GB1484050A - Processes for removing acid gases from gaseous mixtures - Google Patents
Processes for removing acid gases from gaseous mixturesInfo
- Publication number
- GB1484050A GB1484050A GB55851/74A GB5585174A GB1484050A GB 1484050 A GB1484050 A GB 1484050A GB 55851/74 A GB55851/74 A GB 55851/74A GB 5585174 A GB5585174 A GB 5585174A GB 1484050 A GB1484050 A GB 1484050A
- Authority
- GB
- United Kingdom
- Prior art keywords
- steam
- auxiliary
- solution
- gas
- main
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
Abstract
1484050 Removing acid gases F VAN HECKE 23 Dec 1975 [24 Dec 1974] 55851/74 Heading C1A [Also in Division C5] In a cyclic process for regenerating scrubbing solutions used for removing acid components of a gas mixture in which a part of the spent scrubbing solution is steam-stripped in a main regeneration section and a further part is steam stripped in an auxiliary regeneration section, the pressures in the main and auxiliary sections are selected independently and at least a part of the stripping steam required in the auxiliary section is obtained by flashing scrubbing solution in a reduced pressure zone. Connected to the suction side of a steam jet thermocompressor, the mixture of thermocompressor motive steam and recompressed flashed vapour being directly discharged into the auxiliary regeneration section. In one embodiment (Fig. 1) crude gas is fed at 30 to absorption column 1 from which de-acidified gas leaves at 31. Hot spent scrubbing solution leaving 1 via line 21 is sent partly to main regenerator 2 via let-down valve 52 and partly to auxiliary regenerator 3 operated at a lower pressure than 2. In column 2 the spent solution flows counter-current in zone 15 to stripping steam. Some of the solution exits at 40 to provide a semi-lean stream, while the rest flows to the base of 2 where it is heated by reboiler 90 to provide a fully-regenerated (lean) stream. The semi-lean stream flows via valve 56 and line 24 to flash zone 9, while the lean stream flows, via 25 and 57 to expansion vessel 4. Vapour from 4 fed to 3 provides steam to strip, in zone 17, spent solution incoming at 23. Regenerated solution in pan 41 is withdrawn via 271, mixed with liquor from flash zone 9 and fed to expansion vessel 5 which is connected to the suction side of steam jet ejector 80 operated by motive steam supply 34. The recompressed mixture of flashed vapour and motive steam is fed via line 35 to column 3 for use as stripping steam. After flashing in 5, semilean solution is fed, via 281, to an intermediate level of absorption column 1, while lean solution, after heat exchange at 99, is pumped via 261 to the top of column 1. Desorbed acid gas and residual steam flows are cooled at 93 and the condensate recycled via 29 to boiling kettle 95, to produce motive steam, or to valve 62 as process reflux In modification (not shown) (1), all the stripping steam for the auxiliary regenerator is derived from a steam jet ejector; (2) gas from the absorber 1 is partially regenerated as one stream before distribution to main and auxiliary regenerators; (3) two different scrubbing solutions used in different parts of the absorber are regenerated. Since the pressures in the main and auxiliary regenerators are independently selected, the pressure in the latter may be lower than, equal to or higher than the pressure in the main regenerator. The process may be applied to the removal of acid gases from natural gas or industrial process gas. In examples, CO 2 is scrubbed from a process gas stream with K 2 CO 3 or in 2 stages with K 2 CO 3 and diethanolamine.
Priority Applications (17)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB55851/74A GB1484050A (en) | 1974-12-24 | 1974-12-24 | Processes for removing acid gases from gaseous mixtures |
DE2557531A DE2557531C2 (en) | 1974-12-24 | 1975-12-19 | Process for regenerating aqueous washing solutions |
IE2794/75A IE41981B1 (en) | 1974-12-24 | 1975-12-22 | Improvements to the processes for removing acid gases from gaseous mixtures |
BE162992A BE836929A (en) | 1974-12-24 | 1975-12-22 | IMPROVEMENTS IN THE REGENERATION OF AQUEOUS ABSORBENT SOLUTIONS USED TO SEPARATE ACID GAS FROM GASEOUS MIXTURES |
ZA757939A ZA757939B (en) | 1974-12-24 | 1975-12-22 | Improvements to the regeneration of regenerable aqueous scrubbing solution used for removing acidic gases from gas mixture |
NZ179638A NZ179638A (en) | 1974-12-24 | 1975-12-22 | Regeneration of gas scrubbing solution |
CA242,505A CA1068638A (en) | 1974-12-24 | 1975-12-22 | Regeneration of regenerable aqueous scrubbing solutions used for removing acidic gases from gas mixture |
BR7508536*A BR7508536A (en) | 1974-12-24 | 1975-12-22 | IMPROVEMENT IN PROCESS FOR REGENERATION OF Aqueous WASHING SOLUTIONS |
IT30629/75A IT1051858B (en) | 1974-12-24 | 1975-12-22 | IMPROVEMENTS IN THE REGENERATION OF REGENERABLE WASHING WATER SOLUTIONS USED TO SEPARATE ACID GASES FROM GASEOUS MIXTURES |
IN2370/CAL/75A IN144785B (en) | 1974-12-24 | 1975-12-22 | |
PH17916A PH12514A (en) | 1974-12-24 | 1975-12-23 | Process for the regeneration of regenerable aqueous scrubbing solutions used for removing acidic gases from gas mixture |
AT0979075A AT369421B (en) | 1974-12-24 | 1975-12-23 | REGENERATION METHOD FOR REGENERABLE AQUEOUS WASH SOLUTIONS |
DK588975A DK588975A (en) | 1974-12-24 | 1975-12-23 | PROCEDURE FOR REGENERATION OF AQUATIC SCRUBBING SOLUTIONS TO REMOVE ACID GASES FROM GAS MIXTURES |
FR7539546A FR2295781A1 (en) | 1974-12-24 | 1975-12-23 | IMPROVEMENTS IN THE REGENERATION OF AQUEOUS ABSORBENT SOLUTIONS USED TO SEPARATE ACID GAS FROM GASEOUS MIXTURES |
AU87819/75A AU503541B2 (en) | 1974-12-24 | 1975-12-23 | Regeneration of aqueous scrubbing solutions |
ES443792A ES443792A1 (en) | 1974-12-24 | 1975-12-23 | Processes for removing acid gases from gaseous mixtures |
JP50153860A JPS597487B2 (en) | 1974-12-24 | 1975-12-23 | Sansei Kitaijiyokiyonimochiil Senjiyouekinokairiyo Saiseihou |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB55851/74A GB1484050A (en) | 1974-12-24 | 1974-12-24 | Processes for removing acid gases from gaseous mixtures |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1484050A true GB1484050A (en) | 1977-08-24 |
Family
ID=10475044
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB55851/74A Expired GB1484050A (en) | 1974-12-24 | 1974-12-24 | Processes for removing acid gases from gaseous mixtures |
Country Status (16)
Country | Link |
---|---|
AT (1) | AT369421B (en) |
AU (1) | AU503541B2 (en) |
BE (1) | BE836929A (en) |
BR (1) | BR7508536A (en) |
CA (1) | CA1068638A (en) |
DE (1) | DE2557531C2 (en) |
DK (1) | DK588975A (en) |
ES (1) | ES443792A1 (en) |
FR (1) | FR2295781A1 (en) |
GB (1) | GB1484050A (en) |
IE (1) | IE41981B1 (en) |
IN (1) | IN144785B (en) |
IT (1) | IT1051858B (en) |
NZ (1) | NZ179638A (en) |
PH (1) | PH12514A (en) |
ZA (1) | ZA757939B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004080573A1 (en) * | 2003-03-10 | 2004-09-23 | Board Of Regents - The University Of Texas System | Regeneration of an aqueous solution from an acid gas absorption process by multistage flashing and stripping |
WO2010086039A1 (en) * | 2009-01-28 | 2010-08-05 | Siemens Aktiengesellschaft | Method and device for separating carbon dioxide from an exhaust gas of a fossil fired power plant |
WO2011124425A1 (en) * | 2010-04-07 | 2011-10-13 | Siemens Aktiengesellschaft | Separating device for co2 and power plant |
WO2012038865A1 (en) * | 2010-09-20 | 2012-03-29 | Prateek Bumb | A system and process for carbon dioxide recovery |
US8303685B2 (en) | 2003-07-22 | 2012-11-06 | Dow Global Technologies Llc | Regeneration of acid gas-containing treatment fluids |
EP2668996B1 (en) * | 2011-01-27 | 2019-06-19 | IHI Corporation | Method for recovering carbon dioxide and recovery apparatus |
CN114262635A (en) * | 2021-12-09 | 2022-04-01 | 中国石油大学(北京) | Natural gas reinforced desulfurization and decarburization system and method |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2646804C3 (en) * | 1976-10-16 | 1982-03-11 | Basf Ag, 6700 Ludwigshafen | Process for the production of pure ammonia from gas mixtures containing ammonia and carbon dioxide |
US4198378A (en) * | 1976-11-12 | 1980-04-15 | Giuseppe Giammarco | Process for removing CO2, H2 S and other gaseous impurities from gaseous mixtures |
FR2417331A1 (en) * | 1978-02-21 | 1979-09-14 | Percevaut Emile | Compsn. used in scrubbing polluting gases - esp. from engine exhausts, contains sodium carbonate, water, urea and satd. soln. of tetra:chlorophenol:phthalein |
IT1156991B (en) * | 1978-04-27 | 1987-02-04 | Giuseppe Giammarco | IMPROVED PROCEDURE FOR THE PURIFICATION OF LIQUIDS AND OR FOR THE REGENERATION OF ABSORBENT SOLUTIONS |
DE2856078A1 (en) * | 1978-12-23 | 1980-07-10 | Linde Ag | METHOD FOR SEPARATING AND RECOVERING GAS-SHAPED COMPONENTS FROM A GAS MIXTURE BY PHYSICAL LAUNDRY |
PL2164608T3 (en) | 2007-05-29 | 2018-04-30 | University Of Regina | Method for recovering a gaseous component from a gas stream |
CN114224262B (en) * | 2021-12-18 | 2022-07-26 | 平湖市旭阳电子科技有限公司 | Steam generator water vapor recycling device and method |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL7402037A (en) * | 1973-02-16 | 1974-08-20 |
-
1974
- 1974-12-24 GB GB55851/74A patent/GB1484050A/en not_active Expired
-
1975
- 1975-12-19 DE DE2557531A patent/DE2557531C2/en not_active Expired
- 1975-12-22 IE IE2794/75A patent/IE41981B1/en unknown
- 1975-12-22 BR BR7508536*A patent/BR7508536A/en unknown
- 1975-12-22 NZ NZ179638A patent/NZ179638A/en unknown
- 1975-12-22 IN IN2370/CAL/75A patent/IN144785B/en unknown
- 1975-12-22 ZA ZA757939A patent/ZA757939B/en unknown
- 1975-12-22 IT IT30629/75A patent/IT1051858B/en active
- 1975-12-22 BE BE162992A patent/BE836929A/en not_active IP Right Cessation
- 1975-12-22 CA CA242,505A patent/CA1068638A/en not_active Expired
- 1975-12-23 AU AU87819/75A patent/AU503541B2/en not_active Expired
- 1975-12-23 DK DK588975A patent/DK588975A/en not_active Application Discontinuation
- 1975-12-23 PH PH17916A patent/PH12514A/en unknown
- 1975-12-23 FR FR7539546A patent/FR2295781A1/en active Granted
- 1975-12-23 ES ES443792A patent/ES443792A1/en not_active Expired
- 1975-12-23 AT AT0979075A patent/AT369421B/en not_active IP Right Cessation
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004080573A1 (en) * | 2003-03-10 | 2004-09-23 | Board Of Regents - The University Of Texas System | Regeneration of an aqueous solution from an acid gas absorption process by multistage flashing and stripping |
US7901487B2 (en) | 2003-03-10 | 2011-03-08 | Board Of Regents, The University Of Texas System | Regeneration of an aqueous solution from an acid gas absorption process by multistage flashing and stripping |
US8303685B2 (en) | 2003-07-22 | 2012-11-06 | Dow Global Technologies Llc | Regeneration of acid gas-containing treatment fluids |
WO2010086039A1 (en) * | 2009-01-28 | 2010-08-05 | Siemens Aktiengesellschaft | Method and device for separating carbon dioxide from an exhaust gas of a fossil fired power plant |
US8557205B2 (en) | 2009-01-28 | 2013-10-15 | Siemens Aktiengesellschaft | Method and device for separating of carbon dioxide from an exhaust gas of a fossil-fired power plant |
RU2495707C2 (en) * | 2009-01-28 | 2013-10-20 | Сименс Акциенгезелльшафт | Method and device for separation of carbon dioxide from offgas at electric power station running on fossil fuel |
WO2011124425A1 (en) * | 2010-04-07 | 2011-10-13 | Siemens Aktiengesellschaft | Separating device for co2 and power plant |
WO2012038865A1 (en) * | 2010-09-20 | 2012-03-29 | Prateek Bumb | A system and process for carbon dioxide recovery |
EP2668996B1 (en) * | 2011-01-27 | 2019-06-19 | IHI Corporation | Method for recovering carbon dioxide and recovery apparatus |
CN114262635A (en) * | 2021-12-09 | 2022-04-01 | 中国石油大学(北京) | Natural gas reinforced desulfurization and decarburization system and method |
Also Published As
Publication number | Publication date |
---|---|
BR7508536A (en) | 1976-08-24 |
IT1051858B (en) | 1981-05-20 |
IE41981B1 (en) | 1980-05-07 |
FR2295781A1 (en) | 1976-07-23 |
AU503541B2 (en) | 1979-09-06 |
IN144785B (en) | 1978-07-08 |
ES443792A1 (en) | 1977-04-16 |
DE2557531A1 (en) | 1976-07-08 |
DE2557531C2 (en) | 1985-01-24 |
AT369421B (en) | 1982-12-27 |
DK588975A (en) | 1976-06-25 |
BE836929A (en) | 1976-06-22 |
PH12514A (en) | 1979-04-20 |
AU8781975A (en) | 1977-06-30 |
CA1068638A (en) | 1979-12-25 |
IE41981L (en) | 1976-06-24 |
NZ179638A (en) | 1978-12-18 |
FR2295781B1 (en) | 1983-04-01 |
ZA757939B (en) | 1976-11-24 |
ATA979075A (en) | 1982-05-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |