GB1524163A - Catalytic systems for metathesis of olefins - Google Patents

Catalytic systems for metathesis of olefins

Info

Publication number
GB1524163A
GB1524163A GB4355676A GB4355676A GB1524163A GB 1524163 A GB1524163 A GB 1524163A GB 4355676 A GB4355676 A GB 4355676A GB 4355676 A GB4355676 A GB 4355676A GB 1524163 A GB1524163 A GB 1524163A
Authority
GB
United Kingdom
Prior art keywords
ether
organic
alkyl
complex
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4355676A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe National Elf Aquitaine
Original Assignee
Societe National Elf Aquitaine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe National Elf Aquitaine filed Critical Societe National Elf Aquitaine
Publication of GB1524163A publication Critical patent/GB1524163A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

1524163 Olefin metathesis catalyst SOC NATIONALE ELF AQUITAINE 20 Oct 1976 [31 Oct 1975] 43556/76 Heading B1E [Also in Divisions C3 and C5] An olefin metathesis catalyst composition comprises (i) a complex of zero-valent tungsten or molybdenum; (ii) an aluminium compound R 3-a Al Ya wherein R is alkyl, Y is Cl or Br and a is 0, 1, 2 or 3; (iii) oxygen or a substance capable of liberating oxygen, e.g. a peroxide or organic hydroperoxide; and, (iv) an organic compound containing at least one ether or thioether function. The complex may be (a) Y M(CO) 6-z wherein M is W or Mo, Y is an aromatic hydrocarbon, ethylene-diamine, diethylene triamine, a trialkyl phosphine a triaryl phosphine, P(OR) 3 where R is alkyl or aryl, an amine, a pyridine, a nitrile, Cl (NR 4 ) where R is alkyl or aryl, C(OR)R' or C(CLi)R where R, R' are alkyl or aryl, and z represents the number of covalent bonds between Y and M; (b) M(NO) 2 Cl 2 X 2 where X is an organic phosphine or phosphate; or (c) X 2 M (CO), where X is a pyridine, an organic phosphine or an organic phosphate. The ether component may be diethyl-, dibutyl or diphenyl ether, a furan, tetrahydrofuran, dioxan, diethyl-thioether, thiophane or thiophene. The composition may be formed by dissolving the complex in an organic solvent, introducing the ether compound, then adding the aluminium compound and, finally, adding the oxygen or oxygenliberator. The composition may contain 1 to 1000 moles of aluminium compound and 0.1 to 10 moles of ether compound per mole of complex. The Examples described compositions containing, in chlorobenzene, ethylaluminium dichloride, diethyl-ether, oxygen and W (CO) 5 P (Ph) 3 or W (CO) 6 .
GB4355676A 1975-10-31 1976-10-20 Catalytic systems for metathesis of olefins Expired GB1524163A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7533460A FR2346047A1 (en) 1975-10-31 1975-10-31 CATALYTIC SYSTEM FOR THE CONVERSION OF UNSATURATED HYDROCARBONS

Publications (1)

Publication Number Publication Date
GB1524163A true GB1524163A (en) 1978-09-06

Family

ID=9161911

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4355676A Expired GB1524163A (en) 1975-10-31 1976-10-20 Catalytic systems for metathesis of olefins

Country Status (7)

Country Link
JP (1) JPS5257092A (en)
BE (1) BE847420A (en)
DE (1) DE2649750A1 (en)
FR (1) FR2346047A1 (en)
GB (1) GB1524163A (en)
IT (1) IT1069006B (en)
NL (1) NL7612116A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0057736A1 (en) * 1981-02-05 1982-08-18 Phillips Petroleum Company Olefin disproportionation process and catalyst

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4380617A (en) * 1982-01-20 1983-04-19 The B. F. Goodrich Company Preparation of polymers from cycloolefins
US4426502A (en) * 1982-06-14 1984-01-17 The B. F. Goodrich Company Bulk polymerization of cycloolefins
EP0106519A1 (en) * 1982-09-13 1984-04-25 National Research Development Corporation Block copolymers
US4418179A (en) * 1982-09-29 1983-11-29 The B. F. Goodrich Company Impact modified polycycloolefins
IN167757B (en) * 1985-12-16 1990-12-15 Goodrich Co B F
US4754099A (en) * 1987-05-27 1988-06-28 Shell Oil Company Disproportionation of olefins
US4962263A (en) * 1988-05-20 1990-10-09 Shell Oil Company Disproportionation of olefins
US4956516A (en) * 1988-05-20 1990-09-11 Shell Oil Company Disproportionation of olefins
US5578658A (en) * 1993-12-20 1996-11-26 Mitsui Toatsu Chemicals, Inc. High-speed polymerizable resin composition and lenses obtained therefrom

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0057736A1 (en) * 1981-02-05 1982-08-18 Phillips Petroleum Company Olefin disproportionation process and catalyst

Also Published As

Publication number Publication date
DE2649750A1 (en) 1977-05-12
IT1069006B (en) 1985-03-21
FR2346047A1 (en) 1977-10-28
JPS5257092A (en) 1977-05-11
NL7612116A (en) 1977-05-03
BE847420A (en) 1977-02-14

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