GB1603446A - Electrodeposition of zinc - Google Patents
Electrodeposition of zinc Download PDFInfo
- Publication number
- GB1603446A GB1603446A GB1699178A GB1699178A GB1603446A GB 1603446 A GB1603446 A GB 1603446A GB 1699178 A GB1699178 A GB 1699178A GB 1699178 A GB1699178 A GB 1699178A GB 1603446 A GB1603446 A GB 1603446A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zinc
- bath
- electroplating bath
- carbon atoms
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 52
- 229910052725 zinc Inorganic materials 0.000 title claims description 52
- 239000011701 zinc Substances 0.000 title claims description 52
- 238000004070 electrodeposition Methods 0.000 title description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 239000007795 chemical reaction product Substances 0.000 claims description 15
- 238000009713 electroplating Methods 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- -1 quaternary ammonium halide Chemical class 0.000 claims description 11
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 238000005282 brightening Methods 0.000 claims description 4
- 125000004181 carboxyalkyl group Chemical group 0.000 claims description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 238000000151 deposition Methods 0.000 claims 3
- 239000002659 electrodeposit Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 33
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 238000007747 plating Methods 0.000 description 11
- 235000011121 sodium hydroxide Nutrition 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 4
- 229920001281 polyalkylene Polymers 0.000 description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 4
- CSPHGSFZFWKVDL-UHFFFAOYSA-M (3-chloro-2-hydroxypropyl)-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC(O)CCl CSPHGSFZFWKVDL-UHFFFAOYSA-M 0.000 description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 3
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 230000002152 alkylating effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- OLVYOPBFTQXYON-UHFFFAOYSA-M (3-bromo-2-hydroxypropyl)-trimethylazanium;bromide Chemical compound [Br-].C[N+](C)(C)CC(O)CBr OLVYOPBFTQXYON-UHFFFAOYSA-M 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000001888 Peptone Substances 0.000 description 1
- 108010080698 Peptones Proteins 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 235000019319 peptone Nutrition 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- GTLDTDOJJJZVBW-UHFFFAOYSA-N zinc cyanide Chemical compound [Zn+2].N#[C-].N#[C-] GTLDTDOJJJZVBW-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C08G73/0226—Quaternisation of polyalkylene(poly)amines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US79380577A | 1977-05-04 | 1977-05-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1603446A true GB1603446A (en) | 1981-11-25 |
Family
ID=25160844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1699178A Expired GB1603446A (en) | 1977-05-04 | 1978-04-28 | Electrodeposition of zinc |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS53137833A (enExample) |
| AU (1) | AU519624B2 (enExample) |
| CA (1) | CA1119997A (enExample) |
| DE (1) | DE2819161C2 (enExample) |
| FR (1) | FR2389688B1 (enExample) |
| GB (1) | GB1603446A (enExample) |
| NL (1) | NL185359C (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2294472A (en) * | 1994-10-25 | 1996-05-01 | Enthone Omi Inc | Cationic quaternary ammonium polymer additive in alkaline zinc and zinc alloy electroplating baths |
| EP2431500A1 (de) * | 2010-09-21 | 2012-03-21 | Dr.Ing. Max Schlötter GmbH & Co. KG | Regeneration alkalischer Zinknickelelektrolyte durch Entfernen von Cyanidionen mit Hilfe von löslichen quartären Ammoniumverbindungen |
| US10633755B2 (en) * | 2015-09-10 | 2020-04-28 | Atotech Deutschland Gmbh | Copper plating bath composition and method for deposition of copper |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3853718A (en) * | 1973-01-05 | 1974-12-10 | Oxy Metal Finishing Corp | Method to improve zinc deposition employing multi-nitrogen quaternaries |
| FR2276394A2 (fr) * | 1974-06-28 | 1976-01-23 | Popescu Francine | Zingage electrolytique brillant en bain alcalin |
-
1978
- 1978-04-11 CA CA000300888A patent/CA1119997A/en not_active Expired
- 1978-04-21 FR FR7811895A patent/FR2389688B1/fr not_active Expired
- 1978-04-28 GB GB1699178A patent/GB1603446A/en not_active Expired
- 1978-05-02 DE DE19782819161 patent/DE2819161C2/de not_active Expired
- 1978-05-03 NL NL7804809A patent/NL185359C/xx not_active IP Right Cessation
- 1978-05-03 AU AU35726/78A patent/AU519624B2/en not_active Expired
- 1978-05-04 JP JP5364078A patent/JPS53137833A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2294472A (en) * | 1994-10-25 | 1996-05-01 | Enthone Omi Inc | Cationic quaternary ammonium polymer additive in alkaline zinc and zinc alloy electroplating baths |
| GB2294472B (en) * | 1994-10-25 | 1998-04-29 | Enthone Omi Inc | Alkaline zinc and zinc alloy electroplating baths and processes |
| EP2431500A1 (de) * | 2010-09-21 | 2012-03-21 | Dr.Ing. Max Schlötter GmbH & Co. KG | Regeneration alkalischer Zinknickelelektrolyte durch Entfernen von Cyanidionen mit Hilfe von löslichen quartären Ammoniumverbindungen |
| US10633755B2 (en) * | 2015-09-10 | 2020-04-28 | Atotech Deutschland Gmbh | Copper plating bath composition and method for deposition of copper |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2389688B1 (enExample) | 1983-01-28 |
| JPS5628997B2 (enExample) | 1981-07-06 |
| AU519624B2 (en) | 1981-12-17 |
| AU3572678A (en) | 1979-11-08 |
| NL185359B (nl) | 1989-10-16 |
| JPS53137833A (en) | 1978-12-01 |
| DE2819161A1 (de) | 1978-11-16 |
| NL7804809A (nl) | 1978-11-07 |
| DE2819161C2 (de) | 1982-11-11 |
| FR2389688A1 (enExample) | 1978-12-01 |
| NL185359C (nl) | 1990-03-16 |
| CA1119997A (en) | 1982-03-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3706634A (en) | Electrochemical compositions and processes | |
| US4134802A (en) | Electrolyte and method for electrodepositing bright metal deposits | |
| US4246077A (en) | Non-cyanide bright silver electroplating bath therefor, silver compounds and method of making silver compounds | |
| US4098656A (en) | Bright palladium electroplating baths | |
| US5405523A (en) | Zinc alloy plating with quaternary ammonium polymer | |
| US4169772A (en) | Acid zinc plating baths, compositions useful therein, and methods for electrodepositing bright zinc deposits | |
| US3853718A (en) | Method to improve zinc deposition employing multi-nitrogen quaternaries | |
| US4877496A (en) | Zinc-nickel alloy plating solution | |
| US5169514A (en) | Plating compositions and processes | |
| GB2144769A (en) | Zinc and zinc alloy electroplating | |
| US4066517A (en) | Electrodeposition of palladium | |
| EP1075553B1 (en) | Zinc and zinc alloy electroplating additives and electroplating methods | |
| US3884774A (en) | Electrolytic deposition of zinc | |
| DE3428277A1 (de) | Waessriges bad und ein verfahren zur galvanischen abscheidung einer zink-eisen-legierung | |
| US4061547A (en) | Acidic plating bath and additives for electrodeposition of bright tin | |
| EP1315849B1 (en) | Zinc and zinc alloy electroplating methods | |
| CA1050472A (en) | Zinc electrodeposition process and bath for use therein | |
| US4002543A (en) | Electrodeposition of bright nickel-iron deposits | |
| US3824158A (en) | Composition of baths for electrodeposition of bright zinc | |
| CA1077429A (en) | Bath and process for the electrodeposition of a palladium-nickel alloy | |
| US3871974A (en) | Alkaline bright zinc plating | |
| US4730022A (en) | Polymer compositions and alkaline zinc electroplating baths | |
| US4101387A (en) | Composition for electrodeposition of metal deposits, its method of preparation and uses thereof | |
| US4113583A (en) | Method for brightening the electrodeposits of zinc from alkaline zinc electroplating baths | |
| GB1603446A (en) | Electrodeposition of zinc |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19940428 |