GB1451775A - Preparation of polyurethanes branched aromatic polycarbonates - Google Patents

Preparation of polyurethanes branched aromatic polycarbonates

Info

Publication number
GB1451775A
GB1451775A GB5187673A GB5187673A GB1451775A GB 1451775 A GB1451775 A GB 1451775A GB 5187673 A GB5187673 A GB 5187673A GB 5187673 A GB5187673 A GB 5187673A GB 1451775 A GB1451775 A GB 1451775A
Authority
GB
United Kingdom
Prior art keywords
polyurethanes
koh
polyol
polyester
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5187673A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB5187673A priority Critical patent/GB1451775A/en
Publication of GB1451775A publication Critical patent/GB1451775A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C08G18/4241Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols from dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

1451775 Polyurethanes IMPERIAL CHEMICAL INDUSTRIES Ltd 24 Sept 1974 [8 Nov 1973] 51876/73 Addition to 1429296 Heading C3R A process for preparing polyurethanes comprises reacting diphenylmethane diisocyanate at a NCO : OH ratio of from 0À88 : 1 to 1À20 : 1 under substantially anhydrous conditions with, as sole isocyanate-reactive component, a polyester having a viscosity within the range 100 to 250 centistokes at 100‹ C., a hydroxyl value within the range 50 to 100 mg KOH/g. and an acid value less than 2À0 mg. KOH/g., which has been formed by condensing adipic acid with a molecular excess of a mixture of polyols consisting of ethylene and propylene glycols in a molar ratio of from 65 : 35 to 75 : 25 together with a polyol having 3 or more hydroxyl groups and a molecular weight below 500, the amount of the latter being such as to give up to 0À2 branch points per 1000 units of molecular weight of the polyester. The examples describe reacting polyesters, in which the polyol is trimethylolpropane, with 4,4<SP>1</SP>-diphenylmethane diisocyanate.
GB5187673A 1973-11-08 1973-11-08 Preparation of polyurethanes branched aromatic polycarbonates Expired GB1451775A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB5187673A GB1451775A (en) 1973-11-08 1973-11-08 Preparation of polyurethanes branched aromatic polycarbonates

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5187673A GB1451775A (en) 1973-11-08 1973-11-08 Preparation of polyurethanes branched aromatic polycarbonates

Publications (1)

Publication Number Publication Date
GB1451775A true GB1451775A (en) 1976-10-06

Family

ID=10461740

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5187673A Expired GB1451775A (en) 1973-11-08 1973-11-08 Preparation of polyurethanes branched aromatic polycarbonates

Country Status (1)

Country Link
GB (1) GB1451775A (en)

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Legal Events

Date Code Title Description
PS Patent sealed
732 Registration of transactions, instruments or events in the register (sect. 32/1977)
PCNP Patent ceased through non-payment of renewal fee