GB2003474A - Liquid phase fluorination process - Google Patents
Liquid phase fluorination processInfo
- Publication number
- GB2003474A GB2003474A GB7834925A GB7834925A GB2003474A GB 2003474 A GB2003474 A GB 2003474A GB 7834925 A GB7834925 A GB 7834925A GB 7834925 A GB7834925 A GB 7834925A GB 2003474 A GB2003474 A GB 2003474A
- Authority
- GB
- United Kingdom
- Prior art keywords
- liquid phase
- phase fluorination
- fluorination process
- moocl3
- moo2cl2
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007791 liquid phase Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000003682 fluorination reaction Methods 0.000 title 1
- XZQYTGKSBZGQMO-UHFFFAOYSA-I rhenium pentachloride Chemical compound Cl[Re](Cl)(Cl)(Cl)Cl XZQYTGKSBZGQMO-UHFFFAOYSA-I 0.000 abstract 2
- 229910015227 MoCl3 Inorganic materials 0.000 abstract 1
- 229910015218 MoCl4 Inorganic materials 0.000 abstract 1
- 229910015255 MoF6 Inorganic materials 0.000 abstract 1
- -1 MoOCl3 Chemical compound 0.000 abstract 1
- 229910015686 MoOCl4 Inorganic materials 0.000 abstract 1
- 229910019804 NbCl5 Inorganic materials 0.000 abstract 1
- 229910019787 NbF5 Inorganic materials 0.000 abstract 1
- 229910019594 ReF5 Inorganic materials 0.000 abstract 1
- 229910004537 TaCl5 Inorganic materials 0.000 abstract 1
- 229910004546 TaF5 Inorganic materials 0.000 abstract 1
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- ASLHVQCNFUOEEN-UHFFFAOYSA-N dioxomolybdenum;dihydrochloride Chemical compound Cl.Cl.O=[Mo]=O ASLHVQCNFUOEEN-UHFFFAOYSA-N 0.000 abstract 1
- RLCOZMCCEKDUPY-UHFFFAOYSA-H molybdenum hexafluoride Chemical compound F[Mo](F)(F)(F)(F)F RLCOZMCCEKDUPY-UHFFFAOYSA-H 0.000 abstract 1
- OYMJNIHGVDEDFX-UHFFFAOYSA-J molybdenum tetrachloride Chemical compound Cl[Mo](Cl)(Cl)Cl OYMJNIHGVDEDFX-UHFFFAOYSA-J 0.000 abstract 1
- ZSSVQAGPXAAOPV-UHFFFAOYSA-K molybdenum trichloride Chemical compound Cl[Mo](Cl)Cl ZSSVQAGPXAAOPV-UHFFFAOYSA-K 0.000 abstract 1
- SFPKXFFNQYDGAH-UHFFFAOYSA-N oxomolybdenum;tetrahydrochloride Chemical compound Cl.Cl.Cl.Cl.[Mo]=O SFPKXFFNQYDGAH-UHFFFAOYSA-N 0.000 abstract 1
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 abstract 1
- AOLPZAHRYHXPLR-UHFFFAOYSA-I pentafluoroniobium Chemical compound F[Nb](F)(F)(F)F AOLPZAHRYHXPLR-UHFFFAOYSA-I 0.000 abstract 1
- YRGLXIVYESZPLQ-UHFFFAOYSA-I tantalum pentafluoride Chemical compound F[Ta](F)(F)(F)F YRGLXIVYESZPLQ-UHFFFAOYSA-I 0.000 abstract 1
- OEIMLTQPLAGXMX-UHFFFAOYSA-I tantalum(v) chloride Chemical compound Cl[Ta](Cl)(Cl)(Cl)Cl OEIMLTQPLAGXMX-UHFFFAOYSA-I 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B39/00—Halogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
A liquid phase process in which aromatic compounds having at least one halomethyl substituent are fluorinated in the side-claim by reaction with HF using, as catalyst, TaCl5, NbCl5, ReCl5, TaF5, NbF5, ReF5, MoCl3, MoCl4, MoOCl3, MoOCl4, MoO2Cl2, or MoF6.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82984777A | 1977-09-01 | 1977-09-01 | |
US05/829,846 US4129602A (en) | 1977-09-01 | 1977-09-01 | Liquid phase fluorination process |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2003474A true GB2003474A (en) | 1979-03-14 |
GB2003474B GB2003474B (en) | 1982-03-17 |
Family
ID=27125304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7834925A Expired GB2003474B (en) | 1977-09-01 | 1978-08-30 | Liquid phase fluorination process |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5446726A (en) |
BR (1) | BR7805684A (en) |
CA (1) | CA1108651A (en) |
DE (1) | DE2837690A1 (en) |
FR (1) | FR2401892A1 (en) |
GB (1) | GB2003474B (en) |
IT (1) | IT1202766B (en) |
NL (1) | NL7808902A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024029524A1 (en) * | 2022-08-02 | 2024-02-08 | ダイキン工業株式会社 | Method for producing fluorine-containing aromatic compound |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1967244A (en) * | 1932-08-31 | 1934-07-24 | Kinetic Chemicals Inc | Production of organic fluorine compounds |
US3258500A (en) * | 1959-08-17 | 1966-06-28 | Du Pont | Process for fluorinating halohydro-carbons |
US3859372A (en) * | 1969-12-03 | 1975-01-07 | Hooker Chemicals Plastics Corp | Process for the preparation of organic fluorine compounds |
US4098832A (en) * | 1976-11-01 | 1978-07-04 | Hooker Chemicals & Plastics Corp. | Fluorination process catalysed by molybdenum pentachloride |
-
1978
- 1978-08-24 CA CA310,012A patent/CA1108651A/en not_active Expired
- 1978-08-29 DE DE19782837690 patent/DE2837690A1/en active Granted
- 1978-08-30 NL NL7808902A patent/NL7808902A/en not_active Application Discontinuation
- 1978-08-30 FR FR7825044A patent/FR2401892A1/en active Granted
- 1978-08-30 GB GB7834925A patent/GB2003474B/en not_active Expired
- 1978-08-30 JP JP10616578A patent/JPS5446726A/en active Granted
- 1978-08-31 BR BR7805684A patent/BR7805684A/en unknown
- 1978-09-01 IT IT27262/78A patent/IT1202766B/en active
Also Published As
Publication number | Publication date |
---|---|
IT1202766B (en) | 1989-02-09 |
CA1108651A (en) | 1981-09-08 |
GB2003474B (en) | 1982-03-17 |
IT7827262A0 (en) | 1978-09-01 |
BR7805684A (en) | 1979-04-24 |
JPS6334128B2 (en) | 1988-07-08 |
DE2837690C2 (en) | 1988-03-17 |
FR2401892A1 (en) | 1979-03-30 |
NL7808902A (en) | 1979-03-05 |
FR2401892B1 (en) | 1984-05-25 |
JPS5446726A (en) | 1979-04-12 |
DE2837690A1 (en) | 1979-03-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19940830 |