GB2057261A - Hair conditioning composition and method - Google Patents
Hair conditioning composition and method Download PDFInfo
- Publication number
- GB2057261A GB2057261A GB8021576A GB8021576A GB2057261A GB 2057261 A GB2057261 A GB 2057261A GB 8021576 A GB8021576 A GB 8021576A GB 8021576 A GB8021576 A GB 8021576A GB 2057261 A GB2057261 A GB 2057261A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- hair
- betaine
- conditioning
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 74
- 230000003750 conditioning effect Effects 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims description 18
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 14
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 5
- 239000008365 aqueous carrier Substances 0.000 claims abstract description 3
- 239000003599 detergent Substances 0.000 claims description 14
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 238000011282 treatment Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 7
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 5
- 229960003237 betaine Drugs 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- AMRBZKOCOOPYNY-QXMHVHEDSA-N 2-[dimethyl-[(z)-octadec-9-enyl]azaniumyl]acetate Chemical compound CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)CC([O-])=O AMRBZKOCOOPYNY-QXMHVHEDSA-N 0.000 claims description 4
- TYIOVYZMKITKRO-UHFFFAOYSA-N 2-[hexadecyl(dimethyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O TYIOVYZMKITKRO-UHFFFAOYSA-N 0.000 claims description 4
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 3
- HHLJUSLZGFYWKW-UHFFFAOYSA-N triethanolamine hydrochloride Chemical compound Cl.OCCN(CCO)CCO HHLJUSLZGFYWKW-UHFFFAOYSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 230000001143 conditioned effect Effects 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 229940094506 lauryl betaine Drugs 0.000 claims description 2
- XWAKKPDDQPWGAQ-UHFFFAOYSA-N n,n-dimethylbut-1-en-1-amine Chemical compound CCC=CN(C)C XWAKKPDDQPWGAQ-UHFFFAOYSA-N 0.000 claims description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 2
- 229920002717 polyvinylpyridine Polymers 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 150000005846 sugar alcohols Polymers 0.000 claims 1
- -1 amine compounds Chemical class 0.000 description 17
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 16
- 239000004615 ingredient Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 9
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000003205 fragrance Substances 0.000 description 9
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 9
- 235000011007 phosphoric acid Nutrition 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000002453 shampoo Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000008406 cosmetic ingredient Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 238000004061 bleaching Methods 0.000 description 4
- UKHVLWKBNNSRRR-ODZAUARKSA-M dowicil 200 Chemical compound [Cl-].C1N(C2)CN3CN2C[N+]1(C\C=C/Cl)C3 UKHVLWKBNNSRRR-ODZAUARKSA-M 0.000 description 4
- 229960002163 hydrogen peroxide Drugs 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- 229920001213 Polysorbate 20 Polymers 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 230000003766 combability Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 3
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 2
- SIHSSUWJKIEVGQ-UHFFFAOYSA-N 14-methyl-1-(14-methylpentadecoxy)pentadecane Chemical compound CC(C)CCCCCCCCCCCCCOCCCCCCCCCCCCCC(C)C SIHSSUWJKIEVGQ-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- AEDQNOLIADXSBB-UHFFFAOYSA-N 3-(dodecylazaniumyl)propanoate Chemical compound CCCCCCCCCCCCNCCC(O)=O AEDQNOLIADXSBB-UHFFFAOYSA-N 0.000 description 2
- XYYUAOIALFMRGY-UHFFFAOYSA-N 3-[2-carboxyethyl(dodecyl)amino]propanoic acid Chemical compound CCCCCCCCCCCCN(CCC(O)=O)CCC(O)=O XYYUAOIALFMRGY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229940068977 polysorbate 20 Drugs 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 235000010199 sorbic acid Nutrition 0.000 description 2
- 239000004334 sorbic acid Substances 0.000 description 2
- 229940075582 sorbic acid Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- HLNJFEXZDGURGZ-UHFFFAOYSA-M 1-methylpyridin-1-ium;iodide Chemical compound [I-].C[N+]1=CC=CC=C1 HLNJFEXZDGURGZ-UHFFFAOYSA-M 0.000 description 1
- FECNOIODIVNEKI-UHFFFAOYSA-N 2-[(2-aminobenzoyl)amino]benzoic acid Chemical class NC1=CC=CC=C1C(=O)NC1=CC=CC=C1C(O)=O FECNOIODIVNEKI-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- JYCQQPHGFMYQCF-UHFFFAOYSA-N 4-tert-Octylphenol monoethoxylate Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCO)C=C1 JYCQQPHGFMYQCF-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- JMRTYUSPEJKGQB-UHFFFAOYSA-N [NH4+].[Cl-].CCO.CCO.CCO Chemical class [NH4+].[Cl-].CCO.CCO.CCO JMRTYUSPEJKGQB-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000003113 alkalizing effect Effects 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000008135 aqueous vehicle Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- PASCYLAFGHJSHW-UHFFFAOYSA-N ethyl 2-[(4-methoxyphenyl)methyl]-3-(methylamino)propanoate Chemical compound CCOC(=O)C(CNC)CC1=CC=C(OC)C=C1 PASCYLAFGHJSHW-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 235000011167 hydrochloric acid Nutrition 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229940087419 nonoxynol-9 Drugs 0.000 description 1
- 229920004918 nonoxynol-9 Polymers 0.000 description 1
- 229940116390 octoxynol-1 Drugs 0.000 description 1
- 229920004899 octoxynol-1 Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229940096792 quaternium-15 Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
An aqueous composition useful for conditioning hair consisting essentially of an aqueous carrier containing a cationic polymer and amphoteric surfactant in specified proportions and having a pH in the range of from about 1 to about 6.
Description
SPECIFICATION
Hair conditioning composition and method
This invention relates to compositions that are
useful in conditioning hair and to processes for conditioning hair by employing such compositions.
It is known in the prior art to treat hair with certain quaternary amine compounds for the purpose of conditioning hair i.e. to improve its combability, manageability, softness, etc. Although such prior art compositions have proven to be effective in varying degrees, one of the chief drawbacks has been the factthatthe effect has not been long-lasting i.e. it does not survive repeated shampooings.
It is accordingly an object of the present invention to provide a hair conditioning composition that retains its conditioning effect through repeated hair shampooings.
It is also an object of the present invention to provide a process for treating hair using the aforesaid composition which has a conditioning effect on the hair that is relatively stable to repeated shampooings.
Other and more detailed objects of this invention will be apparent from the following description and claims.
The present invention relates to compositions for conditioning hair, which includes, based on the total weight of the composition, from about 0.4% to about 10% of at least one cationic polymer, from about 0.2% to about 20% of an amphoteric surfactant; and sufficient acid to give the composition a pH in the range from about 1 to about 6; the ratio: a = polymer rtrer)l
detergent(mol being from about 0.2 to about 5; in an aqueous carrier. Optionally the composition also includes an effective amount, such as from about 0.1% to about 5% of a betaine having the formula:
wherein R is a long chain aliphatic radical containing
from about 10 to about 24 carbon atoms.The pres
ent invention also involves a method for condition
ing hair which has been previously treated with an
agent having an alkaline pH, by applying thereto the composition ofthis invention.
The cationic polymers that are useful for the purposes of the present invention can vary somewhat.
Three classes of polymers that have been found to be particularly useful are those sold under the trade names MERQUAT (e.g. MERQUAT 100), ONAMER (e.g. ONAMER M) and quaternized polyvinylpiridine.
The MERQUAT 100 is a polymer of dimethyldiallyl ammonium chloride and are probably mixtures of compounds having the following formula:
Wherein n is a cardinal number dependent on molecular weight. These can vary in molecular weight, however, ordinarily the polymers of this class that will be employed have a molecularweight in the range of from 4,000 to 550,000 and preferably in the range of from about 20,000 to about 100,000.
The ONAMER type polymers that are useful for the present purposes are poly(dimethyl butenyl ammonium chlonde)-a,"-bis(triethanol ammonium chlorides) that may be described by the formula:
Certain of the chemical formula(e) appearing in the printed specification were submitted after the date of filing, the formula(e) originally submitted being incapable
of being satisfactorily reproduced.
Wherein n is a cardinal number dependent on molecular weight.
The molecular weights of these ONAMER type polymers that may be employed herein can also vary somewhat. For the most part, however, this will be in the range of from about 800 to about 5,000 and preferably, in the range of from about 1,000 to about 3,000.
The polymers and copolymers of quaternized polyvinylpyridine that can be used in accordance with this invention are described by the generar for-
/Vhere n is a cardinal number depending on molecularweight, R is an alkyl radical of C,-C20 and the X is a cosmetically acceptable anion such as halide, sulrate or carboxylate. These also will have a weight average molecular weight in the range of from about 5,000 to about 100,000.
As an example of the cationic polymer of this group, the following may be mentioned:
polyvinyl methyl pyridinium iodide
Where n is the cardinal number depending on
molecular weight. The weight average molecular
weight is suitably about 50,000.
The quantity of cationic polymer contained in the
present aqueous solutions will depend on the particular results that are desired. Ordinarily, this will
constitute between about 0.4% to about 10% by
weight based on the total weight of the aqueous
composition with the optimal range being between
about 1% to about 5% on the same weight basis.
The second essential component of the composi
tions of this invention are the amphoteric surfac
tants. A characteristics of these materials is that
many assume the character of an anionic or a
cationic surfactant compound depending upon the
pH of the solution in which it may be contained.
There are a numberofamphoteric detergents that
are suitable for use in the present invention. However, two classes of detergents have been found to be especially effective. The first class can be defined by the formula:
in which R is a long chain fatty radical containing from 10 to 18 carbon atoms. A typical example of such a compound orcompounds is the case in which
R represents coconut fatty radicals. A material of this character is sold under the trade name MIRANOL
C2MSF and is described in the CTFA Cosmetic
Ingredient Dictionary (1973) under the name
AMPHOTERIC-2.
A second class of amphoteric detergents that is particularly effective for the purposes of the present invention can be defined by the formula:
I R-NH-CH2-CH2-COOH wherein R is a long chain fatty alkyl group having from 10 to 18 carbon atoms. An example of such a detergent is marketed under the trade name
DERIPHAT 170C in which the R in formula IV is a mixture of lauryl and myristyl fatty alkyl groups. This material is described in the CTFA Cosmetic Ingredient Dictionary (1973) as Lauraminopropionic Acid.
The quantity of amphoteric detergent which will be contained in the composition of this invention will vary somewhat again depending on the economics and the results sought However, usually this will be in the range of from about 0.2 to about 20% by weight and ideally in the range of from about 1% to about 5% by weight based on the total weight of the composition.
Another essential feature of the present composition is that the solution have an acid pH that is a pH that falls in the range of from about 1 to 6. Any of a variety of acids may be used in adjusting the pH of these compositions to the proper level, hydrochloric, citric, and phosphoric acids were found to be particularly useful and suitable.
The betaines that are optionally useful for the pur
poses of the present invention are of the formula:
in which R is a long chain aliphatic radical containing lotto 24 carbon atoms. As used herein, the term long
chain aliphatic radical includes saturated and
unsaturated straight chain and branched chain radi 5 cals, hydrocarbon radicals as well as chain radicals
that include other atoms in addition to carbon atoms
in the chain (e.g. oxygen, nitrogen, etc.).
By way of illustrating typical betains that may be used in this invention, mention may be made of cocamidopropyl betaine, oleyl betaine, cetyl betaine, coco betaine, etc. Cocamidopropyl betaine is described by the formula:
wherein
the coco fatty acid acyl radical. Coco fatty acid is a mixture of fatty acids obtained from Cocunut Oil which are predominantly
C,2 acids. Oleyl betaine, on the other hand, has the formula:
Structurally the coco betaine and cetyl betaine resemble the oleyl betain shown in formula Ill above excepting that the oleyl radical is replaced with coco fatty radicals or the cetyl radical respectively. A number of betaines that are useful forthe purposes of the present invention are available commercially.
Among these mention may be made of
CHEMADENE NA 30, LONZAINE 12C, LONZAINE 14C, LONZAINE 165, etc.
The quantity of the betaine that may be incorporated in the composition of the present invention may vary. Usually, it will comprise between about 0.1% to about 5% by weight and preferably between about 0.3% to about 3% by weight based on the total weight of the composition.
Although the cationic polymers, the amphoteric surfactants and the acids mentioned above are the essential active ingredients in the present compositions, the compositions contemplated by the present invention may also contain other ingredients which may serve to improve the organoleptic character of the product or its ease of application. Thus, it is within the purview of th is invention to incorporate in the present compositions one or more of such materials as fragrances, thickening agents, fragrance sol ubil izers, bactericides, etc.
Optionally a variety of solvents can be employed in the compositions of this invention. These will usually take the form of an aliphatic alcohol, either a monohydric or polyhydric, preferably having from 1 to 6 carbon atoms. As employed herein, the term "aliphatic alcohol" is used in its generic sense and includes such alcohols as straight chain and branched chain alkyl alcohols that can be monohydric or polyhydric (e.g. dihydroxy) ether alcohols, ester alcohols, etc. By way of illustrating the solvents that may be useful for the present composition, mention may be made of ethanol, carbitol, hexylene glycol, propylene glycol. The solvents may be used at levels from 0% to about 50% and preferably in the range of from 0% to 5% by weight based on the total weight of the composition.
Optionally, a neutral surfactant may also be incorporated in the compositions of this invention. These will constitute between 0%to 10% by weight based on the total weight of the composition but more often, a range of 0% to 2% is preferred. Suitable examples of such neutral surfactants are Igepal
CO-630 (CTFA name nonoxynol-9); Arlasolve 200 (polyoxyethylene(20)isohexadecyl ether); Tween 20 (CTFA name polysorbate 20).
To facilitate the application of the present compositions to the hair it is often useful to increase its viscosity somewhat. Many thickening agents can be used for this purpose. Among these mention may be made of hydroxyethyl cellulose, carboxymethyl cellulose, the Carbopols e.g. Carbopol 940. However, hydroxyethyl cellulose has been found to be particularly suitable. The concentration of the thickening agent may vary somewhat depending on the results desired. Usually, this will be present in the range of from 0% to about 10% by weight based on the total weight of the composition.
It is often useful to incorporate a bactericide in the compositions of this invention. A variety of materials are known in the prior art that will serve this purpose. By way of illustration, mention may be made of a material sold underthetrade name DOWICIL 200. This is identified in the CTFA Cosmetic Ingredient Dictionary, second edition, as quaternium-15 and chemically as 1 - (3 - chloro - allyl) - 3,5,7 -triaza 1 - azoniaadamantane chloride. The quantity of bactericide that will be contained in the present compositions will vary somewhat depending on the nature ofthe particular composition. Usually, however, it will comprise between 0%to about 10% by weight based on the total weight of the composition.
Aside from the absolute quantities of the cationic polymer and amphoteric detergent contained in the present compositions, it has been found that their conditioning effectiveness is highly dependent upon the "molar ratio" of polymer to detergent. The term "molar ratio" as used herein is designated by the letter a and is defined as: (y= I Polymer (mer)]
t LDetergent (mol) In the above expression and elsewhere in the specification and claims, the term [Polymer (mer) refers to the number of mols of the repeating units of the polymer contained in the composition and bearing a positive charge. The term [Detergent (mol)J in the aforesaid expression and elsewhere is defined as the number of mols of detergent contained in the composition. The ratio a may vary somewhat.Ordinarily, this will be in the range of from about 0.2 to about 5 and and preferably in the range of from about 1 to about 2.
The compositions of this invention may be applied to hair in any suitable manner. One typical procedure involves applying the conditioning composition, such as described in Example 1 below to freshly dyed or bleached hair, working it gently into the hair mass, leaving the said composition on hair for one to
three minutes and rinsing the hair thoroughly with
water priorto combing and drying. Amount of the
conditioning composition applied to hair may vary,
in general, should not be less than 1% of the hair i weight and does not need to exceed 20% of hair
weight.
It is generally visualized that the compositions of
this invention will be applied to hair that has previ
ously been given a treatment that leaves the hair somewhat alkaline. Typical of such treatment are
treatments with oxidation hair dye systems or
bleaching systems. One such treatment involves
mixing a dye base containing amongotherthings the oxidation dye intermediates with an aqueous
vehicle containing an oxidizing agent such as hyd
rogen peroxide and then shampooing this mixture
into the hair. These mixtures before being applied to
the hair usually have an alkaline pH e.g. in the range
of from 7 to 12 and preferably 8 to 11.Another such
treatment involves for example treating the hair with
an alkaline bleaching solution which contains the
usual oxidizing agent (e.g. aqueous hydrogen perox
ide), boosters (e.g. potassium persulfate and
ammonium persulfate), alkalizing agents, etc.
When the compositions of this invention are
applied to hairthat has been previously treated as
indicated above the combination of am photeric detergent and cationic polymer precipitates out on
the hair forming a conditioning complex that is retained on the hair throughout repeated shampo
oings.
The pH of the hair conditioning compositions that
are employed in the present invention will be
selected to some extent on the basis of the alkalinity
of the hair to be treated and the relative amounts of
cationic polymers and amphoteric detergent In gen
eral, the pH is selected so that after the composition
is applied to the hair and comes under the influence
of the alkalinity of the hairthatthe pH of the compos
ition is increased by approximately 1 pH unit above
which the precipitation of the complex takes place.
Generally, underthese conditions the optimum pre
cipitation of the conditioning complex appears to
take place.
The following Examples are given to further illus
trate the present invention. It is to be understood,
however, that the invention is not limited thereto.
Where the CTFA name is given herein, reference is
made to the name given to the material in the CTFA
Cosmetic Ingredient Dictionary of 1973 or the 2nd
Edition of 1977.
EXAMPLE 1
Ingredient %bywt.
* Merquat 100 2.00
** MiranolC2MSF 4.00
Hydroxyethyl cellulose 2.00
Phosphoric acid 1.60
Fragrance 0.10 Water QS to 100.00
pH 4.5
* CTFA name Quaternium-40
** CTFA name Amphoteric-2
EXAMPLE2
Ingredient %byWt.
*** OnamerM 1.00
Miranol C2MSF 2.00
Hydroxyethyl cellulose 2.00
Phosphoric acid 0.90
Fragrance 0.10 Water QS to 100.00
pH 4.5 poly(diethyl butenyl ammonium chloride) - a,1
bis (triethanol ammonium chloride) Av. M.W. about 1,000-2,000 EXAMPLE 3 Ingredient %bywt.
Poly-4-vinyl methyl 2.00 pyridiniumi iodide
Miranol C2MSF 4.00
Hydroxyethyl cellulose 2.00
Phosphoric acid 1.60
Fragrance 0.10
Water QS to- 100.00 pH 4.5
EXAMPLE 4
Ingredient %byWt.
Poly-4-vinyl lauryl 1.00 pyridininium sulfate
Merquat 100 1.00
Miranol C2MSF 4.00
Hydroxyethyl cellulose 2.00
Phosphoric acid 1.60
Fragrance 0.10
WaterOSto 100.00 pH 4.5
EXAMPLE 5
Ingredient %by Wt Merquat100 3.50
Miranol C2MSF 1.75
Hydroxyethyl cellulose 2.00
Sodium hydroxide 0.01
Phosphoric acid 0.07
Ethanol 4.00
Chemadene NA-30' 2.00
Water OS to 100.00 pH 4.5 1 Made by the Richardson Chemical Company. Its
CTFA name is Cocamidopropyl betaine.
EXAMPLE 6
Same asExample 5 exceptthat2.00%oleyl betaine is used in place of the cocamidopropyl betaine used in Example 5. This composition had a pH of 4.5
The following procedures illustrate the use of the conditioning agent of this invention after a hair bleaching treatment. It has been found thattreatment of bleached hair with the present compositions also improves its feel and combability.
Two 3 gram swatches of brown Caucasian hair were bleached for 1 hour at 30"C with 20 grams of the following bleach compositon.
COMPOSITION B
% by Wt. based on
total weight of
composition
Potassium persulfate 11.0
Ammonium persulfate 6.0
Sodium stearate 3.5
Sodium metasilicate 3.5
Hydrogen peroxide 3.5
Cab-O-Sil 2.5
EDTA 0.5
Methocel 0.8
Water QS to
100.0
pH 10.3
After bleaching, the hair was thoroughly rinsed
and one of the bleached tresses was treated for 3
minutes with 1.5 g of the following composition:
EXAMPLE B5
Ingredient %byWt.
Merquat100 2.0 *Deriphatl70C 2.4
Benzyl alcohol 3.5
Phosphoric acid (85%) 1.1
Water QS to 100.0 * Lauraminopropionic acid
The other tress was exposed for the same length
of time to the same conventional hair conditioner as
above. Both tresses were thoroughly rinsed and found to be soft and silky to feel and easy to comb.
Both tresses were then shampooed once and compared again. This time the conventionally con ditioned tress felt sticky, rubbery and difficu It to comb; while the tress that had been treated with conditioning composition given in Example B5 retained the softness of feel and ease of combing.
These conditioning attributes were still much in evi denceforthistressafteras manyas4shampooings.
Ingredient %byWt.
Ex. 7 Ex. 8 Ex. 9 Merquat 100 5.00 Hydroxyethyl cellulose 2.250 Phosphoric Acid 0.450 Sodium hydroxide 0.015 Miranol C2MSF 2.560 Sorbic acid 0.100 Dowicil 200* 0.100 Carbitol 3 00 ? Cocamidopropyl betaine 0.600 Fragrance 0.400 Tween - .001 Arlasolve 200*** - - .001 Waterto 100% pH 4.8 4.5 4.5 * CTFA name Quaternium-1 5 CTFA name Polysorbate-20 *** Polyoxyethylene (20) isohexadecyl ether
Ingredient %by Wt. Ex. 10 Ex. ii Ex. 12 Ex. 13 Ex. 14 Ex.15 Merquat 100 5.0 - - 5.0 5.0 5.0 Hydroxyethyl cellulose 2.25 Sodium hydroxide 0.15 Phosphoric acid .2 0.46 Deriphat 170C 2.0 - - - - Miranol C2MSF - 2.56 Sorbic acid 0.1 0.10 Dowicil 200 .10 0.10 Carbitol 3.0 Fragrance .40 Chemadene NA-303 2.0 2.0 2.0 - - Merquat 12.5 - - Onamer - 5.0 - - - Lonzaine 12C' - - - 2.0 - Lonzaine 14 - - - - 2.0 Lonzaine 16S8 - - - - - 2.0 Water to 100% pH4.5
2 CTFA name Lauramopropionic acid 3 CTFA name Cocamidopropyl betaine 4 CTFA name Ouaternium-41 5 Poly(dimethyl butenyl ammonium chloride)a bis(triethanol ammonium chloride) 6 CTFA name Coco betaine 7 CTFA name Lauryl betaine 8 CTFA name Cetyl betaine
Conditioning formulations of this invention are not only effective in improving wet and dry combing of hair, imparting manageability, softness, etc. but unlike the conventional products, their conditioning effects are stable to repeated shampooings. This conditioning durability is illustrated in the following
experiment, the dyed hair being used as the test
substrate.
Swatches of intact Caucasian hair were colored
with Composition A belowfor20 minutes, in accor
dance with the procedure of the instructions. The
ratio of the amount of solution to weight of hair, temperature and quantity of water used for rinsing
after treatment, were all maintained so as to simu
late conditions on the head. After rinsing, a conventional hair condition in which the conditioning ingredient was Stearelkonium chloride (CTFA name) and on another similarly treated swatch the conditioning material of Example 1 and on a similarlytreated swatch the composition of Example 5 above was applied to hair (0.1 g of each product per 1 g of hair). Both were worked in for 30 seconds and left on the hair for additional 1 minute after which time the hair was rinsed and combed.The combing measurementswere performed bythe procedure described in the paper by Garcia and Diaz (J. Soc.
Cosmt. Chem.27, 379-398,1976). The test essentially involves passing of a hairtressthrough a comb attached to a strain gauge which in turn is connected to a recording device. Work is expended to accomplish the passage of the hair tress through the comb, and this work, read off the integrator, is the objective measure of combing ease/difficulty.
Having determined the combing properties of hair after coloring and conditioning treatment, the swatches were shampooed with HERBAL
ESSENCE'M shampoo three or more times and again tested for combing. The shampooing procedure involved application of the shampoo (0.1 g per 1 g of hair), working it into the hairoverthe period of 60
seconds to produce a copious lather and rinsing the
shampooed hair for at least 1 minute. Each shampoo
step consisted of two lathering/rinsing sequences.
The results of combability tests are summarized in
Table I below. In the Table, the "Work of Combing' is
expressed in units ofwork (gcm). The higherthe val
ues, the harder it wasto comb the hair.
COMPOSITIONA %by Wt. based
on total weight
Ingredient of composition
p-Phenylenediamine 0.35
N,N-bis (2-hydroxyethyl O-p
phenylenediamine sulfate 0.17
Resorcinol 0.31
1-Naphthol 0.08
Oleic acid 7.50
Propylene glycol 4.40
Isopropanol 4.35
Hydrogen peroxide 3.00 *Octoxynol-1 3.50
Sulfated Castor Oil 1.50
Ammonium hydroxide 1.15 *Cocamide DEA 0.75
Fragrance 0.15
Sodium sulfite 0.05
EDTA 0.01
Water QS to 100.00
pH 9.8 * CTFA name (See CTFA Cosmetic Ingredient Dictio
nary,2nd Edition, 1977) TABLE I
Treatment with Average combing work (gcm)on wet halt No +3 +4 +5 +6
shampooing shampoos shampoos shampoos shampoos (A) After dyeing 2,800 (A) + Conventional
conditioner 625 7,350 (A) + Conditioner of
Example 1 346 769 (A) + Conditioner of
Example 5 22 & 349 438 531 (A) + Conditioner of
Example 7 580 641 809 916
The last two results in Table I have been further con
firmed in experiments on live heads.
It should be noted that betaines by themselves do
not effect any conditioning when applied in a formu
lation in combination with the cationic polymer e.g.
MERQUAT 100 or ONAMER M. It is only when other
amphoterics, such as the ones described above, are also present in the formula that additional condition
ing is obtained from the use of the betaine.
Claims (19)
1. A composition for conditioning hair consisting essentially of based on the total weight of the com
position:
(a) from about 0.4% to about 10% of at least one
cationic polymer;
(b) from about 0.2% to about 20% of an amphoteric surfactant; and
(c) sufficient acid to give the composition a pH in the range of from about 1 to about 6;
the ratio ~~~ [polymer (mer)j
ldeter9ent (mol)2 being from about 0.2 to about 5; in (d) an aqueous carrier.
2. A composition according to claim 1 in which said ratio is in the range of from about 1 to about 2.
3. The composition of claims 1 or 2, further comprising from about 0.1% to about 5% of at least one betaine of the formula:
wherein R is an aliphatic radical with about 10 to about 24 C atoms.
4. The composition of claim 3 in which said betaine is at least one of cocamidopropyl betaine, lauryl betaine, oleyl betaine, cetyl betaine and coco betaine.
5. A composition according to claims 1 or 2 in which said cationic polymer is homopolymer of dimethyl diallyl ammonium chloride.
6. Acomposition according to claims 1-4, in which said cationic polymer is homo- or copolymer of a quaternized polyvinyl pyridine having monomeric units of the formula:
Where R is an alkyl radical of C1-C20 and the X is a cosmetically acceptable anion and having a weight average molecular weight in the range of from about 5000 to about 100,000.
7. The composition of claim 6, wherein said anion is a halide, sulfate or carboxylate.
8. A composition according to claims 1 - 4, in which said cationic polymer is a poly(dimethyl butenyl ammonium chioride)-a,w-bis(triethanol ammonium chloride).
9. Acomposition according to claims 1 - 8, wherein said amphoteric detergent is of the formula:
in which R is a long chain fatty radical containing 10 to 18 carbon atoms.
10. Acomposition according to claim 9, wherein
R is a coco fatty radical.
11. A composition according to claims 1 to 8 in which said amphoteric detergent is of the formula: R-NH-CH2-COOH in which R is a long chain fatty alkyl radical having from 10 to 18 carbon atoms.
12. Acomposition according to claims 1 - 11, further including aliphatic monohydric or polyhydric alcohol solvent, suitably having between about 1 and about 6 carbon atoms.
13. A method for conditioning hair which comprises applying to said hair a compositon defined in any of the claims 1 to 12 for sufficient time to improve its combing characteristics and/or its manageability and/or its softness.
14. In a process for conditioning hairwhich has been previously subjected to the treatment with a treating agent having an alkaline pH, the improvement which comprises applying to said pre-treated hair a composition as defined in any of the claims 1 to 12 for sufficient time to improve its combing characteristics and/or its manageability, and/or its softness.
15. A process according to claim 14 in which the pH of said previous employed treating agent is in the range of from about 7 to 12.
16. A process according to claim 14 in which the pH of the said previous employed treating agent is in the range of from about 8 to 11.
17. A composition according to claim 1 substantially as described in any of the foregoing Examples.
18. A method or process for conditioning cut hair which is as defined in claim 13,14, or 16.
19. Conditioned cut hair obtained by a method or process as claimed in claim 18.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5437879A | 1979-07-02 | 1979-07-02 | |
| US8061579A | 1979-10-01 | 1979-10-01 | |
| US16015180A | 1980-06-24 | 1980-06-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2057261A true GB2057261A (en) | 1981-04-01 |
| GB2057261B GB2057261B (en) | 1984-03-28 |
Family
ID=27368628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8021576A Expired GB2057261B (en) | 1979-07-02 | 1980-07-01 | Hair conditioning composition and method |
Country Status (10)
| Country | Link |
|---|---|
| AR (1) | AR230565A1 (en) |
| DE (1) | DE3024578C2 (en) |
| DK (1) | DK165388C (en) |
| FR (1) | FR2460133B1 (en) |
| GB (1) | GB2057261B (en) |
| GR (1) | GR69318B (en) |
| IT (1) | IT1145272B (en) |
| MX (1) | MX154911A (en) |
| NL (1) | NL8003835A (en) |
| SE (1) | SE8004858L (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2122898A (en) * | 1982-07-07 | 1984-01-25 | Unilever Plc | Hair rinse conditioner |
| US4656043A (en) * | 1985-09-13 | 1987-04-07 | Richardson-Vicks Inc. | Peroxide-containing conditioning shampoo |
| WO2002005768A1 (en) * | 2000-07-17 | 2002-01-24 | Mandom Corporation | Pretreatment agents for acidic hair dyes |
| US6495498B2 (en) | 1999-05-27 | 2002-12-17 | Johnson & Johnson Consumer Companies, Inc. | Detergent compositions with enhanced depositing, conditioning and softness capabilities |
| EP1713434A1 (en) * | 2004-01-29 | 2006-10-25 | Avlon Industries Inc. | Conditioning hair lightener system, compositions, method and kit therefor |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19912660A1 (en) * | 1999-03-20 | 2000-09-28 | Wella Ag | Amphoteric acids are used for neutralizing polymers with basic groups in hair treatment agents, e.g. aerosol foam or spray, non-aerosol hair spray or lacquer, gel, wax, microemulsion, color, conditioner or rinse |
| DE102008030138A1 (en) | 2008-06-27 | 2009-12-31 | Beiersdorf Ag | Hair rinse with amphoteric surfactant and special storage stability |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3372149A (en) * | 1964-09-02 | 1968-03-05 | Nat Starch Chem Corp | Process for preparing salts of aminoalkyl esters of carboxylic acid polymers |
| ES378217A1 (en) * | 1969-04-14 | 1973-02-01 | Colgate Palmolive Co | Shampoo compositions |
| US3912808A (en) * | 1970-02-25 | 1975-10-14 | Gillette Co | Hair waving and straightening process and composition containing water-soluble amino and quaternary ammonium polymers |
| US3769398A (en) * | 1970-05-25 | 1973-10-30 | Colgate Palmolive Co | Polyethylenimine shampoo compositions |
| AU461954B2 (en) * | 1970-11-16 | 1975-06-12 | Colgate-Palmolive Company | Cosmetic compositions |
| FR2280361A2 (en) * | 1974-08-02 | 1976-02-27 | Oreal | HAIR TREATMENT AND CONDITIONING COMPOSITIONS |
| LU64371A1 (en) * | 1971-11-29 | 1973-06-21 | ||
| GB1443426A (en) * | 1972-10-28 | 1976-07-21 | Reckitt & Colmann Prod Ltd | Cosmetical compositions |
| CA1022075A (en) * | 1973-05-17 | 1977-12-06 | Earl L. Richardson | Shampoo formulations comprising a quaternary nitrogen containing cellulose polymer |
| DE2327066C3 (en) * | 1973-05-26 | 1975-11-20 | Hans Schwarzkopf Gmbh, 2000 Hamburg | Means and methods for setting hair |
| CA1016464A (en) * | 1973-06-22 | 1977-08-30 | Terry Gerstein | Shampoo conditioner formulations |
| CA1027479A (en) * | 1973-11-19 | 1978-03-07 | Frank A. Nowak (Jr.) | Shampoo composition |
| LU68901A1 (en) * | 1973-11-30 | 1975-08-20 | ||
| FR2368508A2 (en) * | 1977-03-02 | 1978-05-19 | Oreal | HAIR CONDITIONING COMPOSITION |
| US3990991A (en) * | 1974-02-01 | 1976-11-09 | Revlon, Inc. | Shampoo conditioner formulations |
| LU72593A1 (en) * | 1975-05-28 | 1977-02-10 | ||
| GB1540384A (en) * | 1975-06-12 | 1979-02-14 | Beecham Inc | Shampoo |
| US3996146A (en) * | 1975-08-01 | 1976-12-07 | Warner-Lambert Company | Clear shampoo formulation |
| GB1584364A (en) * | 1976-06-21 | 1981-02-11 | Unilever Ltd | Shampoo |
| US4061602A (en) * | 1976-08-03 | 1977-12-06 | American Cyanamid Company | Conditioning shampoo composition containing a cationic derivative of a natural gum (such as guar) as the active conditioning ingredient |
| US4080010A (en) * | 1976-09-07 | 1978-03-21 | Smith International, Inc. | Tandem roller stabilizer for earth boring apparatus |
| US4155994A (en) * | 1977-01-21 | 1979-05-22 | Kewanee Industries, Inc. | Hair conditioning agents |
| FR2382232A1 (en) * | 1977-03-02 | 1978-09-29 | Oreal | HAIR TREATMENT COSMETIC COMPOSITIONS |
| US4180084A (en) * | 1977-05-02 | 1979-12-25 | Ciba-Geigy Corporation | Cosmetic compositions containing polymeric quaternary ammonium salts |
| CA1091160A (en) * | 1977-06-10 | 1980-12-09 | Paritosh M. Chakrabarti | Hair preparation containing vinyl pyrrolidone copolymer |
-
1980
- 1980-06-27 FR FR8014304A patent/FR2460133B1/en not_active Expired
- 1980-06-28 DE DE3024578A patent/DE3024578C2/en not_active Expired
- 1980-06-30 DK DK283080A patent/DK165388C/en active
- 1980-07-01 MX MX182988A patent/MX154911A/en unknown
- 1980-07-01 GR GR62340A patent/GR69318B/el unknown
- 1980-07-01 SE SE8004858A patent/SE8004858L/en unknown
- 1980-07-01 GB GB8021576A patent/GB2057261B/en not_active Expired
- 1980-07-02 AR AR281630A patent/AR230565A1/en active
- 1980-07-02 NL NL8003835A patent/NL8003835A/en not_active Application Discontinuation
- 1980-07-02 IT IT49144/80A patent/IT1145272B/en active
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2122898A (en) * | 1982-07-07 | 1984-01-25 | Unilever Plc | Hair rinse conditioner |
| US4940576A (en) * | 1982-07-07 | 1990-07-10 | Conopco, Inc. D/B/A/ Chesebrough-Pond's Usa Co. | Hair conditioning preparation |
| US4656043A (en) * | 1985-09-13 | 1987-04-07 | Richardson-Vicks Inc. | Peroxide-containing conditioning shampoo |
| US6495498B2 (en) | 1999-05-27 | 2002-12-17 | Johnson & Johnson Consumer Companies, Inc. | Detergent compositions with enhanced depositing, conditioning and softness capabilities |
| US6858202B2 (en) | 1999-05-27 | 2005-02-22 | Johnson & Johnson Consumer Companies, Inc. | Detergent compositions with enhanced depositing, conditioning and softness capabilities |
| US6908889B2 (en) | 1999-05-27 | 2005-06-21 | Johnson & Johnson Consumer Companies, Inc. | Detergent composition with enhanced depositing, conditioning and softness capabilities |
| WO2002005768A1 (en) * | 2000-07-17 | 2002-01-24 | Mandom Corporation | Pretreatment agents for acidic hair dyes |
| US7037347B2 (en) | 2000-07-17 | 2006-05-02 | Mandom Corporation | Pretreatment agents for acidic hair dyes |
| EP1713434A1 (en) * | 2004-01-29 | 2006-10-25 | Avlon Industries Inc. | Conditioning hair lightener system, compositions, method and kit therefor |
| EP1713434A4 (en) * | 2004-01-29 | 2009-01-07 | Avlon Ind Inc | Conditioning hair lightener system, compositions, method and kit therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| DK165388C (en) | 1993-04-05 |
| DK165388B (en) | 1992-11-23 |
| FR2460133A1 (en) | 1981-01-23 |
| IT1145272B (en) | 1986-11-05 |
| MX154911A (en) | 1987-12-22 |
| DE3024578C2 (en) | 1985-09-05 |
| DK283080A (en) | 1981-01-03 |
| IT8049144A0 (en) | 1980-07-02 |
| GB2057261B (en) | 1984-03-28 |
| DE3024578A1 (en) | 1981-06-04 |
| NL8003835A (en) | 1981-01-06 |
| SE8004858L (en) | 1981-01-03 |
| GR69318B (en) | 1982-05-14 |
| AR230565A1 (en) | 1984-05-31 |
| FR2460133B1 (en) | 1986-11-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PE20 | Patent expired after termination of 20 years |
Effective date: 20000630 |