GB2177250A - Burnable absorber coated nuclear fuel - Google Patents
Burnable absorber coated nuclear fuel Download PDFInfo
- Publication number
- GB2177250A GB2177250A GB08616520A GB8616520A GB2177250A GB 2177250 A GB2177250 A GB 2177250A GB 08616520 A GB08616520 A GB 08616520A GB 8616520 A GB8616520 A GB 8616520A GB 2177250 A GB2177250 A GB 2177250A
- Authority
- GB
- United Kingdom
- Prior art keywords
- layer
- fuel
- niobium
- burnable
- nuclear fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/02—Fuel elements
- G21C3/04—Constructional details
- G21C3/16—Details of the construction within the casing
- G21C3/20—Details of the construction within the casing with coating on fuel or on inside of casing; with non-active interlayer between casing and active material with multiple casings or multiple active layers
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/42—Selection of substances for use as reactor fuel
- G21C3/58—Solid reactor fuel Pellets made of fissile material
- G21C3/62—Ceramic fuel
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C7/00—Control of nuclear reaction
- G21C7/02—Control of nuclear reaction by using self-regulating properties of reactor materials, e.g. Doppler effect
- G21C7/04—Control of nuclear reaction by using self-regulating properties of reactor materials, e.g. Doppler effect of burnable poisons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- High Energy & Nuclear Physics (AREA)
- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Monitoring And Testing Of Nuclear Reactors (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
In a method of coating a UO2 containing nuclear fuel body with a ZrB2 containing burnable poison layer a layer containing Nb is first bondably deposited on the fuel body eg by chemical vapour deposition and a layer of the burnable poison is then bondably deposited by chemical vapour deposition on the Nb containing layer.
Description
1 GB2177250A 1
SPECIFICATION
Burnable absorber coated nuclear fuel The present invention relates generally to burnable neutron absorbers (also called burnable 5 poisons) for nuclear reactors and, more particularly, to a method for coating a nuclear fuel body with a burnable poison.
It is known that nuclear fuel may have various shapes such as plates, columns, and fuel pellets disposed in end-to-end abutment within a tube or cladding made of a zirconium alloy or stainless steel. The fuel pellets contain fissionable material, such as uranium dioxide, thorium 10 dioxide, plutonium dioxide or mixtures therof. The fuel rods are usually grouped together to form a fuel assembly. The fuel assemblies are arranged together to constitute the core of a nuclear reactor.
The subject of the present intention has been divided from Application 8402535 in which there is disclosed and claimed a burnable neutron absorber coated nuclear fuel body comprising 15 a nuclear fuel substrate containing a fissionable material and a layer containing a burnable absorber covering at least a part of said substrate, characterized by an overcoat layer containing a reactor compatible, hydrophobic material generally covering, and bonded directly to, said burnable neutron absorber layer.
It is well known that the process of nuclear fission involves the disintegration of the fissiona- 20 ble nuclear fuel material into two or more fission products of lower mass number. Among other things the process also generates neutrons which are the basis for a self- sustaining reaction.
When a reactor has operated over a period of time, the fuel assembly with fissionable material must ultimately be replaced due to depletion. Inasmuch as the process of replacement is time consuming and costly, it is desirable to extend the list of a given fuel assembly as long as pratically feasible. For that reason, deliberate additions to the reactor fuel of parasitic neutron capturing elements in calculated small amounts may lead to highly beneficial effects on a thermal reactor. Such neutron-capturing elements are usually designated as "burnable absorbers" since they too are depleted after some time so that there is a compensation with respect to the concomitant reduction in the fissionable material.
The life of a fuel assembly may be extended by combining an initially larger amount of fissionable material as well as a calculated amount of burnable absorber. During the early stages of operation of such a fuel assembly, excessive neutrons are absorbed by the burnable absorber which undergoes transformation to elements of low neutron absorbing cross section which do not substantially affect the reactivity of the fuel assembly in the latter period of its life when the availability of fissionable material is lower. Accordingly, with a fuel assembly containing both fuel and burnable absorber in carefully proportioned quantity, an extended fuel assembly life can be achieved with relatively constant neutron production and reactivity.
Burnable absorbers which may be used include boron, gadolinium, samarium, europium, and the like. Burnable absorbers are used either uniformly mixed with the fuel (i.e., distributed absorber) or are placed discretely as separate elements in the reactor, so arranged that they burn out or are depleted at about the same rate as the fuel. Thus, the net reactivity of the core is maintained relatively constant over the active life of the core.
U.S. Patent 3,427,222 discloses a uranium dioxide fuel pellet coated with a mixture of uranium dioxide and a zirconium diboride burnable poison applied by a plasma spraying technique (see 45 column 4, "Example I"). That patent also disclosed a uranium dioxide fuel pellet coated with the burnable poison boron applied by chemical vapor deposition. It is noted therein that the deposi tion rate was slow at low temperatures while the coating was not as adherent at high tempera tures (see column 5, "Example 111").
It is known that a nuclear fuel contained in an aluminum can may be coated with a layer of 50 niobium to prevent the fuel from reacting with the can (British Patent 859,206; page 1; lines 12-30). It is also known that minute nuclear fuel particles, such as uranium dioxide particles, may be coated with a single layer or several layers of the same or different non-absorber materials, including niobium, for such purposes as protecting the fuel from corrosion and helping to retain the products of fission. The coatings may be applied by various techniques, such as 55 depositing from a vapor of the coating material, depositing from a decomposing vapor, and electroplating (British Patent 933,500).
In Dispersion Fuel Elements, an AEC Monograph by A. N. Holden published in 1967 by Gordon and Breach of New York, there is mentioned coating fuel particles in dispersion fuels to prevent interaction of the particles with the matrix and to retain fission products (page 30).
Uranium dioxide coated with niobium by vapor-phase reduction is disclosed (page 48). Also disclosed is uranium dioxide coated with chromium, by vapor-phase reduction using chromium dichloride, which was deposited over a niobium undercoat (page 48).
The present inventors are aware of the earlier documented work disclosed in a commonly assigned U.S. Patent Application entitled "Coating a Uranium Dioxide Nuclear Fuel With a 65 2 GB2177250A 2 Zirconium Diboride Burnable Poison", by Walston Chubb, concomitantly filed with the present application, wherein spalling problems with chemically vapor depositing zirconium diboride on uranium dioxide were overcome by first deposition (by sputtering, chemical vapor deposition, etc.) a thin undercoat layer of niobium (of between about 3 microns and about 6 microns in thickness) on the uranium dioxide and then chemically vapor depositing the zirconium diboride on 5 the niobium layer.
Fuel pellets coated with a boron containing burnable absorber such as elemental boron, boron isotope (the isotope of elemental boron having the burnable absorber property), zirconium diboride, boron carbide, boron nitride and the like suffer from varying degrees of moisture adsorption. For example, uranium dioxide fuel pellets coated with zirconium diboride, after manu- 10 facture, must be furnace dried in a time-consuming operation and then loaded into the fuel rods in a low humidity glove box environment. This is required because the zirconium diboride, being hygroscopic, takes on a thin layer of moisture (moisture adsorption) from the air itself. The added lengthy drying step (typically about 1 to 3 hours at temperatures of 200-600C in a vacuum of less than or equal to 1 torr) and humidity controlled pellet loading environment add to 15 the time, complexity and the cost of the nuclear fuel processing line. Moisture is to be avoided in nuclear fuel because excessive hydrogen in the fuel pellet, appearing mostly as moisture, causes hybriding of the Zircaloy fuel rod cladding which may result in a breach in the fuel rod cladding.
The invention consists in a method for coating a uranium dioxide containing nuclear fuel body 20 with a zirconium diboride containing burnable poison, characterized in that a layer containing niobium is first bondably deposited on at least a portion of said nuclear fuel body, and a layer of said burnable poison is then bondably deposited, by chemical vapor deposition, on at least a part of said niobium containing layer.
The invention will become more readily apparent from the following description of a preferred 25 embodiment thereof shown, by way of example only, in the accompanying drawings, in which:
Figure I is a longitudinal sectional view of a fuel rod containing burnable absorber coated fuel pellets having a non-hydroscopic overcoat layer.
Figure 2 is a transverse sectional view along the line 11-11 of Fig. 1.
Figure 3 adds an undercoat layer to the fuel pellets of the fuel rod of Fig. 1.
Figure 4 is a transverse sectional view along the line IV-IV of Fig. 3.
Nuclear fuel includes uranium in the form of uranium dioxide (or thorium dioxide, plutonium dioxide, or mixtures thereof) pellets each having a generally cylindrical configuration with an approximately 8 mm diameter and an approximately 12 mm length. Desirable zirconium diboride burnable absorber coating thicknesses on the fuel pellets include a thickness of between about 8 35 and 16 microns (and preferably of between about 9 and 10 microns which corresponds to a target boron-10 loading of generally 0.6 mg per lineal cm).
The degree of moisture adsorption depends on the technique used to deposit the zirconium diboride layer. It has been found that sputtering produces a somewhat porous coating which contributes to moisture adsorption, while chemical vapor deposition appears to have less mois- 40 ture adsorption problems.
As shown in Figs. 1 and 2, a fuel rod 10, for use in a nuclear reactor fuel assembly, includes a tube 12 having a top end plug 14 and a bottom end plug 16 providing a chamber 18 in which a plurality of fissionable fuel pellets 20 are placed in end-to-end abutment biased against the bottom end plug 16 by the action of a spring 22. The pellet 20 diameter is slightly less than that of the tube 12 so as to form a clearance space 24. Both the spring 22 and clearance space 24 accommodate any thermal expansion of the pellets 20 during operation.
Preferably the fissionable body portion or substrate 26 of the fuel pellet 20 consists essen tially of uranium dioxide, although other forms of uranium, as well as plutonium or thorium, may be used. Also, preferably the burnable absorber layer 30 covering at least a part of the substrate 26 consists essentially of elemental boron or zirconium diboride, although other forms of boron, as well as gadolinium, samarium, europium, and the like, may be used.
To make the burnable absorber coated nuclear fuel pellet 20 nonhygroscopic (hydrophobic), the burnable absorber layer 30 is covered by an overcoat layer 32 which is directly bonded to it. The overcoat layer 32 contains a reactor compatible, hydrophobic material. Preferably the 55 overcoat layer 32 has a thickness of between about 2 microns and about 6 microns. The overcoat layer 32 should be applied before the burnable absorber layer 30 has been exposed to air to avoid trapping any moisture (absorbed by the burnable absorber) in the fuel pellet 20.
Reactor compatibility factors to be considered for such an overcoat layer include cost, neutron absorption cross section, compatibility with burnable absorbers, compatibility with the tube 60 (cladding) 12, and melting point. Therefore, a reactor compatible, hydrophobic material is deemed to be a material chosen from the following group: niobium, zirconium, magnesium, aluminum, silicon, carbon, titanium, chromium, iron, nickel, copper, yttrium, molybdenum, barium, and cerium.
In a first preferred embodiment, elemental boron is used for the burnable absorber layer 30 65 3 GB2177250A and is bonded directly to the substrate 26 which is uranium dioxide, while the overcoat layer 32 consists essentially of niobium. In one example, uranium dioxide fuel pellets were coated by conventional chemical vapor deposition (CVD) techniques first with elemental boron and then with niobium utilizing a vertical pipe surrounding vertically stacked fuel pellets. The boron coating 30 was prepared via the pyrolysis of B2H,, and the niobium coating 32 was prepared via the hydrogen reduction of niobium pentachloride (NbC'5). These gaseous CVD precursors were introduced into the bottom of the pipe and the by-products were exhausted from the top of the pipe. The fuel pellet substrates 26 had been cleaned by light sanding, repeated ultrasonic cleaning in distilled water, and vacuum drying. Thermocouples were mounted on the walls of the pipe. The pellet substrates 26 were heated to a thermocouple-measured predetermined wall 10 temperature by an upper furnace while the precursor gases were preheated to a thermocouplemeasured preselected wall temperature by a lower furnace. Satisfactory coatings were obtained under various conditions as summarized in Table 1.
1 -P- TABLE 1
SUWARY OF CONDITIONS FOR PREPARING BORONINIOBIUM COATINGS Run Time remporatures (c) Finwa (Mole PercentL Total Flow Rtin No. loye r (min) Gns Profiont rellot Zone aú H(, H2 Nbc!s. (cc/min) n 45 230 600 0.015 99.985 -- 17010 Nb 172 650 850 --- 99.930 0.062 16510 2 n 60 230 615 0.015 99.905 - 17010 Hh 20 650 850 -- 99.983.0.107 16017 3 n Gro 230 610 0.015 99.985 --- 17010 Nb 35 650 850 --- 99.909 0.091 16315 n 35 230 610 0.015 99.905 --- 17010 Nb 3's 650 8135 --- 99.946 0.054 17169 A, G) ca N 4 14 N) cn 0 -PI GB2177250A In a second preferred embodiment, as shown in Figs. 3 and 4, zirconium diboride is used for the burnable absorber layer 30 and is bonded by CV1) to an undercoat layer 28 of niobium, with the undercoat layer 28 being bonded by CV1) to the substrate 26 which is uranium dioxide. The overcoat layer 32 consists essentially of CV1) niobium. The necessity for an undercoat layer of niobium (or the like) when depositing zirconium diboride by chemical vapor deposition (CVD) on 5 uranium dioxide has been previously mentioned. Preferably the undercoat layer 28 has a thick ness of between about 3 microns and about 6 microns. The technique is similar to that discussed in the first preferred embodiment. The CV1) precursor for the zirconium diboride was zirconium tetrachloride and boron trichloride. Gaseous zirconium chloride was prepared by react ing HCI and zirconium and carrying the reaction products in a hydrogen stream. Satisfactory 10 coatings were obtained under various conditions as summarized in Table 2.
t (3) TAULC 2 SUSjAny (y CONplygotIS ron PREPARING Nb/Zrgtl%b COATINGS 10tal F" 1 PYLAM-0-11I _pc rpt!! M r 1 ow 1 7--- teelmlry) e--"p -- WFOWE zarle ficti #Act it., 11he 1A l -rely Itim tin. Layer (Mill) or. ralmat till to rp 650 850... 99.921 0.mg --- 15632 07-1zo 0.053 99.600 --- 0.128 17090 Z rllz 61) 6U0 duo --- --- 15665 H13. 67 65(1 850 --- 99.946 0.41511 2 fill, 59 650 050 --- --- 99.942 (1.050 --- 17059 Z r 37 609) 1105 0.279 0.204 99.290 --- 0.220 17196 M11,,z 69 650 850 99.951 0.049 --- 17088 lib 1111 6,13 065 --- --- 99.907 0.093 --- 17136 7 r02 76 600 lino 0.187 0.234 99.498 --- 0.002 1711 lb die 650 550 99.915 0.085 --- 17155 4 %h GU 650 54(3 ---... 99.9112 0.059 --- 17195 7.1 Ill 313 605 D05 0.279.204 99.298 --- 0. P20 17196 lib so 660 8,40 --- 99.932 0.068 17197 11h 55 6511 055 --- --- 99.941 0.059 17280 0.204 99.298 --- 0.220 17196 Zrtlx 25 600 805 0.279 17231 Hh 55 G50 843 --- 991.938 0.062 6 NI) at 650 8113 --- --99.959 0.041 --- 17192 r 21 Gill) 8011 0.279 0.204 99.298 --- 0.220 17196 1 2 --- --- 99.945 0.055 --- 117194 lit: 72 650 of&'$ RID 27 650 871) ----- 99.811 0.1eg --- 17112 Z r02. 75 600 825 0. 1 fig 0.234 99.544 --0.082 17106 Nb 33 650 890 --- --- 99.870 0.130 17062 a Hh 65 65(1 8113 ----- 99.920 0.000 --- 17199 zrB2 37 602 003 0.279 0.204 99.295 --- 0.220 17196 Nb 518 650 843 --- --- 99.922 0.075 --- 17153 9 Nto 614 650 860 ---- 99.936 0.064 --- 17105 Zo-DZ 55 620 817 0.140 0:234 99.543 --- 0.082 17106 Nto 77 650 853... --- 99.946 0.054 --- 17103 Ifto 71 650 050 99.9149 0.052 --- 171911 Zrt),% 37 600 810 0.279 04 99.298 --- 0.220 17196 Hh 52 650 850 --- 99.934 0.066 --- 17196 11 lib 69 650 stle 0:- 99.956 0.044 --- 17225 zo,Bl 55 6U0 009 o. 1;o 103 99.6910 --- 0.114 17101 mb 77 650 845 --- 99.956 0.00011 --- 17206 141 '1 141 1 11 (7) W N) j -j N) (71 0 0) 7 GB2177250A Typically, the invention is used to circurnferentially surround (i.e., coat only the cylindrical wall of) the fuel pellet substrate 26 with a burnable absorber layer 30 and the overcoat layer 32 (and the undercoat layer 28 if needed). However, in some applications it may be desirable to coat the entire fuel pellet substrate 26, including its top and bottom surfaces. In other applications, it may be advantageous to coat only a part of the nuclear fuel substrate with the burnable absorber layer and then generally cover (or partially cover) the burnable absorber layer with the overcoat layer. Also, where substrates, burnable absorber layers, and overcoats/undercoats may contain uranium dioxide, zirconium diboride, and niobium, respectively, it is preferred that they respectively consist essentially of such uranium dioxide, zirconium cliboride, and niobium.
Claims (3)
1. A method for coating a uranium dioxide containing nuclear fuel body with a zirconium diboride containing burnable poison, characterized in that a layer containing niobium is first bondably deposited on at least a portion of said nuclear fuel body, and a layer of said burnable poison is then bondably deposited, by chemical vapor deposition, on at least a part of said niobium containing layer.
2. A method as claimed in claim 1, characterized in that said niobium containing layer consists essentially of niobium which is deposited by chemaical vapor deposition.
3. A method as claimed in claim 1 or 2, characterized in that said burnable poison layer consists essentially of zirconium diboride.
Printed in the United Kingdom for Her Majesty's Stationary Office, Dd 8818935, 1987, 4235. Published at The Patent Office, 25 Southampton Buildings, London, WC2A I AY, from which copies may be obtained.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/468,788 US4587087A (en) | 1983-02-22 | 1983-02-22 | Burnable absorber coated nuclear fuel |
US06/468,743 US4582676A (en) | 1983-02-22 | 1983-02-22 | Coating a uranium dioxide nuclear fuel with a zirconium diboride burnable poison |
Publications (3)
Publication Number | Publication Date |
---|---|
GB8616520D0 GB8616520D0 (en) | 1986-08-13 |
GB2177250A true GB2177250A (en) | 1987-01-14 |
GB2177250B GB2177250B (en) | 1987-12-31 |
Family
ID=27042518
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08402535A Expired GB2137012B (en) | 1983-02-22 | 1984-01-31 | Burnable absorber coated nuclear fuel |
GB08616520A Expired GB2177250B (en) | 1983-02-22 | 1986-07-07 | Burnable absorber coated nuclear fuel |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08402535A Expired GB2137012B (en) | 1983-02-22 | 1984-01-31 | Burnable absorber coated nuclear fuel |
Country Status (6)
Country | Link |
---|---|
KR (1) | KR910005068B1 (en) |
CH (1) | CH664036A5 (en) |
DE (1) | DE3402192A1 (en) |
FR (1) | FR2541495B1 (en) |
GB (2) | GB2137012B (en) |
SE (1) | SE458810B (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4626404A (en) * | 1983-12-21 | 1986-12-02 | Westinghouse Electric Corp. | Annular burnable absorber rod |
GB8802419D0 (en) * | 1988-02-03 | 1988-03-02 | British Nuclear Fuels Plc | Fuel elements containing burnable poison |
US5075075A (en) * | 1990-01-16 | 1991-12-24 | Westinghouse Electric Corp. | Nuclear reactor core having nuclear fuel and composite burnable absorber arranged for power peaking and moderator temperature coefficient control |
US5147598A (en) * | 1990-01-16 | 1992-09-15 | Westinghouse Electric Corp. | Nuclear reactor core having nuclear fuel and composite burnable absorber arranged for power peaking and moderator temperature coefficient control |
DE19636563C1 (en) * | 1996-09-09 | 1998-03-26 | Siemens Ag | Nuclear reactor fuel assemblies with high burn-up and process for their production |
US11289213B2 (en) * | 2017-08-31 | 2022-03-29 | Westinghouse Electric Company Llc | Control rods for light water reactors |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB933500A (en) * | 1960-08-23 | 1963-08-08 | Nuclear Materials & Equipment | Nuclear fuel element |
BE653174A (en) * | 1963-10-21 | 1965-03-17 | ||
US3427222A (en) * | 1965-10-15 | 1969-02-11 | Westinghouse Electric Corp | Nuclear fuel elements |
SE327763B (en) * | 1967-05-26 | 1970-08-31 | Asea Ab | |
US3625821A (en) * | 1968-06-26 | 1971-12-07 | Westinghouse Electric Corp | Fuel-element coating containing burnable poison |
GB1507487A (en) * | 1974-06-24 | 1978-04-12 | Gen Electric | Nuclear fuel element |
-
1984
- 1984-01-24 DE DE3402192A patent/DE3402192A1/en not_active Withdrawn
- 1984-01-31 GB GB08402535A patent/GB2137012B/en not_active Expired
- 1984-02-06 SE SE8400596A patent/SE458810B/en not_active IP Right Cessation
- 1984-02-16 CH CH752/84A patent/CH664036A5/en not_active IP Right Cessation
- 1984-02-21 FR FR8402600A patent/FR2541495B1/en not_active Expired
- 1984-02-21 KR KR1019840000825A patent/KR910005068B1/en active IP Right Grant
-
1986
- 1986-07-07 GB GB08616520A patent/GB2177250B/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
SE458810B (en) | 1989-05-08 |
GB8616520D0 (en) | 1986-08-13 |
CH664036A5 (en) | 1988-01-29 |
DE3402192A1 (en) | 1984-08-23 |
GB2137012B (en) | 1987-06-24 |
GB2177250B (en) | 1987-12-31 |
FR2541495A1 (en) | 1984-08-24 |
GB8402535D0 (en) | 1984-03-07 |
KR840007790A (en) | 1984-12-10 |
GB2137012A (en) | 1984-09-26 |
FR2541495B1 (en) | 1988-04-22 |
SE8400596D0 (en) | 1984-02-06 |
KR910005068B1 (en) | 1991-07-22 |
SE8400596L (en) | 1984-08-23 |
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PCNP | Patent ceased through non-payment of renewal fee |