GB1456410A - Catalyst component for olefin polymerization - Google Patents
Catalyst component for olefin polymerizationInfo
- Publication number
- GB1456410A GB1456410A GB5485374A GB5485374A GB1456410A GB 1456410 A GB1456410 A GB 1456410A GB 5485374 A GB5485374 A GB 5485374A GB 5485374 A GB5485374 A GB 5485374A GB 1456410 A GB1456410 A GB 1456410A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ticl
- olefin polymerization
- phenyl
- alkyl
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
1456410 Olefin polymerization catalyst BASF AG 19 Dec 1974 [21 Dec 1973] 54853/74 Addition to 1456408 Heading C3P An olefin polymerization catalyst comprises (A) an organoaluminium, -zinc or -magnesium compound and (B) a titanium component obtained by (i) reacting, in suspension, a metal salt of a CH-acid organic compound of formula where M is magnesium or manganese, R<SP>1</SP> is CN, COR<SP>3</SP> or COOR<SP>4</SP>, R<SP>2</SP> is COR<SP>3</SP>, COOR<SP>4</SP> or phenyl, R<SP>3</SP> is alkyl, alkyl phenyl or phenyl and R<SP>4</SP> is alkyl, with an organoaluminium compound, and (ii) reacting, in suspension, the solid product of (i) with a reaction product of the formula TiZ q (OQ) 4-q , where Z is halogen, Q is hydrocarbyl, and q is 1 to 2À5. The titanium halo-hydrocarbyloxide is obtainable by simply mixing compounds of formulae TiZ 4 and Ti(OQ) 4 in the ratio q : 4-q. Specified salt compounds are the magnesium salts of acetoacetic acid ethyl ester, acetylacetone, malonic acid diethylester, benzylcyanide and dibenzoylmethane. Examples refer to the homopolymerization of ethylene in a polyethylene bed or in isobutane in the presence of hydrogen and of a catalyst comprising (A) AliBu 3 , AlEt 3 or Al(C 8 H 17 ) 3 and (B) (i) the reaction product of the Mg salt of acetoacetic acid ethyl ester or of acetylacetone and AlEt 2 Cl, followed by reaction with (ii) TiCl q (OiPr) 4-q , where q = 1À25, 1À62, 2 or 2À44, TiCl q (On-Bu) 4-q , where q = 2 or 1À33, or TiCl 2 (Oi-Bu) 2 .
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2363697A DE2363697C3 (en) | 1973-12-21 | 1973-12-21 | Process for the production of homopolymers of ethylene or copolymers of ethylene with α monoolefins BASF AG, 6700 Ludwigshafen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1456410A true GB1456410A (en) | 1976-11-24 |
Family
ID=5901474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5485374A Expired GB1456410A (en) | 1973-12-21 | 1974-12-19 | Catalyst component for olefin polymerization |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS5096686A (en) |
| AT (1) | AT333501B (en) |
| AU (1) | AU498151B2 (en) |
| BE (1) | BE823378A (en) |
| DE (1) | DE2363697C3 (en) |
| FR (1) | FR2255318B1 (en) |
| GB (1) | GB1456410A (en) |
| IT (1) | IT1025555B (en) |
| NO (1) | NO744558L (en) |
| SE (1) | SE7416070L (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5274686A (en) * | 1975-12-18 | 1977-06-22 | Sumitomo Chem Co Ltd | Process for polymerizing olefins |
-
1973
- 1973-12-21 DE DE2363697A patent/DE2363697C3/en not_active Expired
-
1974
- 1974-11-12 IT IT29358/74A patent/IT1025555B/en active
- 1974-12-12 AU AU76355/74A patent/AU498151B2/en not_active Expired
- 1974-12-16 BE BE151524A patent/BE823378A/en unknown
- 1974-12-17 NO NO744558A patent/NO744558L/no unknown
- 1974-12-19 FR FR7442037A patent/FR2255318B1/fr not_active Expired
- 1974-12-19 GB GB5485374A patent/GB1456410A/en not_active Expired
- 1974-12-19 SE SE7416070A patent/SE7416070L/xx unknown
- 1974-12-20 JP JP49145800A patent/JPS5096686A/ja active Pending
- 1974-12-20 AT AT1022274A patent/AT333501B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| IT1025555B (en) | 1978-08-30 |
| FR2255318A1 (en) | 1975-07-18 |
| NO744558L (en) | 1975-07-21 |
| DE2363697C3 (en) | 1981-01-15 |
| BE823378A (en) | 1975-06-16 |
| AT333501B (en) | 1976-11-25 |
| AU7635574A (en) | 1976-06-17 |
| JPS5096686A (en) | 1975-07-31 |
| SE7416070L (en) | 1975-06-23 |
| AU498151B2 (en) | 1979-02-15 |
| DE2363697A1 (en) | 1975-07-03 |
| ATA1022274A (en) | 1976-03-15 |
| DE2363697B2 (en) | 1980-04-30 |
| FR2255318B1 (en) | 1978-03-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |