GB1486664A - Polyamide acids and polyimides containing methylenebisanthranilic acid units - Google Patents

Polyamide acids and polyimides containing methylenebisanthranilic acid units

Info

Publication number
GB1486664A
GB1486664A GB292675A GB292675A GB1486664A GB 1486664 A GB1486664 A GB 1486664A GB 292675 A GB292675 A GB 292675A GB 292675 A GB292675 A GB 292675A GB 1486664 A GB1486664 A GB 1486664A
Authority
GB
United Kingdom
Prior art keywords
polymer
diamine
polyimides
dianhydride
pyromellitic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB292675A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of GB1486664A publication Critical patent/GB1486664A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1075—Partially aromatic polyimides
    • C08G73/1082—Partially aromatic polyimides wholly aromatic in the tetracarboxylic moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1042—Copolyimides derived from at least two different tetracarboxylic compounds or two different diamino compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1046—Polyimides containing oxygen in the form of ether bonds in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1057—Polyimides containing other atoms than carbon, hydrogen, nitrogen or oxygen in the main chain
    • C08G73/1064—Polyimides containing other atoms than carbon, hydrogen, nitrogen or oxygen in the main chain containing sulfur
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/303—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups H01B3/38 or H01B3/302
    • H01B3/306—Polyimides or polyesterimides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

1486664 Polyimides BASF AG 23 Jan 1975 [24 Jan 1974] 2926/75 Heading C3R Polyamide-acids convertible to heat-resistant polyimides are reaction products of a dianhydride comprising pyromellitic and 3,3<SP>1</SP>,4,4<SP>1</SP>- benzophenonetetraoic dianhydride and primary aromatic diamines of which 1 to 25 mol. per cent is 3,3<SP>1</SP>-dicarboxy-4,4<SP>1</SP>-diaminodiphenylmethane. Other diacids which may be additionally used and aromatic diamines which constitute the balance of the diamine reactant are specified. The polymer may have an intrinsic vicosity of 0À1 to 3À0 dl./g. (0À5 g./dl. solution at 30‹ C. in N-methylpyrrolidone for the amide acid and in H 2 SO 4 for the imides). They may be prepared by reaction in polar solvents and the solution used for wire coatings, films, fibres, moulding compositions impregnants and adhesives. The polymers may be blended with reinforcing materials, e.g. glass mats or glass, metal or graphite fibres. Specific examples illustrate the use of pyromellitic alone and a mixture of both anhydrides; in both the balance of the diamine is 4,4<SP>1</SP>-diaminodiphenyl ether. Comparative examples show that the storage stability of the polymer is much greater than that of analogous polymer wherein 4,4<SP>1</SP>-diaminodiphenyl ether is the sole diamine. Reference is made to Specification 1,239,272.
GB292675A 1974-01-24 1975-01-23 Polyamide acids and polyimides containing methylenebisanthranilic acid units Expired GB1486664A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19742403284 DE2403284C2 (en) 1974-01-24 1974-01-24 Storage-stable polyamic acids

Publications (1)

Publication Number Publication Date
GB1486664A true GB1486664A (en) 1977-09-21

Family

ID=5905550

Family Applications (1)

Application Number Title Priority Date Filing Date
GB292675A Expired GB1486664A (en) 1974-01-24 1975-01-23 Polyamide acids and polyimides containing methylenebisanthranilic acid units

Country Status (4)

Country Link
DE (1) DE2403284C2 (en)
FR (1) FR2259122B3 (en)
GB (1) GB1486664A (en)
IT (1) IT1026951B (en)

Also Published As

Publication number Publication date
FR2259122A1 (en) 1975-08-22
DE2403284A1 (en) 1975-07-31
IT1026951B (en) 1978-10-20
DE2403284C2 (en) 1981-12-17
FR2259122B3 (en) 1977-10-21

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Legal Events

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