GB2164449A - Monitoring temperature induced deterioration of stored articles - Google Patents

Monitoring temperature induced deterioration of stored articles Download PDF

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Publication number
GB2164449A
GB2164449A GB08521028A GB8521028A GB2164449A GB 2164449 A GB2164449 A GB 2164449A GB 08521028 A GB08521028 A GB 08521028A GB 8521028 A GB8521028 A GB 8521028A GB 2164449 A GB2164449 A GB 2164449A
Authority
GB
United Kingdom
Prior art keywords
output
input
circuit
instrument according
thermistor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB08521028A
Other versions
GB8521028D0 (en
Inventor
Robin Andras Benedek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of GB8521028D0 publication Critical patent/GB8521028D0/en
Publication of GB2164449A publication Critical patent/GB2164449A/en
Withdrawn legal-status Critical Current

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Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K3/00Thermometers giving results other than momentary value of temperature
    • G01K3/02Thermometers giving results other than momentary value of temperature giving means values; giving integrated values
    • G01K3/04Thermometers giving results other than momentary value of temperature giving means values; giving integrated values in respect of time

Abstract

An instrument for monitoring the deterioration of articles held in storage in particular, food in cold storage, comprises an input circuit including a temperature sensor and arranged to produce an output proportional to the rate of change at the sensed temperature of a property of the article, the output of the circuit being connected to the input of a linear amplifier, the output of which is integrated by an integrating device. As shown, a Wheatstone bridge includes a thermistor and is arranged to produce an output which is a quadratic function of the temperature in degrees Celsius, and the integrating device is a mercury coulometer display. <IMAGE>

Description

SPECIFICATION Monitoring instrument The invention relates to a monitoring instrument for monitoring the deterioration of articles held in storage in particular, food in cold storage.
The present invention provides an instrument for monitoring changes in an article during storage, comprising an input circuit including a temperature sensor and arranged to produce an output proportional to the rate of change at the sensed temperature of a property of the article, the output of the circuit being connected to the input of a linear amplifier, the output of which is integrated by an integrating device.
The input circuit and amplifier are preferably powered by a battery.
In monitoring food spoilage, as will be shown below, a Wheatstone bridge circuit with a thermistor in one arm may be made to model with considerable accuracy the rate of spoilage of food stuffs in chilled storage, which, as has been shown, can be expressed as a quadratic function of temperature in degrees Celsius.
Preferably the amplifier is a CMOS-type operational amplifier which has a very low current drain, and is therefore suitable for long term operation from a battery. Further operational amplifiers of this type with negative feedback may be included in the circuit to provide a very high input impedence, so that the resistor network may itself be constructed with high resistance components and so require only a small current in operation.
The invention will now be further described by way of example with reference to the accompanying drawing, which is a circuit diagram of a food spoilage monitor according to the invention.
Referring to the drawing the circuit of the food spoilage monitor consists of four parts, indicated by the dotted outlines 1, 2, 3, and 4. Of these 1 is the temperature sensing circuit, comprising a thermistor connected in a Whealstone bridge network, 2 is an amplifier section, 3 is a range-setting network by means of which the range of the monitor can be set to correspond to the characteristics of the food being monitored, and 4 is an indicator showing how much of the shelf life of the stored food has expired.
It has been shown, in a paper by Ratkowsky and others in Journal of Bacteriology Jan.
1982 pp. 1-5, that the relative rate of food spoilage can be represented by an equation of the form: r=a (T,+T)2, where a and To are constants. For a wide range of chilled foods it is shown that this can be expressed in the form r=b (1+0.1T)2.
The constant b varies with the type of food.
The above equation can be modelled to a satisfactorily high accuracy by a thermistor placed in one arm of a Wheatstone bridge circuit. The thermistor is an RSR-T matched thermistor, stock number 151-243, and was selected both for its temperature resistance characteristic and for its high resistance, which enables relatively high resistor values to be used in the rest of the bridge circuit, and thereby minimises current drain from the battery supplying the circuit. The thermistor is placed in the arm AC of the bridge circuit and the arm BC contains a variable resistor which allows for variations in the resistance of the thermistor, as small deviations have disproportionately larger effects on the potential difference across the output terminal CD of the bridge.The arm BC of the bridge circuit may also contain a small adjustable resistor to null any input offset voltages of the operational amplifiers in the amplifier portion of the circuit which is about to be described.
The amplifier 2 comprises two operational amplifiers IC 1 IC2 connected respectively to the terminals D and C of the Wheatstone bridge, and provided with feedback so as each to have unity gain. These present a very high input impedence to the bridge network terminals, which renders insignificant the effects of current drawn from the bridge, and their outputs are connected to the differential inputs of a further operational amplifier IC3.
This amplifier is provided with a resistor network for generating negative feedback, and this network includes a small variable resistor for precise adjustment of the gain. The operational amplifiers IC1, IC2 and IC3, are all CMOS amplifiers type RS 7611.
The output from the amplifier 2 is applied to a range-setting network 3. This consists simply of a set of series resistors arranged in five pairs with a switch provided for shorting out each resistor pair. The resistances of the pairs are in the ratios 1: 2: 4: 8: 16 so that all ratios between 1 and 31 can be obtained by a suitable selection of switches. This range setting network determines the contant b in the equation set out above.
The output from the range-setting network passes through a mercury coulometer and series resistor, the coulometer providing the output indication of the instrument. This is a Curtis CP3 elapsed time meter, obtainable from Curtis Instruments (UK) Limited of Northampton and it has a full-scale deflection at 3.2 m. amp hours.
Many foods have shelf lives at 0 C in the range 5-36 days. With the components described above, and the resistor value shown in the drawing, the time to full-scale deflection with all the switches in the range-setting network closed is 5 days. If it is desired to monitor a food with a shelf life of 26 days at 0 C, then switches 1, 3 and 5 would be open.
These correspond to 1, 4 and 16 days respectively, which together with the preset 5 days make up the desired 26 days shelf life.

Claims (6)

1. An instrument for monitoring changes in an article during storage, comprising an input circuit including a temperature sensor and arranged to produce an output proportional to the rate of change at the sensed temperature of a property of the article, the output of the circuit being connected to the input of a linear amplifier, the output of which is integrated by an integrating device.
2. An instrument according to claim 1 for monitoring the spoilage of food in cold storage, in which the temperature sensor is a thermistor and the input circuit produces an output voltage which is a quadratic function of temperature expressed in degrees Celsius.
3. An instrument according to claim 2 in which the input circuit is a Wheatstone bridge circuit with the thermistor connected in one arm.
4. An instrument according to any preceding claim in which the integrating device is a mercury coulometer.
5. An instrument according to any preceding claim in which the linear amplifier has a voltage-follower input.
6. An instrument according to any preceding claims which is portable and battery-operated.
GB08521028A 1984-08-23 1985-08-22 Monitoring temperature induced deterioration of stored articles Withdrawn GB2164449A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB848421452A GB8421452D0 (en) 1984-08-23 1984-08-23 Temperature sensitive elapsed time indicator

Publications (2)

Publication Number Publication Date
GB8521028D0 GB8521028D0 (en) 1985-09-25
GB2164449A true GB2164449A (en) 1986-03-19

Family

ID=10565744

Family Applications (2)

Application Number Title Priority Date Filing Date
GB848421452A Pending GB8421452D0 (en) 1984-08-23 1984-08-23 Temperature sensitive elapsed time indicator
GB08521028A Withdrawn GB2164449A (en) 1984-08-23 1985-08-22 Monitoring temperature induced deterioration of stored articles

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB848421452A Pending GB8421452D0 (en) 1984-08-23 1984-08-23 Temperature sensitive elapsed time indicator

Country Status (1)

Country Link
GB (2) GB8421452D0 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2235780A (en) * 1989-09-05 1991-03-13 Barker George & Co Ltd A Temperature monitoring apparatus

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1104141A (en) * 1964-04-24 1968-02-21 Smiths Industries Ltd Improvements in or relating to electrical apparatus for providing a representation of engine-life
GB1104949A (en) * 1966-03-24 1968-03-06 Commissariat Energie Atomique Heat-quantity measuring unit
US3638495A (en) * 1968-08-07 1972-02-01 Dynametric Inc Method for detecting aging of articles
GB1427515A (en) * 1972-03-07 1976-03-10 Secretary Trade Ind Brit Explosive gas detectors
US4277974A (en) * 1979-07-12 1981-07-14 Karr Lawrence J Time-temperature indication
GB2077928A (en) * 1980-06-17 1981-12-23 Fiat Ricerche Heat meter device
GB2102964A (en) * 1981-07-30 1983-02-09 Satchwell Controls Limited Meters
GB2145526A (en) * 1983-08-26 1985-03-27 Shirley Inst Measuring temperature functions

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1104141A (en) * 1964-04-24 1968-02-21 Smiths Industries Ltd Improvements in or relating to electrical apparatus for providing a representation of engine-life
GB1104949A (en) * 1966-03-24 1968-03-06 Commissariat Energie Atomique Heat-quantity measuring unit
US3638495A (en) * 1968-08-07 1972-02-01 Dynametric Inc Method for detecting aging of articles
GB1427515A (en) * 1972-03-07 1976-03-10 Secretary Trade Ind Brit Explosive gas detectors
US4277974A (en) * 1979-07-12 1981-07-14 Karr Lawrence J Time-temperature indication
GB2077928A (en) * 1980-06-17 1981-12-23 Fiat Ricerche Heat meter device
GB2102964A (en) * 1981-07-30 1983-02-09 Satchwell Controls Limited Meters
GB2145526A (en) * 1983-08-26 1985-03-27 Shirley Inst Measuring temperature functions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2235780A (en) * 1989-09-05 1991-03-13 Barker George & Co Ltd A Temperature monitoring apparatus

Also Published As

Publication number Publication date
GB8421452D0 (en) 1984-09-26
GB8521028D0 (en) 1985-09-25

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WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)