GB2013207A - Hydrosilylation Catalysts - Google Patents
Hydrosilylation CatalystsInfo
- Publication number
- GB2013207A GB2013207A GB7844197A GB7844197A GB2013207A GB 2013207 A GB2013207 A GB 2013207A GB 7844197 A GB7844197 A GB 7844197A GB 7844197 A GB7844197 A GB 7844197A GB 2013207 A GB2013207 A GB 2013207A
- Authority
- GB
- United Kingdom
- Prior art keywords
- group
- hydrosilylation catalysts
- complexes
- catalysts
- hydrogermylation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000006459 hydrosilylation reaction Methods 0.000 title abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000003800 germyl group Chemical group [H][Ge]([H])([H])[*] 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000002940 palladium Chemical class 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 125000002577 pseudohalo group Chemical group 0.000 abstract 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/14—Preparation thereof from optionally substituted halogenated silanes and hydrocarbons hydrosilylation reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0013—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0825—Preparations of compounds not comprising Si-Si or Si-cyano linkages
- C07F7/0827—Syntheses with formation of a Si-C bond
- C07F7/0829—Hydrosilylation reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/30—Germanium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
Abstract
Binuclear platinum or palladium complexes having the general formulae: <IMAGE> where X is H, a silyl group, an alkyl group, a germyl group, an aryl group, a vinyl group, a halogen, or a pseudohalogen, and L is a TT-acceptor ligand, and methods of effecting hydrosilylation and hydrogermylation using such complexes as catalysts.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB7844197A GB2013207B (en) | 1977-11-14 | 1978-11-13 | Hydrosilylation catalysts |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4732077 | 1977-11-14 | ||
GB7844197A GB2013207B (en) | 1977-11-14 | 1978-11-13 | Hydrosilylation catalysts |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2013207A true GB2013207A (en) | 1979-08-08 |
GB2013207B GB2013207B (en) | 1982-10-27 |
Family
ID=26266016
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7844197A Expired GB2013207B (en) | 1977-11-14 | 1978-11-13 | Hydrosilylation catalysts |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2013207B (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0355224A1 (en) * | 1988-08-22 | 1990-02-28 | E.I. Du Pont De Nemours And Company | 1,4 -O- metallation process and composition |
EP0460589A1 (en) * | 1990-06-07 | 1991-12-11 | Shin-Etsu Chemical Co., Ltd. | Method for the preparation of cyclopentyl Trichlorosilane |
EP0546716A1 (en) * | 1991-12-07 | 1993-06-16 | Dow Corning Limited | Hydrosilylation process |
EP1236731A1 (en) * | 2001-02-26 | 2002-09-04 | General Electric Company | Method and apparatus for forming a carbon-silicon bond in a silane |
WO2004030816A1 (en) * | 2002-10-04 | 2004-04-15 | Johnson Matthey Public Limited Company | Hydrosilation catalyst |
US20140330024A1 (en) * | 2013-05-06 | 2014-11-06 | Crisita Carmen Hojilla Atienza | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
US9381506B2 (en) | 2013-11-19 | 2016-07-05 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
US9381505B2 (en) | 2013-11-19 | 2016-07-05 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
US9387468B2 (en) | 2013-11-19 | 2016-07-12 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
US9440999B2 (en) | 2013-05-15 | 2016-09-13 | Momentive Performance Materials Inc. | Activation of metal salts with silylhydrides and their use in hydrosilylation reactions |
US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
US9782763B2 (en) | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
CN108516993A (en) * | 2018-05-07 | 2018-09-11 | 广东工业大学 | A kind of sulfur poisoning-resistant platinum complex compound and its application |
-
1978
- 1978-11-13 GB GB7844197A patent/GB2013207B/en not_active Expired
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0355224A1 (en) * | 1988-08-22 | 1990-02-28 | E.I. Du Pont De Nemours And Company | 1,4 -O- metallation process and composition |
EP0460589A1 (en) * | 1990-06-07 | 1991-12-11 | Shin-Etsu Chemical Co., Ltd. | Method for the preparation of cyclopentyl Trichlorosilane |
EP0546716A1 (en) * | 1991-12-07 | 1993-06-16 | Dow Corning Limited | Hydrosilylation process |
EP1236731A1 (en) * | 2001-02-26 | 2002-09-04 | General Electric Company | Method and apparatus for forming a carbon-silicon bond in a silane |
US6489501B2 (en) | 2001-02-26 | 2002-12-03 | General Electric Company | Method and apparatus for forming a carbon-silicon bond in a silane |
WO2004030816A1 (en) * | 2002-10-04 | 2004-04-15 | Johnson Matthey Public Limited Company | Hydrosilation catalyst |
US9782763B2 (en) | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
US11052383B2 (en) | 2011-12-14 | 2021-07-06 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
US9890182B2 (en) | 2013-05-06 | 2018-02-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
US20140330024A1 (en) * | 2013-05-06 | 2014-11-06 | Crisita Carmen Hojilla Atienza | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
WO2014182670A3 (en) * | 2013-05-06 | 2015-02-19 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
US9440999B2 (en) | 2013-05-15 | 2016-09-13 | Momentive Performance Materials Inc. | Activation of metal salts with silylhydrides and their use in hydrosilylation reactions |
US9387468B2 (en) | 2013-11-19 | 2016-07-12 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
US9381505B2 (en) | 2013-11-19 | 2016-07-05 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
US9381506B2 (en) | 2013-11-19 | 2016-07-05 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
CN108516993A (en) * | 2018-05-07 | 2018-09-11 | 广东工业大学 | A kind of sulfur poisoning-resistant platinum complex compound and its application |
CN108516993B (en) * | 2018-05-07 | 2020-11-10 | 广东工业大学 | Sulfur poisoning resistant platinum complex and application thereof |
Also Published As
Publication number | Publication date |
---|---|
GB2013207B (en) | 1982-10-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |