GB2019862A - Phenoxyalkyl-, thiophenoxyalkyl- and pyridyloxyalkyl-silanes - Google Patents
Phenoxyalkyl-, thiophenoxyalkyl- and pyridyloxyalkyl-silanesInfo
- Publication number
- GB2019862A GB2019862A GB7911609A GB7911609A GB2019862A GB 2019862 A GB2019862 A GB 2019862A GB 7911609 A GB7911609 A GB 7911609A GB 7911609 A GB7911609 A GB 7911609A GB 2019862 A GB2019862 A GB 2019862A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silanes
- thiophenoxyalkyl
- carbon atoms
- formula
- phenoxyalkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000005359 phenoxyalkyl group Chemical group 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal phenoxide Chemical class 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 239000000010 aprotic solvent Substances 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000007822 coupling agent Substances 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000008394 flocculating agent Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 150000004756 silanes Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/302—Water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2125/00—Compositions for processes using internal mould release agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
Novel phenoxyalkyl-, thiophenoxyalkyl- and pyridyl- oxyalkyl-silanes of formula <IMAGE> wherein R<1> is -NH2, NR<4>H, NR2<4>, -CHO, -CN, -COR, Cl, Br, I, -SO2R<4>, -SOR<4>, -NO2, -SR<4> or -OR<4>, R<2> is a methylene group or an alkylene group containing 3 to 12 carbon atoms, each of R<3> and R<4> is selected from alkyl, cycloalkyl, aryl, alkaryl and aralkyl groups, any alkyl group present in R<3> and R<4> containing 1 to 12 carbon atoms, and Z is oxygen or sulphur, are prepared by reacting substantially equimolar amounts of an alkali metal phenoxide, thiophenoxide or pyridyloxide with a silane of formula XR<2>Si(OR<3>)3, where x is halogen, under anhydrous conditions in the presence of a dipolar aprotic solvent and a liquid hydrocarbon. The silanes are useful as coupling agents for glass fibre- reinforced composites, as flocculating agents for water purification and as sizes for glass fibres or fabrics.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US90019778A | 1978-04-26 | 1978-04-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2019862A true GB2019862A (en) | 1979-11-07 |
GB2019862B GB2019862B (en) | 1982-05-19 |
Family
ID=25412119
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7911609A Expired GB2019862B (en) | 1978-04-26 | 1979-04-03 | Phenoxyalkyl-silanes |
Country Status (15)
Country | Link |
---|---|
JP (1) | JPS54144344A (en) |
KR (1) | KR850000074B1 (en) |
BE (1) | BE875801A (en) |
CA (1) | CA1109889A (en) |
CH (1) | CH639392A5 (en) |
DE (1) | DE2915072A1 (en) |
DK (1) | DK148710C (en) |
ES (1) | ES479900A1 (en) |
FR (1) | FR2424281B1 (en) |
GB (1) | GB2019862B (en) |
IT (1) | IT1165955B (en) |
MX (1) | MX149694A (en) |
NL (1) | NL7903128A (en) |
NO (2) | NO156610C (en) |
SE (1) | SE7903595L (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES491385A0 (en) * | 1979-08-08 | 1981-05-16 | A METHOD FOR PREPARING A SILANO | |
CA1152512A (en) * | 1979-08-31 | 1983-08-23 | Abe Berger | Method for preparing aryloxyalkylsilanes |
JP2630596B2 (en) * | 1987-07-27 | 1997-07-16 | 株式会社ブリヂストン | Silane coupling agent |
DE3935638A1 (en) * | 1989-10-26 | 1991-05-02 | Consortium Elektrochem Ind | ORGANOSILYL ALKYL FLAVORS |
JP5245076B2 (en) * | 2008-09-30 | 2013-07-24 | 大同化学工業株式会社 | Waste liquid treatment method |
JP5360814B2 (en) * | 2009-03-12 | 2013-12-04 | 独立行政法人産業技術総合研究所 | Method for producing organic-inorganic composite material |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1054041A (en) * | 1900-01-01 | |||
GB1062418A (en) * | 1964-01-27 | 1967-03-22 | Ici Ltd | New nitrogen-containing siloxanes |
US3355425A (en) * | 1964-08-06 | 1967-11-28 | Dow Corning | Organopolysiloxanes |
DE2215629A1 (en) * | 1972-03-30 | 1973-10-04 | Dynamit Nobel Ag | CORE SUBSTITUTED ARALKYL SILANES |
FR2226407B1 (en) * | 1973-04-17 | 1978-05-26 | Rhone Progil | |
US3926911A (en) * | 1973-06-07 | 1975-12-16 | Ciba Geigy Corp | Crosslinked polymers containing siloxane groups |
FR2245663A1 (en) * | 1973-08-17 | 1975-04-25 | Rhone Progil | Aminophenoxy alkyl silanes and dimers, polymers - by catalytic hydrogenation of corresponding nitrophenols |
FR2243022B1 (en) * | 1973-09-10 | 1977-09-23 | Rhone Progil |
-
1979
- 1979-04-03 GB GB7911609A patent/GB2019862B/en not_active Expired
- 1979-04-06 KR KR7901084A patent/KR850000074B1/en active
- 1979-04-12 DE DE19792915072 patent/DE2915072A1/en active Granted
- 1979-04-13 JP JP4430979A patent/JPS54144344A/en active Pending
- 1979-04-19 FR FR7909922A patent/FR2424281B1/en not_active Expired
- 1979-04-20 NL NL7903128A patent/NL7903128A/en not_active Application Discontinuation
- 1979-04-23 CH CH378979A patent/CH639392A5/en not_active IP Right Cessation
- 1979-04-23 NO NO791349A patent/NO156610C/en unknown
- 1979-04-23 BE BE0/194795A patent/BE875801A/en not_active IP Right Cessation
- 1979-04-24 SE SE7903595A patent/SE7903595L/en not_active Application Discontinuation
- 1979-04-24 MX MX177424A patent/MX149694A/en unknown
- 1979-04-24 IT IT09404/79A patent/IT1165955B/en active
- 1979-04-25 CA CA326,358A patent/CA1109889A/en not_active Expired
- 1979-04-25 DK DK170779A patent/DK148710C/en active IP Right Grant
- 1979-04-25 ES ES479900A patent/ES479900A1/en not_active Expired
-
1985
- 1985-04-30 NO NO851716A patent/NO851716L/en unknown
Also Published As
Publication number | Publication date |
---|---|
CA1109889A (en) | 1981-09-29 |
NO791349L (en) | 1979-10-29 |
NO156610B (en) | 1987-07-13 |
FR2424281B1 (en) | 1985-06-28 |
IT7909404A0 (en) | 1979-04-24 |
ES479900A1 (en) | 1979-11-16 |
DK148710B (en) | 1985-09-09 |
GB2019862B (en) | 1982-05-19 |
JPS54144344A (en) | 1979-11-10 |
KR850000074B1 (en) | 1985-02-18 |
DE2915072A1 (en) | 1979-11-08 |
NO851716L (en) | 1979-10-29 |
DK170779A (en) | 1979-10-27 |
DE2915072C2 (en) | 1989-08-10 |
NO156610C (en) | 1987-10-21 |
KR830001963A (en) | 1983-05-21 |
DK148710C (en) | 1986-01-27 |
CH639392A5 (en) | 1983-11-15 |
MX149694A (en) | 1983-12-13 |
FR2424281A1 (en) | 1979-11-23 |
NL7903128A (en) | 1979-10-30 |
BE875801A (en) | 1979-08-16 |
IT1165955B (en) | 1987-04-29 |
SE7903595L (en) | 1979-10-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |