GB2053954A - Detergent Composition - Google Patents
Detergent Composition Download PDFInfo
- Publication number
- GB2053954A GB2053954A GB8020473A GB8020473A GB2053954A GB 2053954 A GB2053954 A GB 2053954A GB 8020473 A GB8020473 A GB 8020473A GB 8020473 A GB8020473 A GB 8020473A GB 2053954 A GB2053954 A GB 2053954A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- parts
- component
- detergent composition
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 239000003599 detergent Substances 0.000 title claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- -1 glycerine fatty acid Chemical class 0.000 claims abstract description 13
- 229920000151 polyglycol Polymers 0.000 claims abstract description 12
- 239000010695 polyglycol Substances 0.000 claims abstract description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003960 organic solvent Substances 0.000 claims abstract description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004927 clay Substances 0.000 claims abstract description 6
- 125000003827 glycol group Chemical group 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- 239000002562 thickening agent Substances 0.000 claims abstract description 6
- 150000002170 ethers Chemical class 0.000 claims abstract description 5
- 150000002576 ketones Chemical class 0.000 claims abstract description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000005037 alkyl phenyl group Chemical group 0.000 claims abstract description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 4
- 229920001400 block copolymer Polymers 0.000 claims abstract description 4
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims abstract description 4
- 239000008139 complexing agent Substances 0.000 claims abstract description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 4
- 239000000194 fatty acid Substances 0.000 claims abstract description 4
- 229930195729 fatty acid Natural products 0.000 claims abstract description 4
- 235000011187 glycerol Nutrition 0.000 claims abstract description 4
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 4
- 239000002304 perfume Substances 0.000 claims abstract description 4
- 150000001298 alcohols Chemical class 0.000 claims abstract description 3
- 239000003513 alkali Substances 0.000 claims abstract description 3
- 239000000975 dye Substances 0.000 claims abstract description 3
- 150000002334 glycols Chemical class 0.000 claims abstract description 3
- 239000000344 soap Substances 0.000 claims abstract description 3
- 125000002947 alkylene group Chemical group 0.000 claims abstract 2
- YQEMORVAKMFKLG-UHFFFAOYSA-N 2-stearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 150000003839 salts Chemical group 0.000 claims description 5
- 229960000892 attapulgite Drugs 0.000 claims description 4
- 229910052625 palygorskite Inorganic materials 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 4
- 238000002360 preparation method Methods 0.000 claims 1
- 229960004418 trolamine Drugs 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 240000008886 Ceratonia siliqua Species 0.000 description 2
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 239000010665 pine oil Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical class ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 240000008299 Pinus lambertiana Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000010630 cinnamon oil Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical group 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
A detergent composition comprising the following components: A 0.1 to 5 parts by weight of a natural alkali- and metal-resistant thickening agent B 2 to 20 parts by weight of a mixture comprising 3 to 15 parts by weight of a higher (C8-24)alkyl-phenyl polyglycol ether having from 5 to 25 glycol residues; 5 to 15 parts by weight of an alkanolamine; 2 to 8 parts by weight of a complexing agent, and 1 to 3 parts by weight of a block copolymer of propylene oxide and ethylene oxide of an average molecular weight from 1500 to 2500 and containing from 5 to 15% by weight of ethylene oxide end units C 10 to 60 parts by weight of finely divided clay material having a hardness degree from 2 to 3 D 0 to 20 parts by weight of a glycerine fatty acid monoester E 0 to 1 part by weight of a perfume F 0 to 5 parts by weight of an alkali-resistant soap dyestuff, and G 20 to 80 parts by weight of demineralised water or a mixture of demineralised water and one or more organic solvents selected from alcohols, ketones, glycols, glycol ethers, (C1-4)alkylene oxide polyglycol ethers, aromatic hydrocarbons, alicyclic hydrocarbons and/or chlorinated hydrocarbons. s
Description
SPECIFICATION
Detergent Compositions
The present invention relates to detergent compositions, particularly in the form of a hand cleansing paste.
The invention provides a detergent composition comprising, for 100 parts by weight, the following components:
A 0.1 to 5 parts by weight of a natural alkali- and metal-resistant thickening agent
B 2 to 20 parts by weight of a mixture comprising 3 to 1 5 parts by weight of a higher (C824) alkyl-phenyl polyglycol ether having from 5 to 25 glycol residues; 5 to 1 5 parts by weight of
an alkanolamine 2 to 8 parts by weight of a complexing agent, and 1 to 3 parts by weight of
a block copolymer of propylene oxide and ethylene oxide of an average molecular weight
from 1500 to 2500 and containing from 5 to 15% by weight of ethylene oxide end units
C 10 to 60 parts by weight of finely divided clay material having a hardness degree from 2 to 3
D O to 20 parts by weight of a glycerine fatty acid monoester
E O to 1 part by weight of a perfume
F O to 5 parts by weight of an alkali-resistant soap dyestuff, and
G 20 to 80 parts by weight of demineralised water or a mixture of demineralised water and one
or more organic solvents selected from alcohols, ketones, glycols, glycol ethers, (C~4) alkyiene oxide polyglycol ethers, aromatic hydrocarbons, alicyclic hydrocarbons and/or chlorinated hydrocarbons.
Component A is a known commercially available product. A preferred thickening agent is for example etherified locust bean flour.
Preferred higher (C824) alkylphenyl polyglycol ethers present in the mixture of component B are the commercially available nonylphenol polyglycol ethers having an average of from 8 to 12, preferably 10, glycol units per molecule.
Preferred alkanolamines present in the mixture of component B are mono-, di- and triethanolamine, particularly monoethanolamine.
A preferred complexing agent of the mixture B is a nitrilocarboxylic acid, more preferably nitrilotriacetic acid [N(CH2COOH)3] or ethylenediaminetetraacetic acid (EDTA), most preferably EDTA, in free acid or salt form, preferably in salt form. Suitable salts of nitrilocarboxylic acids are e.g. salts of alkaline metals such as lithium, sodium or potassium, preferably sodium.
The block copolymer of propylene oxide and ethylene oxide present in the mixture B is preferably a polymer containing an average of 28-32 propylene oxide units per molecule (average molecular weight 1650--1850) to which on average 812%, preferably 10% ethylene oxide units are copolymerised. Such polymers are commercially available, for example under the Trade Mark
PLURONIC, particularly PLURONIC L-61 and similar types.
Component C is a hydrated crystalline magnesium silicate as present in nature having a
SiO2:MgO weight ratio from 52:22 to 60:25. Such a silicate may have a water content from 9 to 11%.
Suitable magnesium silicates are those referred to as sepiolithic, preferably bentonite or attapulgite.
Such clay materials are present in the composition in a finely divided form, preferably with a grinding degree from 10/100 to 90/100.
Component D is present in the composition particularly when the latter is to be employed for hand cleansing. When component D is present, it is preferably present in the amount of 2 to 20 parts by weight. Component D is a glycerine fatty acid monoester as used in cosmetics for the protection of the skin and for pore dilatation. A preferred monoester is glycerine monostearate.
Component E is preferably a perfuming agent as used in cosmetics e.g. pine oil, lemon oil, cinnamon oil and the like. When component E is present, it is preferably at an amount from 0.01 to 1 part weight.
Component F is a commercially available product. Components E and F are more particularly present in the composition for hand cleansing. When component F is present, it is preferably at an amount from 0.1 to 5 parts by weight.
The alcohol, ketone, glycol, glycol ether and/or polyglycol ether which may be added to the composition may be miscible or immiscible with water. Preferred organic solvents which may be contained in the composition are for example:
alcohol: a lower alcohol, e.g. (C,~3)alcohol, particularly a C3-alcohol;
ketone: a C3- or C4-ketone, particularly acetone;
glycol: a lower glycol, particularly a water-soluble glycol, more preferably hexyleneglycol;
chlorinated hydrocarbon: chlorinated benzenes, preferably mono-, di- or trichlorobenzenes;
alicyclic hydrocarbon: decalin;
aromatic hydrocarbon: tetralin.
The minimum amount of water which is contained in the composition is the amount necessary to prepare an aqueous thickening containing from 5 to 15%, preferably 10% of thickening agent. The rest of the water may be replaced partially or totally by an organic solvent or a mixture of organic solvents.
Preferably, the amount of organic solvent contained in the composition is up to 10%. Where a substantial amount (within the indicated range) of an organic solvent immiscible with water is present, it is convenient to add an emulsifying agent in order to avoid separation of the composition.
Preferred proportions of the components in the mixture are as follows. All percentages are by weight.
Component A: 1 to 3%
Component B: 3 to 10%
Component C: 20 to 40%
Component D: 2 to 10%
Component E: 0.01 to 0.1%
Component F: 0.1 to 1% Component G: 30 to 60%
The detergent composition of the invention may be prepared as follows: a 5 to 1 5% aqueous thickening is prepared and diluted with the remaining demineralised water or amount of component G.
Subsequently, the mixture of component B is added thereto and then the other components in any order; however it is preferred to add the clay material last. The addition of the various ingredients is carried out with stirring and the resulting mixture is stirred until it is homogeneous.
The detergent composition according to the invention may be in form of a paste, a cream or powder, depending on the amount of water, organic solvent and clay material. Preferably, the composition is in paste form. The detergent composition of the invention is stable on storage.
The detergent composition may be used for the cleaning of contaminated objects. It may be used for example for the cleaning of apparatus, equipment, particularly of metal or plastic, as well as of surfaces. It may be employed for removing for example deposits of dyestuffs, oils or graphite. The detergent composition of the invention has a strong cleaning power. The composition also exhibits a strong cleansing power when used for hand cleansing.
The following Examples, in which all parts and percentages are by weight, illustrate the invention.
Example 1
To a container are added at room temperature 27.5 parts of demineralised water. The following components are then added singly in the order given, with continuous stirring. As each component is added, stirring is continued until mixing is complete before addition of the next component.
20 parts of a commercially available alkali-and metal-resistant thickening agent based on modified locust bean flour (10% solution)
1 5 parts of the following mixture:
to 73 parts of demineralised water are added successively at room temperature in the order given
and with continuous stirring:
11 parts commercial nonylphenyl polyglycol ether containing 10 ethylene oxide units/mol, in
35% aqueous solution (corresponding to approximately 4 parts anhydrous substance)
10 parts monoethanolamine
4 parts commercial EDTA in sodium salt form
2 parts PLURONIC L 61 (commercial ethylene oxide-propylene oxide block copolymer of MW approx. 1950, of which the polypropylene oxide part has MW approx.1750) 0.25 parts of C.l. Direct Blue 199
5 parts of glycerine monostearate
0.05 parts of pine oil, and
32.2 parts of commercially available attapulgite (grinding degree: 60/100).
After stirring for a further 1 5 to 20 minutes, the composition in paste form may be filled into tubes or jars.
Example 2
Example 1 is repeated except that the 1 5 parts of the 4-component mixture are replaced by 20, 25 or 30 parts of the same. The initial quantity of water is consequently adjusted.
The detergent compositions of Examples 1 and 2 may be used for example by garage-workers for cleaning their hands.
Claims (12)
1. A detergent composition comprising, for 100 parts by weight, the following components:
A 0.1 to 5 parts by weight of a natural alkali-and metal-resistant thickening agent
B 2 to 20 parts by weight of a mixture comprising 3 to 1 5 parts by weight of a higher (cm~24) alkyl-phenyl polyglycol ether having from 5 to 25 glycol residues; 5 to 15 parts by weight of
an alkanolamine; 2 to 8 parts by weight of a complexing agent, and 1 to 3 parts by weight of
a block copolymer of propylene oxide and ethylene oxide of an average molecular weight
from 1 500 to 2500 and containing from 5 to 15% by weight of ethylene oxide end units
C 10 to 60 parts by weight of finely divided clay material having a hardness degree from 2 to 3
D O to 20 parts by weight of a glycerine fatty acid monoester
E O to 1 part by weight of a perfume
F O to 5 parts by weight of an alkali-resistant soap dyestuff, and
G 20 to 80 parts by weight of demineralised water or a mixture of demineralised water and one
or more organic solvents selected from alcohols, ketones, glycols, glycol ethers, (cm~4) alkylene oxide polyglycol ethers, aromatic hydrocarbons, alicyclic hydrocarbons and/or
chlorinated hydrocarbons.
2. A detergent composition according to Claim 1, in which the quantity of component D is zero.
3. A detergent composition according to Claim 1, in which component D is present in the amount of 2 to 20 parts by weight.
4. A detergent composition according to Claim 3, in which the active components are present in the following proportions by weight:
A 1 to 3%
B 3to10% C 20 to 40% D 2to10% E 0.01 to 0.1 % F 0.1 to 1% G 30 to 60%
5.A detergent composition according to any one of Claims 1,3 and 4, in which component B is a mixture of
a nonylphenol polyglycol ether having an average of 8 to 12 glycol units per molecule,
mono-, di- or tri-ethanolamine,
nitrilotriacetic acid or ethylenediamine tetraacetic acid in free or salt form, and
a polymer containing an average of 28 to 32 propylene oxide units per molecule to which an average of 8 to 1 2% by weight of the ethylene oxide units are copolymerised, component C is bentonite or attapulgite, component D is glycerine monostearate and component G is water.
6. A detergent composition according to Claim 5, in which component B is a mixture of
a nonylphenol polyglycol ether having an average of 10 glycol units per molecule
monoethanolamine
ethylenediaminetetraacetic acid sodium salt, and
a polymer containing an average of 28 to 32 propylene oxide units per molecule to which an average of 8 to 12% by weight of ethylene oxide units are copolymerised component C is attapulgite, component D is glycerine monostearate and component G is water.
7. A detergent composition according to any one of the preceding Claims 1 to 6, in paste form.
8. A process for the preparation of a detergent composition of Claim 1 comprising the steps of adding component A to demineralised water, then successively the remaining amount of component G and components B to F and stirring until the mixture is homogeneous.
9. A process according to Claim 8, in which component C is added last.
10. A process for cleaning contaminated articles comprising treatment with a detergent composition of Claim 1.
11. A process for hand cleansing comprising treatment with a detergent composition according to any one of Claims 3 to 7.
12. A detergent composition substantially as hereinbefore described with reference to any one of
Examples 1 and 2.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH599879A CH642104A5 (en) | 1979-06-27 | 1979-06-27 | PASTE CLEANER. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2053954A true GB2053954A (en) | 1981-02-11 |
| GB2053954B GB2053954B (en) | 1983-10-19 |
Family
ID=4302738
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8020473A Expired GB2053954B (en) | 1979-06-27 | 1980-06-23 | Detergent composition |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE883952A (en) |
| CH (1) | CH642104A5 (en) |
| DE (1) | DE3022816A1 (en) |
| FR (1) | FR2459829A1 (en) |
| GB (1) | GB2053954B (en) |
| IT (1) | IT8049048A0 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4615819A (en) * | 1984-02-26 | 1986-10-07 | Lever Brothers Company | Detergent gel compositions in hexagonal liquid crystal form |
| WO1998049261A1 (en) * | 1997-04-25 | 1998-11-05 | Unilever Plc | Abrasive cleaning composition |
| WO1999018184A1 (en) * | 1997-10-08 | 1999-04-15 | Chemische Fabrik Dr. Weigert (Gmbh & Co.) | Process for cleaning surgical instruments |
| WO2000020544A1 (en) * | 1998-10-06 | 2000-04-13 | Unilever Plc | Non-liquid abrasive composition |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3637711A1 (en) * | 1986-11-05 | 1988-05-11 | Remmers Chemie Gmbh & Co | Composition for cleaning porous mineral building elements |
| AU355934S (en) * | 2013-10-03 | 2014-06-16 | G H MUMM ET CIE SOCIAƒA©TAƒA© VINICOLE DE CHAMPAGNE | Bottle |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3277013A (en) * | 1963-10-03 | 1966-10-04 | G H Packwood Mfg Company | Waterless skin cleaner and process for producing the same |
| DE2836567C2 (en) * | 1977-08-29 | 1986-12-11 | Sandoz-Patent-Gmbh, 7850 Loerrach | Cleaning agents and processes |
-
1979
- 1979-06-27 CH CH599879A patent/CH642104A5/en not_active IP Right Cessation
-
1980
- 1980-06-19 DE DE19803022816 patent/DE3022816A1/en not_active Withdrawn
- 1980-06-23 BE BE1/9858A patent/BE883952A/en not_active IP Right Cessation
- 1980-06-23 GB GB8020473A patent/GB2053954B/en not_active Expired
- 1980-06-24 IT IT8049048A patent/IT8049048A0/en unknown
- 1980-06-25 FR FR8014076A patent/FR2459829A1/en active Granted
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4615819A (en) * | 1984-02-26 | 1986-10-07 | Lever Brothers Company | Detergent gel compositions in hexagonal liquid crystal form |
| WO1998049261A1 (en) * | 1997-04-25 | 1998-11-05 | Unilever Plc | Abrasive cleaning composition |
| WO1999018184A1 (en) * | 1997-10-08 | 1999-04-15 | Chemische Fabrik Dr. Weigert (Gmbh & Co.) | Process for cleaning surgical instruments |
| AU743118B2 (en) * | 1997-10-08 | 2002-01-17 | Chemische Fabrik Dr. Weigert Gmbh & Co. Kg | Process for cleaning surgical instruments |
| US6562296B1 (en) | 1997-10-08 | 2003-05-13 | Chemische Fabrik Dr. Weigert Gmbh & Co. Kg | Process for cleaning surgical instruments |
| WO2000020544A1 (en) * | 1998-10-06 | 2000-04-13 | Unilever Plc | Non-liquid abrasive composition |
Also Published As
| Publication number | Publication date |
|---|---|
| BE883952A (en) | 1980-12-23 |
| FR2459829A1 (en) | 1981-01-16 |
| CH642104A5 (en) | 1984-03-30 |
| FR2459829B1 (en) | 1983-06-24 |
| IT8049048A0 (en) | 1980-06-24 |
| DE3022816A1 (en) | 1981-01-22 |
| GB2053954B (en) | 1983-10-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |