GB2118939B - Conversion of alkanes to unsaturated aldehydes - Google Patents
Conversion of alkanes to unsaturated aldehydesInfo
- Publication number
- GB2118939B GB2118939B GB08310123A GB8310123A GB2118939B GB 2118939 B GB2118939 B GB 2118939B GB 08310123 A GB08310123 A GB 08310123A GB 8310123 A GB8310123 A GB 8310123A GB 2118939 B GB2118939 B GB 2118939B
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkanes
- conversion
- unsaturated aldehydes
- aldehydes
- unsaturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001299 aldehydes Chemical class 0.000 title 1
- 150000001335 aliphatic alkanes Chemical class 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
- B01J27/192—Molybdenum with bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3332—Catalytic processes with metal oxides or metal sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/368,196 US4413147A (en) | 1982-04-14 | 1982-04-14 | Conversion of isobutane to methacrolein |
US06/420,077 US4535188A (en) | 1982-04-14 | 1982-09-20 | Conversion of isobutane to methacrolein |
US06/468,524 US4532365A (en) | 1982-09-20 | 1983-02-22 | Conversion of alkanes to unsaturated aldehydes |
Publications (3)
Publication Number | Publication Date |
---|---|
GB8310123D0 GB8310123D0 (en) | 1983-05-18 |
GB2118939A GB2118939A (en) | 1983-11-09 |
GB2118939B true GB2118939B (en) | 1986-04-30 |
Family
ID=27408852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB08310123A Expired GB2118939B (en) | 1982-04-14 | 1983-04-14 | Conversion of alkanes to unsaturated aldehydes |
Country Status (8)
Country | Link |
---|---|
AU (1) | AU560458B2 (en) |
BR (1) | BR8301915A (en) |
CA (1) | CA1217502A (en) |
DE (1) | DE3313573C2 (en) |
FR (1) | FR2525212B1 (en) |
GB (1) | GB2118939B (en) |
IT (1) | IT1167404B (en) |
NL (1) | NL8301303A (en) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3461782D1 (en) * | 1983-02-22 | 1987-02-05 | Halcon Sd Group Inc | Conversion of propane to acrylic acid |
DE3800991A1 (en) * | 1988-01-15 | 1989-07-27 | Basf Ag | METHOD FOR THE PRODUCTION OF (ALPHA), (BETA) -MONOOLEFINICALLY UNSATURATED 3 TO 4 C-ATOMES CONTAINING CARBONIC ACIDS BY GAS PHASE OXIDATION |
ES2139266T3 (en) * | 1995-03-10 | 2000-02-01 | Basf Ag | PROCEDURE FOR THE OBTAINING OF ACROLEIN, ACRYLIC ACID, OR ITS MIXTURE FROM PROPANE. |
US6492548B1 (en) | 1996-04-01 | 2002-12-10 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the oxidation of alkanes |
EP0938463B1 (en) * | 1996-04-01 | 2002-06-19 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for the oxidation of alkanes |
DE19837517A1 (en) | 1998-08-19 | 2000-02-24 | Basf Ag | Production of acrolein and/or acrylic acid involves two stage catalytic oxydehydrogenation of propane, using modified air with less nitrogen and more oxygen than normal air as the oxygen source |
DE19837519A1 (en) | 1998-08-19 | 2000-02-24 | Basf Ag | Production of acrolein and/or acrylic acid involves two stage catalytic oxydehydrogenation of propane, using air as the oxygen source and removing nitrogen from residual gas before recycling |
DE10028582A1 (en) * | 2000-06-14 | 2001-12-20 | Basf Ag | Production of acrolein or acrylic acid from propane, involves partial gas-phase dehydrogenation, removal of hydrogen and partial gas-phase oxidation of propene with nitrogen as diluent, and recycling of unreacted propane |
KR100740728B1 (en) | 2000-06-14 | 2007-07-19 | 바스프 악티엔게젤샤프트 | Method for Producing Acrolein and/or Acrylic Acid |
DE10131297A1 (en) * | 2001-06-29 | 2003-01-09 | Basf Ag | Production of partial (ammo)oxidation products of an olefinic hydrocarbon, useful for acrolein/acrylic acid from propane, comprises intermittent supplementation of olefin from another source. |
JP2004530723A (en) * | 2001-06-29 | 2004-10-07 | ビーエーエスエフ アクチェンゲゼルシャフト | Method for producing methacrolein from isobutane |
CN1219737C (en) * | 2001-06-29 | 2005-09-21 | 巴斯福股份公司 | Method for producing methacrolein from isobutane |
DE10316039A1 (en) | 2003-04-07 | 2004-10-21 | Basf Ag | Preparation of at least one partial oxidation and/or ammoxidation product of a hydrocarbon e.g. isobutane involves partially dehydrogenating saturated hydrocarbon under heterogeneous catalysis |
US7592483B2 (en) | 2004-07-01 | 2009-09-22 | Basf Aktiengesellschaft | Preparation of acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas phase oxidation of propylene |
US7601866B2 (en) | 2005-03-01 | 2009-10-13 | Basf Aktiengesellschaft | Process for removing methacrolein from liquid phase comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component |
US7705181B2 (en) | 2005-03-01 | 2010-04-27 | Basf Akiengesellschaft | Process for removing methacrylic acid from liquid phase comprising acrylic acid as a main constituent and target product, and methacrylic acid as a secondary component |
DE502006003491D1 (en) | 2005-11-03 | 2009-05-28 | Basf Se | METHOD FOR THE STABLE OPERATION OF A CONTINUOUS EXTRACTION PROCESS FOR THE PRODUCTION OF ACROLEINE, OR ACRYLIC ACID OR THEIR PROPANE MIXTURE |
MY143542A (en) * | 2005-11-24 | 2011-05-31 | Basf Se | Process for preparing acrolein or acrylic acid or a mixture thereof from propane |
KR101370749B1 (en) * | 2005-11-24 | 2014-03-06 | 바스프 에스이 | Process for preparing acrolein or acrylic acid or a mixture thereof from propane |
DE102005062026A1 (en) | 2005-12-22 | 2007-06-28 | Basf Ag | Catalytic partial gas phase oxidation of propylene to acrylic acid comprises introducing propylene, oxygen and inert dilution gas into first reaction zone, adding secondary gas and introducing the mixture into second reaction stage |
DE102005062010A1 (en) | 2005-12-22 | 2007-06-28 | Basf Ag | Heterogeneously catalyzed partial gas phase oxidation of propylene to acrylic acid comprises introducing a reaction gas mixture into a reaction zone, and transferring the product gas mixture into a condensed phase and a separation zone |
DE102006024901A1 (en) | 2006-05-24 | 2007-11-29 | Basf Ag | Preparing acrylic acid comprises supplying propane gas to a zone to give a gas containing e.g. propylene, supplying molecular oxygen, feeding oxidation reactor with another gas containing e.g. propylene and subjecting the gas to oxidation |
DE102007006647A1 (en) | 2007-02-06 | 2008-08-07 | Basf Se | Process for the regeneration of a catalyst bed deactivated in the context of a heterogeneously catalyzed partial dehydrogenation of a hydrocarbon |
WO2009028292A1 (en) * | 2007-08-30 | 2009-03-05 | Nippon Shokubai Co., Ltd. | Process for producing acrylic acid |
DE102007043758A1 (en) | 2007-09-13 | 2008-10-23 | Basf Se | Target product continuous separating operation in form of fine crystals from liquid phase, includes heat exchanger having secondary space and primary space |
BE1018537A3 (en) | 2007-09-13 | 2011-03-01 | Basf Se | METHOD FOR OPERATING A CONTINUOUS SEPARATION OF TARGET PRODUCT X IN THE FORM OF A FINALLY DIVIDED CRYSTALLISATE |
DE102007043759A1 (en) | 2007-09-13 | 2008-09-11 | Basf Se | Procedure for continuous separation of target product in the form of fine particle of crystallisate, comprises indirectly operating a heat exchanger having primary and secondary areas, which are spatially separated with one another |
DE102007043748A1 (en) | 2007-09-13 | 2008-09-11 | Basf Se | Method for separating target product i.e. acrylic acid, methacrylic acid, p-xylene or N-vinylpyrrolidone in form of fine crystallized product, involves utilizing heat exchanger, where heat flow is gathered from heat exchanger |
DE102008044946B4 (en) | 2008-08-29 | 2022-06-15 | Evonik Superabsorber Gmbh | Use of foam bodies in oxidation reactors for the production of unsaturated carboxylic acids |
FR2952053B1 (en) | 2009-11-02 | 2011-12-16 | Air Liquide | PROCESS AND DEVICE FOR PRODUCING ALKENES DERIVATIVES |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3161670A (en) * | 1960-12-12 | 1964-12-15 | Shell Oil Co | Preparation of olefinic compounds |
BE623670R (en) * | 1962-07-06 | 1963-04-16 | Stamicarbon | Process for preparing acrolein or methacrolein by catalytic oxidation of propene or isobutene |
GB1426303A (en) * | 1972-08-25 | 1976-02-25 | Ube Industries | Catalyst and process for oxidation of ammoxidation of olefin mixtures |
GB1467865A (en) * | 1973-07-27 | 1977-03-23 | Basf Ag | Catalytic oxidation or ammoxidation of a-olefins to alpha,beta- olefinically unsaturated aldehydes acids or nitriles |
JPS5341648B2 (en) * | 1974-12-06 | 1978-11-06 | ||
US4335264A (en) * | 1976-07-07 | 1982-06-15 | E. I. Du Pont De Nemours And Company | High yield, low byproduct α, β-unsaturated aldehydes from olefins |
US4217309A (en) * | 1978-06-12 | 1980-08-12 | Ube Industries, Ltd. | Process for producing methacrolein |
-
1983
- 1983-04-12 CA CA000425653A patent/CA1217502A/en not_active Expired
- 1983-04-13 FR FR8306052A patent/FR2525212B1/en not_active Expired
- 1983-04-13 IT IT48091/83A patent/IT1167404B/en active
- 1983-04-13 AU AU13492/83A patent/AU560458B2/en not_active Ceased
- 1983-04-14 GB GB08310123A patent/GB2118939B/en not_active Expired
- 1983-04-14 NL NL8301303A patent/NL8301303A/en not_active Application Discontinuation
- 1983-04-14 BR BR8301915A patent/BR8301915A/en unknown
- 1983-04-14 DE DE3313573A patent/DE3313573C2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR2525212B1 (en) | 1986-12-05 |
AU1349283A (en) | 1983-10-20 |
FR2525212A1 (en) | 1983-10-21 |
DE3313573C2 (en) | 1987-05-07 |
GB8310123D0 (en) | 1983-05-18 |
CA1217502A (en) | 1987-02-03 |
NL8301303A (en) | 1983-11-01 |
IT1167404B (en) | 1987-05-13 |
AU560458B2 (en) | 1987-04-09 |
GB2118939A (en) | 1983-11-09 |
BR8301915A (en) | 1983-12-20 |
DE3313573A1 (en) | 1983-10-20 |
IT8348091A0 (en) | 1983-04-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB2118939B (en) | Conversion of alkanes to unsaturated aldehydes | |
JPS5576825A (en) | Conversion of dimethylether | |
DE3370150D1 (en) | Process for the conversion of linear butenes to propylene | |
AU1532383A (en) | Conversion of methanol to petrochemicals | |
JPS5772959A (en) | Conversion of dialkylsulfide to alkylmercaptane | |
GB2030885B (en) | Catalysts for the preparation of unsalturated aldehydes | |
GB2064352B (en) | Preparation of copper-zinc aluminium catalyst compositions | |
GB8327495D0 (en) | Preparation of alcohols by hydration of olefins | |
AU562524B2 (en) | Catalytic conversion of c2-c5 olefines | |
GB2028367B (en) | Conversion of solid fuels into fluid fuels | |
JPS54115331A (en) | Catalytic isomerization of oocresol | |
ZA79758B (en) | Passivation of cracking catalyst | |
JPS5560586A (en) | Utilization of purification residue | |
GB2127403B (en) | Production of unsaturated alcohols | |
ZA836350B (en) | Gypsum conversion | |
JPS54127833A (en) | Purification of gold | |
ZA836997B (en) | Catalytic conversion of methanol into light olefins | |
JPS55351A (en) | Oxoosynthesis of olefin | |
GB2079277B (en) | Conversion of olefins to unsaturated esters | |
JPS54138588A (en) | Conversion of 10*111epoxyy10*111dihydroo5hhdibenz*b*f*azepinn55carboxamide to 100oxoo10*111dihydroo5hhdibenz*b*f*azepinn55carboxamide | |
JPS57203026A (en) | Conversion of hexafluorothioacetone dimer to hexafluoroacetone | |
JPS559076A (en) | Purification of propylene | |
ZA839354B (en) | Conversion of methanol and methyl ether to light olefins | |
JPS5541201A (en) | Preparation of honeycomb | |
GB8323073D0 (en) | Gypsum conversion |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |