GB1592592A

GB1592592A - Cumene production

Info

Publication number: GB1592592A
Application number: GB2699/77A
Authority: GB
Original assignee: UOP LLC
Current assignee: Honeywell UOP LLC
Priority date: 1978-01-23
Filing date: 1978-01-23
Publication date: 1981-07-08

Description

(54) CUMENE PRODUCTION (71) We, UOP INC, a corporation organized under the laws of the State of Delaware United States of America, of Ten UOP Plaza, Algonquin & Mt. Prospect Roads, Des Plaines, Illinois, 60016, United States of America, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following state ment This invention relates to an improved process for producing cumene from benzene and propylene in the presence of an alkylation catalyst and including the transalkylation of di- and triisopropylbenzene obtained as by-products with benzene in the presence of a transalkylation catalyst to produce additional cumene.

Cumene, otherwise known as isopropylbenzene, is a reactant finding utility in the preparation of phenol, acetone, alphamethylstyrene and acetophenone.

In the usual commercial process for the production of cumene, it is the practice to charge liquid benzene and liquid propylene into a reactor and to react the same therein in one or more alkylation zones in contact with an alkylation catalyst. In order to minimize the production of dialkylated products of benzene it has been the practice to maintain a molar excess of benzene throughout the reaction zone ranging from 4:1 to 16:1, and more preferably about 8:1 of benzene to propylene. Two competing reactions with the desired production of isopropylbenzene have created problems in the prior commercial processes used. One of these as indicated above has been the formation of dialkylated benzenes such as di- and triisopropylbenzene rather than the desired monoalkylated product. This competing reaction has been controlled by means of employing large molar excesses of benzene as indicated above. The other competing reaction causing losses in the yield of cumene based on propylene reactant charged is the formation of oligomers of propylene such as propylene dimer and trimer which occur to a limited extent even with the large molar excesses of benzene present. Propylene trimers and some of the propylene tetramers boil with cumene. Since the presence of these olefins interfere with the oxidation reaction used to make phenol from cumene, this oligomerization side reaction must be minimized to make a high purity product.

The alkylation of benzene is exothermic in nature and the temperature within the reactor tends to increase at a rapid rate. This increase in temperature caused by the exothermic reaction likewise tends to increase the production of cumene bottoms products by the competing reactions. In the past it has been customary to control the temperature rise by catalyzing the reaction in multiple separate zones and employing a quenching medium between each of several successive alkylation zones. This quenching has served to control the temperature at which the reaction mixture enters each successive zone and thus the temperature rise throughout each zone. The temperature rise from inlet to outlet of the reactor has also been controlled by controlling the molar excess of benzene charged to the reactor, the benzene acting as a heat sink to absorb heat released by the alkylation reaction. Accordingly, increasing the molar excess of benzene charged to the reactor, with a corresponding dilution of the propylene reactant therein, not only provides more aromatic sites subject to alkylation and a resulting reduction in oligomers and over alkylated by-products, but also reduces the formation of undesirable by-products resulting from an excessive temperature rise across an alkylation zone or zones.

To obtain the desired high molar excess of benzene in the reactor charge, it has been the practice to separate the reaction zone effluent to obtain a benzene-rich stream suitabie to recycle to the reactor. Since the two principal components of the reaction zone effluent are benzene and cumene, it is necessary to make a separation of the benzene and cumene, the latter being the higher boiling component.

Consequently, to obtain a purified stream of benzene relatively free of cumene and suitable for recycling to the reaction zone, benzene is vaporized and fractionated, thus requiring consumption of suhstantial heat to vaporize benzene and provide adequate reflux in a benzene fractionator, the heat requirement being substantially proportional to the ratio of benzene to propylcne desired in the charge to the reactor. At the present time, relatively high fuel cost necessitates review of processes requiring high utility consumption with the result that alternative processing schemes which previously were unattractive are becoming more desirable if utility consumption is reduced.

The present invention seeks to provide an improved process for the alkylation of benzene with propyl( nc to produce cumene in the presence of a solid phosphoric acid catalyst, the process requiring a relatively lower molar excess of benzene to propylene than prior art processes as provided by recycle of excess benzene separated from the reaction zone effluent.

According to the present invention there is provided a process for the production of cumene which comprises the steps of: (a) reacting propylene with an excess of benzene in the presence of a solid phosphoric acid alkylation catalyst at alkylation reaction conditions in an alkylation zone: (b) dividing the total liquid effluent from the alkylation zone into at least two portions of like composition; (c) recirculating one of said portions of the efflrlcnt to the alkylation zone: (d) introducing another of said portions of the effluent and a transalkylation zone effluent stream, formed as hereinafter set forth, into a separation zone; (e) separating from the admixed effluents in the separation zone a benzene-rich stream, a cumene product stream and a di- and tri-isopropylbenzene-rich stream; (f) transalkylating the last named stream with benzene in the presence of a transalkylation catalyst in a transalkylation zone to form additional cumene; (g) supplying the effluent of the last mentioned zone to the separation zone as the transalkylation zone effluent stream; (h) passing at least a portion of the benzene-rich stream from the separation zone to the alkylation reaction zone; and (i) recovering the cumene product stream from the separation zone.

Thus, in the process of the present invention, propylene and excess benzene are reacted in an alkylation reaction zone wherein a solid phosphoric acid alkylation catalyst is employed, and a portion of the resultant effluent is recirculated without separation to the inlet of the reaction zone. A second portion of reaction zone effluent, i.e., net effluent, is passed into a separation zone in which excess benzene, cumene, di- and triisopropylbenzene, and other components are separated. As stated hereinabove, it is desirable to reduce the quantity of excess benzene separated from the net effluent stream in order to reduce utility consumption. while at the same time it is desired to maintain a sufficient quantity of excess benzene in the reaction zone to prevent excessive formation of propylene oligomers.

This is accomplished by recirculation of a portion of the resultant reaction zone effluent without separation. The principal effects of operation in the hereinabove described manner include: (1) a reduction of utility consumption resulting from a reduction of excess benzene separated from cumene in the net reaction zone effluent stream; and (2) formation of relatively more di- and trialkylated benzene products than in processes known in the prior art. In the separation zone of the present process, di- and triisopropylbenzenes are concentrated and passed in admixture with excess benzene into a transalkylation reaction zone, wherein a transalkylation catalyst is employed in a preferred embodiment. The cumene-rich transalkylation reaction zone effluent stream is returned to the separation zone.

This invention will now be described with reference to the drawing accompanying the provisional specification which illustrates a preferred embodiment. While of necessity, certain limitations must be present in such a schematic description, no intention is meant thereby to limit the generally broad scope of the invention. As stated hereinabove, the first step of the process of the present invention comprises alkylating benzene with propylene in an akylation reaction zone in the presence of a solid phosphoric alkylation catalyst. In the drawing, this first step is represented as taking place in alkylation reaction zone 1.

However, a mixture of benzene and propylene must be furnished to this reaction zone.

In the drawing, a propylene-rich feed stream is supplied to the alkylation zone 1 via conduit 2; benzene is prepared as a recycle stream as hereinbelow described and furnished to the alkylation zone 1 via conduit 3, which links with conduit 2; and an alkylation zone effluent recirculation stream including principally benzene and cumene is prepared as described hereinbelow and furnished to the alkylation zone inlet via conduits 4 and 2.

The last-mentioned stream provides additional benzene for the purpose of increasing the benzene/propylene molar ratio in the alkylation reaction zone. The combined mixture of propylene reactant, recycle benzene, and recirculated reaction zone effluent is then introduced into reaction zone I via conduit 2. Effluent from the alkylation reaction zone 1 is withdrawn via conduit 5, a portion is recirculated via conduit 4 to provide the recirculation stream described hereinabove, and the remaining portion is passed via conduit 5 into a separation zone 6.

Also introduced into the separation zone 6 is an effluent stream from a transalkylation reaction zone as described hereinbelow, the transalkylation zone effluent stream passing through conduit 7. A benzene feed stream via conduit 8 is also introduced into the separation zone 6 of the present process.

The propylene-rich feed stream supplied to the alkylation reaction zone via conduit 2 can be prepared as an effluent stream from various processes such as fluid catalytic cracking or pyrolysis, and will normally include non-reactive paraffins, principally propane, but also substantially smaller quantities of ethane and butane. Olefins other than propylene result in undesirable products in the alkylation reaction to produce cumene, therefore propylene normally forms at least 99 percent of the olefin content of this stream. The benzene feed stream introduced into the process in conduit 8 is a high purity stream commonly containing at least 99.5 percent benzene which is frequently available as an effluent stream from an aromatics extraction process. Other aromatics are harmful in the sense that undesirable byproducts result from their presence, and nonaromatics are normally undesirable because of difficulty in separation of these nonaromatics from benzene in the separation zone 6. Accordingly, the present process, the streams introduced into the separation zone 6 are principally composed of benzene, cumene, propane, and di- and triisopropylbenzene, with relatively smaller amounts of light paraffins (ethane and butane), aromatics (toluene and xylene), butylbenzene, and oligomers of propylene.

In the separation zone 6, by suitable combination of flashing, fractionation, absorption, and stripping, several streams are separated to withdraw the inlet components stated hereinabove. A propane-rich product stream including other light paraffins is withdrawn via conduit 9; a benzene-rich product drag stream including non-aromatic components is withdrawn via conduit 10; an excess benzene-rich stream is withdrawn via conduit 3, a portion is recycled to the alkylation reaction zone I via conduit 3 as hereinabove described and a second portion is passed via conduit Il to a transalkylation reaction zone as described hereinbelow; a butylbenzene-rich product stream is withdrawn via conduit 12; a cumene product stream is withdrawn via conduit 13; a propylene oligomer product stream is withdrawn via conduit 14; and a di- and triisopropylbenzene-rich stream is withdrawn via conduit 15.

The di- and triisopropylbenzene-rich stream withdrawn from the separation zone via conduit 15 is admixed with recycle benzene via conduit I I, and the mixture is passed into a transalkylation reaction zone 16, which in a preferred embodiment contains a solid phosphoric acid catalyst. Cumene-rich effluent of the transalkylation reaction zone is passed via conduit 7 into the separation zone 6, as descried hereinabove.

The reactants used in the present invention to produce cumene are propylene and benzene. Propylene is normally supplied in admixture with propane in an effluent stream from a fluid catalytic cracking unit, a pyrolysis unit, a thermal cracking unit, or other refining unit. Other light paraffinic hydrocarbons such as ethane and butane may be present in limited quantity in a propylenerich feed stream to the present process, but olefinic compounds other than propylene lead to production of alkyl-aromatics other than cumene and accordingly are undesirable as a feedstock. A typical propylene feed stream is as follows in mole percent: ethane 0.10, propane 24.80, propylene 74.95, isobutane 0.11, n-butane 0.01, and butylene 0.03.

Benzene is supplied to the present process in high purity, greater than 99.5 percent, to prevent undesirable side reactions and to eliminate additional fractionation requirements to separate benzene and close boiling non-aromatic components within the present process. A typical benzene feed stream is prepared in an aromatics extraction unit and contains the following components in mole percent: benzene 99.90, toluene 0.05, and non-aromatics 0.05. While in the drawing referred to above the benzene feed stream is introduced into the separation zone of the process, this stream may also be introduced into the alkylation reaction zone or the transalkylation reaction zone.

The inlet stream to the alkylation reaction zone of the present process comprises three streams in admixture: the fresh propylenerich feed stream, a recirculated portion of the resultant effluent from the alkylation reaction zone as described hereinbelow, and a benzene-rich stream which may be supplied to the present process as a fresh feed stream, or more preferably, as a recycle benzene-rich stream as described hereinbelow. Typical operating conditions in the alkylation reaction zone include an inlet temperature of 150 to 260'C. with a preferred temperature of 195 to 215"C.; 20 to 60 atmospheres pressure; 0.2 to 2 volumes of catalyst per volume/hour of net reaction zone effluent hereinbelow defined, 2 to 6 moles of benzene in the recycle benzene-rich stream per mole of propylene in the inlet stream to the alkylation reaction zone, with a preferred molar ratio of recycle benzene to propylene in the inlet stream of about 3:1, and I to 100 moles of benzene in the recirculated effluent stream per mole of propylene in the inlet stream to the alkylation reaction zone, with a preferred molar ratio of recirculated benzene to propylene in the inlet stream of 3:1 to 20:1. The process of the present invention may be carried out in a single reactor or in multiple reactors in series or parallel flow, flow through each reactor being downflow, upflow, radial flow, or other. there being no limitation in the inventive concept to the configuration of reaction zone design.

The alkylation step of the present invention is carried out in the presence of a solid phosphoric acid catalyst. Solid phosphoric acid catalysts for use in the method of the present invention may be made by mixing an acid of phosphorus. such as ortho-, pyro- or tetra-phosphoric cid. and a finely divided.

generally siliceous. solid carrier (such as diatomaceous enrlh. prepared forms of silica or rcactivated clays) to form a wet paste. The paste is then calcined at temperatures generally below 5()0at to produce a solid cake which is thereafter ground and sized to produce particles of useable mesh. If the calcination is carried out at temperatures above 4()f)'C., it may be desirable to rehydrate the catalyst granules at a temperature between 200"C. and 350"C., typically 260"C., to produce an acid composition corresponding to high alkylating activity. The catalyst preparation procedure may be varied by forming particles of the original paste by extrusion or by pelleting methods after which the formed particles are calcined and, if necessary, rehydrated. A solid phosphoric acid catalyst prepared from a major proportion by weight of a phosphoric acid having at least as large a water content as that of the pyro acid and a minor proportion of the siliceous carrier, such as kieselguhr, is preferred for use in the present process. In a preferred embodiment of the present invention, the solid phosphoric acid alkylation catalyst includes 50 to 75 percent by weight phosphorus. A further description of a satisfactory solid phosphoric acid catalyst is available in U.S. Patent No. 1,993,513.

The resultant effluent of the alkylation reaction zone is divided into two streams, the first being a recirculated effluent stream and the second being a net reaction zone effluent stream. An important part of the inventive concept of the present process concerns recirculating a portion of the alkylation reaction zone effluent to the inlet of the alkylation zone to admix with the fresh propylene-rich feed stream and the recycle benzene-rich stream to form the inlet stream to the alkylation reaction zone as described hereinabove. The alkylation zone effluent is principally composed of benzene with relatively lesser amounts of propane, cumene, and di- and triisopropylbenzene, and relatively even smaller amounts of butylbenzene, propylene, oligomers and non-aromatics.

Propylene is essentially 100 percent reacted in the alkylation reaction zone, while benzene forms at least 50 molar percent and preferably 60 to 80 molar percent of the effluent. Accordingly, recirculation of a portion of the effluent to the inlet of the alkylation reaction zone increases the benzene/propylene ratio in the alkylation reaction zone.

Several benefits result as the benzene/propylene ratio increases in the alkylation reaction zone, including (1) a dilution of propylene molecules with benzene molecules favoring formation of isopropylbenzene (cumene) and limiting formation of propylene oligomers, and (2) a benzene/propylene ratio greater than one is indicative of the presence of excess benzene, which acts as a heat sink to absorb heat generated by the exothermic alkylation reaction and to limit the formation of propylene oligomers and solid hydrocarbon deposits on the catalyst, both of which increase with higher temperature in the alkylation reaction zone. In prior art processes. a temperature increase from inlet to outlet of the alkylation reaction zone of 20 to 40"C. is typical without quench, and in the present process, a similar temperature increase or lower is desired, and is attained by suitably increasing the flow rate of recirculated effluent.

The recirculated effluent stream may be indirectly cooled by cooling means such as a water cooled exchanger, an air cooled exchanger, or an exchanger in which another hydrocarbon stream is used as the coolant to a temperature of 150 to 260"C., i.e. to a temperature essentially equivalent to the temperature of the reaction zone inlet stream, or it may be admixed without cooling with a mixture of the propylene feed stream and the recycle benzene stream, the mixture being at a suitable temperature to provide an alkylation reaction zone inlet temperature of 150 to 260"C., and preferably 195 to 215'C.

Furthermore, a third portion of the reaction zone effluent stream may be indirectly cooled by similar cooling means as stated hereinbefore to a temperature of 35 to 150"C. and passed into the reaction zone at suitable points to act as quench to cool the reactants and prevent excessive increase of temperature from inlet to outlet of the alkylation reaction zone. Suitable quench points may be chosen by dividing the solid phosphoric acid catalyst bed into several successive separate beds and passing a portion of the quenching medium between each of the successive beds. In a preferred mode of operation, a portion of alkylation reaction zone effluent is cooled to 35"--95"C. and introduced into the reaction mixture as a quenching medium between at least two successive catalyst beds in an amount sufficient to reduce the temperature of the reaction mixture to within - 4" C. of the temperature of the reaction mixture entering the last preceding catalyst bed.

As recirculation of alkylation reaction zone effluent to the inlet of the reaction zone increases, the concentration of cumene in the alkylation reaction zone also increases, thus providing more potential sites for polyalkylated benzene products and resulting in increased production of di- and triisopropylbenzene as compared to prior art processes.

Whereas di- and triisopropylbenzene production in prior art processes is typically less than 5 mole percent as compared with cumene production, the present process results in 5 to 20 mole percent or more.

Propane, butane, benzene and cumene together typically comprise 90 to 95 mole percent of the alkylation reaction zone effluent, and toluene, butylbenzene, di- and triisopropylbenzene, propylene oligomers and other components in trace amounts together typically comprise 10 to 5 mole percent. The net alkylation zone effluent stream withdrawn from the alkylation reaction zone is passed separately or in admixture with a transalkylation reaction zone effluent stream set forth hereinbelow into a separation zone, wherein by means of a combination of fractional distillation, absorption, stripping, and flashing, the desired components are separated at separation conditions selected to minimize utility consumption.

Product streams withdrawn from the separation zone include a propane-rich stream, a cumene stream, a butylbenzene-rich stream, a propylene oligomer stream, and a benzene drag stream, the last-stated stream serving to remove trace quantities of non-aromatic components boiling between propane and cumene.

The present inventive concept is not limited by a specific combination of separation steps, however the separation of excess benzene and cumene is at present most economically accomplished by fractional distillation, in which benzene and lighter components are separated into an overhead fraction and cumene and heavier components are separated into a bottoms fraction. The separation of excess benzene in prior art processes has a relatively large capital and utility requirement resulting from the greater quantity of excess benzene separated from cumene as compared with the present process. While benzene/cumene molar ratios in the reaction zone net effluent of prior art processes are typically about 6.5:1, this ratio in the present process is 2:1 to 5:1 with a constant benzene/cumene molar ratio in the alkylation reaction zone. Excess benzene separated from the alkylation reaction zone effluent may be withdrawn from the process as a product stream. but preferably a first portion is passed to the inlet of the alkylation reaction zone as a recycle benzene-rich stream and a second portion is passed into a transalkylation reaction zone in admixture with a di-and triisopropylbenzene-rich stream. also separated and withdrawn from the separation zone. The admixture of benzene and di-and triisopropylbenzene is passed into a transalkylation reaction zone, wherein the reactants combine to produce cumene.

The inventive process of the present invention is not limited by the catalyst incorporated in the transalkylation reaction zone.

Various catalysts are known to one skilled in the art, such as a boron trifluoride-modified inorganic oxide catalyst described in U.S.

Patent 3,200,163, an acid extracted crystalline aluminosilicate catalyst described in U.S. Patent 3,551,510, or a fluorine containing refractory inorganic oxide described in U.S. Patent 3,205,277. Preferred as a transalkylation catalyst in the present invention is a solid phosphoric acid catalyst prepared in a similar manner as the one used hereinabove in the alkylation reaction zone, or especially preferred is a solid phosphoric acid catalyst containing 70 to 90 weight percent phosphorus. The transalkylation zone may be equipped with heat transfer means, baffles, trays, heating means and pumping means.

The reaction zone is preferably of the adiabatic type, and is not limited by reactor design or configuration. Conditions utilized in the transalkylation reaction zone may be varied over a relatively wide range; the transalkylation reaction is typically effected at a temperature of from 35 to 370to., a pressure of 15 to 200 atmospheres, a benzene/polyisopropylbenzene molar ratio of 4:1 to 16:1, and a liquid hourly space velocity based on reaction zone effluent of 0.1 to 20. Preferred transalkylation reaction conditions include a solid phosphoric acid catalyst, a temperature of 175 to 290"C., a pressure of 20 to 40 atmospheres, a benzene/polypropylbenzene molar ration of 4:1 to 16:1 and a liquid hourly space velocity based on reaction zone effluent of 0.5 to 5. As described hereinabove, effluent of the transalkylation reaction zone is passed into the separation zone.

WHAT WE CLAIM IS: 1. A process for the production of cumene which comprises the steps of: (a) reacting propylene with an excess of benzene in the presence of a solid phosphoric acid alkylation catalyst at alkylation reaction conditions in an alkylation zone; (b) dividing the total liquid effluent from the alkylation zone into at least two portions of like composition; (c) recirculating one of said portions of the effluent from the alkylation zone to the alkylation zone; (d) introducing another of said portions of the effluent from the alkylation zone and a transalkylation zone effluent stream, formed as hereinafter set forth, into a separation zone; (e) separating from the admixed effluents in the separation zone a benzene-rich

**WARNING** end of DESC field may overlap start of CLMS **.

Claims

**WARNING** start of CLMS field may overlap end of DESC **. providing more potential sites for polyalkylated benzene products and resulting in increased production of di- and triisopropylbenzene as compared to prior art processes. Whereas di- and triisopropylbenzene production in prior art processes is typically less than 5 mole percent as compared with cumene production, the present process results in 5 to 20 mole percent or more. Propane, butane, benzene and cumene together typically comprise 90 to 95 mole percent of the alkylation reaction zone effluent, and toluene, butylbenzene, di- and triisopropylbenzene, propylene oligomers and other components in trace amounts together typically comprise 10 to 5 mole percent. The net alkylation zone effluent stream withdrawn from the alkylation reaction zone is passed separately or in admixture with a transalkylation reaction zone effluent stream set forth hereinbelow into a separation zone, wherein by means of a combination of fractional distillation, absorption, stripping, and flashing, the desired components are separated at separation conditions selected to minimize utility consumption. Product streams withdrawn from the separation zone include a propane-rich stream, a cumene stream, a butylbenzene-rich stream, a propylene oligomer stream, and a benzene drag stream, the last-stated stream serving to remove trace quantities of non-aromatic components boiling between propane and cumene. The present inventive concept is not limited by a specific combination of separation steps, however the separation of excess benzene and cumene is at present most economically accomplished by fractional distillation, in which benzene and lighter components are separated into an overhead fraction and cumene and heavier components are separated into a bottoms fraction. The separation of excess benzene in prior art processes has a relatively large capital and utility requirement resulting from the greater quantity of excess benzene separated from cumene as compared with the present process. While benzene/cumene molar ratios in the reaction zone net effluent of prior art processes are typically about 6.5:1, this ratio in the present process is 2:1 to 5:1 with a constant benzene/cumene molar ratio in the alkylation reaction zone. Excess benzene separated from the alkylation reaction zone effluent may be withdrawn from the process as a product stream. but preferably a first portion is passed to the inlet of the alkylation reaction zone as a recycle benzene-rich stream and a second portion is passed into a transalkylation reaction zone in admixture with a di-and triisopropylbenzene-rich stream. also separated and withdrawn from the separation zone. The admixture of benzene and di-and triisopropylbenzene is passed into a transalkylation reaction zone, wherein the reactants combine to produce cumene. The inventive process of the present invention is not limited by the catalyst incorporated in the transalkylation reaction zone. Various catalysts are known to one skilled in the art, such as a boron trifluoride-modified inorganic oxide catalyst described in U.S. Patent 3,200,163, an acid extracted crystalline aluminosilicate catalyst described in U.S. Patent 3,551,510, or a fluorine containing refractory inorganic oxide described in U.S. Patent 3,205,277. Preferred as a transalkylation catalyst in the present invention is a solid phosphoric acid catalyst prepared in a similar manner as the one used hereinabove in the alkylation reaction zone, or especially preferred is a solid phosphoric acid catalyst containing 70 to 90 weight percent phosphorus. The transalkylation zone may be equipped with heat transfer means, baffles, trays, heating means and pumping means. The reaction zone is preferably of the adiabatic type, and is not limited by reactor design or configuration. Conditions utilized in the transalkylation reaction zone may be varied over a relatively wide range; the transalkylation reaction is typically effected at a temperature of from 35 to 370to., a pressure of 15 to 200 atmospheres, a benzene/polyisopropylbenzene molar ratio of 4:1 to 16:1, and a liquid hourly space velocity based on reaction zone effluent of 0.1 to 20. Preferred transalkylation reaction conditions include a solid phosphoric acid catalyst, a temperature of 175 to 290"C., a pressure of 20 to 40 atmospheres, a benzene/polypropylbenzene molar ration of 4:1 to 16:1 and a liquid hourly space velocity based on reaction zone effluent of 0.5 to 5. As described hereinabove, effluent of the transalkylation reaction zone is passed into the separation zone. WHAT WE CLAIM IS:

1. A process for the production of cumene which comprises the steps of: (a) reacting propylene with an excess of benzene in the presence of a solid phosphoric acid alkylation catalyst at alkylation reaction conditions in an alkylation zone; (b) dividing the total liquid effluent from the alkylation zone into at least two portions of like composition; (c) recirculating one of said portions of the effluent from the alkylation zone to the alkylation zone; (d) introducing another of said portions of the effluent from the alkylation zone and a transalkylation zone effluent stream, formed as hereinafter set forth, into a separation zone; (e) separating from the admixed effluents in the separation zone a benzene-rich

stream, a cumene product stream and a diand tri-isopropylhenzene-rich stream; (f) transalkylating the last named stream with benzene in the presence of a transalkylation catalyst in a transalkylation zone to form additional cumene; (g) supplying the effluent of the last mentioned zone to the separation zone as the transalkylation zone effluent stream; (ill) passing at least a portion of the benzene-rich stream from the separation zone to the alkylation reaction zone; and (i) recovering the cumene product stream from the separation zone.

2. A process as claimed in claim I wherein at least a portion of the fresh benzene for reaction with the propylene in step (a) is supplied to the separation zone.

3. A process as claimed in claim 1 wherein at least a portion of the benzene reactant for step (t) is supplied to the separation zone and then to the transalkylation zone.

4. A process as claimed in claim I wherein the benzene for reaction in steps (a) and (f) is supplied to the separation zone.

5. A process as claimed in claim I wherein at least a portion of the benzene-rich stream from the separation zone is supplied to the transalkylation zone.

6. A process as claimed in any of claims I to 5 wherein the alkylation catalyst is a solid phosphoric acid catalyst containing from 50 to 75 wt 'Y, phosphorus.

7. A process as claimed in any of claims I to 6 wherein the transalkylation catalyst is a solid phosphoric acid catalyst.

8. A process as claimed in claim 7 wherein the transalkylation catalyst is a solid phosphoric acid catalyst containing from 70 to 90 wt. 6/., phosphorous.

9. A process as claimed in any of claims 1 to 8 wherein the molar ratio of benzene to propylene in the alkylation zone is from 2:1 to 6; 1 ignoring the portion of the alkylation zone effluent stream recirculated to the alkylation zone.

10. A process as claimed in any of claims 1 to 9 wherein the catalyst in the alkylation zone is in the form of at least two successive catalyst beds and a third portion of the effluent from the alkylation zone is cooled to a temperature of from 35 to 150"C. and introduced into the reaction mixture between successive catalyst beds as quenching medium.

11. A process as claimed in any ofclaims I to 1() wherein the portion of the effluent from the alkylation zone which is to be recycled to the alkylation zone is cooled to a temperature of from 150 to 260"C.

12. A process for the production of cumene carried out substantially as hereinbefore described with reference to the drawing accompanying the provisional specification.

13. Cumene when produced by a process as claimed in any of claims 1 to 12.