GB1455823A - Dishwashing compositions - Google Patents

Dishwashing compositions

Info

Publication number
GB1455823A
GB1455823A GB5410972A GB5410972A GB1455823A GB 1455823 A GB1455823 A GB 1455823A GB 5410972 A GB5410972 A GB 5410972A GB 5410972 A GB5410972 A GB 5410972A GB 1455823 A GB1455823 A GB 1455823A
Authority
GB
United Kingdom
Prior art keywords
composition
zero
weight
alkyl
random
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5410972A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Original Assignee
Unilever PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to GB4568072A priority Critical patent/GB1441588A/en
Application filed by Unilever PLC filed Critical Unilever PLC
Priority to GB5410972A priority patent/GB1455823A/en
Priority to CA182,362A priority patent/CA992424A/en
Priority to US05/402,428 priority patent/US3941713A/en
Priority to FR7335180A priority patent/FR2208973B1/fr
Priority to AU60884/73A priority patent/AU474195B2/en
Priority to DE19732349739 priority patent/DE2349739A1/en
Priority to NL7313623A priority patent/NL7313623A/xx
Priority to US05/415,709 priority patent/US3956199A/en
Priority to FR7340725A priority patent/FR2207979B1/fr
Priority to AT965173A priority patent/AT330931B/en
Priority to ZA00738823A priority patent/ZA738823B/en
Priority to AU62647/73A priority patent/AU479715B2/en
Priority to CH1630473A priority patent/CH590921A5/xx
Priority to NO4447/73A priority patent/NO141370C/en
Priority to CA186,269A priority patent/CA979316A/en
Priority to DE2358116A priority patent/DE2358116A1/en
Priority to IT70431/73A priority patent/IT999797B/en
Priority to JP48131163A priority patent/JPS4982710A/ja
Priority to SE7315781A priority patent/SE414187B/en
Priority to NLAANVRAGE7315974,A priority patent/NL181211C/en
Priority to BE138065A priority patent/BE807685A/en
Publication of GB1455823A publication Critical patent/GB1455823A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

1455823 Dishwashing compositions UNILEVER Ltd 20 Nov 1973 [22 Nov 1972] 54109/72 Heading C5D An unbuilt composition having a pH in the range 4-8À5, and suitable for hand dishwashing, comprises (a) 10-50% by weight of a mixture of synthetic organic detergents, 4-40% by weight of which, based on the total composition, is a calcium/magnesium sensitive anionic synthetic detergent (which precipitates in salt form in presence of hard water under specified conditions) and at least 1% by weight of which, based on the total composition, is an anionic or non-ionic surface active solubilizer for the anti-resoiling agent and (b) 0À015-0À45% by weight of an anti-resoiling agent which is an organic phosphonate chosen from the following acids and their salts: (1) wherein x+y+z=8-16 and x, y or z may be zero; (2) wherein p+q=8-14 and p or q may be zero; (3a) wherein n+d+e+f=8-14 and n, d, e or f may be zero; (3b) wherein r+s+t=8-14 and r, s or t may be zero; (4) wherein a+b+c=10-17 and a, b and c may be zero. The pH of the composition may be adjusted to the required value by the addition of tris-(hydroxymethyl)aminomethane, triethanolamine, phosphoric acid, o-aminobenzoic acid or 2,4,6-trichlorophenol or by the addition of a weak organic acid (e.g. one or more of malonic, succinic, glutaric, citric, tartaric, lactic, phthalic, adipic, fumaric and benzoic acids or partial salts thereof) followed by NaOH, ammonia or a substituted ammonia derivative. The calcium/magnesium sensitive anionic synthetic detergent may be an alkali metal, ammonium or substituted ammonium salt of a C 11 -C 18 alkyl α or random alkene sulphonate; random C 13 -C 18 alkyl sulphonate; C 10 -C 15 alkyl benzene sulphonate; C 11 -C 15 primary or secondary alcohol sulphate; or mixtures of these. The solubilizer may be an ethylene oxide condensation product of a primary or secondary aliphatic alcohol or alkyl phenol; or an alkali metal, ammonium or substituted ammonium salt of (i) hydroxyalkane sulphonates and disulphonates derived from sulphonation of C 11 - C 18 random and alpha-olefins or (ii) sulphated ethylene oxide condensation products of C 11 - C 15 primary or secondary alcohols. The composition may contain perfume, colourants, fruit juices. Where the composition is in powder or paste form, fillers (e.g. sodium sulphate or polyethylene gylcol) may be included. Where the composition is in liquid form, water, hydrotropes, viscosity modifiers and opacifiers may be included, gelatin and ethanol being exemplified. The composition in paste form may be incorporated within fleeces, wools or sponges of one or more of nylon, steel, copper or polyurethane.
GB5410972A 1972-10-04 1972-11-22 Dishwashing compositions Expired GB1455823A (en)

Priority Applications (22)

Application Number Priority Date Filing Date Title
GB4568072A GB1441588A (en) 1972-10-04 1972-10-04 Rinse composition
GB5410972A GB1455823A (en) 1972-10-04 1972-11-22 Dishwashing compositions
CA182,362A CA992424A (en) 1972-10-04 1973-09-28 Rinse composition
US05/402,428 US3941713A (en) 1972-10-04 1973-10-01 Rinse composition
FR7335180A FR2208973B1 (en) 1972-10-04 1973-10-02
AU60884/73A AU474195B2 (en) 1972-10-04 1973-10-02 Rinse composition
DE19732349739 DE2349739A1 (en) 1972-10-04 1973-10-03 LIQUID DETERGENT COMPOSITION
NL7313623A NL7313623A (en) 1972-10-04 1973-10-04
US05/415,709 US3956199A (en) 1972-10-04 1973-11-14 Dishwashing compositions
FR7340725A FR2207979B1 (en) 1972-10-04 1973-11-15
AT965173A AT330931B (en) 1972-10-04 1973-11-16 DISHWASHING AGENT COMPOSITIONS
ZA00738823A ZA738823B (en) 1972-11-22 1973-11-19 Dishwashing compositions
AU62647/73A AU479715B2 (en) 1972-11-22 1973-11-19 Dishwashing compositions
CH1630473A CH590921A5 (en) 1972-10-04 1973-11-20
NO4447/73A NO141370C (en) 1972-11-22 1973-11-20 DETERGENT MIXING FOR MANUAL DISH
CA186,269A CA979316A (en) 1972-10-04 1973-11-20 Dishwashing compositions
DE2358116A DE2358116A1 (en) 1972-10-04 1973-11-21 DISHWASHING DETERGENT COMPOSITIONS
IT70431/73A IT999797B (en) 1972-11-22 1973-11-21 COMPOSITION FOR WASHING DISHES
JP48131163A JPS4982710A (en) 1972-11-22 1973-11-21
SE7315781A SE414187B (en) 1972-11-22 1973-11-21 DISC MEDICINAL COMPOSITION CONTAINING AN ANIONIC TENSID AND AN ORGANIC PHOSPHONATE OR SALT THEREOF
NLAANVRAGE7315974,A NL181211C (en) 1972-10-04 1973-11-22 METHOD FOR PREPARING HANDLE DETERGENTS.
BE138065A BE807685A (en) 1972-10-04 1973-11-22 DISHWASHING COMPOSITIONS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB4568072A GB1441588A (en) 1972-10-04 1972-10-04 Rinse composition
GB5410972A GB1455823A (en) 1972-10-04 1972-11-22 Dishwashing compositions

Publications (1)

Publication Number Publication Date
GB1455823A true GB1455823A (en) 1976-11-17

Family

ID=26265640

Family Applications (2)

Application Number Title Priority Date Filing Date
GB4568072A Expired GB1441588A (en) 1972-10-04 1972-10-04 Rinse composition
GB5410972A Expired GB1455823A (en) 1972-10-04 1972-11-22 Dishwashing compositions

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB4568072A Expired GB1441588A (en) 1972-10-04 1972-10-04 Rinse composition

Country Status (10)

Country Link
US (2) US3941713A (en)
AT (1) AT330931B (en)
AU (1) AU474195B2 (en)
BE (1) BE807685A (en)
CA (2) CA992424A (en)
CH (1) CH590921A5 (en)
DE (2) DE2349739A1 (en)
FR (2) FR2208973B1 (en)
GB (2) GB1441588A (en)
NL (2) NL7313623A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3439247A1 (en) * 1983-11-09 1985-05-15 Colgate-Palmolive Co., New York, N.Y. ACID, LIQUID, CLEANING AGENT FOR CERAMIC PLATES, WHICH DOES NOT DETERMINE THE Potting Material

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3929678A (en) * 1974-08-01 1975-12-30 Procter & Gamble Detergent composition having enhanced particulate soil removal performance
US4079020A (en) * 1975-11-07 1978-03-14 Lever Brothers Company Cleaning composition
US4070309A (en) * 1976-07-27 1978-01-24 The Procter & Gamble Company Detergent composition
US4105573A (en) * 1976-10-01 1978-08-08 The Procter & Gamble Company Dishwasher detergent composition
GB1538174A (en) * 1976-11-05 1979-01-10 Unilever Ltd Cleaning composition
DE2727382A1 (en) * 1977-06-18 1979-01-04 Basf Ag FOAM DAMPERS CONTAINING MONO AND / OR DIALKYL PHOSPHATES
DE2833991A1 (en) * 1978-08-03 1980-02-21 Basf Ag METHOD FOR MECHANICALLY RINSING DISHES USING MULTI-VALUE ALCOHOLS, CARBONIC ACIDS AND / OR ESTERS THEREOF AS A RINSE AID
JPS6039719B2 (en) * 1982-05-11 1985-09-07 花王株式会社 liquid cleaning composition
DE3240688A1 (en) * 1982-11-04 1984-05-30 Henkel KGaA, 4000 Düsseldorf USE OF ALKYLMONOPHOSPHONIC ACIDS AS A KILLING SUBSTANCE
FR2536675A1 (en) * 1982-11-26 1984-06-01 Inmont Sa COMPOSITIONS FOR WATER OFFSET PLATE WET
GB8404120D0 (en) * 1984-02-16 1984-03-21 Unilever Plc Liquid detergent compositions
US4624713A (en) * 1984-11-15 1986-11-25 Economics Laboratory, Inc. Solid rinse aids and methods of warewashing utilizing solid rinse aids
US4737314A (en) 1985-02-08 1988-04-12 Nippon Shokubai Kagaku Kogyo Co., Ltd. Stabilized alkylene oxide adduct containing lactic acid or a lactate
DE3645248C2 (en) * 1985-02-08 1996-01-25 Nippon Catalytic Chem Ind Stabilised alkoxylate of organic hydroxy cpd.
US5427707A (en) * 1985-06-14 1995-06-27 Colgate Palmolive Co. Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer
DE3523319A1 (en) * 1985-06-29 1987-01-08 Basf Ag BINDING AGENT FOR AQUEOUS, PHYSICAL DRYING CORROSION PROTECTION COATINGS BASED ON A POLYMER DISPERSION CONTAINING PHOSPHORIC ACID MONOALKYLESTER
US4749516A (en) * 1985-09-24 1988-06-07 S. C. Johnson & Son, Inc. Anionic emulsion pre-spotting composition
US4877691A (en) * 1985-11-27 1989-10-31 Kay Chemical Company Soil release agent and method to facilitate the cleaning of ovens used for cooking
US4769159A (en) * 1986-02-18 1988-09-06 Ecolab Inc. Institutional softener containing cationic surfactant and organic acid
US4935158A (en) * 1986-10-30 1990-06-19 Aszman Harry W Solid detergent cleaning composition, reusable cleaning pad containing same and method of manufacture
EP0317614A4 (en) * 1987-05-18 1989-07-24 Staley Continental Inc Low foaming detergent composition.
US5034556A (en) * 1989-04-03 1991-07-23 Ppg Industries, Inc. Reaction products of alpha-aminomethylene phosphonic acids and epoxy compounds and their use in coating compositions
US5137793A (en) * 1990-08-01 1992-08-11 Kay Chemical Company Cooking equipment pretreatment composition and method of use
US5306526A (en) * 1992-04-02 1994-04-26 Ppg Industries, Inc. Method of treating nonferrous metal surfaces by means of an acid activating agent and an organophosphate or organophosphonate and substrates treated by such method
US5294265A (en) * 1992-04-02 1994-03-15 Ppg Industries, Inc. Non-chrome passivation for metal substrates
US5389138A (en) * 1993-03-31 1995-02-14 Kay Chemical Company Oven pretreatment and cleaning composition containing silicone
US6257253B1 (en) 1994-04-19 2001-07-10 Ecolab Inc. Percarboxylic acid rinse method
US5578134A (en) * 1994-04-19 1996-11-26 Ecolab Inc. Method of sanitizing and destaining tableware
US6302968B1 (en) 1994-04-19 2001-10-16 Ecolab Inc. Precarboxylic acid rinse method
NL9401098A (en) * 1994-06-30 1996-02-01 Petrus Johannes Maria Van Leeu Method for applying an anti-bacterial protective layer on dishes and tools used in the food industry.
US5686023A (en) * 1995-04-27 1997-11-11 Witco Corporation C7 -C12 diol and diol alkoxylates as coupling agents for surfactant formulations
US6110886A (en) * 1995-06-16 2000-08-29 Sunburst Chemicals, Inc. Solid cast fabric softening compositions for application in a washing machine
EP0851021A3 (en) * 1996-12-28 1999-12-22 Basf Corporation Improved rinse aid compositions
US5753608A (en) * 1996-12-28 1998-05-19 Basf Corporation Rinse aid compositions containing phosphate esters
US5977041A (en) * 1997-09-23 1999-11-02 Olin Microelectronic Chemicals Aqueous rinsing composition
AU2110500A (en) * 1999-02-05 2000-08-25 Unilever Plc Dish washing process and compositions relating thereto
AU4405600A (en) * 1999-06-25 2001-01-31 Unilever Plc Dish washing process and compositions relating thereto
DE60104208T2 (en) * 2000-10-10 2004-11-04 JohnsonDiversey, Inc., Sturtevant DETERGENT COMPOSITION AND DISHWASHING METHOD
ATE528386T1 (en) * 2001-05-14 2011-10-15 Procter & Gamble CLEANING SUPPLIES
DE10163668A1 (en) * 2001-12-21 2003-07-10 Henkel Kgaa Device for improving the rinse aid effect in dishwashers
US20140308162A1 (en) 2013-04-15 2014-10-16 Ecolab Usa Inc. Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing
US9752105B2 (en) 2012-09-13 2017-09-05 Ecolab Usa Inc. Two step method of cleaning, sanitizing, and rinsing a surface
CN107163078B (en) * 2017-04-18 2019-09-17 清华大学 The application of organic phosphine acid compounds and perovskite solar battery thin film and preparation method thereof
CN115038333A (en) 2020-03-23 2022-09-09 埃科莱布美国股份有限公司 Novel 2 in 1 germicidal rinse aid compositions using amine based surfactants in warewashing

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US3139119A (en) * 1960-05-18 1964-06-30 William E Buchanan Fourdrinier fabric
CA789509A (en) * 1964-05-27 1968-07-09 R. Schmolka Irving Low foaming detergent
US3832396A (en) * 1966-03-29 1974-08-27 Monsanto Co Anhydrides of organo-phosphonic acids
AU2373767A (en) * 1966-08-12 1969-01-09 W. R. Grace & Co Rinse and compositions
US3592774A (en) * 1968-05-03 1971-07-13 Henkel & Cie Gmbh Novel rinsing agents
US3629127A (en) * 1968-08-05 1971-12-21 Basf Wyandotte Corp Low foaming rinse additive
DE1962125B2 (en) * 1969-12-11 1973-11-08 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Use of polyoxypolycar bonsauren as building salts in detergents, bleaches and cleaning agents
US3833517A (en) * 1971-03-12 1974-09-03 Benckiser Knapsack Gmbh Agent for the treatment of cellulosic fiber materials and process
GB1315363A (en) * 1970-05-29 1973-05-02 Unilever Ltd Liquid detergents

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3439247A1 (en) * 1983-11-09 1985-05-15 Colgate-Palmolive Co., New York, N.Y. ACID, LIQUID, CLEANING AGENT FOR CERAMIC PLATES, WHICH DOES NOT DETERMINE THE Potting Material

Also Published As

Publication number Publication date
NL181211B (en) 1987-02-02
CA992424A (en) 1976-07-06
NL7315974A (en) 1974-05-27
DE2349739A1 (en) 1974-04-11
CA979316A (en) 1975-12-09
ATA965173A (en) 1975-10-15
US3941713A (en) 1976-03-02
US3956199A (en) 1976-05-11
AU474195B2 (en) 1976-07-15
NL181211C (en) 1987-07-01
BE807685A (en) 1974-05-22
GB1441588A (en) 1976-07-07
FR2208973B1 (en) 1976-11-19
AU6088473A (en) 1975-04-10
FR2208973A1 (en) 1974-06-28
FR2207979A1 (en) 1974-06-21
FR2207979B1 (en) 1977-08-12
NL7313623A (en) 1974-04-08
AT330931B (en) 1976-07-26
CH590921A5 (en) 1977-08-31
DE2358116A1 (en) 1974-05-30
AU6264773A (en) 1975-07-17

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years

Effective date: 19931119