GB2135139A

GB2135139A - Heat recoverable article

Info

Publication number: GB2135139A
Application number: GB08403791A
Authority: GB
Inventors: Groot Hubert De
Original assignee: Raychem NV SA
Current assignee: Commscope Connectivity Belgium BVBA
Priority date: 1983-02-14
Filing date: 1984-02-14
Publication date: 1984-08-22
Also published as: GB8403791D0; GB2135139B

Abstract

An article for forming a cable block or for enclosing a cable splice comprises a heat-recoverable driver sleeve 1 and a particulate heat- activatable adhesive 3, e.g. a hot-melt adhesive, temporarily restrained adjacent an inner surface of the sleeve, e.g. by a substantially non-cross-linked polyolefin net or mesh 2 which may be bonded to the sleeve 1 around its edges. The sleeve 1 may be coated on its inner surface with an adhesive or scalant coating 4. An internal heat barrier net or mesh 5 may be provided. The sleeve 1 may be a wrap-around sleeve, Figure 5, having closure rails 11 held together by a C-section channel. <IMAGE>

Description

SPECIFICATION Heat-recoverable article This invention relates to a heat-recoverable article for protecting or blocking elongate substrates such as cables, joints in cables or pipes.

Heat-recoverable articles, whose dimensional configuration may be made substantially to change when subjected to heat treatment, usually recover towards an original shape from which they have previously been deformed but the term "heatrecoverable", as used herein, also includes an article which, on heating, adopts a new configuration, even if it has not been previously deformed.

In their most common form, such articles comprise a heat-shrinkable sleeve made from a polymeric material exhibiting the property of elastic or plastic memory as described, for example, in U.S.

Patents 2,027,962; 3,086,242 and 3,597,372. As is made clear in, for example, U.S. Patent 2,027,962, the original dimensionally heat-stable form may be a transient form in a continuous process in which, for example, an extruded tube is expanded, whilst hot, to a dimensionally heat-unstable form but, in other applications, a preformed dimensionally heat stable article is deformed to a dimensionally heat-unstable form in a separate stage.

In the production of heat recoverable articles, the polymeric material may be cross-linked at any stage in the production of the article that will enhance the desired dimensional recoverability. One manner of producing a heat-recoverable article comprises shaping the polymeric material into the desired heat-stable form, subsequently cross-linking the polymeric material, heating the article to a temperature above the crystalline melting point or, for amorphous materials the softening point, as the case may be, of the polymer, deforming the article and cooling the article whilst in the deformed state so that the deformed state of the article is retained, In use, since the deformed state of the article is heat-unstable, application of heat will cause the article to assume its original heat-stable shape.

In other articles, as described, for example, in British Patent 1,440,524, an elastomeric member such as an outer tubular member is held in a stretched state by a second member, such as an inner tubular member, which, upon heating weakens and thus allows the elastomeric member to recover.

An example of the use of a heat-recoverable articles for cable blocking (by which we mean the prevention of passage of a fluid along the inside of a cable) is to be found in German Patent specification 2539325 (Kabel-und Metallwerke). A pressurised communications cable is blocked by removing a band of cable jacket and installing around the exposed part of the cable a heat-recoverable tube, the ends of which are shrunk down onto the cable jacket either side of the exposed part. This first step provides a container sealed around the exposed part of the cable into which one pours a casting resin. The resin flows between the conductors to a certain extent, but it is the final step of shrinking down the central part of the container which drives the resin along the cable core forming an excellent cable block.This system produces good results but requires careful sealing of the hole through which the resin was introduced, and the use of a separate liquid component makes the technique somewhat craft-sensitive in certain applications.

The use of a liquid is avoided in the method disclosed in UK Patent specification 1603298 (N.V.

Raychem SA). This method, which is particularly applicable for blocking telecommunications cables of up to 20 pairs, makes use of a recoverable sleeve having a hot-melt adhesive insert (generaliy a tube coaxial with the sleeve) and, positioned between these two components, a heat barrier layer such as a tubular net. The article is used to surround the conductors of a cable at a discontinuity in the cable jacket. The heat barrier, which should be capable of preserving its structural integrity during installation of the product, allows through sufficient heat to melt the adhesive but insufficient to damage the cable.

This article also produces good results but it can have disadvantages when used with larger cables.

The large inner adhesive layer required to block a large cable is more be difficult to melt and may cause leak paths to remain in the installed product if improperly installed. If further heat is applied in an attempt to overcome this problem, damage to the insulation of the conductors or sleeve splitting may occur. (Large adhesive coated sleeves can of course be used as mere protective coverings where a small amount only of adhesive is required for bonding, rather than the larger amount required for blocking.) The present invention provides an assembly for applying a heat-activatable adhesive to an elongate substrate, which comprises: a heat-recoverable driver sleeve; a particulate heat-activatable adhesive; and temporary restraining means for mechanically locating the adhesive adjacent an inner surface of the sleeve until heat-recovery of the sleeve.

The means by which the particulate adhesive is maintained in place is additional to any adhesive bonding which may be obtained for example when a layer of particulate adhesive is adhered, by presscoating or otherwise, to the recoverable sleeve. In general, the amount of adhesive present will greatly exceed that amount which could be accommodated thus as one coating and, in such a situation, the particles nearest the sleeve may be bonded but the remainder will be located as hereinafter described.

The invention also provides a method of blocking a cable, which comprises: surrounding a portion of the cable having a section thereof at least partially bare of jacket with an assembly according to the invention; and heating the assembly to recover the sleeve and activate the adhesive, recovery causing the adhesive to be displaced from the temporary restraining means and driven into the core of the cable at the bared section thereof.

The invention further provides a method of environmentally sealing a cable splice which comprises using the assembly in an analogous way over the splice; here, however, it is not essential that the adhesive permeate the cable core since an external coating (around the conductors or around a super imposed liner) is may all be that is required.

The assembly of the invention may also be used to cover pipes or joints in pipes particularly where a substantial amount of void filling is also required.

Before the three components of the assembly are individually discussed, a preferred form of the complete assembly will be described.

If the assembly of the invention is to be used to form a cable block, or to seal a splice without the use of a liner, the amount of adhesive required will be larger than that required simply to bond a sleeve to an underlying surface. The amount of adhesive required can easily be determined by the skilled worker by measuring the cable or splice diameter and the volume of conductors to be contained.

Where a cable block is being constructed, some assessment will also need to be made of adhesive flow along the cable core. The length of the recoverable sleeve will depend on the length of bared cable that has to be bridged, and on the strength of seal required which will determine any additional length of sleeve required to bond to the cable jacket on either side of the bared portion. The recovered diameter of the central part of the sleeve will generally be slightiy less than the cable diameter for a cable block, and will depend on the size of the splice bundle for a cable splice. The internal diameter of the assembly before recovery wil depend on the largest part of the substrate the assembly must pass over to reach its location.Once these factors have been borne in mind one can calculate the volume of adhesive required as a fraction of the volume of the sleeve, either before or after recovery.

Since the adhesive need not extend the entire length of the sleeve (the ends of the sleeve may be free of adhesive or have a thin coating sufficient only to bond them to the cable jacket) a more general characteristic is the ratio between cross-sectional area of the sleeve after recovery and the crosssectional area of adhesive within it. The particulate adhesive need not be distributed uniformly within that part of the sleeve where it is present, and when it is not uniform this ratio can be regarded as an average. Preferred values for the ratio are 2-3:1, more preferably 2-2.5:1, especially 2.1-2.3:1.

The sleeve is preferably tubular and has a central portion of larger diameter forming an annular space which contains the particulate adhesive since in this way the channel through the centre of the assembly may by cylindrical. Alternatively, the sleeve may be a wrap-around sleeve comprising a sheet of recoverable material, closure means for maintaining it in a wrap-around configuration, and a particulate adhesive secured to one side by a restaining means.

Of the three components of the assembly of the invention, the sleeve will be discussed first. It is preferably formed from a cross-linked polymeric material such as a modified polyolefin, and may be rendered heat-recoverable by any of the techniques mentioned above. The recovery temperature is preferably 115-125"C, more preferably about 1200C, although this will depend on the adhesive used, the means for heating available, and on the susceptibility of the cable to damage by heat. We prefer that the sleeve be substantiallytransparent in order that the installer can watch the progress of installation, although the presence of an externai temperature indicator such as a thermochromic paint may render this feature unnecessary.

The adhesive used should be heat-activatable in orderthat installation can be carried out by the single step of heating. In general recovery and activation of the adhesive will both be accomplished by the use of, say, a propane torch, but separate heating means may be provided for the two components. We prefer that the particulate adhesive has a low activation temperature, and that it is closely matched to the recovery temperature of the sleeve.

In this way quick installation and avoidance of cable damage may be ensured.

A preferred heat-activatable adhesive is a hot-melt adhesive, although reactive systems and thermosets may be used. An activation temperature from 65 80"C is preferred, 73-77"C being especially preferred.

We prefer that the activation temperature of the adhesive is less than 55"C, more preferably less than 45"C, below the recovery temperature of the sleeve.

By careful choice of recovery temperature it is possible to ensure that the adhesive will be properly activated by the time it is driven by the recovering sleeve into the core of the cable or around the cable splice. This feature is particularly useful where the adhesive melts on activation (this includes some reactive systems and thermosets, as well as truely hot-melt adhesives) since it can then flow properly as the sleeve recovers.

The size of the particles of the adhesive is not critical, it being surprisingly found that good adhesive activation and flow at low heat input can be achieved over a wide range of particle size. it might be expected that the better heat conductivity of a solid adhesive sheet would lead to more satisfactory heat-activation, since the ability of particles to move away from each other and the entrapment of air could delay proper activation; the explanation for the superior performance of a particulate adhesive in these circumstances is not in fact fully understood.

Where the adhesive is a hot-melt adhesive the particles are preferably of an average diameter (if spherical) of 0.5-4mm, more preferably 1-3mm especially about 1.5mum. A suitable hot-melt adhesive is a polyamide or a polyester based material, in particular a polyamide modified with a wax.

As an alternative to a hot-melt adhesive, one may use a powdered reactive system such as a polyamide and an epoxy compound. This system allows for long shelf-life at one temperature and a very quick reaction time at a temperature only slightly higher.

Another factor which may influence the choice of adhesive is its melt viscosity, and this will be more critical for cable blocking than for simple environmental protection of splices since in the former case full penetration of the cable core is desirable.

Preferred values are from 4-8, PA/sec more preferably from 5-7, PA/sec at a temperature of 1600c as measured byASTM D 1084 The third component is the temporary restraining means for maintainig the adhesive adjacent an inner surface of the sleeve. A balance must be attained here between the ability of the restraining means to retain the integrity of the product before use without loss of adhesive, and the ease with which the adhesive can flow into a cable core or around a splice on installation. The situation is further complicated by the requirement that the adhesive become properly activated, since a premature flowing of adhesive would in fact cause more heat ultimately to be required, possibly leading to conductor insulation damage.The following sequence of events is preferred: the sleeve is heated causing gradual activation of adhesive throughout its bulk, then the sleeve begins to recover and seals to the cables at its ends, the restraining means becomes ineffective and recovery drives activated adhesive to the regions of the cable where it is wanted. This sequence is not essential since recovery can, at least to some extent, occur before activation, or failure of the mechanical means may occur earlier provided it does not lead to excessive loss of adhesive. The mechanical means preferably fails at a temperature from 40-60"c, more preferably from 45-55"c.

The restraining means may be a film which melts or recovers below the recovery temperature of the sleeve but is preferably a net, which traps the adhesive against an inner surface of the sleeve. The net may be made of a non-cross-linked polyolefin in order that it melts when the adhesive has been heated sufficiently for activation. The net conveniently is cylindrical and lies concentrically within the recoverable sleeve, closing an annular void within the sleeve resulting from the sleeve's nonuniform cross-sectional size (this is illustrated below). The sleeve may be moulded or otherwise formed with this shape, but it will generally be found more convenient to form a cylincrical sleeve, and expand its central region to a greater extent than its ends, or partially to recover its ends after uniform expansion.The net is preferably bonded to the sleeve, but it may simply be an interference fit within it. As an alternative, the net may entirely enclose the adhesive, and the bag of adhesive so formed be locatable within the sleeve. Such a bag may for example be formed as a bandolier, having a plurality of compartments arranged around the inner circumference os the sleeve, each containing the adhesive or a component thereof. Reference to the restraining means becoming ineffective preferably means that it looses its structural integrity, especially by melting, but it may merely become disbonded or dislodged from the sleeve, or the melted adhesive may simply be able to pass through or around it.

The product may include as a fourth component a further net which is installed directly around the cable and within the assembly of the other components. This further net will generally be discrete but it may be supplied affixed to the inside of the sleeve.

Its purpose is to provide additional heat protection to the cable and it should therefore be heat resistant. A suitable material is a cross-linked polyethylene, which should be flexible so that the net can follow the surface of the cable, and be sufficiently perforate to allow passage of activated adhesive. As a further important feature, the net may be coloured in order to provide a visual indication of when proper sealing has occurred : at first this net will be invisible through the transparent sleeve due to the intervening particulate adhesive, but after activation and coalescence of the adhesive its colour will become visible.

The assembly of the invention may be used in conjunction with other components. In particular, where a cable splice is to be sealed, a branch-off can be effected by using a clip as a means of forming at least two conduits at an end of the recoverable sleeve.

The invention will now be further illustrated with reference to the accompanying drawings in which: Figure 1 shows an assembly of the invention; Figure 2 shows a similar article together with a heat protective net; Figure 3 shows the assembly used for forming a cable block; Figure 4 shows the assembly used for sealing a cable splice; Figure 5 shows an assembly using a wrap-around, rather than tubular, sleeve; and Figure Shows an assembly where the adhesive is trapped in a bag.

Figure 1 shows the basic assembly consisting of a recoverable sleeve 1 having an annular void resulting from the sleeve's non-uniform cross-sectional size. This annular void is closed by a mesh or net 2 and contains a particulate heat-activatable adhesive 3. For use with telecommunications distribution cables of up to, say, 100 pairs the recoverable sleeve preferably has an expanded diameter of 3.5-5.5cm, especially about 4.5cm, and a recovered diameter of from 1.5-2cm, especially about 1.8cm.

Figure 2 adds two further features : the sleeve 1 is coated on its internal surface with an adhesive or sealant coating 4, and an internal heat barrier net or mesh 5 is provided. The coating 4 need not extend the entire length of the sleeve (as shown) since it is primarily required at the ends of the sleeve for bonding to an underlying cable.

The formation of a cable block is shown in Figure 3 : the upper half of the figure shows the assembly of the invention before heating, and the lower half shows the installed product. A portion of cable jacket has been removed from a cable 6 to expose its conductors 7. A cut-away at the left hand side of the figure shows the adhesive 3 having permeated the cable core to form a cable block 8.

A cable splice 9 is shown in Figure 4, and again the Figure is divided to show the situation before and after installation is complete. A liner 10 is positioned around the splice 9 to protect it mechanically and thermally from the outer sleeve during heat recovery. The liner has a larger central region to accommodate the splice and tapering end portions which provide a gentle transition to the cables. The liner 10 may be based, for example, on cardboard, a thermoplastics material or a metal such as aluminium. If the conductors are sufficiently rugged or the recovery temperature of the sleeve and activation temperature of the adhesive are sufficiently low the liner 10 could be omitted. The adhesive 3 would then be driven between the spliced conductors thereby sealing them from the environment. A disadvantage of this is that it makes re-entry difficult.

A wrap-around sleeve 1 having closure rails 11 is shown in Figure 5. The closure rails may be held together by means of a C-shaped channel, or another closure mechanism or bonding may be used. The particulate adhesive 3 is held against the sleeve 1 by a net 2 which is bonded to the sleeve around its edges.

Figure 6 illustrates an assembly in which the sleeve 1 is generally cylindrical and has the particulate adhesive 3 contained within a net bag 2 situated within the sleeve.

Claims

1. An assembly for applying a heat-activatable adhesive to an elongate substrate, which comprises: a heat-recoverable driver sleeve; a particulate heat-activatable adhesive; and temporary restraining means for locating the adhesive adjacent an inner surface of the sleeve until heatrecovery of the sleeve.

2. An assembly according to Claim 1, in which the sleeve has end regions of smaller cross-section and an intermediate region of larger cross-section, the particulate adhesive being located adjacent said intermediate region such that an internal passage through the assembly is substantially cylindrical.

3. An assembly according to Claim 1 or 2, in which end regions of the sleeve are coated with an adhesive.

4. An assembly according to any preceding claim, in which the particulate adhesive is a hot-melt adhesive.

5. An assembly according to any preceding claim, in which the ratio between the cross-sectional area of the sleeve after recovery and the average cross-sectional area of particulate adhesive within it, taken over that length of the sleeve where the particulate adhesive is present, is from 2:1 to 3; 1.

6. An assembly according to any preceding claim, in which the restraining means for locating the particulate adhesive is a net.

7. An assembly according to Claim 6, in which the net is bonded to the sleeve.

8. An assembly according to Claim 6 or 7, in which the net comprise a substantially non-crosslinked polyolefin.

9. An assembly according to Claim 6,7 or 8, in which the net has a melting point below the recovery temperature of the sleeve.

10. An assembly according to any preceding claim, which additionally comprises a heat-resistant barrier which can surround the substrate inwardly of the sleeve and particulate adhesive.

11. An assembly according to Claim 10, in which the barrier is a cross-linked polymeric net.

12. An assembly according to Claim 10 or 11, in which the sleeve is substantially transparent and the barrier is coloured.

13. An assembly according to Claim 1, substantially as herein described with reference to any of the accompanying Drawings.

14. A method of producing a cable block, which comprises: surrounding a portion of the cable having a section thereof at least partially bare of jacket with an assembly according to any preceding claim; and heating the assembly to recover the sleeve and activate the adhesive, recovery causing the adhesive to be displaced from the temporary restraining means and driven into the core of the cable at the bared section thereof.

15. A method of sealing a cable splice, which comprises; surrounding a cable splice with an assembly according to any of Claims 1-13; and heating the assembly to recover the sleeve and to activate the adhesive, recovery causing the adhesive to be displaced from the temporary restraining means and driven around the spliced conductors.

16. A method according to Claim 14 or 15, in which on heating the foilowing steps take place in sequence: a) end portions of the sleeve recover into engagement with the cable jacket; b) at least a part of the adhesive is activated; c) the temporary restraining means becomes ineffective; and d) the adhesive is displaced by recovery of a central portion of the sleeve.

17. An assembly according to claim 1 substantially as herein described with reference to any of the accompanying drawings.