GB1581157A - Open shroud trickle valve - Google Patents

Open shroud trickle valve Download PDF

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Publication number
GB1581157A
GB1581157A GB22073/77A GB2207377A GB1581157A GB 1581157 A GB1581157 A GB 1581157A GB 22073/77 A GB22073/77 A GB 22073/77A GB 2207377 A GB2207377 A GB 2207377A GB 1581157 A GB1581157 A GB 1581157A
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GB
United Kingdom
Prior art keywords
valve
plate
trickle
vertical portion
flapper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22073/77A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1581157A publication Critical patent/GB1581157A/en
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/003Feeding of the particles in the reactor; Evacuation of the particles out of the reactor in a downward flow
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16KVALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
    • F16K1/00Lift valves or globe valves, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces
    • F16K1/16Lift valves or globe valves, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces with pivoted closure-members
    • F16K1/18Lift valves or globe valves, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces with pivoted closure-members with pivoted discs or flaps
    • F16K1/20Lift valves or globe valves, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces with pivoted closure-members with pivoted discs or flaps with axis of rotation arranged externally of valve member
    • F16K1/2014Shaping of the valve member
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/6851With casing, support, protector or static constructional installations
    • Y10T137/7043Guards and shields
    • Y10T137/7062Valve guards
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/7722Line condition change responsive valves
    • Y10T137/7837Direct response valves [i.e., check valve type]
    • Y10T137/7898Pivoted valves
    • Y10T137/7902Valve mounted on end of pipe

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Cyclones (AREA)
  • Check Valves (AREA)

Description

PATENT SPECIFICATION
( 11) 1581157 ( 21) ( 31) ( 33) ( 44) ( 51) Application No 22073/77 ( 22) Filed 25 May 1977 ( 19) Convention Application No 701 598 ( 32) Filed 1 July 1976 in United States of America (US,
Complete Specification published 10 Dec 1980
INT CL BO 1 J 8/24 ( 52) Index at acceptance B 85 BK BIF CIG C 1 H F 2 V D 5 C E 1 B ( 72) Inventor EDWARD COOPER LUCKENBACH ( 54) OPEN SHROUD TRICKLE VALVE ( 71) We, EXXON RESEARCH AND ENGINEERING COMPANY, a Corporation duly organised and existing under the laws of the State of Delaware, United States of America, of Linden, New Jersey, United States of America, do hereby declare the invention, for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:-
As a general rule in processes such as those for fluid cat crackers it has been common practice to employ fully-shrouded trickle valves on all of the primary and secondary cyclone diplegs for sealing the legs in order to insure good cyclone operation These valves generally are located in the fluid beds such that if the valve fails, a hydraulic seal will result That is, the solids will be directly discharged into the bed and solids can be sucked up into the dipleg from the bed to establish a level of catalyst in the dipleg which will correspond to the pressure in the dipleg This pressure is generally lower than the pressure at the top of the bed so that the level will be higher than the bed level.
To prevent action of the bubbles which occur in the fluid bed from affecting the flapper action (i e, opening and closing motion) of the valve, it is common to employ a large pipe shroud around the valve Valves which employ such expedients are commonly referred to as fully-shrouded valves such as disclosed in U S Patent No 2,838,062 Other aspects and applications of these conventional valves may be found by referring to U.S Patent Nos 2,838,065; 2,901,331; and 2,838,063, the latter of which is considered most relevant to the present invention Alternatively, oftentimes splash baffles are used on the cyclone diplegs because of the relatively large cost of the alloy trickle valves.
It is desirable, however, to use these valves in order to maximize the density of the catalyst in the cyclone diplegs and to maintain the catalyst flow down the dipleg, i e, preserve the collection efficiency of the cyclone, especially during times when the catalyst levels are below the level of the outlet from the diplegs 50 The use of full shrouds was developed at a time when the size of the bubbles which are developed in the fluid cat cracker beds was a relatively unknown factor At the time it was suspected that large bubbles existed 55 which would violently and undesirably move the flapper plate out of its desired position.
In accordance with recent investigations in fluid solids technology, it is now believed that these bubbles, in the use of regenerators, 60 are substantially smaller than originally anticipated, being about one inch in diameter, and in the case of reactors, are about three inches in diameter It, therefore, has become apparent that the need for these large full 65 shrouds heretofore employed no longer exists.
However, it is apparent that some protection of the flapper plate is necessary in order to prevent a local disturbance from torch oil, spray water, eroded grid holes, broken 70 seals, etc, from affecting its position with respect to the outlet opening from the dipleg, which could result in displacing the flapper and/or diverting gas directly into the dipleg.
Further incentives for eliminating the shroud 75 are the relatively high cost of the valves which are usually made of a high cost alloy steel and, therefore, the shroud adds considerably to the valve cost The shrouds also are extremely large, e g 26 inches in dia 80 meter for typical 16 inch dipleg, and take up a large amount of the bed or cross-sectional area, which reduces the volume available for effective regeneration or reaction of catalyst In addition, the relatively large 85 weight of the shrouds places an undesirable bending moment on the diplegs.
With the foregoing in mind, the present invention is directed towards providing an improved trickle valve which will overcome 90 the disadvantages and deficiencies of prior art valves.
The present invention provides a trickle valve comprising a conduit having a disCon te O 1,581,157 charge opening, a hingedly mounted valve closure plate disposed with respect to said discharge opening for movement between opened and closed positions, and a baffle plate fixedly secured about said conduit at a location spaced rearwardly from said discharge opening, said baffle plate comprising a vertical portion and a lower deflector portion angularly disposed with respect to said vertical portion, said vertical portion extending transversely beyond said valve closure plate, and said deflector portion extending forward of said discharge opening for a predetermined distance.
The trickle valve of the invention is openshrouded and capable of use with conduits such as cyclone diplegs, and is of simple and low cost construction, and provides effective protection for the valve flapper plate without occupying the amount of space heretofore occupied by conventional valves The flapper plate is mounted for movement between opened and closed positions for sealing the conduit, e g a dipleg, in the event that large quantities of gas could be diverted up the dipleg At a distance situated rearwardly of the closure or flapper plate, which distance may be 3 inches or some other suitable distance depending upon the size of the plate with regard to the size of the flapper, there is provided an essentially vertically disposed baffle plate portion which is wider than the flapper plate and serves the purpose of the previously employed shroud without the attendant disadvantages as discussed heretofore The baffle plate extends vertically beyond the end or terminal portion of the flapper plate for a predetermined distance and thereafter, the lower deflector portion is disposed at an angular orientation of, e g, approximately 450 with respect to the vertical The angularly disposed lower portion preferably is rigidly secured to the upper vertical portion by means of transversely spaced gussets at opposite sides of the baffle plate The orientation of the lower portion of the baffle plate may extend through and beyond the plane containing the outlet of the dipleg for approximately at least 2 inches beyond the vertical plane of the bottom edge of the closure or flapper plate in its most open position and preferably a minimum of 3 inches for larger valves bigger than 10 inch pipe size The bend or angle orientation of the bottom portion begins at a point about one inch below the termination of the flapper plate, which is required in order to prevent stagnant solids, if any, from interfering with the movement of the plate The plate terminates in a point at a slightly flatter slope, 200 to the horizontal, to minimize the amount of metal in the bottom portion.
In the Weits U S patent 2,838,063, there is no disclosure of protecting the flapper plate from horizontal forces in the fluid bed by employing a partially shrouded valve.
The patent discloses that the so-called shroud or baffle is located completely beneath the trickle valve in a substantially horizontal 70 disposition to prevent large bubbles from flowing directly upward past the flapper plate and disrupting its position These valves are conventionally used in the dilute catalyst phase above a bed where only vertically 75 directed forces exist The Weits patent discloses that the support for the lower plate may prevent some horizontal forces from acting only on the extreme lower tip of the valve (i e, flapper plate) However, contrary 80 to the present invention, the support is not wider than the flapper plate and therefore has a minimal, if any, effect to prevent horizontal forces from working and acting on the upper portion of the flapper plate It is 85 apparent that this prior art horizontal baffle does not prevent horizontal forces from acting on the flapper, but merely provides rigidity to support the plate beneath the valve In contrast, the flat protective baffle 90 plate of the present invention prevents the horizontal forces from acting on the valve and because it is situated at a predetermined fairly close distance to the flapper plate, this avoids the need for making it large The 95 plate also has the added advantage that it can mount the hinge ring and flapper support and thus minimize the amount of valve fabrication This location of the relatively small baffle plate directly behind the flapper 100 to protect the flapper action is not disclosed in the prior art.
The foregoing and other objects and advantages of the present invention will be apparent to those skilled in the art upon 105 reading of the following detailed description in conjunction with the accompanying drawings, in which Fig 1 is a side elevational view of a preferred embodiment of an open shroud trickle 110 valve according to the present invention; Fig 2 is a front elevational view of the trickle valve shown in Fig 1; and Fig 3 is a cross sectional view taken substantially along the line 3-3 of Fig 1 115 Referring now to the drawings wherein like parts are designated throughout the several views by the same reference numeral, there is shown in Fig 1 a trickle valve generally designated 10 The valve basically 120 comprises a pair of interconnected angularly disposed conduit members 12 and 14, the upper one of which is lineal and connected with the lower vertical portion of the cyclone dipleg 16 The bottom conduit 14 is angu 125 larly disposed with respect to the lineal portion at a typical angle of 30 relative to the vertical This relationship permits the freeflow of catalyst out of the valve by preventing solids buildup on the sloped portion 130 1,581,157 This slope must be steeper than the angle of repose of the catalyst At the exit or outlet end of the angularly disposed bottom conduit 14 is an opening 18 and a valve closure means according to the present invention described in detail hereinafter At a predetermined distance rearwardly of the opening 18 is a baffle plate which comprises a vertical portion 20 and an angularly disposed lower portion 22 The vertical portion typically is unitary with the bottom 22 or alternatively they may be separate members secured together by welding or the like.
The vertical portion 20 contains a cutout area 24 of generally elliptical shape which is complementary to the peripheral configuration of the conduit 14 so that it fits over the conduit 14 and is set back rearwardly from the outlet An essentially conventional T-shaped bracket 26 is welded or otherwise fixedly secured to the outer surface at the upper end of the vertical baffle plate 20.
The outer or head portion of the bracket 26 comprises an essentially flat member 28 having a pair of transversely spaced openings 30 through which respective annular 0-shaped hinges 32 are mounted The openings typically are greater in diameter than that of the hinges, such that the hinges can freely move within the openings both in vertical and lateral directions and even in the presence of operating temperatures which the valve may be subject to The hinges support for pivotal movement a flat rectangular valve flapper plate 34 which has a conventional shape and mounting arrangement The plate at its upper end adjacent the bracket 26 has a pair of openings 36 which are transversely spaced through which the hinges 32 extend and which are designed similar to those in the bracket in order to permit easy rotational movement of the hinges with respect to the openings and also to permit limited lateral movement of the hinges within the openings The flapper plate 34 seats against the discharge opening 18 at the end of the lower conduit portion 14.
The plate is elongated and tongue-shaped and is substantially larger in area in all directions than the opening 18 Its maximum horizontal and vertical dimensions are greater than the corresponding dimensions of the end of the conduit 14 defining the opening 18 and which serves as a valve seat such that the plate will be properly seated against the said valve seat in any position regardless of the movement of the plate.
Thus the valve plate can move in a generally parallel direction with respect to the seat or for that matter in almost any other direction without affecting the desired seating relationship The plate in accordance with the preferred embodiment has a substantially elliptical configuration which essentially conforms with that of the discharge opening It is understood that the shape may be otherwise, e g, rectangular or truncated at the edges The valve is provided with the typical vertically spaced valve stops, each of which comprise essentially U-shaped rod-like mem 70 bers 38 which are secured at their outer end to transversely spaced connecting members or rods 40 The opposite end of each of the stops is secured, for example by welding, to the baffle plate on either side of the dis 75 charge opening 18 The lower stop extends further outward from the plate 20 so that all stops will be in contact with plate 20 when the plate is swung to its most open position.
This arrangement permits movement of the 80 valve plate 34 between opened and closed positions, while restricting movement to a desired range as determined by the distance (minimum) between opening 18 and the upper stop 38 85 The disposition of the discharge opening 18 with respect to a vertical plane is angular such that the valve flapper plate 34 will essentially always be biased into a closed position when it is in a neutral position 90 because of the force of gravity.
The baffle plate 20, 22 and its location comprise a significant improvement over the prior art The vertical portion 20 of the plate is mounted preferably at a distance 95 of approximately 3 inches rearward of the valve seat and at an angular disposition with respect to the vertical parallel to the slope of the opening of the valve The particular rearward location of this portion of the plate 100 is determined by the space and clearance necessary for installation, support and movement of the hinge rings A suitable range for the rearward disposition of the plate may comprise 2 to 4 inches The bottom 105 angularly disposed portion 22 of the baffle plate is rigidly conrnected by means of transversely spaced gussets 42 on opposite sides of the plate at the bend between portions 20, 22 The angular disposition of the bottom 110 portion 22 is at about 450 with respect to the horizontal, although it may range from 450 to 600 depending upon the vertical height available for installation of the valve.
The bottom portion terminates in a tip 44 115 (shown as triangular in shape) which extends forwardly of the maximum opening of the flapper plate with a downward inclination so as to spaced apart from the bottom of the valve opening by a selected distance, 120 preferably a maximum of 4 inches This distance may vary depending upon the size of the valve; however, a preferred range would be 3 to 6 inches Another important factor in the baffle plate arrangement is that 125 the vertical portion 20 extends below the bottom or free end of the flapper plate 34 for about 1 inch in order to insure that any catalyst which may have deaerated and settled on the plate will be far enough from 130 1,581,157 the flapper plate and actual opening of the valve so as not to impede action of the plate.
The bottom portion 22 functions as a deflector plate which serves to cause any of the upwardly moving catalyst particles to move away from the valve flapper plate 34 itself and thus avoid any possible injury to the closure member The tip on the plate merely reduces the amount of metal in the plate Further advantages of the bottom deflector plate are to insure that any high velocity vertically oriented jet streams that might exist will not directly impinge on the flapper and opening or bottom surface of the pipe 14 of the valve The presently constructed and mounted baffle plate will protect the flapper plate valve from local disturbances which may affect the positioning of the plate and by extending the deflector plate a sufficient distance, e g, 3 inches forward of the flapper plate in order to prevent undesirable movement of the plate due to the bubble action in the fluidized beds This plate will have a minimum of interference with the gas flow up from the fluid bed because of the minimal cross- ectional area it occupies and also in reactors will reduce interference with the gas and catalyst flows in the bed, thus providing an overall better flow for cat cracking processes The vertically disposed portion 20 of the baffle plate because of its size aids in preventing any horizontal forces from acting not only on the lower tip of the valve plate 34 but also the whole plate The relatively close location of the baffle plate to the flapper plate avoids the need for having to provide too large a protective plate and further, the plate provides a support for the hinge rings which minimizes the amount of fabrication effort required in the valve.
The plate 20 preferably should be at least 4 inches wider than flapper plate 34, and if the distance of plate 20 behind plate 34 is 4 inches or greater, it should be 6 inches wider so as to insure proper prevention of horizontal forces from acting in the valve.
Plate 20 may be even wider; however, this merely adds to the weight and cost of the valve.
Numerous alterations of the structure herein disclosed will suggest themselves to those skilled in the art; however, it is to be understood that the present disclosure relates to a preferred embodiment of the invention, which is for purposes of illustration only and not to be construed as a limitation of the invention as defined by the appended claims.

Claims (6)

WHAT WE CLAIM IS: -
1 A trickle valve comprising a conduit having a discharge opening, a hingedly mounted valve closure plate disposed with respect to said discharge opening for movement between opened and closed positions, and a baffle plate fixedly secured about said conduit at a location spaced rearwardly from said discharge opening, said baffle plate comprising a vertical portion and a lower deflector portion angularly disposed with respect to said vertical portion, said vertical portion extending transversely beyond said valve closure plate, and said deflector portion extending forward of said discharge opening for a predetermined distance.
2 The trickle valve of claim 1 comprising means rigidly securing said deflector portion to said vertical portion.
3 The trickle valve of claim 1 or claim 2 comprising support means hingedly mounting said valve closure plate to said baffle plate at the upper end of said vertical portion.
4 The trickle valve of any one of claims 1 to 3 comprising a tip at the end of said lower deflector portion which extends forward of the position of maximum opening of said valve closure plate.
The trickle valve of any one of claims 1 to 4 substantially as hereinbefore described.
6 A trickle valve substantially as hereinbefore described with reference to the accompanying drawings.
K J VERYARD, Suffolk Street, London SW 1 Y 4 HS.
Agent for the Applicants.
Printed for Hfer Majesty's Stationery Office by Burgess & Son (Abingdon), Ltd -1980.
Published at The Patent Office, 25 Southampton Buildings, London, WC 2 A l AY, from which copies may be obtained.
GB22073/77A 1976-07-01 1977-05-25 Open shroud trickle valve Expired GB1581157A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/701,598 US4074691A (en) 1976-07-01 1976-07-01 Open shroud trickle valve

Publications (1)

Publication Number Publication Date
GB1581157A true GB1581157A (en) 1980-12-10

Family

ID=24817978

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22073/77A Expired GB1581157A (en) 1976-07-01 1977-05-25 Open shroud trickle valve

Country Status (8)

Country Link
US (1) US4074691A (en)
JP (1) JPS6051396B2 (en)
CA (1) CA1047985A (en)
DE (1) DE2728482A1 (en)
ES (1) ES460289A1 (en)
FR (1) FR2356864A1 (en)
GB (1) GB1581157A (en)
IT (1) IT1084971B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4184662A (en) * 1978-07-25 1980-01-22 The United States Of America As Represented By The United States Department Of Energy Valve for controlling solids flow
US4246231A (en) * 1979-03-27 1981-01-20 Standard Oil Company (Indiana) Fluidized solids apparatus
JPS58161655U (en) * 1982-04-21 1983-10-27 株式会社細川粉体工学研究所 Powder discharge device
JPS58166850U (en) * 1982-04-30 1983-11-07 株式会社細川粉体工学研究所 Powder discharge device
US4871514A (en) * 1987-11-09 1989-10-03 Mobil Oil Corporation Flapper valve
US4996028A (en) * 1989-02-15 1991-02-26 Exxon Research And Engineering Company Trickle valve
US5428907A (en) * 1994-08-03 1995-07-04 Noxso Corporation Downcomer and flapper valve
US5740834A (en) * 1996-08-02 1998-04-21 Exxon Research And Engineering Company Reverse angle integrally counter-weighted trickle valve
DE19851423A1 (en) * 1998-11-07 2000-05-11 Krupp Uhde Gmbh Device for providing a block flange of a manhole opening or the like, in particular in the case of fluidized bed reactors
US6569317B1 (en) * 1999-07-09 2003-05-27 Shell Oil Company Trickle valve
BR9905842A (en) * 1999-12-14 2001-07-17 Petroleo Brasileiro Sa Cyclone leg sealing system

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US608450A (en) * 1898-08-02 William godfrey
US2838065A (en) * 1955-09-12 1958-06-10 Ducon Co Trickle valve
US2838062A (en) * 1955-09-12 1958-06-10 Ducon Co Trickle valve
US2838063A (en) * 1955-10-10 1958-06-10 Ducon Co Trickle valve

Also Published As

Publication number Publication date
CA1047985A (en) 1979-02-06
DE2728482A1 (en) 1978-01-05
FR2356864A1 (en) 1978-01-27
IT1084971B (en) 1985-05-28
JPS535429A (en) 1978-01-19
DE2728482C2 (en) 1987-12-10
FR2356864B1 (en) 1982-06-18
ES460289A1 (en) 1979-06-01
US4074691A (en) 1978-02-21
JPS6051396B2 (en) 1985-11-13

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
746 Register noted 'licences of right' (sect. 46/1977)
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19950525