GB2199336A - Electro-rheological fluids - Google Patents

Electro-rheological fluids Download PDF

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Publication number
GB2199336A
GB2199336A GB08711542A GB8711542A GB2199336A GB 2199336 A GB2199336 A GB 2199336A GB 08711542 A GB08711542 A GB 08711542A GB 8711542 A GB8711542 A GB 8711542A GB 2199336 A GB2199336 A GB 2199336A
Authority
GB
United Kingdom
Prior art keywords
fluid
electro
liquid crystal
insulating material
rheological
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB08711542A
Other versions
GB8711542D0 (en
Inventor
Dennis William George Byatt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co PLC
Original Assignee
General Electric Co PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB868630747A external-priority patent/GB8630747D0/en
Priority claimed from GB8702381A external-priority patent/GB2189803B/en
Application filed by General Electric Co PLC filed Critical General Electric Co PLC
Priority to GB08711542A priority Critical patent/GB2199336A/en
Publication of GB8711542D0 publication Critical patent/GB8711542D0/en
Priority to GB8811444A priority patent/GB2208515B/en
Priority to EP88304372A priority patent/EP0291338A3/en
Publication of GB2199336A publication Critical patent/GB2199336A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/001Electrorheological fluids; smart fluids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/08Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/12Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings at least two benzene rings directly linked, e.g. biphenyls
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/08Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/12Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings at least two benzene rings directly linked, e.g. biphenyls
    • C09K2019/121Compounds containing phenylene-1,4-diyl (-Ph-)
    • C09K2019/122Ph-Ph
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00Liquid crystal materials
    • C09K19/52Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
    • C09K2019/521Inorganic solid particles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/12Glass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/16Dielectric; Insulating oil or insulators
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/17Electric or magnetic purposes for electric contacts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/175Pantographs, i.e. printing devices
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/18Electric or magnetic purposes in connection with recordings on magnetic tape or disc
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/185Magnetic fluids

Abstract

An electro-rheological fluid comprises liquid crystal material (e.g. type E7) which may have suspended therein a quantity of dry microscopic glass bubbles of which the majority have diameters between 20 and 120 microns and wall thicknesses of between 0.5 and 2 microns.

Description

Improvements in or Relating to Electro-Rheological Fluids This invention relates to electro-rheological fluids, that is to say fluids which exhibit an apparent change of viscosity when subject to the influence of an electric field, and arrangements utilising such fluids.
Conventional electro-rheological fluids essentially comprise a fluid carrier medium in which are suspended particles of material. In operation the viscosity of the fluid may be quite low, so as to flow readily, until subjected to the influence of a relatively high voltage electric field whereupon the apparent viscosity increases considerably so as to increa#se the resistance of the liquid to shear stress.
A typical electro-rheological fluid as at present known consists of a light oil (e.g. transformer oil) having suspended therein finely divided solid material (e.g. plastic) with a small quantity of water. Whilst the underlying mechanism is not presently well understood, it is believed that the water effectively coats the particles of solid material and, with electro-rheological fluids as at present known, plays an important part in the operation.
With an electro-rheological fluid as described above there is a tendency for the suspended material to separate out. This may be overcome by providing means for ensuring that the fluid is kept in motion (e.g. by pumping or agitation). the necessity to include a quantity of water within the composition of the fluid presents a more serious problem since not only does this provide a possible cause of deterioration of the fluid itself, but also a possible source of corrosion and an increase in the electrical conductivity of the field. In certain control systems, the last-mentioned may represent a very serious problem indeed.
The present invention seeks to provide an improved electro-rheological fluid and arrangements utilising the same in which one or more of the above problems are avoided or mitigated.
According to this invention an electro-rheological fluid comprises liquid crystal material.
A liquid crystal material presently preferred is that known as FE?I.
Suspended within said liquid crystal material may be particles of an electrically insulating material.
Said electrically insulating material may be nonconductive glass. Glass is of course a dielectric material and other dielectric material may be suitable.
Said electrically insulating material may be provided in the form of hollow particles, for example microscopic glass bubbles. In one example said microscopic glass bubbles are in the form of an aggregate having a size range in which the majority of bubbles have diameters between 20 and 100 microns and wall thicknesses of between 0.5 and 2 microns.
Said insulating material may substantially alone be suspended in said liquid crystal material. However, it may be that satisfactorily low electronical conductance with an improved response time may be achieved by including with said insulating material, semiconductor material, and more particularly organic semiconductor material, for example in substantially equal parts by volume.
The invention is illustrated in and further described with reference to the accompanying drawings of which Figure 1 illustrates in a highly schematic manner and by a section, part of a simple control system utilising an electro-rheological fluid in accordance with the present invention and Figure 2 similarly illustrates part of a printed circuit board test apparatus utilising an electro-rheological fluid in accordance with the present invention.
Referring to Figure 1, the mechanical components of the arrangement comprise a piston 1 connected to drive a rod 2 (which in turn may be connected to actuate a mechanism, not shown). The piston moves within a cylinder 3 of which the wall is formed in part by two opposing electrodes 4 and 5. Apart from the electrodes 4 and 5, the cylinder 3 is of electrically insulating material. The electrodes 4 and 5 are connected to terminals 6 and 7 across which may be applied a high d.c. voltage, in this case of the order of 6kV.
Piston 1 is moved, as known per se, by compressing a fluid 8 within the cylinder 3. The fluid 8 is an electro-rheological fluid in accordance with the present invention and consists of E7 liquid crystal material As is known per se E7 liquid crystal material available, for example, from BDH Limited of Poole, England, is a biphenyl-based room temperature nematic mixture having the following characteristics:: Viscosity 39.0 cSt 20 C Dielectric Permittivities #@ = 5.38 = = 19.05 (i.e. when switched) tt = 13.67 Elastic constants K11 11.1 x 10-12N K11 K22 17.1 x 10-12N K11 K33 1.54 x 10 N E7 liquid crystal material is slightly hydroscopic. In order to drive off water, the material is placed in a vacuum (of the order of 0.1 torr) and heated before use to provide a liquid of high electrical resistance and of homogeneous nature, not likely to separate into constituent parts.
The distance separating the two electrodes 4 and 5 is of the order of 2mm, in this particular example.
When the piston 1 is moved to its desired position as illustrated, with the electrodes 4 and 5 unenergised and thus the viscosity of the fluid relatively low and relatively free flowing, the electrodes 4 and 5 are energised by applying a d.c. voltage of the order of 6kV to the terminals 6 and 7. This establishes an electric field between the electrodes 4 and 5 which causes the visocosity of the liquid 8 to increase markedly. The shear strength of the liquid between electrodes 4 and 5 with the field established approaches that of a solid and the piston 1 is thus held in position until the field is removed.
The piston may be returned to its original position by gravity or by means such as a spring (not shown), as known per se.
In a modification dry microscopic glass bubbles of which the majority have diameters between 20 and 120 microns and wall thicknesses of between 0.5 and 2 microns are suspended within said liquid 8.
Referring to Figure 2, the printed circuit board test apparatus illustrated comprises a metal block 9 which is connected to a mechanical drive (not shown).
At desired points, the block 9 is bored through with 2mm diameter holes 10 to form a number of 2mm diameter cylinders. Individual push rods 11, of diameter lmm, are supported concentrically within each cylinder by bearing plates 4,5. Each push rod 11 is connected to actuate a different mechanism (not shown).
The bearing plates 12,13 are of electrically insulating material whilst the push rods 11 and cylinders 10 are of electrically conductive metal.
Thus the push rods 11 and cylinders 10 form opposing electrodes which are connected across a high d.c.
voltage source, in this case of about lkV.
Every cylinder 10 is connected to one side of the d.c. supply source by a single connection 14, made to the metal block 9. The push rods 11 are individually connected to the other side of the d.c. supply via slip rings 15 and electrical switches 16.
The gap between each push rod and its associated cylinder wall is 0.5mm and is filled with an electrorheological fluid 17 in accordance with this present invention. In this case the electro-rheological fluid 17 comprises, as with the embodiment described with reference to Figure 1, E7 liquid crystal material into which is suspended a quantity of dry microscopic glass bubbles of which the majority have diameters of between 20 and 120 microns and wall thicknesses of between 0.5 and 2 microns. The liquid crystal material is dried before use by heating in a vacuum (of the order of 0.1 torr).
Without any voltage being applied, that is to say with all- of the electrical switches 16 open, the viscosity of the fluid is such that the forces acting upon the push rods 11 by the movement, represented by double-headed arrow 18, of the cylinder block 9 are insufficient to overcome the bearing friction. The application of the high potential across a push rod cylinder pair by the closing of the appropriate electrical switch 16 increases the ability of the fluid contained in the respective cylinder 10 to withstand shearing forces to such an extent that the respective push rod 11 becomes mechanically attached to the metal block and will follow its movements to actuate the aforementioned respective mechanism to which the push rod is connected.

Claims (12)

1. An electro-rheological fluid comprising liquid crystal material.
2. An electro-rheological fluid as claimed in claim 1 and comprising E7 liquid crystal material.
3. An electro-rheological fluid as claimed in claim 1 or 2 and wherein particles of an electrically insulating material are suspended within. said liquid crystal material.
4. A fluid as claimed in claim 3 and wherein said electrically insulating material is non-conductive glass.
5. An electro-rheological fluid as claimed in any of the above claims and wherein said electrically insulating material is provided in the form of hollow particles.
6. A fluid as claimed in claim 5 and wherein said hollow particles are microscopic glass bubbles.
7. A fluid as claimed in claim 6 and wherein said microscopic glass bubbles are in the form of an aggregate having a size range in which the majority of bubbles have diameters between 20 and 100 microns and wall thicknesses of between 0.5 and 2 microns.
8. A fluid as claimed in any of the above claims and wherein said insulating material is substantially alone suspended in said liquid crystal material.
9. A fluid as claimed in any of the claims 1 to 7 and wherein said semiconductor material is included with said insulating material in said suspension.
10. A fluid as claimed in claim 9 and wherein said semiconductor material is included with said insulating material in said suspension in substantially equal parts by volume.
11. A control or actuating apparatus including electro-rheological fluid as claimed in any of the above claims.
12. An apparatus as claimed in claim 11 and comprising a printed circuit board test apparatus.
GB08711542A 1986-12-23 1987-05-15 Electro-rheological fluids Withdrawn GB2199336A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB08711542A GB2199336A (en) 1986-12-23 1987-05-15 Electro-rheological fluids
GB8811444A GB2208515B (en) 1987-05-15 1988-05-13 Electro-rheological fluid materials
EP88304372A EP0291338A3 (en) 1987-05-15 1988-05-13 Electro-rheological fluid materials

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB868630747A GB8630747D0 (en) 1986-03-26 1986-12-23 Electro-rheological fluids
GB8702381A GB2189803B (en) 1986-03-26 1987-02-03 Electro-rheological fluid apparatus
GB08711542A GB2199336A (en) 1986-12-23 1987-05-15 Electro-rheological fluids

Publications (2)

Publication Number Publication Date
GB8711542D0 GB8711542D0 (en) 1987-06-17
GB2199336A true GB2199336A (en) 1988-07-06

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Family Applications (1)

Application Number Title Priority Date Filing Date
GB08711542A Withdrawn GB2199336A (en) 1986-12-23 1987-05-15 Electro-rheological fluids

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GB (1) GB2199336A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0291338A2 (en) * 1987-05-15 1988-11-17 THE GENERAL ELECTRIC COMPANY, p.l.c. Electro-rheological fluid materials
GB2249553A (en) * 1990-11-09 1992-05-13 David Lacey Electro-rheological fluids
EP0567649A4 (en) * 1991-07-24 1993-07-28 Tonen Corp Electroviscous fluid.
US5271858A (en) * 1986-03-24 1993-12-21 Ensci Inc. Field dependent fluids containing electrically conductive tin oxide coated materials
US5437806A (en) * 1991-10-10 1995-08-01 The Lubrizol Corporation Electrorheological fluids containing polyanilines
US5595680A (en) * 1991-10-10 1997-01-21 The Lubrizol Corporation Electrorheological fluids containing polyanilines
US5756207A (en) * 1986-03-24 1998-05-26 Ensci Inc. Transition metal oxide coated substrates

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
WO A1 85/03944 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5271858A (en) * 1986-03-24 1993-12-21 Ensci Inc. Field dependent fluids containing electrically conductive tin oxide coated materials
US5756207A (en) * 1986-03-24 1998-05-26 Ensci Inc. Transition metal oxide coated substrates
EP0291338A2 (en) * 1987-05-15 1988-11-17 THE GENERAL ELECTRIC COMPANY, p.l.c. Electro-rheological fluid materials
EP0291338A3 (en) * 1987-05-15 1989-10-11 THE GENERAL ELECTRIC COMPANY, p.l.c. Electro-rheological fluid materials
GB2249553A (en) * 1990-11-09 1992-05-13 David Lacey Electro-rheological fluids
EP0567649A4 (en) * 1991-07-24 1993-07-28 Tonen Corp Electroviscous fluid.
EP0567649A1 (en) * 1991-07-24 1993-11-03 Tonen Corporation Electroviscous fluid
US5387370A (en) * 1991-07-24 1995-02-07 Tonen Corporation Electroviscous fluid
US5437806A (en) * 1991-10-10 1995-08-01 The Lubrizol Corporation Electrorheological fluids containing polyanilines
US5595680A (en) * 1991-10-10 1997-01-21 The Lubrizol Corporation Electrorheological fluids containing polyanilines

Also Published As

Publication number Publication date
GB8711542D0 (en) 1987-06-17

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