GB2150806A - Tobacco smoke filter - Google Patents
Tobacco smoke filter Download PDFInfo
- Publication number
- GB2150806A GB2150806A GB08331464A GB8331464A GB2150806A GB 2150806 A GB2150806 A GB 2150806A GB 08331464 A GB08331464 A GB 08331464A GB 8331464 A GB8331464 A GB 8331464A GB 2150806 A GB2150806 A GB 2150806A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tobacco smoke
- complex
- smoke
- metal
- tobacco
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
Volatile oxides are removed from tobacco smoke by means of a metal co-ordination complex which is relatively stable in air but which is active in contact with tobacco smoke to result in removal of CO and/or NO from the smoke. Such complexes are suitably oximic complexes of metals having two or more valence states, e.g. ferrous and ferric complexes with alpha -naphthaquinone-2-oxime and beta -naphthaquinone-1-oxime. The complex or complexes, suitably supported by a particulate carrier, can be incorporated in tobacco smoke filters, e.g. cigarette filters.
Description
SPECIFICATION
Tobacco Smoke Filter
The present invention relates to the chemical removal of gaseous components from tobacco smoke, and to filters for this purpose.
The removal of gaseous tobacco smoke components such as carbon monoxide (CO) and nitric oxide (NO) has been the subject of much attention for a considerable time; removal of such components by chemical reaction has seemed an attractive solution, but despite the expenditure of much effort in this direction, there has been no real practical or commercial success in developing chemical means for this purpose.
Prior chemicals suggested as tobacco smoke filter additives for removal of gases such as CO from the smoke have one or more of the following major disadvantages; they are very reactive and so are readily oxidised, thereby rapidly losing their reactivity on exposure to air; they have a high molecular weight to reactive site ratio, i.e. there is a large redundant mass associated with each reaction site; they may become inactive through interaction with other components of tobacco smoke; they may be indirectly or directly poisonous to the smoker.
The present invention resides in the removal of CO and/or NO from tobacco smoke by reaction with a metal co-ordination complex (e.g. an oximic complex and preferably an oximic complex of the type B below) which is relatively stable in air but which is active in contact with tobacco smoke to result in removal of CO and/or NO from the smoke. The metals of the complexes used according to the invention are generally transition or redox or like metals exhibiting more than one valency.
The above-mentioned oximic complexes B may be generally represented by the formula:
wherein R is an aliphatic or organic radical of relatively low molecular weight (e.g. phenyl, benzyl, etc) and
M is a metal (e.g. iron, copper etc) having two or more valence states. These compounds are particularly suitable since the stable complex starting material may be reduced by Lewis base components of the smoke (e.g. nicotine) to produce a reactive species in situ, ready to bind the volatile oxide molecules.This smoke-activation process is shown schematically below using an iron Ill complex as the example:
wherein; - step (1 ) is a fast stoichiometric reaction with Lewis base components of tobacco smoke to form a reactive
intermediate and a ligand radical in situ; and - step (2) is a fast stoichiometric reaction with CO or NO to form a stable complex.
Two particular examples of compounds for use according to the invention are the iron complexes derived from a-naphthaquinone-2-oxime (C) and ,-naphthaquinone-1-oxime (D)
Complexes of both Fe" and Fe"' co-ordinated with oximic ligands have the following advantageous features: i) they react with CO and/or NO under smoking conditions at a rate sufficient to cause significant reduction in volatile oxide concentration in tobacco smoke; (ii) they are essentially stable towards oxidation and do not decompose significantly when stored in the solid state; (iii) their effectiveness is enhanced rather than reduced by contact with major components of tobacco smoke; (iv) the oximic complexes and the reaction products after interaction with tobacco smoke are involatile. Like complexes with other transition metals, copper etc., can have similar advantages.
The invention also provides a tobacco smoke filter, e.g. a cigarette filter, including a metal co-ordination complex as described above for the chemical removal of volatile oxides e.g. CO and/or NO from the tobacco smoke.
In practice it is convenient to incorporate the additive compound in the filter upon an essentially inert substrate, preferably one having a high surface area to density ratio. For example, the complexes previously mentioned may be deposited (suitably from solution) on substrate granules of e.g. pumice, silica gel, magnesium silicate etc. The supported or unsupported complex may be disposed in a filter cavity and/or deposited on or distributed through conventional filter material.
The invention also provides, for incorporation in tobacco smoke filters, an additive comprising a metal co-ordination complex as described above deposited on a particulate carrier.
The invention is illustrated by the following Examples (which are according to the invention) and
Controls (which are not according to the invention).
EXAMPLES 1 < In these Examples the additive compound used was an iron complex of compound C described above and is referred to as Fe(C)3. The complex was deposited onto particulate pumice from solution in acetone.
About 0.1 g of the pumice bearing about 16 mg of complex was used in each filter. Each filter was a wrapped composite rod 25 mm in length and 8 mm diameter comprising a bonded cellulose acetate tow filter plug spaced apart from a similar plug with the supported complex disposed in the cavity between these elements. Control filters contained pumice treated with acetone containing no complex and dried.
Filters were attached to standard tobacco rods and the resulting filtered cigarettes were smoked using a standard smoking machine and the total CO delivered per tobacco rod was measured. The results are shown in Table 1. It is clear from the Table that the complex Fe(C)3 supported on pumice is effective in removing CO from tobacco smoke.
In Table 1 each Example (and each corresponding Control) involved five runs 1-5, and each such run involved the simultaneous smoking in parallel of five of the filter cigarettes with the total smoke delivery being collected and the total CO measured and divided by five to give the CO delivery per rod quoted for each Run.
TABLE I
Effect of Fe complex of compound C on carbon monoxide obtained from tobacco smoke
CO Delivery (mg) per tobacco rod Average CO Wt. Difference % Difference Delivery (mg) Between Control & Between Control RUN 1 2 3 4 5 per Tobacco Rod Exemple mg CO and Example Example 1 14.4 14.84 15.00 14.99 15.08 14.86 9.4 Control 16.1 16.28 16.94 16.44 16.24 16.40 1.54 Example 2 15.24 14.84 14.96 15.36 15.06 15.09 8.24 Control 16.22 16.06 16.76 16.94 16.26 16.45 1.38 Example 3 16.04 15.52 16.22 15.98 16.12 15.98 9.7 Control 17.44 17.56 18.06 17.58 17.86 17.7 1.72 Example 4 15.48 15.3 15.48 15.48 15.5 15.46 8.4 Control 16.8 17.24 16.82 16.79 16.8 16.89 1.43 EXAMPLES W6 In these Examples "MYRIA" (Registered Trade Mark) paper filters made from longitudinally corrugated gathered paper were each impregnated with about 16 mg of an iron complex of compound C or D, referred to as Fe(C)3 and Fe(D)3, from solution in chloroform, dried, and tested in a similar way to that used for
Examples 1-4. The controi filters were "MYRIA" filters treated with chloroform alone and then dried. The results of these tests are shown in Table 2.
EXAMPLES 7-8
In these Examples iron complexes of compounds C and D, referred to as Fe(C)3 and Fe(D)3, were deposited on particulate silica gel from solution as in Examples 1--4; similar control filters used silica gel treated with solvent alone and dried. The filters were tested as for Examples 1-4 and the results are shown in Table 2.
As in Table 1 each CO delivery per rod quoted in Table 2 is obtained by smoking five filter cigarettes simultaneously and dividing the total CO delivery by five.
TABLE 2
Effect of Fe Complexes of Compounds C and D on Carbon Monoxide Obtained from Tobacco Smoke
Wt. Difference Between % Difference CO Delivery (mg) Control and Example Between Control Example Filter Type per Tobacco Rod. (mg CO) and Example 5 Myria/Fe(C)3 14.9 1.2 7.4 6 Myria/Fe(D)3 15.0 1.1 6.8 Control 16.1 7 Fe(C), /Si02 14.9 1.5 9.1 8 Fe(D)3/Si02 14.8 1.6 9.1 Control 16.4
Claims (10)
1. Atobacco smoke filter including at least one metal co-oridination complex which is relatively stable in air but which is active in contact with tobacco smoke to result in removal of CO and/or NO from the smoke.
2. Atobacco smoke filter according to claim 1 wherein the or each metal is one which exhibits more than one valency.
3. A tobacco smoke filter according to claim 1 or 2 containing a said complex which is an oximic complex.
4. A tobacco smoke filter according to claim 1 containing at-least one said complex selected from those of formula (B)
wherein R is an aliphatic or aromatic radical and M is a metal having two or more valence states.
5. A tobacco smoke filter according to claim 4 containing at least one saidcomp!ex selected from ferrous and ferric complexes with a-naphthaquinone-2-oxime and ss-naphthaquinone-1--oxime.
6. A tobacco smoke filter according to any preceding claim wherein the complex is present supported upon a particulate substrate.
7. A tobacco smoke filter substantially as hereinbefore described in any one of the Examples.
8. A method of removing CO and/or NO from tobacco smoke which comprises passing the smoke over a metal co-ordination complex which is relatively stable in air but which is active in contact with tobacco smoke to result in removal of CO and/or NO from the smoke.
9. A method according to claim 8 and substantially as hereinbefore described.
10. A metal co-ordination complex supported on a particulate carrier, the complex being one which is relatively stable in air but which is active in contact with tobacco smoke to result in removal of CO and/or
NO from the smoke.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB08331464A GB2150806B (en) | 1983-11-25 | 1983-11-25 | Tobacco smoke filter |
HK87589A HK87589A (en) | 1983-11-25 | 1989-11-02 | Tobacco smoke filter |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB08331464A GB2150806B (en) | 1983-11-25 | 1983-11-25 | Tobacco smoke filter |
Publications (3)
Publication Number | Publication Date |
---|---|
GB8331464D0 GB8331464D0 (en) | 1984-01-04 |
GB2150806A true GB2150806A (en) | 1985-07-10 |
GB2150806B GB2150806B (en) | 1987-12-31 |
Family
ID=10552328
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08331464A Expired GB2150806B (en) | 1983-11-25 | 1983-11-25 | Tobacco smoke filter |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB2150806B (en) |
HK (1) | HK87589A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0351252A2 (en) * | 1988-07-15 | 1990-01-17 | Moskovskaya Tabachnaya Fabrika "Yava" | Nitrogen monoxide absorbing compositions |
EP0659355A2 (en) * | 1993-12-22 | 1995-06-28 | Hoechst Aktiengesellschaft | Filter for eliminating nitrogen oxides from tobacco smoke |
US6848450B2 (en) * | 2000-02-07 | 2005-02-01 | Philip Morris Usa Inc. | Cigarette filter using intermetallic compounds |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1139351A (en) * | 1966-04-18 | 1969-01-08 | Oliver Wallis Burke | Improvements in or relating to tobacco smoke filters |
GB1367366A (en) * | 1971-06-08 | 1974-09-18 | Scheinberg I H | Method of producing solid ferous hemoglobin |
GB1369067A (en) * | 1970-10-29 | 1974-10-02 | Scheinberg I H | Filters and carbon monoxide indicators |
-
1983
- 1983-11-25 GB GB08331464A patent/GB2150806B/en not_active Expired
-
1989
- 1989-11-02 HK HK87589A patent/HK87589A/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1139351A (en) * | 1966-04-18 | 1969-01-08 | Oliver Wallis Burke | Improvements in or relating to tobacco smoke filters |
GB1369067A (en) * | 1970-10-29 | 1974-10-02 | Scheinberg I H | Filters and carbon monoxide indicators |
GB1367366A (en) * | 1971-06-08 | 1974-09-18 | Scheinberg I H | Method of producing solid ferous hemoglobin |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0351252A2 (en) * | 1988-07-15 | 1990-01-17 | Moskovskaya Tabachnaya Fabrika "Yava" | Nitrogen monoxide absorbing compositions |
EP0351252A3 (en) * | 1988-07-15 | 1990-12-19 | Moskovskaya Tabachnaya Fabrika "Yava" | Nitrogen monoxide absorbing compositions |
US5083579A (en) * | 1988-07-15 | 1992-01-28 | Vanin Anatoly F | Composition for absorbing nitrogen oxide from tobacco smoke, method for absorbing nitrogen oxide using said composition, filter for purifying tobacco smoke using said composition, and method for impregnating the base of a filter with said composition |
EP0659355A2 (en) * | 1993-12-22 | 1995-06-28 | Hoechst Aktiengesellschaft | Filter for eliminating nitrogen oxides from tobacco smoke |
US5575302A (en) * | 1993-12-22 | 1996-11-19 | Hoechst Aktiengesellschaft | Filter for removing nitrogen oxides from tobacco smoke |
EP0659355A3 (en) * | 1993-12-22 | 1997-04-16 | Hoechst Ag | Filter for eliminating nitrogen oxides from tobacco smoke. |
US6848450B2 (en) * | 2000-02-07 | 2005-02-01 | Philip Morris Usa Inc. | Cigarette filter using intermetallic compounds |
Also Published As
Publication number | Publication date |
---|---|
GB2150806B (en) | 1987-12-31 |
GB8331464D0 (en) | 1984-01-04 |
HK87589A (en) | 1989-11-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |