GB1484096A - Processes for producing polymer blends - Google Patents

Processes for producing polymer blends

Info

Publication number
GB1484096A
GB1484096A GB32504/75A GB3250475A GB1484096A GB 1484096 A GB1484096 A GB 1484096A GB 32504/75 A GB32504/75 A GB 32504/75A GB 3250475 A GB3250475 A GB 3250475A GB 1484096 A GB1484096 A GB 1484096A
Authority
GB
United Kingdom
Prior art keywords
temperature
tert
polymer blend
partially polymerized
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32504/75A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1484096A publication Critical patent/GB1484096A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

1484096 Graft polymerization process MONSANTO CO 4 Aug 1975 [5 Aug 1974] 32504/75 Heading C3G A polymer blend is produced by a process which comprises (a) dissolving a rubbery polymer, other than an ethylene-propylene-non- conjugated diene terpolymer, in a monomer formulation comprising at least one monovinylidene aromatic monomer; (b) bulk polymerizing the solution from (a), at a temperature of from 95‹ to 125‹ C. with agitation and in the presence of a peroxide catalyst with a half-life of less than one hour at 130‹ C. and often hours at a temperature from 95‹ to 115‹ C., to a partially polymerized mixture having a conversion of 10 to 45%; (c) suspending the partially polymerized mixture in an inert liquid; (d) suspension polymerizing the said mixture at a temperature of from 110‹ to 150‹ C. in the presence of a peroxide catalyst with a half-life of less than one hour at 130‹ C. and of ten hours at a temperature of from 95‹ to 130‹ C., the partially polymerized mixture having an essentially complete conversion to a polymer blend; and (e) recovering the polymer blend from the suspension. Examples are given in which polybutadiene is grafted with styrene using tert.-butyl perbenzoate as catalyst in stages (b) and (d), or tert.-butyl peracetate in stage (b) and tert.- butyl perbenzoate in stage (d). The graft polymers produced are blended with polystyrene.
GB32504/75A 1974-08-05 1975-08-04 Processes for producing polymer blends Expired GB1484096A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US49464774A 1974-08-05 1974-08-05

Publications (1)

Publication Number Publication Date
GB1484096A true GB1484096A (en) 1977-08-24

Family

ID=23965368

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32504/75A Expired GB1484096A (en) 1974-08-05 1975-08-04 Processes for producing polymer blends

Country Status (9)

Country Link
JP (1) JPS5141089A (en)
AU (1) AU8364075A (en)
BR (1) BR7504968A (en)
DE (1) DE2534781A1 (en)
ES (1) ES439942A1 (en)
FR (1) FR2281380A1 (en)
GB (1) GB1484096A (en)
IL (1) IL47882A0 (en)
IT (1) IT1040349B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1597964A (en) * 1977-05-03 1981-09-16 Steigerwald Strahltech Beam welding apparatus including welding pool support devices
ZA7988B (en) 1978-01-19 1980-08-27 Mobil Oil Corp High impact copolymers
JPS59221318A (en) * 1983-06-01 1984-12-12 Asahi Chem Ind Co Ltd Rubber modified aromatic monovinyl resin composition
DE3627639A1 (en) * 1986-08-14 1988-02-18 Basf Ag IMPACT RESISTANT THERMOPLASTIC SHAPE

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL280753A (en) * 1961-07-11
DE1595203A1 (en) * 1963-08-14 1970-04-16 Rexall Drug Chemical Graft polymerization process
US3600466A (en) * 1967-06-16 1971-08-17 Denki Kagaku Kogyo Kk Process for the preparation of pure-white polystyrene compositions

Also Published As

Publication number Publication date
IL47882A0 (en) 1975-11-25
JPS5141089A (en) 1976-04-06
FR2281380A1 (en) 1976-03-05
AU8364075A (en) 1977-02-10
BR7504968A (en) 1976-07-27
IT1040349B (en) 1979-12-20
DE2534781A1 (en) 1976-02-19
FR2281380B1 (en) 1979-05-11
ES439942A1 (en) 1977-03-01

Similar Documents

Publication Publication Date Title
US3887652A (en) Process for producing transparent graft polymer compositions
US3538190A (en) Process for preparing improved plastic compositions and the resulting products
GB1476703A (en) Continuous mass polymerization process
US3463833A (en) Thermoplastic resinous blends of alpha methyl styrene-methyl methacrylate copolymers with graft copolymers
US3487127A (en) Rubber-modified resinous polymers prepared in the presence of a polyphenylene oxide
GB1439010A (en) Polymeric compositions and process for their manufacture
US3719730A (en) Modification of alfin polymers and product
US3914339A (en) Process for producing rubber-modified plastics
GB1484096A (en) Processes for producing polymer blends
ES438750A1 (en) Process for preparing impact resistant styrene polymers
US2957833A (en) Method of making a moldable composition from styrene and a styrene-rubber interpolymer
GB1378906A (en) Graft copolymer preparation
GB1438398A (en) Process for the preparation of impact resistant styrene polymers
US3719731A (en) High-impact moulding compositions and process for preparing same
US3983187A (en) Iodine molecular weight regulators in suspension polymerization systems
US3917748A (en) Process for manufacture of rubber-modified copolymers of an olefinic nitrile and a vinyl aromatic monomer
US4985503A (en) Preparation of impact-resistant poly(alkyl)styrene
US3903201A (en) Suspension polymerization process
US3367995A (en) Method for preparing graft copolymers of diene rubber, styrene, acrylonitrile and alpha-methyl styrene
US4420599A (en) Process of producing copolymers of an aromatic vinyl monomer and maleic anhydride
US3337648A (en) Graft copolymer comprising the reaction product of a carboxy-terminated conjugated diene polymer with a vinyl aromatic hydrocarbon and a lactam
JPH04100810A (en) Polybutadiene rubber and high-impact polystyrene resin prepared by using same
US3309422A (en) Process for preparing interpolymers of styrene and rubbery diolefin polymers
US3691261A (en) Graft copolymer with an alkyl acrylate and ethylthiaethyl metharylate backbone
WO1986005793A1 (en) Improved methacrylate polymers and compositions

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee