GB1443960A - Mild shampoo compositions card system of charge counter - Google Patents
Mild shampoo compositions card system of charge counterInfo
- Publication number
- GB1443960A GB1443960A GB5728673A GB5728673A GB1443960A GB 1443960 A GB1443960 A GB 1443960A GB 5728673 A GB5728673 A GB 5728673A GB 5728673 A GB5728673 A GB 5728673A GB 1443960 A GB1443960 A GB 1443960A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- polyethoxylated
- group
- alkyl
- per molecule
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Emergency Medicine (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
1443960 Shampoos PROCTER & GAMBLE CO 11 Dec 1973 [11 Dec 1972] 57286/73 Heading C5D A mild shampoo composition which does not irritate the eyes comprises: (A) a polyethoxylated anionic surfactant selected from (1) a surfactant having the general formula wherein R is a hydrophobic group selected from alkyl groups containing from 8 to 16 carbon atoms, alkylphenyl groups wherein the alkyl group contains from 6 to 15 carbon atoms, and fatty acid amido groups wherein the fatty acid contains from 8 to 16 carbon atoms; n is a number from 1 to 10; an M is a non-toxic cation which makes the surfactant water-soluble, and (2) a water-soluble polyethoxylated fatty alcohol sulphosuccinate monoester wherein the fatty alcohol contains from 8 to 16 carbon atoms and the polyethoxylated fatty alcohol contains from 1 to 10 ethoxy moieties per molecule; (B) a zwitterionic surfactant having the general formula wherein A is 0 and B is 1, or A is 1 and B is 0; C is 0 or 1 when Y is a carboxylate group, and C can only be 1 when Y is a sulphonate group; each R<SP>2</SP> is an alkyl group containing from 8 to 16 carbon atoms, or a group having the general formula R<SP>5</SP>-C(O)NH-R<SP>6</SP>-, wherein R<SP>5</SP> is an alkyl group containing from 8 to 16 carbon atoms and R<SP>6</SP> is an alkylene group containing from 1 to 5 carbon atoms; each R<SP>3</SP> is an alkyl, hydroxyalkyl or alkoxyalkyl group which can be connected to form a ring and each of which contains from 1 to 3 carbon atoms; Y is a sulphonate or carboxylate group; and R<SP>4</SP> is an alkylene group containing from 1 to 5 carbon atoms when Y is a carboxylate group and R<SP>4</SP> is an alkylene or hydroxyalkylene group containing from 2 to 5 carbon atoms when Y is a sulphonate group, the hydroxy group in said hydroxyalkylene group being on a secondary carbon atom ; (C) a polyethoxylated non-ionic surfactant selected from (1) polyethoxylated alkyl alcohols, said alkyl alcohols containing an alkyl group containing from 8 to 16 carbon atoms and said polyethoxylated alkyl alcohols containing from 10 to 45 ethoxy moieties per molecule, (2) polyethoxylated alkylphenols wherein the alkyl group contains from 6 to 15 carbon atoms and wherein the polyethoxylated alkylphenol contains from 10 to 45 ethoxy moieties per molecule, (3) polyethoxylated mono fatty acid esters of sorbitol wherein said fatty acids contain from 8 to 18 carbon atoms and said polyethoxylated mono fatty acid ester of sorbitol contains from 10 to 45 ethoxy moieties per molecule, (4) polyethoxylated polypropylene glycol, said polypropylene glycol having a molecular weight of from 1000 to 15,000 and said polyethoxylated polypropylene glycol containing from 15 to 300 ethoxy moieties per molecule, and (5) polyethoxylated fatty acids wherein said fatty acid contains from 8 to 16 carbon atoms and said polyethoxylated fatty acid contains from 10 to 45 ethoxy moieties per molecule; and (D) water, the molecular ratio of (A) to (B) being from 1 : 1 to 4 : 1, the weight ratio of (A)+(B) to (C) being from 2 : 1 to 1 : 2; and the pH of the composition being from 6À0 to 8À0. Optional ingredients are (E) thickeners such as hydroxyethyl cellulose and carrageenan, (F) anti-dandruff agents such as zinc pyridinethiol N-oxide and 2-bromo-2- nitro-1,3-propanediol, and (G) other conventional additives. The shampoos may be in liquid or paste form. Specification 1,443,959 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US313908A US3928251A (en) | 1972-12-11 | 1972-12-11 | Mild shampoo compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1443960A true GB1443960A (en) | 1976-07-28 |
Family
ID=23217689
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5728673A Expired GB1443960A (en) | 1972-12-11 | 1973-12-11 | Mild shampoo compositions card system of charge counter |
Country Status (5)
Country | Link |
---|---|
US (1) | US3928251A (en) |
JP (1) | JPS4999104A (en) |
CA (1) | CA1019679A (en) |
DE (1) | DE2361080A1 (en) |
GB (1) | GB1443960A (en) |
Families Citing this family (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4087387A (en) * | 1973-07-10 | 1978-05-02 | Lever Brothers Company | Foam cleaning composition |
US4122043A (en) * | 1973-12-19 | 1978-10-24 | Polytrol Chemical Corporation | Amidobetaine containing detergent composition non-toxic to aquatic life |
CA1088427A (en) * | 1975-12-22 | 1980-10-28 | Andrew W. Finkstein | Imidazoline-containing hair shampoo compositions |
DE2643794A1 (en) * | 1976-04-07 | 1977-10-27 | Gaf Corp | NEW AMPHOTERE SURFACE-ACTIVE CONNECTIONS |
JPS52130806A (en) * | 1976-04-28 | 1977-11-02 | Tsumura Juntendo Kk | Detergent composition |
GB1584364A (en) * | 1976-06-21 | 1981-02-11 | Unilever Ltd | Shampoo |
US4137191A (en) * | 1977-02-14 | 1979-01-30 | Inolex Corporation | Low-irritant surfactant composition |
JPS5849595B2 (en) * | 1977-04-15 | 1983-11-05 | ライオン株式会社 | Shampoo - Composition |
DE2750731C3 (en) * | 1977-11-12 | 1983-05-11 | Rewo Chemische Werke Gmbh, 6497 Steinau | Betaines and cleaning agents, bath preparations and disinfectants containing these compounds |
US4186113A (en) * | 1978-04-03 | 1980-01-29 | Johnson & Johnson | Low irritating detergent compositions |
US4246131A (en) * | 1978-11-20 | 1981-01-20 | Inolex Corporation | Low-irritant surfactant composition |
US4233192A (en) * | 1978-11-30 | 1980-11-11 | Johnson & Johnson | Detergent compositions |
US4231903A (en) * | 1978-11-30 | 1980-11-04 | Johnson & Johnson | Detergent compositions |
US4279891A (en) * | 1979-02-08 | 1981-07-21 | American Cyanamid Company | Low alcohol content after-shave lotion |
US4205063A (en) * | 1979-04-12 | 1980-05-27 | Johnson Products Co., Inc. | Low irritant conditioning shampoo composition |
US4343726A (en) * | 1979-05-07 | 1982-08-10 | Sherex Chemical Company, Inc. | Low irritating high viscosity detergent composition |
US4492646A (en) * | 1980-02-05 | 1985-01-08 | The Procter & Gamble Company | Liquid dishwashing detergent containing anionic surfactant, suds stabilizer and highly ethoxylated nonionic drainage promotor |
USRE30641E (en) * | 1980-05-05 | 1981-06-09 | Johnson & Johnson | Low irritating detergent compositions |
US4472297A (en) * | 1982-03-01 | 1984-09-18 | The Procter & Gamble Company | Shampoo compositions containing hydroxypropyl guar gum |
AU554574B2 (en) | 1982-03-19 | 1986-08-28 | Colgate-Palmolive Pty. Ltd. | Shampoo |
JPS60197614A (en) * | 1984-03-21 | 1985-10-07 | Shionogi & Co Ltd | Shampoo composition of low irritation |
US4544494A (en) * | 1984-04-12 | 1985-10-01 | Fmc Corporation | Homogeneous laundry detergent slurries containing amphoteric surface-active agents |
GB8428149D0 (en) * | 1984-11-07 | 1984-12-12 | Procter & Gamble Ltd | Liquid detergent compositions |
US5167872A (en) * | 1985-10-31 | 1992-12-01 | The Procter & Gamble Company | Comprising anionic surfactant polymeric nonionic surfactant and betaine surfactant |
US4759875A (en) * | 1986-01-14 | 1988-07-26 | S. C. Johnson & Son, Inc. | Oxo-derived mild surfactant blends |
US4908147A (en) * | 1986-02-19 | 1990-03-13 | Ciba-Geigy Corporation | Aqueous self preserving soft contact lens solution and method |
US4726915A (en) * | 1986-03-10 | 1988-02-23 | Johnson & Johnson Baby Products Company | Detergent compositions |
US4824605A (en) * | 1986-07-31 | 1989-04-25 | Hildreth E D | Non-ionic surfactant based detergent formulations with short chain amphoteric additives |
US4759877A (en) * | 1986-07-31 | 1988-07-26 | Hildreth E D | Non-ionic surfactant based detergent formulations with short chain amphoteric additives |
US5028353A (en) * | 1988-10-07 | 1991-07-02 | Colgate-Palmolive Company | Process of preparing a combination detergent and soap bar with enhanced mildness |
US4992211A (en) * | 1988-11-30 | 1991-02-12 | Sandoz Ltd. | Alkylene oxide-containing amphoteric surfactants |
US5336446A (en) * | 1989-02-21 | 1994-08-09 | Goodman Robert M | Compositions and process for non-irritating dense foaming of bath water and peri-vaginal cleaning |
US5116606A (en) * | 1989-03-09 | 1992-05-26 | Alt John P | Skin treatment method and solution |
US4986983A (en) * | 1989-04-03 | 1991-01-22 | Revlon, Inc. | Superfatted betaine and zwitterionic hair and skin conditioner compositions |
US4992266A (en) * | 1989-08-14 | 1991-02-12 | S. C. Johnson & Son, Inc. | Reducing the ocular irritancy of anionic shampoos |
US5540865A (en) * | 1990-01-29 | 1996-07-30 | The Procter & Gamble Company | Hard surface liquid detergent compositions containing hydrocarbylamidoalkylenebetaine |
US5342549A (en) * | 1990-01-29 | 1994-08-30 | The Procter & Gamble Company | Hard surface liquid detergent compositions containing hydrocarbyl-amidoalkylenebetaine |
US5336445A (en) * | 1990-03-27 | 1994-08-09 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing beta-aminoalkanols |
GB9008944D0 (en) * | 1990-04-20 | 1990-06-20 | Unilever Plc | Shampoo composition |
US5540864A (en) * | 1990-12-21 | 1996-07-30 | The Procter & Gamble Company | Liquid hard surfce detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol |
ES2089792T3 (en) * | 1992-01-23 | 1996-10-01 | Procter & Gamble | LIQUID DETERGENT COMPOSITIONS FOR HARD SURFACES CONTAINING HYBRID AND CATIONAL SURFACES AND MONOETHANOLAMINE AND / OR BETA-AMINOALCANOL. |
US5536451A (en) * | 1992-10-26 | 1996-07-16 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing short chain amphocarboxylate detergent surfactant |
CA2161008A1 (en) * | 1993-04-20 | 1994-10-27 | Barry A. Salka | Liquid pearlizing composition |
NZ260848A (en) * | 1993-07-09 | 1996-08-27 | Colgate Palmolive Co | High foaming liquid detergent comprising as nonionic surfactant an alkyl or fatty acid sorbitan ether with an ethylene oxide condensate, or an alkylphenolether of an ethylene oxide/propylene oxide condensate, a betaine and an ethoxylated alkyl ether sulphate |
EP0728177B1 (en) * | 1993-11-12 | 2000-03-01 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing amphoteric detergent surfactant and perfume |
US5531933A (en) * | 1993-12-30 | 1996-07-02 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing specific polycarboxylate detergent builders |
AU1925795A (en) * | 1994-02-28 | 1995-09-11 | Colgate-Palmolive Company, The | Liquid detergent |
US5534198A (en) * | 1994-08-02 | 1996-07-09 | The Procter & Gamble Company | Glass cleaner compositions having good filming/streaking characteristics and substantive modifier to provide long lasting hydrophilicity |
US5767050A (en) * | 1995-01-17 | 1998-06-16 | Colgate-Palmolive Co. | Light duty liquid cleaning compositions comprising partially esterified polyhydric alcohol solubilizing agent |
US6677294B2 (en) * | 2000-11-29 | 2004-01-13 | The Procter & Gamble Company | Cleansing compositions |
DE10136804A1 (en) * | 2001-07-25 | 2003-02-13 | Clariant Gmbh | Reaction products of long-chain carboxylic acids |
US20040121782A1 (en) * | 2002-09-07 | 2004-06-24 | Offshore Data Services, Llc | Personal flotation device transceiver tracking system |
JP5426212B2 (en) * | 2009-03-31 | 2014-02-26 | 花王株式会社 | Aqueous hair cleanser |
US20120022037A1 (en) * | 2009-03-31 | 2012-01-26 | Kao Corporation | Aqueous hair cleansing agent |
JP5426213B2 (en) * | 2009-03-31 | 2014-02-26 | 花王株式会社 | Aqueous hair cleanser |
JP5341029B2 (en) * | 2010-06-18 | 2013-11-13 | 花王株式会社 | Aqueous hair cleanser |
DE102015207735A1 (en) * | 2015-04-28 | 2016-11-03 | Henkel Ag & Co. Kgaa | Sulfobetaine-containing detergents and cleaners |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2781376A (en) * | 1955-12-08 | 1957-02-12 | John J Mccabe Jr | Detergent sulphonic acid and sulphate salts of certain amphoteric detergents |
US2950255A (en) * | 1956-07-03 | 1960-08-23 | Gillette Co | Detergent composition |
US3055836A (en) * | 1957-12-24 | 1962-09-25 | Johnson & Johnson | Detergent composition |
US3156656A (en) * | 1958-01-06 | 1964-11-10 | Gillette Co | Aqueous shampoo composition |
NL127604C (en) * | 1965-03-30 | |||
US3666671A (en) * | 1965-04-23 | 1972-05-30 | Oreal | Detergent composition and process of shampooing hair therewith |
CA783534A (en) * | 1965-06-15 | 1968-04-23 | Unilever Limited | Liquid detergent compositions |
DE1617229B2 (en) * | 1966-08-18 | 1976-12-02 | Unilever N.V., Rotterdam (Niederlande) | DETERGENTS AND DETERGENTS |
US3755559A (en) * | 1971-08-23 | 1973-08-28 | Colgate Palmolive Co | High lathering conditioning shampoo composition |
-
1972
- 1972-12-11 US US313908A patent/US3928251A/en not_active Expired - Lifetime
-
1973
- 1973-12-06 CA CA187,619A patent/CA1019679A/en not_active Expired
- 1973-12-07 DE DE2361080A patent/DE2361080A1/en not_active Withdrawn
- 1973-12-11 GB GB5728673A patent/GB1443960A/en not_active Expired
- 1973-12-11 JP JP48138520A patent/JPS4999104A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JPS4999104A (en) | 1974-09-19 |
CA1019679A (en) | 1977-10-25 |
DE2361080A1 (en) | 1974-06-12 |
US3928251A (en) | 1975-12-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |