GB1478457A - Vinyl polymerisation - Google Patents
Vinyl polymerisationInfo
- Publication number
- GB1478457A GB1478457A GB3015074A GB3015074A GB1478457A GB 1478457 A GB1478457 A GB 1478457A GB 3015074 A GB3015074 A GB 3015074A GB 3015074 A GB3015074 A GB 3015074A GB 1478457 A GB1478457 A GB 1478457A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl halide
- catalyst
- july
- effected
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1478457 Vinyl halide preparation IMPERIAL CHEMICAL INDUSTRIES Ltd 8 July 1974 [19 July 1973] 30150/74 Addition to 1374967 Heading C3P In a process for the gaseous phase polymerization of a vinyl halide, the latter is contacted with a catalyst composition comprising (a) a compound of a transition metal of Groups IVA to VIA of the Periodic Table of Elements and (b) an organoaluminium or organozinc compound containing a ligand derived from a hydroxy ester, the polymerization being effected in the presence of a particulate seed material which comprises a polymer of a vinyl halide. The vinyl halide may be the chloride and bromide, which if desired may be copolymerized. Other copolymerizable unsaturated monomers specified are vinyl acetate, styrene, methyl acrylate, methyl methacrylate, acylonitrile, ethylene, propylene, butene, 4-methylpentene- 1 and butadiene. The catalyst may be supported on the seed material or on, e.g. SiO 2 or Al 2 O 3 . The support materials may have a size of 1- 1000 microns. The process of the invention may be effected in a fluidized bed, e.g. at 40-95‹ C. Examples describe the preparation of P.V.C. in the presence of catalyst compositions disclosed in Specification 1,374,967.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3015074A GB1478457A (en) | 1974-07-08 | 1974-07-08 | Vinyl polymerisation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3015074A GB1478457A (en) | 1974-07-08 | 1974-07-08 | Vinyl polymerisation |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1478457A true GB1478457A (en) | 1977-06-29 |
Family
ID=10303115
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3015074A Expired GB1478457A (en) | 1974-07-08 | 1974-07-08 | Vinyl polymerisation |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1478457A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6462153B1 (en) | 1996-04-03 | 2002-10-08 | Occidental Chemical Corporation | Method of polymerizing vinyl chloride monomer |
-
1974
- 1974-07-08 GB GB3015074A patent/GB1478457A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6462153B1 (en) | 1996-04-03 | 2002-10-08 | Occidental Chemical Corporation | Method of polymerizing vinyl chloride monomer |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed |