GB2131417A - Optical device and reform fabrication - Google Patents

Optical device and reform fabrication Download PDF

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Publication number
GB2131417A
GB2131417A GB08331538A GB8331538A GB2131417A GB 2131417 A GB2131417 A GB 2131417A GB 08331538 A GB08331538 A GB 08331538A GB 8331538 A GB8331538 A GB 8331538A GB 2131417 A GB2131417 A GB 2131417A
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GB
United Kingdom
Prior art keywords
refractive index
soot
optical
optical device
laser beam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08331538A
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GB2131417B (en
GB8331538D0 (en
Inventor
Herman Melvin Presby
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WESTERN ELECTRIC CO Ltd
Original Assignee
WESTERN ELECTRIC CO Ltd
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Filing date
Publication date
Application filed by WESTERN ELECTRIC CO Ltd filed Critical WESTERN ELECTRIC CO Ltd
Publication of GB8331538D0 publication Critical patent/GB8331538D0/en
Publication of GB2131417A publication Critical patent/GB2131417A/en
Application granted granted Critical
Publication of GB2131417B publication Critical patent/GB2131417B/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/14Other methods of shaping glass by gas- or vapour- phase reaction processes
    • C03B19/1415Reactant delivery systems
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/14Other methods of shaping glass by gas- or vapour- phase reaction processes
    • C03B19/1453Thermal after-treatment of the shaped article, e.g. dehydrating, consolidating, sintering
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/01446Thermal after-treatment of preforms, e.g. dehydrating, consolidating, sintering
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/0148Means for heating preforms during or immediately prior to deposition
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/0005Other surface treatment of glass not in the form of fibres or filaments by irradiation
    • C03C23/0025Other surface treatment of glass not in the form of fibres or filaments by irradiation by a laser beam
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/10Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type
    • G02B6/12Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings of the optical waveguide type of the integrated circuit kind
    • G02B6/13Integrated optical circuits characterised by the manufacturing method
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00Type of glass produced
    • C03B2201/06Doped silica-based glasses

Abstract

A method of fabricating an optical device having a prescribed refractive index profile, comprises forming a surface with an initial refractive index formation and altering it by directing a laser beam onto the surface, either as it is formed or afterwards, so as to selectively evaporate material from a predetermined part of the surface. The refractive index profile of a growing soot form fabricated by the axial vapor deposition method is altered by evaporating the index modifying dopant from selected portion of the form. In an illustrative embodiment of the invention described, a laser beam (17) is used to "write" the desired pattern on the growing form (10). The technique can be employed to fabricate optical fiber preforms as well as two and three dimensional integrated optical devices and circuits. <IMAGE>

Description

SPECIFICATION Optical device and preform fabrication This invention relates to a method of fabricating optical devices and optical fiber preforms.
Various techniques for fabricating integrated optical devices and optical fiber are well known.
For example, integrated optical directional couplers are fabricated using conformable mask exposure techniques. To obtain high switching rates, however, very small devices, with spacings of the order of one micron, are required. This, in turn, requires that the masks be made with a high degree of precision in order to obtain these small spacings.
An illustration technique for making optical fiber preforms, from which optical fibers are drawn, is the so-called "Modified Chemical Vapor Deposition" (MCVD) process in which a precursor, in the form of a gas containing glass forming materials and suitable index modifying dopants, is caused to flow into a preform substrate tube wherein it is heated. This causes a layer of glass to be deposited on the inner surface of the tube. The thickness of each deposited layer, and the concentration of dopants within each layer are functions of a number of parameters, all of which must be carefully controlled in order to obtain a fiber with the desired index profile.
Copending G.B. Application No. 8319566 describes the Downward Axial Vapor-phase Deposition (DAVD) method of fabricating soot forms. These forms, when consolidated by heating, produce glass preforms from which optical fibres can be drawn. As noted in the abovecited application, the DAVD process produces a well defined, circular cylindrical soot form with a planar growing surface.
In accordance with the present invention, there is provided a method of fabricating an optical device having a prescribed refractive index profile, said method comprising forming a surface with an initial refractive index formation, and altering said initial refractive index by directing at least one laser beam onto the surface, either as the latter is formed or after it has been formed, so as to selectively evaporate material from a predetermined part of said surface.
The refractive index profile of the growing soot form in the preferred embodiment of the invention is altered by evaporating the index modifying dopants from selected portions of the form. In the illustrative embodiment of the invention described hereinbelow, the growing surface of the soot form is heated locally by a focussed laser beam which "writes" the desired index profile on the growing form. By controlling the motion of the laser beam and its intensity, any desired index profile can be obtained.
For a better understanding of the invention, reference is made to the accompanying drawings, in which: FIG. 1 shows an arrangement for controlling the index profile of soot forms in accordance with the preferred embodiment of the present invention; FIG. 2 shows the method of forming a lower index region in a growing soot form; FIG. 3 shows an arrangement for fabricating more complex index profiles employing a plurality of laser beams: FIG. 4 shows the fabrication of an optical directional coupler in accordance with the teachings of the invention; FIG. 5 shows the removal of a chip from a consolidated soot form; FIGS. 6 and 7 show three dimensional optical circuits; FIG. 8 shows a multilayered chip in which the refractive indices of adjacent chips are different; and FIG. 9 shows a generalized arrangement for practicing the invention.
For purposes of illustration and explanation, the DAVD method of fabricating soot forms can be employed, although other forms of VAD systems may be used. In accordance with this method, the form 10 is grown on a silica starting member 11 which is rotated about its vertical axis, as indicated by arrow 1 2. Means, not shown, are also provided for causing the starting member to move in a downward direction, indicated by arrow 13, as the soot form grows so as to maintain the growing surface 1 6 at a fixed location relative to the flame 14.
Raw material, such as SiCI4, GeCI4, POCI4, oxygen and hydrogen are fed into a torch 15, which produces fine glass particles by the flame hydrolysis reaction. Initially the particles are deposited onto the end of the starting member 11.
As the soot form grows, the glass particles are deposited upon the surface of the downward drawn, axially growing form.
To control the refractive index profile across the growing form, a laser beam 1 7 is directed as shown in Fig. 1 onto the growing surface 1 6 of the form. The beam, derived from a suitable source 1 8 such as a CO2 laser, is directed onto surface 1 6 by means of an oscillating mirror 1 9 that is free to rotate about an axis Z-Z that lies in the plane of the mirror. By means of this motion, the beam can be made to trace a pattern across surface 1 6. The effect of the beam impinging upon the growing surface is to heat the surface portion being written upon sufficiently to evaporate the index modifying dopant.This results in a change in the refractive index relative to that of the surrounding area. For example, to make an optical fiber preform having a step index profile by the MCVD process, a first plurality of layers having a first refractive index are deposited, followed by a plurality of layers having a second, higher index. The starting tube is then collapsed to form a solid rod. As is known, slight variation in the deposition of successive layers, plus the usual center dip result in a relatively irregular index profile.
In this embodiment, the preform is built up as a solid of uniform refractive index composition. The lower index cladding is then formed by evaporating some of the index increasing dopant, as shown in FIG. 2. This Figure shows laser beam 17 being directed onto the growing surface 16 of soot form 10 by mirror 1 9. In particular, the beam is focussed onto a point at a distance R from the center of form 10 by suitable means represented by lens 20. The intensity of the beam, and hence the amount of dopant evaporated, is controlled by means of an attenuator 21 located in the beam path. The width, w, of the cladding is controlled by the oscillation of the mirror 1 9 which causes the beam to scan the interval between R and R + t. As the form rotates, the scanning beam sweeps a circular path to form the cladding of a step index fiber having a core of radius R and a cladding of width w.
A more complicated profile, such as quadruple class fiber can be fabricated by the simultaneous use of a plurality of beams and mirrors. Such an arrangement is illustrated in FIG. 3 wherein a laser beam 9 is divided into four beams 9-1, 9-2, 9-3 and 9-4 by means of beam splitters 30, 31 and 32. The beams are directed onto four oscillating mirrors 1 9-1, 1 9-2, 1 9-3 and 19-4 by means of mirrors 34j 35 and 36. The oscillating mirrors, in turn. direct the four beams onto the rotating growing surface 1 6 of soot form 10. In particular, beam 9-1 is directed onto the soot form so as to scan an annular portion between radii R1 and R2. Beam 9-2 scans between radii R2 and R3.Beam 9-3 scans between R3 and R4, and beam 9-4 scans between R4 and R5. The intensity of each beam is controlled, respectively, by an attenuator 21-1, 21-2, 21-3 and 21-4 to produce the desired index profile.
The invention can also be used to fabricate integrated optical devices such as directional couplers, Y junctions and other novel circuit configurations. For example, to form a directional coupler, the laser beam 1 7 scans a pair of arcs 40 and 41 across the soot form, as shown in FIG. 4.
After the desired pattern has been written into the soot form and the latter has been consolidated, the resulting rod is either sliced, if it has the desired physical dimensions, or it can first be drawn to reduce its dimensions and then sliced to obtain the integrated optical chip. This is illustrated in FIG. 5 wherein the consolidated and, if necessary, drawn soot form 60 has been cut and a chip 61 obtained.
It is an advantage of that embodiment that three dimensional optical circuits of various forms can be readily fabricated, as illustrated in FIG. 6, which shows a chip 70 upon which there is formed a first directional coupler 71 and a second directional coupler 72, separated by a thickness t of substrate. The two couplers can be the same or different than ali others, and each of the four waveguiding strips can be in coupling relationship with each other. By adding pairs of electrodes 73-1, 73-2 and 74-1, 74-2 to the chip, a three dimensional switch can be obtained. It is apparent that this technique can be employed to fabricate other types of three dimensional circuit configurations. For example, an internal (i.e., embedded) optical path can be provided, as indicated in FIG. 7.For purposes of illustration, FIG. 7 shows a three dimensional integrated optical chip 80 having a directional coupler 81 formed on its upper surface 84 and an optical path 82 which runs within the chip substrate from one end of one of the coupler wavepaths 83 to the outer surface 85 of the chip.
FIG. 8 shows a chip 90 in which various layers 91, 92 and 93 have different refractive indices or different compositions, obtained by changing dopants during deposition. These are, in addition, selectively scanned to fabricate optical lasers, amplifiers and LEDs.
FIG. 9 shows a generalized arrangement for practicing the invention comprising a pair of mirrors 100 and 101 supported so as to oscillate about mutually orthogonal axes under the control of motors 110 and 111, respectfully. Also shown is a laser source 104 and a growing soot form 103 that is rotated about its vertical axis by a third motor 112.
The position of the laser beam. the rate at which the soot form rotates and control of the laser output are determined by a controller 11 3 which, in its most general form, can be a computer programmed to produce the desired index patterns. (Laser beam positioning devices are sold commercially. See, for example, products offered by General Scanning, Inc. of Watertown, Maine.) Depending upon the pattern to be laid down, the process can proceed continuously or operate in an incremental fashion. It should be noted that the DAVD process can be started and stopped without any difficulty so that the beam can be made to scan the soot form surface while the latter is either in motion or at rest. If stopped, the DAVD process can then be restarted and additional soot deposited while the scanning proceeds incrementally or continuously.
The amount of laser power required to evaporate material from the soot form will, of course, depend upon the material involved. For example, germanium doped silica is deposited within the temperature range from 300 to 800 degrees F. However, germanium will evaporate at 900 degrees F. Therefor, in this case, it is obvious that a temperature rise of 900 degrees F is not required.

Claims (17)

1. A method of fabricating an optical device having a prescribed refractive index profile, said method comprising forming a surface with an initial refractive index formation, and altering said initial refractive index by directing at least one laser beam onto the surface, either as the latter is formed or after it has been formed, so as to selectively evaporate material from a predetermined path of said surface.
2. A method according to claim 1, wherein the initial refractive index formation is of constant refractive index.
3. A method according to claim 2, wherein the optical device is a glass soot form in which the soot, capable of being consolidated into a glass, is directed onto the growing end surface of the soot form.
4. The method according to claim 3, wherein said soot is directed in a downward direction onto said growing end surface as said form is rotating about an axis that is perpendicular, and wherein said laser beam scans across at least a portion of said end surface.
5. The method according to claim 4, wherein said laser beam scans an annular region over said end surface to form a first region of lower refractive index adjacent a second region of higher refractive index.
6. The method according to claim 3, wherein a plurality of laser beams are directed onto said growing end surface.
7. The method according to claim 6, wherein each beam scans an annular region of different radii.
8. The method according to claim 7, wherein each beam has an intensity which is different from that of the other beams.
9. The method according to claim 3, wherein the soot and the laser beam are directed onto said end surface either sequentially or simultaneously.
10. The method according to claim 3, wherein the refractive index is caused to vary along the direction of form growth and/or in the direction perpendicular to the direction of form growth.
11. The method according to claim 3, wherein the composition of said soot form is varied along the direction of form growth.
12. The method according to claim 1, said regions extend along the surfaces of said portion and within the interior of said portion to form three dimensional optical circuits.
13. A method according to claim 1, wherein the optical device is a three dimensional, integrated optical chip, wherein the initial surface is of constant refractive index formed on a surface, and wherein waveguiding regions of lower refractive index extend along at least two surfaces of said chip.
14. The method according to claim 13, wherein at least one waveguiding region on one of said surfaces is in coupling relationship with at least one waveguiding region on the other of said surfaces.
1 5. The method according to claim 13, wherein said waveguiding regions form a first optical directional coupler along a first of said surfaces and a second optical directional coupler along a second of said surfaces; and wherein the waveguiding regions of said two directional couplers are in coupling relationship to form a three dimensional coupling array.
16. The method according to claim 15, comprising varying the refractive index along said waveguiding regions as to to control the coupling among said regions.
17. A method of fabricating an optical device, substantially as hereinbefore described with reference to any one of the figures of the accompanying drawing.
1 8. A three dimensional, integrated optical chip comprising a substrate having a first refractive index; wherein waveguiding regions of lower refractive index extend along a surface of said chip and are embedded within the body of said chip.
1 9. An optical device prepared by the method according toany one of claims 1 to 17.
GB08331538A 1982-12-02 1983-11-25 Optical device and preform fabrication Expired GB2131417B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US44632782A 1982-12-02 1982-12-02

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GB8331538D0 GB8331538D0 (en) 1984-01-04
GB2131417A true GB2131417A (en) 1984-06-20
GB2131417B GB2131417B (en) 1987-04-08

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JP (1) JPS59111941A (en)
DE (1) DE3343549A1 (en)
FR (1) FR2537291B1 (en)
GB (1) GB2131417B (en)
IT (1) IT1168733B (en)
NL (1) NL8304128A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2180667A (en) * 1985-09-23 1987-04-01 Gen Electric Plc Manufacture of channel waveguides
GB2182349A (en) * 1985-11-05 1987-05-13 Sec Dep For Trade & Industry T Laser coating with inorganic materials
GB2189901A (en) * 1986-04-25 1987-11-04 Stc Plc Laser-induced fibre grating devices
GB2210470A (en) * 1987-09-25 1989-06-07 Plessey Co Plc Inducing refractive index changes in localized regions of optical fibres
EP0391598A1 (en) * 1989-04-05 1990-10-10 AT&T Corp. Method and apparatus for fabricating microlenses on optical fibers
US5653900A (en) * 1991-01-17 1997-08-05 United Distillers Plc Dynamic laser marking
EP1183214A1 (en) * 1999-04-09 2002-03-06 The University of New Mexico Large photosensitivity in lead silicate glasses
US6791592B2 (en) 2000-04-18 2004-09-14 Laserink Printing a code on a product
US10583668B2 (en) 2018-08-07 2020-03-10 Markem-Imaje Corporation Symbol grouping and striping for wide field matrix laser marking

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63217307A (en) * 1987-03-06 1988-09-09 Hitachi Ltd Optical multiplexer/demultiplexer and its manufacture
JPS63223712A (en) * 1987-03-13 1988-09-19 Hitachi Ltd Light guide and its production
JPH0196604A (en) * 1987-10-09 1989-04-14 Hitachi Ltd Optical waveguide and its manufacture
DE3739189A1 (en) * 1987-11-19 1989-06-01 Rheydt Kabelwerk Ag Process for collapsing preforms for optical waveguides

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1490700A (en) * 1973-12-20 1977-11-02 Standard Telephones Cables Ltd Optical fibre preform manufacture
NL165134B (en) * 1974-04-24 1980-10-15 Nippon Telegraph & Telephone METHOD FOR MANUFACTURING A BAR AS AN INTERMEDIATE FOR THE MANUFACTURE OF AN OPTICAL FIBER AND METHOD FOR MANUFACTURING AN OPTICAL FIBER FROM SUCH AN INTERMEDIATE.
DE2605483A1 (en) * 1976-02-12 1977-08-18 Licentia Gmbh Photoconductor having radially decreasing refractive index - formed on heated rotating glass rod using heat decomposing gases
GB1574115A (en) * 1978-05-18 1980-09-03 Standard Telephones Cables Ltd Optical fibre manufacture

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2180667B (en) * 1985-09-23 1989-09-13 Gen Electric Plc The manufacture of channel waveguides
GB2180667A (en) * 1985-09-23 1987-04-01 Gen Electric Plc Manufacture of channel waveguides
GB2182349A (en) * 1985-11-05 1987-05-13 Sec Dep For Trade & Industry T Laser coating with inorganic materials
GB2189901B (en) * 1986-04-25 1989-12-06 Stc Plc Laser induced optical fibre grating devices.
US4793680A (en) * 1986-04-25 1988-12-27 Stc Plc Induced grating devices and method of making same
GB2189901A (en) * 1986-04-25 1987-11-04 Stc Plc Laser-induced fibre grating devices
GB2210470A (en) * 1987-09-25 1989-06-07 Plessey Co Plc Inducing refractive index changes in localized regions of optical fibres
EP0391598A1 (en) * 1989-04-05 1990-10-10 AT&T Corp. Method and apparatus for fabricating microlenses on optical fibers
US5653900A (en) * 1991-01-17 1997-08-05 United Distillers Plc Dynamic laser marking
EP1183214A1 (en) * 1999-04-09 2002-03-06 The University of New Mexico Large photosensitivity in lead silicate glasses
EP1183214A4 (en) * 1999-04-09 2008-12-17 Univ New Mexico Large photosensitivity in lead silicate glasses
US6791592B2 (en) 2000-04-18 2004-09-14 Laserink Printing a code on a product
US6829000B2 (en) 2000-04-18 2004-12-07 Laserink Printing a code on a product
US10583668B2 (en) 2018-08-07 2020-03-10 Markem-Imaje Corporation Symbol grouping and striping for wide field matrix laser marking

Also Published As

Publication number Publication date
IT8323988A0 (en) 1983-12-01
DE3343549A1 (en) 1984-06-07
JPS59111941A (en) 1984-06-28
NL8304128A (en) 1984-07-02
IT8323988A1 (en) 1985-06-01
FR2537291B1 (en) 1988-02-12
GB2131417B (en) 1987-04-08
IT1168733B (en) 1987-05-20
FR2537291A1 (en) 1984-06-08
GB8331538D0 (en) 1984-01-04

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