GB2195353A

GB2195353A - Detergent flakes

Info

Publication number: GB2195353A
Application number: GB08722748A
Authority: GB
Inventors: Carl Martin Irvin
Original assignee: Unilever PLC
Current assignee: Unilever PLC
Priority date: 1986-09-30
Filing date: 1987-09-28
Publication date: 1988-04-07
Anticipated expiration: 2007-09-28
Also published as: EP0262896A2; EP0262896A3; EP0262896B1; DE3777517D1; GB2195353B; GB8722748D0; GB8623426D0

Abstract

Cut soap flakes having a thickness between 0.05 mm and 0.2 mm comprise 80 to 90 wt% soap calculated on an anhydrous basis, 1 to 10 wt% free fatty acid and 6 to 11 wt% moisture. The presence of the free fatty acid can improve the solubility of the product in wash water at low temperatures for laundering.

Description

1 1 GB2195353A -1

SPECIFICATION

Detergent flakes and a process for making detergent flakes The present invention relates to detergent flakes and to a process for making detergent flakes.

Detergent flakes are intended primarily for laundry uses. They are particularly appropriate for laundering delicate and fine fabrics at a relatively low temperature, for example between 20 and 40'C. Typically detergent flakes are employed when washing a small quantity of laundry by hand. It is therefore a necessary requirement of detergent flakes that they dissolve relatively readily in the low temperature washing water employed.

According to a first aspect of the present invention there are provided cut detergent flakes having a thickness between 0.05mm and 0.2mm and comprising 80 to 90wt% soap calculated on an anhydrous basis, 1 to 10wt% free fatty acid and 6 to 12wt% moisture.

The present invention can thus provide cut detergent flakes whose major components are derived wholly from soap and/or soap-making sources. Minor components that can additionally 15 be present include sequestrants, anti-oxidants, preservatives, perfumes and dyes.

The detergent flakes embodying the present invention have a substantially constant thickness within the range 0.05 to 0.2mm, preferably 0.05mm to 0. 1mm. The overall dimensions of the flakes are determined primarily by the requirement that the flakes dissolve within a relative short space of time. Preferably the individual total perimeter dimension of each flake is between 20mm 20 and 50mm. Suitably the flakes are diamond shaped. Other shapes and sizes can however be envisaged.

The presence of the free fatty acid in the present flakes can improve the solubility of the flakes comp ared to equivalent flakes not containing free fatty acid. The increased solubility in terms of time taken to achieve substantially full dissolution can be particularly noticeable at temperatures of 30'C and below. Th e present invention can additionally allow good solubility to be achieved when the soap component of the flakes is derived solely from cheap and readily available sources such as a major proportion tallow and a minor proportion of coconut oil.

Preferably the free fatty acid is derived wholly from soap and/or soapmaking sources. The major components of the present detergent flakes can thus be derived wholly from natural renewable resources. The presence of the free fatty acid can moreover render the washing solution less irritant to the skin. The added free fatty acid can, but need not necessarily, be distilled free fatty acid. The flakes can contain a dye, but in the absence of any added colouring matter the flakes can have a good white colour.

The detergent flakes preferably comprise 84 to 88wt% soap, 3 to 10wt% free fatty acid and 35 7 to 1 lwt% moisture, more preferably 85 to 87wt% soap, 3 to 5wt% free fatty acid and 8 to 10wt% moisture. The precise composition will depend on the actual ingredients employed, but must be within the presently defined limits in order for the composition to be in cut flake form.

The free fatty acid is calculated with respect to the actual quantities of free fatty acid present in the end product, which may be less than, for example, the amount of distilled fatty acid added, 40 but would include free fatty acid already present in the soap components of the composition.

Sources for the soap can be any conventional soap-making material. Preferably however they are derived from renewable natural resources such as triglycericle fats and oils. A preferred composition includes a tallow or tallow-like material combined with a lauric-containing material.

Suitably the soap component comprises 40 to 95wt% tallow soap and 60 to 5wt% coconut soap, more suitably 60 to 95wt% tallow soap and 40 to 5wt% coconut soap, even more suitably 75 to 90wt% tallow soap and 25 to 10wt% coconut soap.

The fatty acid is preferably derived from a triglyceride oil or fat. Suitably it is coconut or palm kernel or a tallow/coconut mixture of fatty acids.

According to a second aspect of the present invention there is provided a process for making 50 detergent flakes comprising rolling into sheet form a composition comprising 80 to 90wt% soap calculated on an anhydrous basis, 1 to 10wt% free fatty acid and 6 to 12wt% moisture to a thickness between 0.05mm and 0.2mm and cutting the resulting sheet into flakes.

The composition has the preferred compositional ranges and sources mentioned above. Prefer ably the composition is rolled and cut into flakes having a thickness between 0.05mm and 55 0. 1 mm.

By use of the present process it has been found possible to make cut flakes of the present thickness containing free fatty acid. It is essential that the present compositional ranges are employed. If the composition contains too much moisture and/or free fatty acid, the resulting sheet will be difficult to roll and too sticky to form into discrete flakes and if too little moisture 69 and/or free fatty acid it will be too dry and fragile to form flakes. The precise composition selected will depend on the ingredients and more importantly on the process conditions and the actual design of the rolling mill employed. For example, a multi roll mill or single roll mill can be employed.

SLitably the present process includes blending the free fatty acid with a neat soap solution 65 2 GB2195353A 2 containing the appropriate soap ingredients. Minor ingredients such as sequestrants, preservatives and anti-oxidants can be conveniently added at this stage. The resulting molten mixture at a temperature between 100 and 160C can then be preferably dried to a moisture content between 6 and 12wt% using for example a vacuum drier or alternatively an expansion chamber/chilled drum. The composition can be removed from the drier and, optionally after an ageing step, it can then be noodled and can be stored until required. Any perfume can be added prior to an optional further noodling step and milling. Suitably a three or a five roll mill can be employed. The rolling step suitably takes place with the composition at a temperature between 20 and 30'C. The resulting sheet is cut into flakes and the flakes can be ready for packing. The cutting action can be full thickness through the sheet or to a partial depth sufficient in a subsequent step of stripping the flakes from the end roller by means of a doctor blade to cause the sheet to break crisply into discrete flakes of the intended shape. The flakes can be cut into any desired size and shape. A suitable size is flakes having individual total perimeter between 20mm and 50mm.. A suitable shape is diamond shaped, but other shapes can be chosen.

Embodiments of the present invention will now be described by way of example only with reference to the following Examples.

Example 1

A blend of 82wt% high grade tallow and 18wt% coconut oil was saponified using sodium hydroxide and steam. The neat soap, containing 63wt% total fatty matter, was separated from 20 the glycerine by washing with brine.

4.7wt%, based on the weight of the final product, of distilled free fatty acid (Prifac 7970) and small amounts of conventional sequestrant, anti-oxidants and perfume were admixed with the neat soap. 4.7 wt% distilled free.fatty acid is equivalent to 3.9 wt% free fatty acid in the final product- The resulting mixture was dried to reduce its water content from about 30wt% to about 9wt%. Perfume was added to the composition which was then noodled and roll milled to the desired thickness of 0.05 to O.1mm. The- resulting thin sheet was cut into diamond shaped flakes having a side length of 5mm, collected and packed. The resulting flakes had a final composition of 86wt% soap and 8.8wt% moisture (including salt and glycerol) plus the ingredi ents mentioned above.

Example 2

The procedure of Example 1 was followed with the difference that 3.6 wt%, based on the weight of the final product, of distilled free fatty acid (Prifac 7970) were employed in place of the 4.7 wt% used in Example 1. 3.6 wt% distilled free fatty acid is equivalent to 3.0 wt% free 35 fatty acid in the final product.

The product flakes having a thickness between 0.05 and 0.1 mm were readily formed by rolling and cutting. The flakes had a final composition of 87 wt% soap and 8.9 wt% moisture (including salt and glycerol) plus the free fatty acid and added sesquestant, anti-oxidant and perfume.

Tests were performed on the product flakes of Examples 1 and 2, on equivalent flakes (B) not containing distilled fatty acid, and for further comparison on two commercially available soap flake products (C and D) based on soap and moisture only as their main ingredients.

Each test was performed twice on each product and the average of the results taken. Each test comprised placing 40OcM3 water of 26'FI-1 in a standard beaker and stabilising the water temperature at either 3WC or 4WC. The water was stirred by a mechanical stirrer to create a vortex and 49 of test product was poured into the vortex. The solution was stirred at a fixed rate for 2 minutes and was then filtered so as to allow the undissolved residues of each product to be collected and weighed and hence to yield a figure for the insolubility of each product. Each product was tested at 3WC and 4WC. The results are given in the Table below.

Table:

Product wt% insoluble wt% insoluble at WC at 400C 55 Example 1 0.70 0.20 Example 2 2.20 0.20 Comparative product B 45.20 0.44 Commercial product C 57.24 7.19 60 Commercial product D 42.72 0.67 As can be seen from the above Table, the flakes of Examples 1 and 2 embodying the present invention showed significantly better solubility, especially at WC than the comparative test 65 1 ii- 1 3 GB2195353A 3 products.

Claims

1. Cut detergent flakes having a thickness between 0.05mm and 0.2mm and comprising 80 to 90wt% soap calculated on an anhydrous basis, 1 to 10wt% free fatty acid and 6 to 1 lwt% 5 moisture.

2. Detergent flakes according to claim 1 comprising 84 to 88wt% soap, 3 to 10wt% free fatty acid and 7 to 11 wt% moisture.

3. Detergent flakes according to claim 2 comprising 85 to 87 wt% soap, 3 to 5wt% free fatty acid and 8 to 10 wt% moisture.

4. Detergent flakes according to any one of claims 1 to 3 wherein the soap component comprises 40 to 95wt% tallow soap and 60 to 5wt% coconut soap, calculated with respect to the soap content.

5. Detergent flakes according to claim 4 wherein the soap component comprises 60 to 95wt% tallow soap and 40 to 5wt% coconut soap.

6. Detergent flakes according to any one of the preceding claims wherein the free fatty acid is a distilled fatty acid derived from triglyceride oil or fat.

7. Process for making detergent flakes comprising rolling into sheet form a composition comprising 80 to 90wt% soap calculated on an anhydrous basis, 1 to 10wt% free fatty acid and 6 to 12wt% moisture to a thickness between 0.05mm and 0.2mm and cutting the resulting 20 sheet into flakes.

8. Process according to claim 7 wherein the composition comprises about 84 to 88wt% soap, 3 to 1 Owt% free fatty acid and 7 to 11 wt% moisture.

9. Process according to claim 8 wherein the composition comprises 85 to 87 wt% soap, 3 to 5 wt% free fatty acid and 8 to 10 wt% moisture.

10. Process according to any one of claims 7 to 9 comprising admixing free fatty acid with a neat soap solution, drying the resulting solution and noodling the resulting composition prior to rolling the composition into sheet form.

11. A process according to any one of claims 7 to 10 wherein the composition is rolled at a temperature between 20 and 30oC.

12. Detergent flakes substantially as hereinbefore described with reference to any one of Examples 1 to 2.

13. A process for making detergent flakes substantially as hereinbefore described with reference any one of Examples 1 to 2.

Published 1988 at The Patent Office, State House, 66/71 High Holborn, London WC1R 4TP. Further copies may be obtained from The Patent Office, Sales Branch, St Mary Cray, Orpington, Kent BR5 3RD. Printed by Burgess & Son (Abingdon) Ltd. Con. 1/87.