GB2135918A - Pouring tube for casting steel - Google Patents

Pouring tube for casting steel Download PDF

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Publication number
GB2135918A
GB2135918A GB08334549A GB8334549A GB2135918A GB 2135918 A GB2135918 A GB 2135918A GB 08334549 A GB08334549 A GB 08334549A GB 8334549 A GB8334549 A GB 8334549A GB 2135918 A GB2135918 A GB 2135918A
Authority
GB
United Kingdom
Prior art keywords
outlet
delivery outlet
inner part
refractory
deposits
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08334549A
Other versions
GB8334549D0 (en
GB2135918B (en
Inventor
Hans Georg Rosenstock
Peter Walter Valentin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ARBED SAARSTAHL GmbH
Original Assignee
ARBED SAARSTAHL GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ARBED SAARSTAHL GmbH filed Critical ARBED SAARSTAHL GmbH
Publication of GB8334549D0 publication Critical patent/GB8334549D0/en
Publication of GB2135918A publication Critical patent/GB2135918A/en
Application granted granted Critical
Publication of GB2135918B publication Critical patent/GB2135918B/en
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/50Pouring-nozzles
    • B22D41/52Manufacturing or repairing thereof
    • B22D41/54Manufacturing or repairing thereof characterised by the materials used therefor

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
  • Continuous Casting (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Furnace Charging Or Discharging (AREA)
  • Ceramic Products (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

A composite delivery outlet (1) for casting plant has an inner lining (2) made of magnesium oxide, to prevent the accumulation of solid oxide deposits. An outer layer (3) of a refractory oxide such as Al2O3 or SiO2 is provided to strengthen the outlet, the two layers being spaced by an air gap (4). <IMAGE>

Description

SPECIFICATION Delivery outlet for continuous casting plant The invention concerns a delivery outlet for continuous casting plant made of a refractory material which prevents the accumulation of solid oxide deposits.
In the continuous casting of steel delivery outlets are used which consist essentially of one or more fire-resistant oxides (Al203, SiO2), carbon (graphite) and a binding agent. In these outlets alumina deposits form on the inner walls and cause a diminution of the internal diameter of the outlet, which results in a reduction in the speed of flow.
Moreover, pieces of alumina broken off from these deposits form inclusions which impair the finished steel.
A known method of prevention (DE-OS 27 31 367) is to add Ca or CaSi alloys to the molten steel in order to prevent the deposition of alumina particles in the delivery outlet. In this way the Awl203 particles resulting from an aluminium treatment are modified, i.e. they are converted to a liquid form (Ca aluminates).
This procedure is not always successful. It is also laborious and costly. Finally it does not take account of the fact that in delivery outlets of Awl203 or SiO3 deposits or accumulations form on the internal wall as a result of reactions between the refractory mass of the outlet, alumina or silicon dioxide as the molten steel.
The invention has a purpose of proposing a delivery outlet for continuous casting plant in which accumulations of solid oxide phases are prevented.
According to the invention this is achieved by making the inner part of the outlet which comes into contact with the molten steel of magnesium oxide.
It is expedient to surround the inner part of the outlet with a layer of refractory oxides commonly used in outlets, such as At203 or SiO2.
In accordance with a further development of the invention an air gap is provided between the inner part and the layer surrounding it.
The essential advantage to be obtained by the invention is that by a simple expedient the disruptive deposits on the inner walls of delivery outlets are prevented and thus the disadvantages mentioned earlier are not suffered.
The drawing shows an example of the application of the invention.
The inner part (2) of the delivery outlet (1), the part which comes into contact with the molten steel, is made of magnesium oxide (MgO). It has proved expedient to surround the inner part (2) with a layer (3) of known refractory oxides such as for example Al203, SiO2 or another suitable fire-resistant material. In this way the delivery outlet (1) is sufficiently durable in spite of the not very good mechanical strength of MgO.
If the coefficients of expansion of the inner part (2) and the outer layer (3) are very different it is appropiate to provide an air gap (4).
Tests have shown that surprisingly the delivery outlet described remains clean in its inner part (2), so that casting can continue at a constant speed.
1. A composite delivery outlet for continuous casting plant, made of a refractory material, wherein the inner part of the outlet, which comes into contact with the molten steel, is made of magnesium oxide to prevent the accumulation of solid oxide deposits.
2. A composite delivery outlet in accordance with Claim 1, wherein the said inner part of the outlet is surrounded by a layer of a refractory oxide or oxides.
3. A composite delivery outlet in accordance with Claim 2 wherein the surrounding refractory oxide layer comprises A1203 and/or SiO2.
4. A composite delivery outlet in accordance with Claim 2 or Claim 3, wherein an air gap is provided between the inner part and the surrounding refractory oxide layer.
5. A composite delivery outlet for continuous casting plant, substantially as herein described with reference to the acompanying drawing.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (5)

**WARNING** start of CLMS field may overlap end of DESC **. SPECIFICATION Delivery outlet for continuous casting plant The invention concerns a delivery outlet for continuous casting plant made of a refractory material which prevents the accumulation of solid oxide deposits. In the continuous casting of steel delivery outlets are used which consist essentially of one or more fire-resistant oxides (Al203, SiO2), carbon (graphite) and a binding agent. In these outlets alumina deposits form on the inner walls and cause a diminution of the internal diameter of the outlet, which results in a reduction in the speed of flow. Moreover, pieces of alumina broken off from these deposits form inclusions which impair the finished steel. A known method of prevention (DE-OS 27 31 367) is to add Ca or CaSi alloys to the molten steel in order to prevent the deposition of alumina particles in the delivery outlet. In this way the Awl203 particles resulting from an aluminium treatment are modified, i.e. they are converted to a liquid form (Ca aluminates). This procedure is not always successful. It is also laborious and costly. Finally it does not take account of the fact that in delivery outlets of Awl203 or SiO3 deposits or accumulations form on the internal wall as a result of reactions between the refractory mass of the outlet, alumina or silicon dioxide as the molten steel. The invention has a purpose of proposing a delivery outlet for continuous casting plant in which accumulations of solid oxide phases are prevented. According to the invention this is achieved by making the inner part of the outlet which comes into contact with the molten steel of magnesium oxide. It is expedient to surround the inner part of the outlet with a layer of refractory oxides commonly used in outlets, such as At203 or SiO2. In accordance with a further development of the invention an air gap is provided between the inner part and the layer surrounding it. The essential advantage to be obtained by the invention is that by a simple expedient the disruptive deposits on the inner walls of delivery outlets are prevented and thus the disadvantages mentioned earlier are not suffered. The drawing shows an example of the application of the invention. The inner part (2) of the delivery outlet (1), the part which comes into contact with the molten steel, is made of magnesium oxide (MgO). It has proved expedient to surround the inner part (2) with a layer (3) of known refractory oxides such as for example Al203, SiO2 or another suitable fire-resistant material. In this way the delivery outlet (1) is sufficiently durable in spite of the not very good mechanical strength of MgO. If the coefficients of expansion of the inner part (2) and the outer layer (3) are very different it is appropiate to provide an air gap (4). Tests have shown that surprisingly the delivery outlet described remains clean in its inner part (2), so that casting can continue at a constant speed. CLAIMS
1. A composite delivery outlet for continuous casting plant, made of a refractory material, wherein the inner part of the outlet, which comes into contact with the molten steel, is made of magnesium oxide to prevent the accumulation of solid oxide deposits.
2. A composite delivery outlet in accordance with Claim 1, wherein the said inner part of the outlet is surrounded by a layer of a refractory oxide or oxides.
3. A composite delivery outlet in accordance with Claim 2 wherein the surrounding refractory oxide layer comprises A1203 and/or SiO2.
4. A composite delivery outlet in accordance with Claim 2 or Claim 3, wherein an air gap is provided between the inner part and the surrounding refractory oxide layer.
5. A composite delivery outlet for continuous casting plant, substantially as herein described with reference to the acompanying drawing.
GB08334549A 1983-01-05 1983-12-29 Pouring tube for casting steel Expired GB2135918B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3300166A DE3300166C2 (en) 1983-01-05 1983-01-05 Multi-part immersion nozzle for continuous casting plants

Publications (3)

Publication Number Publication Date
GB8334549D0 GB8334549D0 (en) 1984-02-01
GB2135918A true GB2135918A (en) 1984-09-12
GB2135918B GB2135918B (en) 1986-02-19

Family

ID=6187742

Family Applications (1)

Application Number Title Priority Date Filing Date
GB08334549A Expired GB2135918B (en) 1983-01-05 1983-12-29 Pouring tube for casting steel

Country Status (7)

Country Link
JP (1) JPS59141354A (en)
DE (1) DE3300166C2 (en)
ES (1) ES284621Y (en)
FR (1) FR2538724B1 (en)
GB (1) GB2135918B (en)
IT (1) IT1195989B (en)
SE (1) SE8307234L (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2148765A (en) * 1983-11-02 1985-06-05 Didier Werke Ag Immersion nozzle
DE4003608C1 (en) * 1990-02-07 1991-06-27 Didier-Werke Ag, 6200 Wiesbaden, De
US5370370A (en) * 1993-02-19 1994-12-06 Vesuvius Crucible Company Liner for submerged entry nozzle
US5691061A (en) * 1994-06-15 1997-11-25 Vesuvius Crucible Company Refractory shape having an external layer capable of forming a layer impermeable to gases and process for its preparation
EP0826447A1 (en) * 1996-08-26 1998-03-04 Shinagawa Refractories Co., Ltd. Nozzle for continuous casting
US6321953B1 (en) * 1996-04-11 2001-11-27 Shinagawa Refractories, Co., Ltd. Composite immersion nozzle
US6475426B1 (en) 2001-03-27 2002-11-05 Vesuvius Crucible Company Resin-bonded liner
US6537486B1 (en) 2000-03-17 2003-03-25 Yesuvius Crucible Company Anti-buildup liner

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3420835C2 (en) * 1984-06-05 1989-11-23 Chamotte- und Tonwerk Kurt Hagenburger, 6718 Grünstadt Ceramic sink
CH674813A5 (en) * 1987-07-31 1990-07-31 Stopinc Ag
US4870037A (en) * 1987-09-23 1989-09-26 Vesuvius Crucible Company Prevention of Al2 O3 formation in pouring nozzles and the like
US5011049A (en) * 1989-04-17 1991-04-30 General Electric Company Molten metal transfer tube
JP3219095B2 (en) * 1990-02-20 2001-10-15 日新製鋼株式会社 Nozzle for continuous casting

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1148340A (en) * 1966-07-15 1969-04-10 Vesuvius Crucible Co Nozzle for a bottom pouring ladle for molten metal
GB1454265A (en) * 1973-01-23 1976-11-03 Flogates Ltd Casting of metals
EP0066492A1 (en) * 1981-05-27 1982-12-08 Daussan Et Compagnie Process for the manufacturing of a casting tube

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2804025A1 (en) * 1977-02-02 1978-08-03 Centre Rech Metallurgique Continuous casting refractory nozzle mfr. - with addn. of finely divided refractory oxide to improve resistance to chemical attack
DE2731367A1 (en) * 1977-07-12 1979-02-08 Sueddeutsche Kalkstickstoff Molten steel treatment to prevent reoxidation - by adding a calcium-silicon alloy to the steel stream during casting

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1148340A (en) * 1966-07-15 1969-04-10 Vesuvius Crucible Co Nozzle for a bottom pouring ladle for molten metal
GB1454265A (en) * 1973-01-23 1976-11-03 Flogates Ltd Casting of metals
EP0066492A1 (en) * 1981-05-27 1982-12-08 Daussan Et Compagnie Process for the manufacturing of a casting tube

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2148765A (en) * 1983-11-02 1985-06-05 Didier Werke Ag Immersion nozzle
DE4003608C1 (en) * 1990-02-07 1991-06-27 Didier-Werke Ag, 6200 Wiesbaden, De
US5370370A (en) * 1993-02-19 1994-12-06 Vesuvius Crucible Company Liner for submerged entry nozzle
US5691061A (en) * 1994-06-15 1997-11-25 Vesuvius Crucible Company Refractory shape having an external layer capable of forming a layer impermeable to gases and process for its preparation
US6321953B1 (en) * 1996-04-11 2001-11-27 Shinagawa Refractories, Co., Ltd. Composite immersion nozzle
EP0826447A1 (en) * 1996-08-26 1998-03-04 Shinagawa Refractories Co., Ltd. Nozzle for continuous casting
US5908577A (en) * 1996-08-26 1999-06-01 Shinagawa Refractories Co., Ltd. Nozzle for continuous casting
US6537486B1 (en) 2000-03-17 2003-03-25 Yesuvius Crucible Company Anti-buildup liner
US6475426B1 (en) 2001-03-27 2002-11-05 Vesuvius Crucible Company Resin-bonded liner

Also Published As

Publication number Publication date
FR2538724A1 (en) 1984-07-06
IT1195989B (en) 1988-11-03
ES284621U (en) 1985-08-01
GB8334549D0 (en) 1984-02-01
JPS59141354A (en) 1984-08-14
SE8307234D0 (en) 1983-12-30
GB2135918B (en) 1986-02-19
DE3300166A1 (en) 1984-07-12
ES284621Y (en) 1986-04-16
FR2538724B1 (en) 1986-09-05
IT8419016A0 (en) 1984-01-04
DE3300166C2 (en) 1986-07-17
SE8307234L (en) 1984-07-06

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PCNP Patent ceased through non-payment of renewal fee