GB2098195A - Gun propellants - Google Patents
Gun propellants Download PDFInfo
- Publication number
- GB2098195A GB2098195A GB8114170A GB8114170A GB2098195A GB 2098195 A GB2098195 A GB 2098195A GB 8114170 A GB8114170 A GB 8114170A GB 8114170 A GB8114170 A GB 8114170A GB 2098195 A GB2098195 A GB 2098195A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight percent
- propellant
- gap
- propellants
- hmx
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/18—Compositions containing a nitrated organic compound the compound being nitrocellulose present as 10% or more by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/04—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive
- C06B45/06—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component
- C06B45/10—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component the organic component containing a resin
- C06B45/105—The resin being a polymer bearing energetic groups or containing a soluble organic explosive
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A propellant composition comprises polyglycidyl azide and nitrocellulose. The composition may also contain resorcinol as a stabiliser. There may also be present cyclotetramethylene tetranitramine (HMX) and/or triaminoguanidine nitrate (TAGN). This family of propellant compositions is said to combine reduced flame temperatures with high mass impetus.
Description
SPECIFICATION
Gun propellants
Background of the Invention
1. Field of the invention
This invention relates to propellants and is particularly directed to gun propellant formulations employing a copolymer of polyglycidyl azide (GAP) and nitrocellulose (NC) to provide low isochoric flame temperatures and high mass impetus.
2. Description of the Prior Art
Considerable advances have been realized in the area of improved gun propellants during the last ten years. The conventional gun propellants described in U. S. Army Propellant Manual No.
AMCP-706-150, published February 1965, are based upon nitrocellulose, nitroglycerin (NG), and nitroguanidine (NQ).
Improvements in performance over those listed in Manual No. AMCP-706-150 have been made by incorporating triaminoguanidine nitrate (TAGN) and cyclotetramethylene tetranitramine (HMX) into the basic nitrocellulose matrix as described in U.S. Patents 3,732,130; 3,732,131 and 3,909,323.
However, while the advanced propellants based upon TAGN/HMX/NC yield higher performance, these propellants generally contain more of the solid oxidizers (TAGN and HMX) on a weight basis than the binder (NC). This, in turn, can lead to erratic ballistics at extreme weather conditions where the propellant is subjected to very low temperatures (less than - 25"F). Due to the low level of polymer (binder) present, the propellant can become brittle and crack, thereby exposing larger areas for instantaneous burning. This results in overpressures in the gun breech.
In a similar manner, propellants which are to be inhibited according to U.S. Patent 3,948,697 must rely on the residual hydroxyl groups in nitrocellulose for superior surface bonding. Incorporation of plasticizers which contain additional hydroxyl groups, such as polyethelene glycol, drastically lower the overall propellant performance since the heat of formation of the plasticizer is degraded by hydroxyl moieties.
Summary of the Invention
Accordingly, there is provided by the present invention a family of propellants having low isochoric flame temperature and high mass impetus. These propellants basically comprise nitrocellulose and polyglycidyl azide. Additionally, they may be solids loaded with TAGN and/or
HMX. Although primarily designed as a gun propellant, the addition of various propellant adjuvants will enhance the ballistic, chemical, and physical properties such that the propellant composition can be used in other pyrotechnic devices.
Objects of the Invention
Accordingly, it is an object of the present invention to provide improved propellants.
Another object of the present invention is to provide improved gun propellants.
Yet another object of the present invention is to provide gun propellants having high mass impetus and superior properties at low ambient temperatures.
A specific object of the present invention is to provide gun propellant formulations employing
GAP as a copolymer with NC.
Description of the Preferred Embodiments
In accordance with the present invention there is provided a propellant which comprises nitrocellulose (NC) and polyglycidyl azide (GAP). Basically, the polyglycidyl azide is used as an energetic binder and comprises a hydroxy-terminated aliphatic polyether having pendent alkyl azide groups. The GAP energetic binder is more fully described in copending U.S. patent application S.N. 4,978, filed January 8, 1979.
The NC/GAP propellant can be prepared having a ratio of ingredients ranging from one part
NC to two parts GAP up to four parts NC to one part GAP. The preferred range would be from about 55 to about 85 weight percent NC and from about 45 to about 1 5 weight percent GAP.
In addition, trace amounts up to about 0.5 weight percent of resorcinol stabilizer should be added.
The mass impetus of the NC/GAP based propellants can be increased by solids loading of the subject propellant. One such family of solids loaded propellants comprises from about 10 to about 40 weight percent NC, about 1 5 to about 30 weight percent GAP, from about 20 to about 70 weight percent HMX, and from about 0.2 to about 0.5 weight percent resorcinol.
Another family of solids loaded NC/GAP based propellants comprises from about 10 to about 40 weight percent NC, from about 1 5 to about 30 weight percent GAP, from about 20 to about 75 weight percent TAGN, from about 5 to about 55 weight percent HMX, and from about 0.2 to about 0.5 weight percent resorcinol.
A comparison of the NC/GAP propellant family with NC/NG and TAGN/HMX/NC propellants is given in Table 1.
TABLE 1
Mass Impetus Flame Molecular
Propellant Type ft-lb/lb Temperature Weight
NC 305,000 2417"K 22.06 NC no 339,000 3000"K 24.58 Non-Solids NC/GAP 327,000 2321 'K 19.74 Loaded : (1.5 to 1) NC/GAP 342,000 2647"K 21.55 (4to 1) I NC/NG/NQ 336,000 2594"K 21.53 NC/TAGN/ 352,000 2483"K 19.60 Solids Loaded q HMX NC/GAP/ 370,000 2595"K 19.51 TAGN/HMX By way of illustration and not limitation, the following examples are given:
EXAMPLE 1
In accordance with the present invention, a gun propellant was formulated consisting of 60% by weight of NC, 40% by weight of GAP.This propellant yielded an isochoric flame temperature of 2321 K, a mass impetus of 327,000 ft-lbs/lb, and a molecular weight of 19.74.
EXAMPLE II
A gun propellant was formulated consisting of 80% by weight of NC, 20% by weight of GAP.
This propellant yielded an isochoric flame temperature of 2647"K, a mass impetus of 342,000 ft-lbs/lb, and a molecular weight of 21.55.
EXAMPLE 111
A gun propellant was formulated consisting of 38% by weight of NC, 20% by weight of GAP, 20% by weight of TAGN, and 22% by weight of HMX. This propellant yielded an isochoric flame temperature of 2483"K, a mass impetus of 352,000 ft-lbs/lb, and a molecular weight of 19.60.
Thus, it is apparent that there is provided by the present invention a nitrocellulose polyglycidyl azide based propellant.
It is to be understood that what has been described is merely illustrative of the principles of the invention and that the full scope of the disclosure and its various aspects will be apparent to those skilled in the art.
Claims (9)
1. A propellant comprising nitrocellulose (NC) and polyglycidyl azide (GAP).
2. The propellant of Claim 1 further comprising from about 0.2 to about 0.5 weight percent resorcinol stabilizers.
3. The propellant of Claim 1 or 2 wherein said nitrocellulose and said polyglycidyl azide are combined in a ratio which ranges from about one part NC to about two parts GAP to form about four parts NC to about one part GAP.
4. The propellant of Claim 3 wherein said NC ranges from about 55 to about 85 weight percent, said GAP ranges from about 45 to about 1 5 weight percent GAP.
5. The propellant of Claim 3 which comprises about 60 weight percent NC and about 40 weight percent GAP.
6. The propellant of Claim 3 which comprises about 80 weight percent NC and about 20 weight percent GAP.
7. The propellant of Claims 1 or 2 which comprises from about 10 to about 40 weight percent NC, from about 1 5 to about 30 weight percent GAP, and from about 20 to about 70 weight percent cyclotetramethylene tetranitramine.
8. The propellant of Claims 1 or 2 which comprises from about 10 to about 40 weight percent NC, from about 1 5 to about 30 weight percent GAP, from about 5 to about 35 weight percent cyclotetramethylene tetranitramine (HMX).
9. The propellant of Claim 8 which comprises about 38 weight percent NC, about 20 weight percent GAP, about 20 weight percent TAGN, and about 22 weight percent HMX.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8114170A GB2098195B (en) | 1981-05-08 | 1981-05-08 | Gun propellants |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8114170A GB2098195B (en) | 1981-05-08 | 1981-05-08 | Gun propellants |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2098195A true GB2098195A (en) | 1982-11-17 |
GB2098195B GB2098195B (en) | 1985-01-23 |
Family
ID=10521676
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8114170A Expired GB2098195B (en) | 1981-05-08 | 1981-05-08 | Gun propellants |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2098195B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2250739A (en) * | 1988-09-10 | 1992-06-17 | Diehl Gmbh & Co | Propellant for a hybrid weapon |
-
1981
- 1981-05-08 GB GB8114170A patent/GB2098195B/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2250739A (en) * | 1988-09-10 | 1992-06-17 | Diehl Gmbh & Co | Propellant for a hybrid weapon |
US5188682A (en) * | 1988-09-10 | 1993-02-23 | Diehl Gmbh & Co. | Propellent medium for hybrid weapon |
Also Published As
Publication number | Publication date |
---|---|
GB2098195B (en) | 1985-01-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4288262A (en) | Gun propellants containing polyglycidyl azide polymer | |
US5076868A (en) | High performance, low cost solid propellant compositions producing halogen free exhaust | |
US5348596A (en) | Solid propellant with non-crystalline polyether/inert plasticizer binder | |
JPH02157177A (en) | Solid rocket fuel | |
US5061330A (en) | Insensitive high energetic explosive formulations | |
US4216039A (en) | Smokeless propellant compositions having polyester or polybutadiene binder system crosslinked with nitrocellulose | |
CA2344232C (en) | Castable double base solid rocket propellant containing ballistic modifier pasted in an inert polymer | |
US4361450A (en) | Plastic bonded explosive compositions | |
US4570540A (en) | LOVA Type black powder propellant surrogate | |
US20170233306A1 (en) | Propellant compositions comprising nitramine oxidants | |
KR20000057253A (en) | Ammonium nitrate propellants with molecular sieve | |
US5798481A (en) | High energy TNAZ, nitrocellulose gun propellant | |
US3732130A (en) | Gun propellant containing nonenergetic plasticizer,nitrocellulose and triaminoguanidine nitrate | |
EP2978731B1 (en) | Non-phthalate propellants | |
GB2098195A (en) | Gun propellants | |
US3732131A (en) | Gun propellant containing nitroplasticized nitrocellulose and triaminoguanidine nitrate | |
CA1145947A (en) | Gun propellants containing polyglycidyl azide polymer | |
US3321341A (en) | Plastic explosive compositions | |
US5053087A (en) | Ultra high-energy azide containing gun propellants | |
US3957549A (en) | Low signature propellants based on acrylic prepolymer binder | |
US4239073A (en) | Propellants in caseless ammunition | |
CA2045926C (en) | Extrudable gun propellant composition | |
US4961380A (en) | Energetic azido eutectics | |
AU756219B2 (en) | High energy gun propellants | |
Singh et al. | Studies on low vulnerability gun propellants based on conventional binders and energetic plasticizers |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19960508 |