GB1477825A - Catalyst component for use in -co-polymerization of ethylene alpha-olefines conjugated and non-conjugated dienes method of preparing and using same - Google Patents

Catalyst component for use in -co-polymerization of ethylene alpha-olefines conjugated and non-conjugated dienes method of preparing and using same

Info

Publication number
GB1477825A
GB1477825A GB3204374A GB3204374A GB1477825A GB 1477825 A GB1477825 A GB 1477825A GB 3204374 A GB3204374 A GB 3204374A GB 3204374 A GB3204374 A GB 3204374A GB 1477825 A GB1477825 A GB 1477825A
Authority
GB
United Kingdom
Prior art keywords
ticl
ethylene
polymerization
ibu
cross
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3204374A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INST NEFTECHIMICHESKOGO SINTEZ
PROMYSH
V NI I PI NEFTEPERERABATYVAJUS
VSES NI I PROEKT INST NEFTEPERERABATYVAJUSCHEI I NEFTEKHIM
AV Topchiev Institute of Petrochemical Synthesis
Original Assignee
INST NEFTECHIMICHESKOGO SINTEZ
PROMYSH
V NI I PI NEFTEPERERABATYVAJUS
VSES NI I PROEKT INST NEFTEPERERABATYVAJUSCHEI I NEFTEKHIM
AV Topchiev Institute of Petrochemical Synthesis
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by INST NEFTECHIMICHESKOGO SINTEZ, PROMYSH, V NI I PI NEFTEPERERABATYVAJUS, VSES NI I PROEKT INST NEFTEPERERABATYVAJUSCHEI I NEFTEKHIM, AV Topchiev Institute of Petrochemical Synthesis filed Critical INST NEFTECHIMICHESKOGO SINTEZ
Publication of GB1477825A publication Critical patent/GB1477825A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1477825 Polymer-supported Ziegler catalysts INST NEFTEKHIMICHE SINTEZA I AV TOPCHIEVA AKAD NAUK SSSR and VSESOJUZ NI I PROEKT INST NEFTEPER ER ABATYVA JUSCHEI I NEFTEKHIMICHES PROMYSHLENNOSTI 19 July 1974 [24 July 1973] 32043/74 Headings C3P and C3E A catalyst component (a), for use in conjunction with organometallic compounds (b) in the polymerization of ethylene, α-monoolefins, or dienes, is obtained by reacting a transition metal compound with a rubbery material containing electron-donor and/or electron-acceptor groups to obtain a gel which is insoluble but swellable in a hydrocarbon or halohydrocarbon medium. The initial rubber reactant may be in a cross-linked gel form or the gel structure may be formed in situ during the bonding reaction with the transition metal compound. The polymerization processes may include the step of recycling the catalyst. Examples refer to the polymerization of butadiene, ethylene, ethylenepropylene, vinylcyclohexane, propylene, isoprene, using (a)reaction products of (C 5 H 5 ) 2 TiCl 2 , TiCl 4 , nickelacetylacetonate, VCl 4 , TiCl 4 and Al(iBu)3,(C 5 H 5 ) 2 TiCl 2 and Al(iBu) 2 Cl, VO(OEt) 3 , Ti(OBu) 3 Cl, Mg, PrCl and TiCl 4 , or VCl 4 and Ni(C 5 H 7 O 2 ) 2 , on cross-linked graft polymers of vinyl pyridine, allyl alcohol, methyl methacrylate, diethylaminoethylmethacrylate or methacrylic acid on an ethylene-propyleneethylidenenorbornene terpolymer, a cross-linked graft polymer of vinyl diphenylphosphine on an ethylene-propylene-dicyclopentadiene terpolymer, a cross-linked graft polymer of vinyl pyridine on a polysiloxane containing unsaturated groups, natural rubber or 1,2-polybutadiene, and (b) Al - (cyolohexenylethyl) 2 Cl, iBu 3 Al, iBu 2 AlCl or (C 7 H 15 ) 3 Al.
GB3204374A 1973-07-24 1974-07-19 Catalyst component for use in -co-polymerization of ethylene alpha-olefines conjugated and non-conjugated dienes method of preparing and using same Expired GB1477825A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU1950384A SU492298A1 (en) 1973-07-24 1973-07-24 Catalyst for the polymerization and copolymerization of ethylene, α-olefins and conjugated and non-conjugated dienes

Publications (1)

Publication Number Publication Date
GB1477825A true GB1477825A (en) 1977-06-29

Family

ID=20561912

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3204374A Expired GB1477825A (en) 1973-07-24 1974-07-19 Catalyst component for use in -co-polymerization of ethylene alpha-olefines conjugated and non-conjugated dienes method of preparing and using same

Country Status (7)

Country Link
BE (1) BE818000A (en)
CA (1) CA1031899A (en)
DE (1) DE2435609A1 (en)
FR (1) FR2245672B1 (en)
GB (1) GB1477825A (en)
IT (1) IT1034066B (en)
SU (1) SU492298A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2000153A (en) * 1977-06-16 1979-01-04 Brintzinger H Cyclopentadienyl-metal-carbonyl compounds bound to polymers and derivatives therefrom processes for their preparation and their use as catalysts
US6063725A (en) * 1995-11-07 2000-05-16 Mitsui Chemicals, Inc. Olefin polymerization catalyst system
US6524986B2 (en) 1993-05-25 2003-02-25 Solvay Polyolefins Europe-Belgium Catalyst support and catalyst for the polymerization of α-olefins

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2835944A1 (en) * 1978-08-17 1980-03-13 Heyl & Co METAL-CONTAINING SOLUBLE POLYMERS CATALYSTS FOR POLYMERIZATIONS, METHODS FOR THE PRODUCTION THEREOF AND THEIR USE IN POLYMERIZATION METHODS

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2000153A (en) * 1977-06-16 1979-01-04 Brintzinger H Cyclopentadienyl-metal-carbonyl compounds bound to polymers and derivatives therefrom processes for their preparation and their use as catalysts
GB2000153B (en) * 1977-06-16 1982-11-24 Brintzinger H Cyclopentadienyl-metal compounds and processes for their preparation
US6524986B2 (en) 1993-05-25 2003-02-25 Solvay Polyolefins Europe-Belgium Catalyst support and catalyst for the polymerization of α-olefins
US6063725A (en) * 1995-11-07 2000-05-16 Mitsui Chemicals, Inc. Olefin polymerization catalyst system

Also Published As

Publication number Publication date
FR2245672A1 (en) 1975-04-25
DE2435609A1 (en) 1975-02-06
SU492298A1 (en) 1975-11-25
CA1031899A (en) 1978-05-23
IT1034066B (en) 1979-09-10
BE818000A (en) 1975-01-23
FR2245672B1 (en) 1977-09-23

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Legal Events

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PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee