the additional filler occupies the interstices of the previously packed coarser foam filler. The filler may be heated by a warm air heater (40). <IMAGE>
Description
THE briANUFACTURE OF LIGHTWEIGHT
STRUCTURAL PROFILE
This invention is concerned with the manufacture of lightweight structural profile, particularly but not exclusively profile suitable for use in the building or joinery industries instead of timber, for example in the construction of window and door frames and the like, but also for floor boards, joists, rafters and other building components.
In International patent specification
No. WO 81/00588 there is described a method of manufacturing window and door frames from cored extruded plastics profiles in which the core material may be of high quality plywood or other suitable material (for example a cement-bonded fibrous material such as cement-bonded clipboard or cement-bonded glass fibres) provided with a cladding of plastics material e.c. nolyvinylchloride.
For such frames the core material is required to possess a high degree of dimensional and shape stability and to be of adequate strength to bear the loads encountered by the frames in use in various weather conditions. Furthermore, as a timber substityte it may be desirable that the core material should possess good screw-holding properties.
In U.R. patent specification No. 2 028 406 B there is disclosed a method of manufacturing an extruded construction strip which is suitable for use in the manufacture of frames for v.ntlows and the like and which comprises a tubular section of thermosoftening plastics material (specifically P\7C) filled with a matrix of me.hylnzethacrylate with hollow silicate spherules as a filler. As described, the con.##ruction strip rnay incorporate within the matrix a number of filaments (specifically glass rovings) extending lengthwise of the strip for reinforcement purposes.In manufacturing the strip the plastics sheath forming the hollow section is extruded by a first extruding machine and the sheath is filled by extrudi na thereinto (by a second extruding machine) the plastics matrix of methylmethacrylate incorporating the silicate spherules, being extruded in the cold state into the hollow sheath whilst the latter is still hot. The lass rovings are drawn into the matrix during its extrusion by some means not disclosed. Curing of the matrix takes place as the strip is fed through a sizing bush of considerable length. It is apparent that the matrix must comprise a relatively high proportion of resin (methylmethacrylate) enabling the matrix to flow freely under pressure to fill the hollow section.
Furthermore, there is described in International patent specification No. WO 82/03243 a method of making somewhat similar structural profile, in which method: a a core comprising an unsaturated polyester resin incorporating a silicate filler and an additional mineral filler, thoroughly mixed and tightly compacted together, is extruded through a die, (ii) a sheath of a plastics material is extruded around the core, and (iii) the sheathed core is cured by means of heat, so as to effect curing of the core and cross-linking between the core and the sheath. The preferred silicate filler for that process, as described therein, is in the form of lightweight hollow microspheres, and an acrylic coating is preferred for the ?i;tics sheath.
According to the process described in specification No. WO 82/03243, a very close packing of the selected fillers could be achieved, resulting in a considerable reduction in the amount of resin required. However, a further reduction in the resin content can be desirable. Furthermore, there could be an advantage in using, at least as the prinary filler for the core of such structural profile, a readily-manufacturable material that could reduce the dependence on commercially supplied fillers.
There are known, and described for example in
European patent specification No. C 096 48q (Al), rigid inorganic foams of cellular structure com,prising one or more layer minerals (hereinafter referred to as layer mineral foams). The term "layer rinerals' includes vermiculite, kaolinite, kaolin-containing clays such as ball clays, china clays and fire clays, montmorillonite and sepiolite. Mixtures of layer minerals inlay be employed in making foams, as also may mixtures of one or more layer minerals with one or more materials other than layer minerals.Where the foam comprises at least a major proportion of clays (hereinafter referred to as a clay foam) it may be sintered to confer improved strength and water-stability.
Such rigid foams have been" proposed for various uses, including insulation uses and the fire-protection of substrates. Whilst often produced in the form of extruded board or slah-stock, the foams are elso produced in a coarse particulate extruded form nown as prills, the prills comprising short extruded strands of the foam material. Production of such foams can be effected utilising readily available materials and relatively simple machinery.
It has been found by the applicant that such rigid foam materials can be used most effectively and advantageously in a method of manufacturing lightweight structural profile in which a core comprising closely compacted and bonded particulate filler comprising layer mineral foam in a coarse particulate form is formed in passage through a shaping die.
In a technique developed by the applicant for the purpose of enabling loose particulate layer mineral foam (i.e. not pre-mixed with liquid resin) to be introduced into a shaping die in an efficient manner, applied vacuum is utilised to draw in and pack the filler. This technique could find wider application in use with other fillers in manufacturing lightweight structural profile.
The invention provides a method of manufacturing lightweight structural profile in which there is formed in passage through a shaping die a body comprising closely compacted and bonded particulate filler comprising a primary filler and a relatively fine additional filler, the method comprising packing loose particulate filler into the shaping die by means of applied vacuum and progressing the packed filler through the die to become bonded in formation of the body, the primary filler and the additional filler being introduced successively into the die, and the additional filler being a relatively fine free-flowing filler which is drawn in to occupy interstices of packed primary filler.
Coarse particulate layer mineral foam may form the primary filler, convenIently in the form of short extruded strands ("prills") . The additional filler, being of a less coarse particulate form, ca: be a silicate filler in the form of hollow microspheres.
The densities and strengths of layer mineral foams can vary over a wide range but can be readily controlled. Their use, together with careful selection of secondAry fillers as appropriate, affords a corresponding versatility in determining the properties of structural profile so manufactured.
To enable vacuum to be applied, the walls of the die can be provided with airways leading from the interior of the die. The airways may lead to one or more manifolds maintained at reduced pressure, a stream of air (or other gas) so being drawn into the die, and filler consequently being drawn into the die and packed. A suitable filter arrangement can prevent filler particles from entering or obstructing the airways in the die walls.
For certain products it might be desirable to arrange to have filler of a higher specific gravity towards the outside of the core than in the mIddle.
This could be achieved by first packing by vacuum the heavier filler against the walls of the die and thereafter packing (also by means of vacuum) lighter filler into the middle.
In a preferred method, after the loose filler has been vacuum packed within the shaping die a bonding rcsin is caused to permeate, the' interstices of the packed filler the resin thereafter being caused or allowed to cure or set. Advantage may be gained from at least the surface of the filler being at an elevated temperature when the bonding resin is introduced.
Pre#erably, after initial packing by means of applied vacuum the packed filler is progressed through a convergent portion of the shaping dic to achieve further consolidation of- the packed filler.
Introduction of a bonding resin into the packed filler preferably occurs as the filler is progressed through the convergent portion.
The manufacturing method can advantageously employ a pultrusion process similar to that described in U.I;.
patent specification No. 2 143 768 A. That is to say, glass fibre rovings, or equivalent materials, can be provided trapped between outer surfaces of a body of packed filler and walls of the shaping die, the rovings being pulled with the packed filler through the die as the profile is formed. Such use of glass fibre rovings can be of particular benefit in easing the process, serving to keep down the back pressure in the die with a consequent saving of wear in the apparatus generally and minimising any breakdown of the filler by crushing owing to excessive pressures. The fibres may provide a complete resin-bonded sheath for the core.If required, a plastics coating can be applied to the outside of the fibre-clad core, again as referred to in patent specification No. 2 i43 768 A, though with suitable resins and pigments this may be unnecessary to provide finished profile with a fully satisfactory outer surface.
Reference is hereby made to Patent Application
No. 2 160 470, also in the name or the present
Applicant.
Reference is also made to Patent Application
No. 2 160 i43 from which the present application is divided.
There now follows a detailed dcscription, to be read with reference to the accompal inc drawings, of a method of making lightweight structural profile which illustrates the invention by way of example.
In the'accompanyins drawings:
Figure 1 is a diagrammatic illustration of a
packing section of pultrusion apparatus for
producing profile;
Figure 2 is a diagrammatic cross-sectional view
of the apparatus on the line II-II of Figure 1;
and
Figure 3 is a schematic illustration of the
apparatus as a whole.
In the manufacture of lightweight structural profile comprising a core of closely compacted resin-bonded particulate filler within a sheath of resin-bonded reinforcing fibres, a shaping die 10 lined with continuously supplied reinforcing fibres in the form of glass rovinss 12 is packed from one end with loose particulate filler, from feeding means comprising a conduit 14, as the rovings are continuously drawn through the die (in the direction of the arrow E in
Figure 1). Reference can be made to U.K. patent specification No. 2 143 768 A for a further example of the manufacture of profile comprising a fibre-sheathed core in such a pultrusion process.
A nose portion 16 of the conduit 14 is received within an entry portion 18 of the die 10 and is shaped similarly to the interior cross-section of the die in that region to define a suitable gap (all around the nose portion) to permit and control introduction of the glass rovings 12 on to the wall surfaces defining the die cavity 20. The glass rovings are fed in, in continuous lengths, from supply drums 21 (Figure 3) and are caused to line the die cavity 20 substantially uniformly over all its wall surfaces.
A generally annular array of airways, comprising fine radial bores 22 in the walls 24 of the die 10, connect the die cavity 20 with the interiors of low pressure manifolds 26. The manifolds are connected to a vacuum pump 27, whereby air can be drawn from the manifolds to reduce air pressure within the die cavity. By this means, particulate filler supplied to ti#e die cavity from the feeding means through the conduit 14 can be vacuumed into a packing region 28 of the cavity (within the array of airways) and so packed xaltllin the sheath of glass rovings 12 in that region.
The sheath of rovings itself serves to some extent as a =kilter preventing filler particles from entering or obstructIng the airways 22, but additional filtering neans (not shown) can be provided to prevent the passage of fine filler particles.
In the construction shown in Figures 1 and 2, a resin feeding tube 30 of resin feeding means extends longitudinally through the conduit 14 and the die cavity 20 substantially to the limit of the packing region 28 (which is to say, it extends to the limit of, or very slightly beyond, that portion of the die 10 provided with the bores 22) . Alternatively, and as indicated in Figure 3, resin can be introduced through e feeding tube 31 through the die wall to a feeding channel 33 in the die wall extending in a loop around the die cavity.
At tile start of operation, a plug 32 (Figure 1) is positioned to occupy the die cavIty 20 immediately beyond the packing region 28. The plug 32 is shaped similarly to the interior cross-section of the die in that region to define a suitable gap to accommodate and hold the glass rovings 12 against the interior die wall surfaces. The plug provides, in effect, a dummy section of core which together with the sheath of rovings around it blocks the die to permit initial vacuum packing of the filler. Once filler has been packed by vacuum into the packing region 28, continuous formation of profile can commence by withdrawal (in the forwards direction) of the plug 32. The plug is of a compressible foam material which permits it to be drawn through the convergent die.The plug is drawn from the die in a similar manner to that in which the profile will thereafter be drawn through and from the die, which is to say by applying a pulling force in the direction of passage to the glass rovings 12 held to the plug/core (in a similar manner to that described in
U.K. patent specification No. 2 143 768 A, hereiflbe#Ore referred to). Liquid resin is fed through the feeding tube 30 or 31 to permeate the packed filler and the glass rovings 12, the resin thereafter being caused or allowed to cure or set to provide a shaped body of predetermined cross-section of sheathed resin-bonded filler.
More or less immediately following the packing region 28, there is a compressing region 34 within the die 10 in which a convergence of the die walls causes compression and further consolidation of the core as it passes to a final forming region 36 of the die.
With particular reference to Figure 3, the feedinc means for supplying particulate filler to the shaping die 1G comprises two feed shutes 38 and 40 leading into the feed conduit 14. Each of the shutes is valved to enable measured portions of filler materials to be delivered into the conduit 14 as required. The vacuum pump 27 in operation draws an air stream through the conduit 14, and heating means 42 within an entry portion of the conduit enables the air to be heated if required. Resin is supplied to the resin feeding tube 30 or 31 by means of a supply pump 44. The resin supply can be controlled by monitoring the pressure in the feeding tube.Profile drawing means 46, of a kind well known in the pultrusion art, acts continuously to draw the glass rovings 12 (and the profile core) through the sheathing die 10.
The particulate filler comprises layer mineral foam in a coarse particulate form as a primary filler.
Suitable clay foam prills (being short extruded strands) are as promoted in the U.K. by Imperial
Chemical Industries PLC as "K4 Inorganic Foam11. The prills may, for example, have a mean extruded length of around 5 mm and a diameter of about 2 mm, and their specific gravity can fall (at choice) anywhere within as wide a range as 0.1 to 0.6; partly reflecting that, the proportion (b weight) of filler in the resin-bonded product can vary between, say, 25% and 80% (depending also on the type of resin used).
Whilst the particulate layer mineral foam alone may constitute the filler, it is usually preferable that a suitable secondary filler be incorporated. This additional filler should be a relatively fine filler, and to permit efficient incorporation by the vacuum packing technique it should be a free-flowing material. A preferred secondary filler comprises (at least as the primary constituent) silicate material in the form of hollow microspheres; such material is widely known as filler ane is available commercially either as recovered from power station waste or as manufactured "glass bubble" filler.
Chopped glass strands may also be introduced in addition to the foam clay and hollow silicate fillers.
Employing the vacuum packing technique (hereinbefore described) the primary and secondary fillers are introduced into the shaping die separately in discrete measured portions. A first of the feed shutes 38 is used to supply the primary filler (the prills), and the second feed shute 40 is used to supply the secondary filler (the microspheres), measured portions of the two fillers being supplied alternately. Accordingly, a portion of primary filler is first released from the first feed shute 38, and the filler is drawn by vacuum into the packing region 28 of the shaping die. A portion of secondary filler is then releasec from the second feed shute 40 and drawn into the packing region 28 and into the interstices of the packed portion of primary filler.A next measured portion of primary filler can be released from the first feed shute 38 at a suitable time, bearing in mind that the glass rovings 12 are being drawn continuously through the die 10 by means of the profile drawing means 46.
Further consolidation of the initially vacuum paced primary and secondary fillers occurs as the core material is progressed next through the compressing region 34 of the die 10. With the resin-feeding arrangement as shown in Figure 3, a bonding resin is introduced through the feeding tube 31 shortly before the end of the compressing region of the die. The resin (whether introduced at the centre of the packed filler as from the tube 30 in Figures 1 and 2, or at the periphery as from the tube 31) permeates the remaining interstices of the packed filler (and the glass fibre rovings 12) by capillary attraction and the effects of increasing pressure as the material moves through the die.A non-foaming phenolic resin system which has been used successfully is one available in the U.K. from BP Chemicals under the trade marks
Cellobond J25/425L resin and Phencat 10 catalyst.
Typically, in use of that resin system, with about 5E of the catalyst, the heating means 42 is utilised to result in the foam clay filler having a surface temperature of around 700C when the resin (i.e. mixed resin and catalyst) is introduced, the shaping die 10 itself being at a temperature ranging from not more than about 900C at its entry end to around 130to towards its outlet end.
In the finished profile the proportions of the constituents (by volume) can be within the following ranges:
Layer mineral foam prills (primary filler) : 50%-60%
Hollow silicate filler (additional filler) : 28%-'2.5E resin : 12t-17 . 52 The finished sheath thickness may typically be 0.5 mm to 0.75 mm.
Claims (5)
1. A method of manufacturing lightweight structural profile in which there is formed in passage through a shaping die a body comprising closely compacted and bonded particulate filler comprising a primary filler and a relatively fine additional filler, the method comprising packing loose particulate filler into the shaping die by means of applied vacuum and progressing the packed filler through the die to become bonded in formation of the body, the primary filler and the additional filler being introduced successively Into the die, and the additional filler being a relatively fine free-flowing filler which is drawn in to occupy interstices of packed primary filler.
2. A method according to claim 1 in which the primary filler is layer mineral foam in a coarse particulate form and the additional filler is a silicate filler in the form of hollow microspheres.
3. A method according to either of claims 1 and 2 in which after initial packing by means of applied vacuum the packed filler is progressed through a convergent portion of the shaping die to achieve further consolidation of the filler.
4. A method according to any one of claims 1 to 3 in which the packed filler is pulled through the shaping die in a pultrusion process.
5. Lightweight structural profile made by a method according to any one of claims 1 to 4.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB848411864A GB8411864D0 (en) | 1984-05-09 | 1984-05-09 | Manufacture of lightweight structural members |
GB848416026A GB8416026D0 (en) | 1984-06-22 | 1984-06-22 | Lightweight structural profile |
PCT/GB1985/000191 WO1985005071A1 (en) | 1984-05-09 | 1985-05-08 | The manufacture of lightweight extruded structural profile |
GB8511762A GB2160143B (en) | 1984-05-09 | 1985-05-09 | The manufacture of lightweight structural profile |
Publications (3)
Publication Number | Publication Date |
---|---|
GB8808463D0 GB8808463D0 (en) | 1988-05-11 |
GB2202180A true GB2202180A (en) | 1988-09-21 |
GB2202180B GB2202180B (en) | 1989-02-08 |
Family
ID=27262354
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08808463A Expired GB2202180B (en) | 1984-05-09 | 1985-05-09 | The manufacture of lightweight structural profile |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB2202180B (en) |
SG (1) | SG11592G (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997049877A1 (en) * | 1996-06-22 | 1997-12-31 | Gerhard Dingler | Structural member |
-
1985
- 1985-05-09 GB GB08808463A patent/GB2202180B/en not_active Expired
-
1992
- 1992-02-06 SG SG115/92A patent/SG11592G/en unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997049877A1 (en) * | 1996-06-22 | 1997-12-31 | Gerhard Dingler | Structural member |
US6505454B2 (en) | 1996-06-22 | 2003-01-14 | Gerhard Dingler | Structural member |
Also Published As
Publication number | Publication date |
---|---|
SG11592G (en) | 1992-03-20 |
GB2202180B (en) | 1989-02-08 |
GB8808463D0 (en) | 1988-05-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19990509 |