GB2023425A - Insecticide preparation - Google Patents
Insecticide preparation Download PDFInfo
- Publication number
- GB2023425A GB2023425A GB7843847A GB7843847A GB2023425A GB 2023425 A GB2023425 A GB 2023425A GB 7843847 A GB7843847 A GB 7843847A GB 7843847 A GB7843847 A GB 7843847A GB 2023425 A GB2023425 A GB 2023425A
- Authority
- GB
- United Kingdom
- Prior art keywords
- insecticide preparation
- compound
- granules
- preparation
- insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
An insecticide preparation is disclosed comprising an organophosphorous compound having the general formula: <IMAGE> in which R1 and R2, which may be the same or different, are alkyl or alkoxy radicals, R3 is an alkyl, aryl, substituted alkyl or substituted aryl radical, and X is sulphur or oxygen, and a further organophosphorous compound having the general formula: <IMAGE> in which, R4 and R5, which may be the same or different, are alkoxy radicals, R3 and X are as above and n is a whole number between 1 and 10.
Description
SPECIFICATION
Insecticide preparation
This invention relates to insecticides and to methods of making and using the insecticides.
According to one aspect of the invention, an insecticide preparation comprises an organophosphorous compound having the general formula:
in which
R1 and R2, which may be the same or different, are alkyl or alkoxy radicals,
R3 is an alkyl, aryl, substituted alkyl, or substituted aryl radical, and
X is sulphur or oxygen, and a further organophosphorous compound having the general formula:
in which,
R4 and Rsl which may be the same or different, are alkoxy radicals,
R3 and X are as above and n is a whole number between 1 and 10.
The alkyl radicals which may comprise R1, R2 and
R3 may be methyl, ethyl, propyl or higher linear or branched chain radicals.
The alkoxy radicals which may comprise R1, R2, R4 and A5 may be methoxy, ethoxy, propoxy, or higher linearorbranch chain radicals.
The aryl radicals which may comprise R3 may be phenyl.
The substituted radicals which may be present in the radicals which may comprise R3 may be alkyl or aryl or may be halides.
The preparations may further comprise conventional adjuvants, as required, such as a solvent (e.g.
butyl, propyl or other alcohol, or mixtures thereof), a stabilizer (e.g. diethylene glycol, propylene glycol, butyl dioxitol or mixtures thereof) or an emulsifier (e.g. benzyl p - oxydiphenyl polyglycol ether), and mixtures thereof.
The preparations are preferably absorbed into an inert carrier, e.g. pumice or absorbent clay granules such as attapulgite, montmorrillonite, diatomite or kaolinite.
When pumice is used as the carrier it may be that no stabilizer need be present in the preparation.
Insecticides of the organophosphorous type are widely used for the control of pests.
Two of the major pests of the brassicas (cabbage, brussel sprouts, cauliflower, kale etc.) are the cabbage root fly (Erioischia brassicae) and the
Cabbage aphid (Brevicoryne brassicae).
Insecticides of the organophosphorous type are widely used for the control of these pests.
For the control of cabbage root fly, a preparation with ethyl S - phenyl ethylphosphonothiolothionate (British Standard common name "Fonofos"), a commercially available example of Formula I, as
active ingredient, has been frequently used.
For the control of cabbage aphid a preparation
with diethyl S - [2 - (ethylthio)ethyl]
phosphorothiolothionate (British Standard common
name "Disulfoton"), a commercially available
example of Formula II, as active ingredient, has been
widely used.
Due to their high mammalian toxicity these
organophosphorous insecticides are normally
applied in the form of a granular preparation, a type
of formulation which is widely used and
acknowledged as a safe means of applying toxic
insecticides.
Neither Fonofos or Disulfoton, nor presently avail
able compounds of similar structure, are claimed to
give worthwhile control of the non-specified pest,
nor in practice do trials results show or suggest any
such control.
In the past, season long control of cabbage root fly
and cabbage aphid has demanded applications of
two or more insecticidal preparations, this being
inconvenient and expensive to the farmer. Most
farmers only have one set of application equipment,
as this is all that they normally require.
It has now been found that a single application of
insecticide preparation according to the invention
gives effective and improved control of both pests.
Not only is it more convenient and cheaperto apply the insecticides in a single operation, but also
trials have shown that the level of insect control may
be greater than by using the two materials sepa
rately. The combined formulation has given better
control of cabbage root fly than Fonofos or compou
nds of similar structure alone and better control of cabbage aphid than Disulfoton or compounds of
similar structure alone.
In view of this it may further be that the combined
formulation offers improvements in the control of
other pests for which Fonofos and Disulfoton type
compounds have been used individually, for exam
ple, to control aphid and carrot fly in carrots, celery,
parsnips and other root crops, wheat bulbfly and
wireworm in many crops, aphids in potatoes, french
and runner beans, marrows and many other crops
and onion fly in onions.
According to a further aspect of the invention, a
method of making an insecticide preparation com
prises absorbing the compounds of Formulas I and
II, optionally with stabilizers, emulsifiers or solvents,
into a granular insert carrier. The compounds may
be premixed before application to the granules, and
may be present in equal or unequal proportions of
from 1 to 20% each by weight of the preparation.
According to yet a further aspect of the invention a
method of controlling crop pests comprises applica
tion of an insecticide preparation as defined above to
the soil carrying or to carry the crop. The application
may be by surface or subsurface placement of the
preparation. The application may be at the drilling
stage for direct drilled crops or at transplanting for
transplanted crops. The preparation may also be
applied, e.g. to the surface of the soil surrounding
the plants at any stage up to 6 weeks before harvest
ing.
The following Examples, in which all parts are by weight, illustrate the invention.
EXAMPLE 1
An insecticide preparation was prepared by
impregnating Fullers earth granules with the following mixture:
Fonofos 4 parts
Disulfoton 6 parts
emulsifier 1 part
solvent 0.6 parts
stabilizer 1 part
12.6 parts of this mixture were absorbed into 87.4 parts of clay granules to yield 100 parts of an insecticide containing 4% Fonofos and 6% Disulfoton.
EXAMPLE 2
A further insecticide preparation was prepared by impregnating pumice granules with the following mixture:
Fonofos 5parts
Disulfoton 5 parts
emulsifier 0.5 parts
solvent 0.6 parts
11.1 parts of this mixture were absorbent into 88.9 parts of pumice to yield 100 parts of an insecticide containing 5% Fonofos and 5% Disulfoton.
EXAMPLE3
Trials identified as Trials 1 to 3 were carried out at three different sites. In each trial three groups of 8
rows of brussel sprouts were treated at planting time
as follows. The application of insecticide was by
subsurface placement.
1st Group: Preparation of Example 1 atthe rate
of 175 gram per 100m row
2nd Group: 10% Fonofos granules at 70 gram per 100m 3rd Group: 10% Disulfoton granules at 105 gram
per 100m.
Afourth Group was left untreated as a control.
Planting took place in mid-May and the plants
were assessed for insect control in early August
See Table 1.
EXAMPLE 4
Three further trials, Trials 4 to 6, were carried out
at three further sites. In each trial three groups of 10
rows of cabbage were treated at drilling time as
follows. The application of insecticide was by the
bow-wave technique.
1st Group: Preparation of Example 2 at the rate
of 175 gram per 100m row
2nd Group: 10% Fonofos granules at 70 gram per 100m 3rd Group: 10% Disulfoton granules at 105
gram per 100m.
Afourth Group was left untreated as a control,
Drilling took place in late April and the plants were
assessed for insect control in early September-See Table 2.
TABLE 1
1st Group 2nd Group 3nd Group 4th Group Treatment (Example 1) (Fonofos) (Disulfoton) (Control) TRIAL 1 Cabbage Root Ply: (a) Mines 13 16 47 29 (b) Larvae 6 7 31 32 and pupae* Cabbage Not Counted Not Counted Not Counted Not Counted Aphid Yield # 10.9 9.3 8.6 9.8 (4.3) (3.7) (3.4) (3.9) TRIAL 2 Cabbage Root Fly:: (a) Mines* 3 13 16 15 (b) Larvae O 12 6 8 and pupae* Cabbage 3 78 68 93 Aphid Yield # 4.8 4.1 4.3 4.2 (1.9) (1.6) (1.7) (1.7) TRIAL 3 cabbage Root Fly:: (a) Mines* 3 9 14 30 (b) Larvae 1 4 10 17 and pupae* cabbage 5 55 25 80 Aphid* Yield # 12.0 11.2 11.7 11.9 (4.8) (4.5) (4.7) (4.7) per 10 Plants. #tons/acre,bracketed: figures tonnes/ hectare.
TABLE 2
1st Group 2nd Group 3nd Group 4th Group Treatment (Example 1) (Fonofos) (Disulfoton) (Control) TRIAL 4 Cabbage Root Fly Larvae and 26 32 46 45 Pupae per 10 plants Cabbage Aphid % Plants 21 60 24 69 Infected TRIAL 5 cabbage Root Fly Larvae and 2 9 13 12 Pupae per 10 plants Cabbage Aphid % Plants 6 56 16 60 Infected TRIAL 6 cabbage Root Ply Larvae and 2 6 14 15 Pupae per 10 plants Cabbage Aphid r Plants 12 47 17 55 Zafected
Claims (12)
1. An insecticide preparation comprising an organophosphorous compound having the general formula:
in which
R, and R2, which may be the same or different, are alkyl or alkoxy radicals,
R3 is an alkyl, aryl, substituted alkyl or substituted aryl radical, and
X is sulphur or oxygen, and a further organophosphourous compound having the general formula:
in which, R4 and R,, which may be the same or different, are alkoxy radicals, R3 and X are as above and n is a whole number between 1 and 10.
2. An insecticide preparation as claimed in Claim 1 in which the compound of Formula I is Fonofos and the compound of Formula II is Disulfoton.
3. An insecticide preparation as claimed in Claim 1 or Claim 2 absorbed into granules of an inert carrier material.
4. An insecticide preparation as claimed in Claim 3 in which the compounds of Formulae land II are present in the granules in equal or unequal propor tionsoffrom 1 to 20% each by weight of the granules.
5. An insecticide preparation substantially as described in Example 1 or Example 2.
6. A method of making an insecticide preparation which comprises absorbing compounds of Formulae
I and II, as herein defined, into a granular inert carrier.
7. A method as claimed in Claim 6 in which the components of Formulae I and II are admixed before absorption into the carrier.
8. A method as claimed in Claim 6 or Claim 7 wherein the compound of Formula I is Fonofos and the compound of Formula II is Disulfoton.
9. A method as claimed in any of Claims 6 to 8 wherein the compounds of Formulae I and II are used in equal or unequal proportions of from 1 to 20% each by weight of the granules.
10. A method of making an insecticide preparation substantially as described in Example 1 or
Example 2.
11. An insecticide preparation produced by the method of any of Claims 6 to 10.
12. A method of controlling crop pests comprising application of an insecticide preparation as claimed in any of Claims 1 to 5 or Claim 11 to the soil carrying orto carry the crop.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB7843847A GB2023425A (en) | 1977-11-11 | 1978-11-09 | Insecticide preparation |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4714677 | 1977-11-11 | ||
GB7843847A GB2023425A (en) | 1977-11-11 | 1978-11-09 | Insecticide preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
GB2023425A true GB2023425A (en) | 1980-01-03 |
Family
ID=26265984
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7843847A Withdrawn GB2023425A (en) | 1977-11-11 | 1978-11-09 | Insecticide preparation |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2023425A (en) |
-
1978
- 1978-11-09 GB GB7843847A patent/GB2023425A/en not_active Withdrawn
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |