GB2030103A - Method of sealing metal foil closures to glass vessels - Google Patents

Method of sealing metal foil closures to glass vessels Download PDF

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Publication number
GB2030103A
GB2030103A GB7924982A GB7924982A GB2030103A GB 2030103 A GB2030103 A GB 2030103A GB 7924982 A GB7924982 A GB 7924982A GB 7924982 A GB7924982 A GB 7924982A GB 2030103 A GB2030103 A GB 2030103A
Authority
GB
United Kingdom
Prior art keywords
vessel
rim
adhesive
glass
bond
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7924982A
Other versions
GB2030103B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gerresheimer Glas AG
Original Assignee
Gerresheimer Glas AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gerresheimer Glas AG filed Critical Gerresheimer Glas AG
Publication of GB2030103A publication Critical patent/GB2030103A/en
Application granted granted Critical
Publication of GB2030103B publication Critical patent/GB2030103B/en
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B7/00Closing containers or receptacles after filling
    • B65B7/16Closing semi-rigid or rigid containers or receptacles not deformed by, or not taking-up shape of, contents, e.g. boxes or cartons
    • B65B7/162Closing semi-rigid or rigid containers or receptacles not deformed by, or not taking-up shape of, contents, e.g. boxes or cartons by feeding web material to securing means
    • B65B7/164Securing by heat-sealing

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Closures For Containers (AREA)
  • Packages (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Closing Of Containers (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
  • Medical Preparation Storing Or Oral Administration Devices (AREA)

Abstract

A metal foil, applied over the opening and the rim of a glass vessel is secured to the rim by a heat activatable adhesive upon the application of heat and pressure. In order to produce a reliable bond between the glass vessel and the foil, without diffusion or harming of the adhesive bond occurring when the vessel holds water-containing contents, a bond promoter, such as a silane, with a high affinity for glass and with free bonds for firm cross-linking to the adhesive is applied to the rim of the vessel or incorporated in the adhesive.

Description

SPECIFICATION Methods of sealing glass vessels This invention relates to methods of sealing glass vessels having an opening surrounded by a rim, in which a metal foil is applied over the opening and the rim, and a heat activatable adhesive is applied to the rim and then the foil is stuck to the rim by pressing the foil against the rim with the adhesive in between under the application of heat.
In order to seal glass vessels, metal foils, for example of aluminium, coated with a thermoplastic adhesive may be used. The adhesive-coated foil is pressed on to the rim of the vessel under the application of heat until the thermoplastic coating adheres to the rim of the vessel and then the heat is removed. Such seals protect the contents of the vessel from the ingress of moisture, dust and gases from outside and are used predominantly for dry, pulverulent contents such as coffee powder and dried milk products.
Other methods of sealing glass vessels include the fitting of screw closure caps with waxed paper inserts so that the rim of the glass vessel mouth is sealed to the waxed paper by the application pressure. When the closure cap is removed, the undamaged paper insert remains in position and shows that the contents of the vessel have not been tampered with. Instead of heat and pressure, the application of electro-magnetic high-frequency induction fields may be used for joining together glass and adhesive-coated metal foil.
Here again, the seal serves only for protecting dry contents.
Vessels made of thermoplastics materials may have sealing membranes welded to them so that there is a hermetic seal between the vessel material and the closure membrane.
Vessels closed in this manner are suitable also for liquid contents. With glass vessels, such welding is, of course, not possible.
Silicon organic compounds may also be used as bond promoters between glass and plastics materials. Silicon organic compounds are also used in the production of glass fibre reinforced plastics materials and when bonding two pieces of glass together. A firm bond between the surfaces results and the bond is also moisture resistant.
When sealing glass vessels with a metal foil using an adhesive, water molecules from moisture-containing contents tend to diffuse beneath the adhesive layer between the glass and the metal foil so that for vessels containing liquid or pasty materials only closure caps of metal of plastics material with or without injected compound have so far been used.
The object of the present invention is to provide a method of sealing glass vessels as initially described, by which a reliable bond between the glass and the metal foil is achieved, the bond resisting deterioration and diffusion when the vessel holds water-containing materials.
To this end, according to this invention, in a method of sealing a glass container as initially described, a bond promoter with a high affinity for glass and with free bonds for firm cross-linking to the adhesive is applied on to the rim of the vessel.
Silanes or other silicon organic compounds are preferably used as the bond promoter.
These are ideal bond promoters, since on account of their silicon content they are related to the glass and they form owing to their organic nature a bridge to the adhesive.
In this manner, a seal between glass and a metal foil, especially an aluminium foil, is obtained which is not diffused beneath by water molecules from liquid or pasty contents in the vessel and is not adversely influenced by such contents in a way which could lead to premature deterioration of the contents.
The bond promoter may be applied in a mono-molecular layer to the rim of the glass vessel. It is also possible to incorporate the bond promoter in a very small proportion into the adhesive which is used. The adhesive itself can be applied to the metal foil or to the rim of the vessel.
Furthermore the rim of the vessel may, immediately after manufacture and cooling of the vessel, be treated with the bond promoter and subsequently by heated with the adhesive. It is alternatively possible to apply an adhesive incorporating a bond promoter to the rim of the vessel immediately after manufacture and cooling of the glass vessel. The metal foil is applied to the rim of the vessel under the application of heat after the vessel has been filled.
1. A method of sealing a glass vessel having an opening surrounded by a rim, in which a metal foil is applied over the opening and the rim, and a heat activatable adhesive is applied to the rim and then the foil is stuck to the rim by pressing the foil against the rim with the adhesive in between under the application of heat, wherein a bond promoter with a high affinity for glass and with free bonds for firm cross-linking to the adhesive is applied on to the rim of the vessel.
2. A method according to Claim 1, in which the bond promoter is a silicon organic compound.
3. A method according to Claim 2, in which the bond promoter is silane.
4. A method according to any one of Claims 1 to 3, in which the bond promoter is applied as a mono-molecular layer to the rim of the vessel.
5. A method according to any one of Claims 1 to 3, in which the bond promoter is incorporated in the adhesive.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (10)

**WARNING** start of CLMS field may overlap end of DESC **. SPECIFICATION Methods of sealing glass vessels This invention relates to methods of sealing glass vessels having an opening surrounded by a rim, in which a metal foil is applied over the opening and the rim, and a heat activatable adhesive is applied to the rim and then the foil is stuck to the rim by pressing the foil against the rim with the adhesive in between under the application of heat. In order to seal glass vessels, metal foils, for example of aluminium, coated with a thermoplastic adhesive may be used. The adhesive-coated foil is pressed on to the rim of the vessel under the application of heat until the thermoplastic coating adheres to the rim of the vessel and then the heat is removed. Such seals protect the contents of the vessel from the ingress of moisture, dust and gases from outside and are used predominantly for dry, pulverulent contents such as coffee powder and dried milk products. Other methods of sealing glass vessels include the fitting of screw closure caps with waxed paper inserts so that the rim of the glass vessel mouth is sealed to the waxed paper by the application pressure. When the closure cap is removed, the undamaged paper insert remains in position and shows that the contents of the vessel have not been tampered with. Instead of heat and pressure, the application of electro-magnetic high-frequency induction fields may be used for joining together glass and adhesive-coated metal foil. Here again, the seal serves only for protecting dry contents. Vessels made of thermoplastics materials may have sealing membranes welded to them so that there is a hermetic seal between the vessel material and the closure membrane. Vessels closed in this manner are suitable also for liquid contents. With glass vessels, such welding is, of course, not possible. Silicon organic compounds may also be used as bond promoters between glass and plastics materials. Silicon organic compounds are also used in the production of glass fibre reinforced plastics materials and when bonding two pieces of glass together. A firm bond between the surfaces results and the bond is also moisture resistant. When sealing glass vessels with a metal foil using an adhesive, water molecules from moisture-containing contents tend to diffuse beneath the adhesive layer between the glass and the metal foil so that for vessels containing liquid or pasty materials only closure caps of metal of plastics material with or without injected compound have so far been used. The object of the present invention is to provide a method of sealing glass vessels as initially described, by which a reliable bond between the glass and the metal foil is achieved, the bond resisting deterioration and diffusion when the vessel holds water-containing materials. To this end, according to this invention, in a method of sealing a glass container as initially described, a bond promoter with a high affinity for glass and with free bonds for firm cross-linking to the adhesive is applied on to the rim of the vessel. Silanes or other silicon organic compounds are preferably used as the bond promoter. These are ideal bond promoters, since on account of their silicon content they are related to the glass and they form owing to their organic nature a bridge to the adhesive. In this manner, a seal between glass and a metal foil, especially an aluminium foil, is obtained which is not diffused beneath by water molecules from liquid or pasty contents in the vessel and is not adversely influenced by such contents in a way which could lead to premature deterioration of the contents. The bond promoter may be applied in a mono-molecular layer to the rim of the glass vessel. It is also possible to incorporate the bond promoter in a very small proportion into the adhesive which is used. The adhesive itself can be applied to the metal foil or to the rim of the vessel. Furthermore the rim of the vessel may, immediately after manufacture and cooling of the vessel, be treated with the bond promoter and subsequently by heated with the adhesive. It is alternatively possible to apply an adhesive incorporating a bond promoter to the rim of the vessel immediately after manufacture and cooling of the glass vessel. The metal foil is applied to the rim of the vessel under the application of heat after the vessel has been filled. CLAIMS
1. A method of sealing a glass vessel having an opening surrounded by a rim, in which a metal foil is applied over the opening and the rim, and a heat activatable adhesive is applied to the rim and then the foil is stuck to the rim by pressing the foil against the rim with the adhesive in between under the application of heat, wherein a bond promoter with a high affinity for glass and with free bonds for firm cross-linking to the adhesive is applied on to the rim of the vessel.
2. A method according to Claim 1, in which the bond promoter is a silicon organic compound.
3. A method according to Claim 2, in which the bond promoter is silane.
4. A method according to any one of Claims 1 to 3, in which the bond promoter is applied as a mono-molecular layer to the rim of the vessel.
5. A method according to any one of Claims 1 to 3, in which the bond promoter is incorporated in the adhesive.
6. A method according to any one of Claims 1 to 5, in which the adhesive is applied as a layer to the metal foil.
7. A method according to any one of Claims 1 to 5, in which the adhesive is applied to the rim of the vessel.
8. A method according to any one of Claims 1 to 4, or Claim 6 or Claim 7 when dependent on any one of Claims 1 to 4, in which the rim of the vessel is treated with the bond promoter immediately after manufacture and cooling of the vessel and is subsequently treated with the adhesive.
9. A method according to Claim 5, or Claim 6 or Claim 7 when dependent on Claim 5, in which the rim of the vessel has the adhesive applied to it immediately after manufacture and cooling of the vessel.
10. A method according to Claim 1, substantially as described herein.
GB7924982A 1978-07-29 1979-07-18 Method of sealing metal foil closure to glass vessels Expired GB2030103B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2833334A DE2833334C2 (en) 1978-07-29 1978-07-29 Method for closing a packaging container made of glass

Publications (2)

Publication Number Publication Date
GB2030103A true GB2030103A (en) 1980-04-02
GB2030103B GB2030103B (en) 1983-04-27

Family

ID=6045702

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7924982A Expired GB2030103B (en) 1978-07-29 1979-07-18 Method of sealing metal foil closure to glass vessels

Country Status (9)

Country Link
BE (1) BE877940A (en)
CH (1) CH640197A5 (en)
DE (1) DE2833334C2 (en)
ES (1) ES482887A1 (en)
FR (1) FR2435439B1 (en)
GB (1) GB2030103B (en)
HK (1) HK34784A (en)
IT (1) IT1118109B (en)
NL (1) NL7905631A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2523112A1 (en) * 1982-03-08 1983-09-16 Owens Illinois Inc PROCESS FOR HERMETICALLY CLOSING A GLASS CONTAINER USING A THIN MEMBRANE AND CONTAINER THUS OBTAINED
GB2130574A (en) * 1982-11-19 1984-06-06 Owens Illinois Inc Process for sealing a glass container with a thin closure
JPS59158253A (en) * 1983-03-01 1984-09-07 大日本インキ化学工業株式会社 Laminate for packing
FR2542700A1 (en) * 1982-11-19 1984-09-21 Owens Illinois Inc Method for the hermetic sealing of a glass container using a thin lid, and resulting container
FR2831550A1 (en) * 2001-10-31 2003-05-02 Poteries Malicornaises Composition for sealing a cover onto a vessel made of mineral material, metal or wood comprises a thermoplastic resin or elastomer and a silane or organosilane additive

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2848568A1 (en) * 1978-11-09 1980-05-22 Aluminium Walzwerke Singen METHOD FOR CLOSING GLASS CONTAINERS WITH PLASTIC-COVERED METAL FILMS

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1454569A (en) * 1974-04-16 1976-11-03 United Glass Ltd Sealing of containers
DE2549474A1 (en) * 1975-11-05 1977-05-12 Dynamit Nobel Ag METHOD FOR MANUFACTURING LAMINATED SAFETY GLASS

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2523112A1 (en) * 1982-03-08 1983-09-16 Owens Illinois Inc PROCESS FOR HERMETICALLY CLOSING A GLASS CONTAINER USING A THIN MEMBRANE AND CONTAINER THUS OBTAINED
GB2130574A (en) * 1982-11-19 1984-06-06 Owens Illinois Inc Process for sealing a glass container with a thin closure
FR2542700A1 (en) * 1982-11-19 1984-09-21 Owens Illinois Inc Method for the hermetic sealing of a glass container using a thin lid, and resulting container
JPS59158253A (en) * 1983-03-01 1984-09-07 大日本インキ化学工業株式会社 Laminate for packing
JPS6311986B2 (en) * 1983-03-01 1988-03-16 Dainippon Ink & Chemicals
FR2831550A1 (en) * 2001-10-31 2003-05-02 Poteries Malicornaises Composition for sealing a cover onto a vessel made of mineral material, metal or wood comprises a thermoplastic resin or elastomer and a silane or organosilane additive
EP1310537A1 (en) * 2001-10-31 2003-05-14 Les Poteries Malicornaises Composition for sealing a cover on a container

Also Published As

Publication number Publication date
DE2833334B1 (en) 1979-06-13
GB2030103B (en) 1983-04-27
ES482887A1 (en) 1980-04-16
HK34784A (en) 1984-04-27
DE2833334C2 (en) 1984-06-14
BE877940A (en) 1979-11-16
NL7905631A (en) 1980-01-31
FR2435439A1 (en) 1980-04-04
IT1118109B (en) 1986-02-24
CH640197A5 (en) 1983-12-30
IT7949860A0 (en) 1979-07-25
FR2435439B1 (en) 1986-03-21

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PCNP Patent ceased through non-payment of renewal fee