GB2148474A - Cryogenic cell - Google Patents

Cryogenic cell Download PDF

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Publication number
GB2148474A
GB2148474A GB8426340A GB8426340A GB2148474A GB 2148474 A GB2148474 A GB 2148474A GB 8426340 A GB8426340 A GB 8426340A GB 8426340 A GB8426340 A GB 8426340A GB 2148474 A GB2148474 A GB 2148474A
Authority
GB
United Kingdom
Prior art keywords
shield
cryogenic cell
chamber
detector
inner chamber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB8426340A
Other versions
GB8426340D0 (en
GB2148474B (en
Inventor
Steven Paul Burchell
Nicholas William Kerley
David William Mellor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB838328236A external-priority patent/GB8328236D0/en
Application filed by BP PLC filed Critical BP PLC
Publication of GB8426340D0 publication Critical patent/GB8426340D0/en
Priority to EP19850301168 priority Critical patent/EP0191962A1/en
Priority claimed from EP19850301168 external-priority patent/EP0191962A1/en
Publication of GB2148474A publication Critical patent/GB2148474A/en
Application granted granted Critical
Publication of GB2148474B publication Critical patent/GB2148474B/en
Expired legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00Vessels not under pressure
    • F17C3/02Vessels not under pressure with provision for thermal insulation
    • F17C3/08Vessels not under pressure with provision for thermal insulation by vacuum spaces, e.g. Dewar flask
    • F17C3/085Cryostats
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B36/00Heating, cooling or insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
    • E21B36/001Cooling arrangements
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01VGEOPHYSICS; GRAVITATIONAL MEASUREMENTS; DETECTING MASSES OR OBJECTS; TAGS
    • G01V5/00Prospecting or detecting by the use of ionising radiation, e.g. of natural or induced radioactivity
    • G01V5/04Prospecting or detecting by the use of ionising radiation, e.g. of natural or induced radioactivity specially adapted for well-logging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/03Orientation
    • F17C2201/032Orientation with substantially vertical main axis
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/01Reinforcing or suspension means
    • F17C2203/014Suspension means
    • F17C2203/018Suspension means by attachment at the neck
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/03Thermal insulations
    • F17C2203/0375Thermal insulations by gas
    • F17C2203/0387Cryogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/03Thermal insulations
    • F17C2203/0391Thermal insulations by vacuum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602Wall structures; Special features thereof
    • F17C2203/0612Wall structures
    • F17C2203/0626Multiple walls
    • F17C2203/0631Three or more walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0639Steels
    • F17C2203/0643Stainless steels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/03Dealing with losses
    • F17C2260/031Dealing with losses due to heat transfer
    • F17C2260/033Dealing with losses due to heat transfer by enhancing insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/04Reducing risks and environmental impact
    • F17C2260/042Reducing risk of explosion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/05Improving chemical properties
    • F17C2260/053Reducing corrosion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/05Applications for industrial use
    • F17C2270/0518Semiconductors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/05Applications for industrial use
    • F17C2270/0545Tools

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Fluid Mechanics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Geophysics (AREA)
  • Measurement Of Radiation (AREA)

Description

SPECIFICATION Cryogenic cell This invention relates to a cryogenic cell and more particularly to a cryogenic cell suitable for use in a neutron activation analysis borehole logging tool.
Borehole logging tools comprise a probe for insertion down the borehole, the probe comprising a radioactive source of neutrons, a shield against radioactivity and a gamma ray detector.
The gamma spectrum obtained from the neutron-gamma method registers the stimu lated emission of gamma rays when the radioactive source is used to bombard the formation surrounding the bore hole with neutrons.
It can be interpreted to give an indication of the nature of the formation.
Such tools are used for well logging in the petroleum industry.
Attention is now turning to the in-situ analy- sis of coal deposits with particular reference to the sulphur content. However, this gives rise to considerable problems. The ten major ele- ments present in coal produce a complex activation gamma spectrum comprising some four hundred gamma lines in the range 0.0 to 10.0 MeV. This implies a mean separation of 25 KeV between lines. In practice, many lines of interest are separated by less than 25 KeV.
Therefore it follows that a gamma ray detector with the capability to resolve lines appreciably less than 25 KeV apart is required.
This restricts the choice of detector to a semi-conductor detector and since the latter must be kept at low temperatures (around -180 C) some form of intensive cooling is necessary.
Another proposal has been to take advantage of the latent heat of fusion of substances such as propane with melting points around -180 C. According to one method of operation, the melting hydrocarbon is contained in a Dewar flask and the resulting vapours are allowed to escape. This has the advantage of maintaining the temperature constant over longer periods but suffers from the disadvantages of the loss of refrigerant and more seriously, the production of a potentially explosive gaseous mixture. Another disadvantage lies in the requirement to use liquid nitrogen in order to cool the hydrocarbon to below its melting point. This process precludes use of the technique in remote areas of the world where liquid nitrogen is unavailable.
It is an object of the present invention to produce a safe, totally enclosed cryogenic neutron activation logging tool which does not suffer from the above disadvantages.
Thus according to the present invention there is provided a cryogenic cell comprising a sealed external annular chamber, adapted to be maintained under vacuum and surrounding an isothermal heat shield, a section of the shield being exposed and adapted to make contact with a closed cycle cooler, the shield enclosing a sealed inner chamber adapted for the storage of a solid/liquid refrigerant, the shield having a well in its upper regon immediately above and in contact with the top of the inner chamber, the inner chamber being connected at its lower end to a section containing an absorbent, the latter section being connected at its lower end to a further chamber suitable for the reception of a gamma radiation detector.
The outer wall of the external chamber is preferably fabricated from a metal resistant to corrosion and of high tensile strength such as stainless steel.
The walls of the isothermal heat shield and internal chamber are preferably fabricated from a material of high thermal conductivity such as copper. The shield is constrained to be relatively thin where it surrounds the inner chamber and is preferably thick where it is exposed.
The well in the isothermal heat shield is adapted to receive a"cold finger"and to transmit the ensuing low temperature to the inner chamber so that the refrigerant is substantially solidified before the commencement of operations, although a small vapour space is preferably left. This eliminates the use of intermediate cryogenic materials such as liquid nitrogen.
The absorbent in the lower tube acts as a cryopump and absorbs impurities within the vacuum chamber. Suitable absorbents include molecular sieves and activated carbon.
Suitable refrigerants include hydrocarbons such as propane and butene-1.
As stated previously the cryogenic cell is particularly suitable for use in maintaining the gamma ray detector of a neutron activation logging tool at the required low temperature.
Thus according to another aspect of the present invention there is provided a neutron logging tool comprising a probe containing in sequence from the bottom end a radioactive source of neutrons, a shield against radioactivity, a semi-conductor detector for gamma radiation and a cryogenic cell as hereinbefore described for maintaining the detector at a low temperature, the detector being positioned in the lowermost chamber of the cryogenic cell.
A suitable source is a 5Ci Amibe neutron source, such as obtained from Amersham International.
The shield is preferably a composite shield assembly comprising a heavy metal scatterer and a hydrogenous moderator.
A suitable detector is a germanium crystal.
The output of a semi-conductor detector is of the order of picoamps and therefore a preamplifier is necessary. Losses and noise may be reduced by positioning the preampli fier in a separate compartment as physically close to the detector as possible. The preamplifier field effect transistor is preferably positioned on the pre-amplifier printed circuit board-this is referred to as a warm FET configuration nd avoids the use of a cold FET within the vacuum chamber.
The cryogenic cell may be chilled by com mercially available closed cycle coolers comprising cold fingers.
Above the cryogenic cell will be the detector EHT supply, the main amplifier and the cable driver which transmits an analogue signal via an ordinary armoured single-core logging cable.
The invention is illustrated with reference to Fig. 1 of the accompanying drawing which is a schematic section of a cryogenic cell.
The cell comprises an inner, oxygen free copper pressure vessel 1 containing mostly solid/liquid propane 2 of 99.99% purity, although a small vapour space 3 is left. The purity level of the propane is important to reduce the risks of supercooling and eutectic shifts in melting point.
The cell is initially charged with propane and then sealed for life. Alternatively the cell may be charged with butene-1 and then sealed for life. Butene-1 offers approximately 3% improvement in holding time over propane.
The inner vessel 1 is placed within a copper isothermal heat shield 4 and the space 5 between the two vessels is evacuated to provide a vacuum.
The heat shield 4 is itself placed within a stainless steel outer vessel 6 and the space 7 between is also evacuated to provide a vacuum. It has a central aperture 8 into which is fitted a stainless steel wall 9, the bottom of the well being directly above the top of the inner vessel 1.
At its lower end, the inner vessel 1 is formed into a cylindrical section 10 containing apertures 11 for containing a molecular sieve absorbent for removing traces of impurities from the vacuum.
A hollow aluminium block 12 containing a detector 13 is connected to the cylindrical section 10.
In order to chill the contents of the ceil before operating the logging tool, a closed cycle cooler is contacted with the exposed upper surface of the heat shield 4 and a"cold finger"is inserted into the well 9.

Claims (7)

1. A cryogenic cell comprising a sealed external annular chamber, adapted to be maintained under vacuum and surrounding an isothermal heat shield, a section of the shield being exposed and adapted to make contact with a closed cycle cooler, the shield enclosing a sealed inner chamber adapted for the storage of a solid/liquid refrigerant, the shield having a well in its upper region immediately above and in contact with the top of the inner chamber, the inner chamber being connected at its lower end to a section containing an absorbent, the latter section being connected at its lower end to a further chamber suitable for the reception of a gamma radiation detector.
2. A cryogenic cell according to claim 1 wherein the outer wall of the external chamber is fabricated from stainless steel.
3. A cryogenic cell according to either of the preceding claims wherein the walls of the isothermal heat shield and internal chamber are fabricated from a material of high thermal conductivity.
4. A cryogenic cell according to claim 3 wherein the shield is relatively thin where it surrounds the inner chamber and thick where it is exposed.
5. A cryogenic cell according to any of the preceding claims wherein the well in the isothermal heat shield is adapted to receive a cold finger and to transmit the ensuing low temperature to the inner chamber.
6. A neutron logging tool comprising a probe containing in sequence from the bottom end a radioactive source of neutrons, a shield against radioactivity, a semi-conductor detector for gamma radiation and a cryogenic cell according to any of the preceding claims for maintaining the detector at a low temperature, the detector being positioned in the lowermost chamber of the cryogenic cell.
7. A cryogenic cell as hereinbefore described with reference to the accompanying drawing.
GB8426340A 1983-10-21 1984-10-18 Cryogenic cell Expired GB2148474B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP19850301168 EP0191962A1 (en) 1983-10-21 1985-02-21 Cryogenic cell

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB838328236A GB8328236D0 (en) 1983-10-21 1983-10-21 Cryogenic cell
EP19850301168 EP0191962A1 (en) 1983-10-21 1985-02-21 Cryogenic cell

Publications (3)

Publication Number Publication Date
GB8426340D0 GB8426340D0 (en) 1984-11-21
GB2148474A true GB2148474A (en) 1985-05-30
GB2148474B GB2148474B (en) 1987-02-18

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ID=26098237

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8426340A Expired GB2148474B (en) 1983-10-21 1984-10-18 Cryogenic cell

Country Status (1)

Country Link
GB (1) GB2148474B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0191962A1 (en) * 1983-10-21 1986-08-27 The British Petroleum Company p.l.c. Cryogenic cell
AU580755B2 (en) * 1983-10-21 1989-02-02 British Petroleum Company Plc, The Cryogenic cell
WO2000020795A2 (en) * 1998-09-14 2000-04-13 Massachusetts Institute Of Technology Superconducting apparatuses and cooling methods
GB2504250A (en) * 1989-01-23 2014-01-29 Hughes Aircraft Co Cooling system for seeker head

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0191962A1 (en) * 1983-10-21 1986-08-27 The British Petroleum Company p.l.c. Cryogenic cell
AU580755B2 (en) * 1983-10-21 1989-02-02 British Petroleum Company Plc, The Cryogenic cell
GB2504250A (en) * 1989-01-23 2014-01-29 Hughes Aircraft Co Cooling system for seeker head
GB2504250B (en) * 1989-01-23 2015-07-22 Hughes Aircraft Co Cryogenic cooling system for airborne use
WO2000020795A2 (en) * 1998-09-14 2000-04-13 Massachusetts Institute Of Technology Superconducting apparatuses and cooling methods
WO2000020795A3 (en) * 1998-09-14 2000-07-27 Massachusetts Inst Technology Superconducting apparatuses and cooling methods
US6622494B1 (en) 1998-09-14 2003-09-23 Massachusetts Institute Of Technology Superconducting apparatus and cooling methods

Also Published As

Publication number Publication date
GB8426340D0 (en) 1984-11-21
GB2148474B (en) 1987-02-18

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