GB2005274A - Process for the production of methylaminomethylphosphonic acid esters and of the corresponding acid - Google Patents
Process for the production of methylaminomethylphosphonic acid esters and of the corresponding acidInfo
- Publication number
- GB2005274A GB2005274A GB7839087A GB7839087A GB2005274A GB 2005274 A GB2005274 A GB 2005274A GB 7839087 A GB7839087 A GB 7839087A GB 7839087 A GB7839087 A GB 7839087A GB 2005274 A GB2005274 A GB 2005274A
- Authority
- GB
- United Kingdom
- Prior art keywords
- production
- methylaminomethylphosphonic
- acid
- acid esters
- esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
- C07F9/657181—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom the ring phosphorus atom and, at least, one ring oxygen atom being part of a (thio)phosphonic acid derivative
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
- C07F9/3804—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se) not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Abstract
A process for the production of methylaminomethylphosphonic acid and its esters is disclosed. It comprises heating trimethylhexahydro-s-triazine with at least 3 moles of a sterically hindered secondary phosphite and if desired converting the resulting diester or salt thereof into a corresponding hemiester or the methylaminomethylphosphonic acid. The invention also includes as novel compounds the diesters and hemiesters obtainable by the defined process.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/182,170 US4351779A (en) | 1977-10-04 | 1980-08-28 | Process for the production of methylaminomethylphosphonic acid esters |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH1210077 | 1977-10-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2005274A true GB2005274A (en) | 1979-04-19 |
GB2005274B GB2005274B (en) | 1982-01-13 |
Family
ID=4379852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7839087A Expired GB2005274B (en) | 1977-10-04 | 1978-10-03 | Process for the production of methylaminomethylphosphonic acod esters and of the corresponding acid |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2005274B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4442044A (en) * | 1981-06-19 | 1984-04-10 | Monsanto Company | Process for preparing monoesters and diesters of N-alkyl substituted amino methyl phosphonic acid |
-
1978
- 1978-10-03 GB GB7839087A patent/GB2005274B/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4442044A (en) * | 1981-06-19 | 1984-04-10 | Monsanto Company | Process for preparing monoesters and diesters of N-alkyl substituted amino methyl phosphonic acid |
Also Published As
Publication number | Publication date |
---|---|
GB2005274B (en) | 1982-01-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |